• Title/Summary/Keyword: F-reduction

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Storage stability of reduced sulfur gases in Tedlar bag sampler: Test of two different storing approaches (Tedlar-bag 시료채집법을 이용한 황화합물의 경시적 농도 변화특성: 시료의 생성방식의 차이에 따른 비교연구)

  • Jo, Hyo-Jae;Kim, Ki-Hyun
    • Analytical Science and Technology
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    • v.24 no.3
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    • pp.212-218
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    • 2011
  • In this study, temporal stability of 5 reduced sulfur compounds (RSCs) including ($H_2S$, $CH_3SH$, DMS, $CS_2$, and DMDS) was investigated up to 30 days. To learn the temporal changes in RSC concentration levels, two types of long-term storage experiment were carried out by employing two different approaches for sample storing in Tedlar bag samplers. The first one named as a forward (F) storage method consists of preparing all samples in the beginning of experiment. All these samples were analyzed sequentially through time. The second approach named as a reversed (R) storage method was carried out by preparing each sample through time and by analyzing all of them in the last day. For these experiments, RSC standards were prepared at 10 ppb in 10 L Tedlar bag. The results of both methods were consistent enough to show a tendency of the concentration reduction through time. Moreover, the lightest RSC, $H_2S$ showed the most significant reduction of 84.8% at the end of experiment. To validate difference between these results, t-test was applied to the data obtained between the two methods at 90% significance level. According to t-test, the results of the two approaches were greatly distinguished from 3 RSCs ($H_2S$, $CH_3SH$, and DMDS). The results also indicated that the temporal reduction of RSC differs greatly between light ($H_2S$ and $CH_3SH$) and heavy RSCs (DMS, DMDS, and $CS_2$). The former generally exhibited much significant reduction through time due probably to their lower stability.

Characteristics and Production of Tantalum Powder on the amount of Diluent By Na Reduction Method (Na환원법에 의한 희석제량에 따른 탄탈 분말 제조와 특성)

  • Yoon, Jae-Sik;Park, Hyeong-Ho;Bae, In-Sung;Kim, Byung-Il;Jung, Sung-Man
    • Korean Journal of Materials Research
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    • v.12 no.9
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    • pp.706-711
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    • 2002
  • High-pure tantalum powder was fabricated through Na reduction process and has been produced by using $K_2$TaF$_{7}$, and KCI, KF for raw material and diluent, respectively. A raw material and diluent were charged at the hestalloy bomb by the weight rate of 1:2, 1:1, 1:0.5 and 1:0.25 each other, investigated properties of morphology, chemical composition and yield and particle size after reduced. Ta metal has been achieved by reduction of $K_2$$TaF_{7}$ 500g with 1% sodium in excess of stoichiometric amount in the charge at a reduction temperature of $850^{\circ}C$ for 3hours. According to amount of the diluent, a formation of the powder doesn't have an effect. The diluent prevented the temperature rising caused from the heat of reaction and it maintained the speed of reducing reaction. But in the mixture ratio of raw material and diluent in the 1 : 2 and 1 : 0.25, an oxide and partially not reacted K were detected. As the amount of diluent increased, the size of tantalum powder decreased. According as raw material and the mixture ratio of diluent change from 1:0.25 to 1:2, the size is decreased from 5$\mu\textrm{m}$ to 1$\mu\textrm{m}$, and a particle size distribution which is below 325 mesh in fined powder increases from 71% to 83%. In the case of average size of Tantalum powder which is the mixture ratio (1:0.5), we would get the Ta powder with grain size about 3$\mu\textrm{m}$, which come close to the average size (2~4$\mu\textrm{m}$) of tantalum powder which is used commonly in the present is Ta powder about 3$\mu\textrm{m}$.

A Review of Pilot Plant Studies on Elemental Mercury Oxidation Using Catalytic DeNOxing Systems in MW-Scale Coal Combustion Flue Gases (MW급 석탄연소 배가스에서 탈질촉매시스템을 이용한 원소수은 산화 실증사례)

  • Kim, Moon Hyeon;Nguyen, Thi Phuong Thao
    • Clean Technology
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    • v.27 no.3
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    • pp.207-216
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    • 2021
  • Major anthropogenic emissions of elemental mercury (Hg0) occur from coal-fired power plants, and the emissions can be controlled successfully using NH3-SCR (selective catalytic reduction) systems with catalysts. Although the catalysts can easily convert the gaseous mercury into Hg2+ species, the reactions are greatly dependent on the flue gas constituents and SCR conditions. Numerous deNOxing catalysts have been proposed for considerable reduction in power plant mercury emissions; however, there are few studies to date of elemental mercury oxidation using SCR processes with MW- and full-scale coal-fired boilers. In these flue gas streams, the chemistry of the mercury oxidation is very complicated. Coal types, deNOxing catalytic systems, and operating conditions are critical in determining the extent of the oxidation. Of these parameters, halogen element levels in coals may become a key vehicle for obtaining better Hg0 oxidation efficiency. Such halogens are Cl, Br, and F and the former one is predominant in coals. The chlorine exists in the form of salts and is transformed to gaseous HCl with a trace amount of Cl2 during the course of coal combustion. The HCl acts as a very powerful promoter for high catalytic Hg0 oxidation; however, this can be strongly dependent on the type of coal because of a wide variation in the chlorine contents of coal.

A Study on the Impact of Forklift Institutional, Technical, and Educational Factors on a Disaster Reduction (지게차의 제도적, 기술적, 교육적 요인이 재해감소에 미치는 영향에 관한 연구)

  • Young Min Park;Jin Eog Kim
    • Journal of the Society of Disaster Information
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    • v.19 no.4
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    • pp.770-778
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    • 2023
  • Purpose: In order to reduce forklift industrial accidents, it is necessary to classify them into institutional, technical, and educational factors and conduct research on whether each factor affects disaster reduction. Method: Descriptive statistical analysis, validity analysis, reliability analysis, and multiple regression analysis were conducted using SPSS 18 program based on an offline questionnaire based on a 5-point Likert scale. Result: As a result of multiple regression analysis, it was found that institutional, technical, and educational factors, which are independent variables for disaster reduction, explain about 62.5% of the variance in disaster prevention, which is the dependent variable. The regression model verification was found to be statistically significant with F=118.775 and significance probability p<0.01. Conclusion: First, there is a need to prevent disasters by including electric forklifts weighing less than 3 tons in the inspection system. Second, there is a need to make it mandatory to install front and rear cameras and forklift line beams to prevent forklift collision disasters. Third, there is a need to conduct special training related to forklifts every year, and drivers and nearby workers need to be included in the special training for forklifts.

Influence of Organic Acids Residual Concentration by the Change of F/M Ratio on Sludge Settleability in Advanced Sewage Treatment Processes (하.폐수 고도처리시 F/M비 변화에 따른 유기산 잔류 농도가 슬러지 침강성에 미치는 영향)

  • Park, Young-Ki;Kim, Young-Il;Kim, Sl-Ki
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.1
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    • pp.42-47
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    • 2006
  • The biological nutrient treatment is formed with repetition and rearrangement of anaerobic, anoxic and oxic tank. In this case, VFAs is generated in the anaerobic tank and the anoxic tank. The VFAs is an important factor for removal of nitrogen and phosphate and SVI. So, in this study I investigated to find a relationship among the generation rate of the VFAs according to the change of F/M ratio and the characteristic which can eliminate organic matter and nitrogen according to the change of residual concentration of the VFAs and the efficiency of the process and also SVI in wastewater treatment. $A^2/O$ process was used for wastewater treatment. F/M ratio was under the control of the change of MLSS concentration. When the F/M ratio was changed from 0.16 to 0.08 kg-BOD/kg-MLSS/day, the VFAs's production volume increased based on the reduction of F/M ratio in batch reaction. And the residual concentration of the VFAs decreased at first and then increased later. SVI and SS were high when F/M ratio was $0.16kg/kg{\cdot}d$ and showed stable status when F/M ratio decreased $0.11{\sim}0.13kg/kg{\cdot}d$. However, SVI and SS continuously increased with decrease of F/M ratio and were high at $0.08kg/kg{\cdot}d$. In the result of comparison between residual concentration of the VFAs and denitrification rate in anoxic tank, the less residual volume of the VFAs was in anoxic tank, the higher denitrification ratio became. The optimal residual-concentration of the VFAs considering SVI and removal efficiency of nitrogenwas $1.4{\sim}2.2mg/L$. At that time F/M ratio was $0.11{\sim}0.13$ kg-BOD/kg-MLSS/day.

The Microtremor HVSRs in the SW Korean Peninsula I: Characteristics of the HVSR Peak Frequency and Amplification (한반도 남서부의 상시미동 HVSR 연구 I: 정점주파수와 증폭효과의 특성)

  • Jung, Hee-Ok;Kim, Hyoung-Jun;Jo, Bong-Gon;Park, Nam-Ryul
    • Journal of the Korean earth science society
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    • v.31 no.6
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    • pp.541-554
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    • 2010
  • Fifteen min-microtremor data sets were collected at 136 sites from a coastal area of Kunsan and 117 sites from an inland area of Jeonju located in SW Korea, and were analyzed for the HVSR (Horizontal to Vertical Spectral Ratio) of the sites. The microtremor spectra of the coastal area have stronger energy in the lower frequency range from 1-6 Hz than those of the coastal area. This result can be attributed to the effect of the waves and tides in the Keum river and the Yellow sea. Twenty four hours of measurement of the microtremor indicated that the microtremor spectrum correlates with the human activities, but the microtremor HVSR peak was observed consistently at the characteristic frequency for the site. The HVSR peaks were grouped into 4 types -"single peak", "double peak", "broad peak" or "no peak"- based on their shapes. More than 90% of the data sets exhibit peak frequencies ($F_0$) which can be easily identified. The distribution of $F_0$ reveals a close relationship with the topography and local geology of the areas, exhibiting high F0s in the hillside areas and low $F_0s$ in the reclaimed land area. While the amplitudes of microtremor HVSR peak frequencies are less than 4 in the downstream of the inland area, those of the recently reclaimed land in the coastal area are extremely high (more than 10). The results of this study indicate that detailed HVSR studies are essential for the earthquake hazard reduction of reclaimed lands.

Prospect on the Fixation of $F_1$ Hybrid Seed by Means of 2n Apomixis (2n性 單爲생殖 이용에 의한 固定 $F_1$種子 생산과 그 展望)

  • 한창열;한지학
    • Korean Journal of Plant Tissue Culture
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    • v.24 no.4
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    • pp.239-256
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    • 1997
  • Plants belonging to the category of 2n apomixis or agamospermy form embryos and seeds without the processes of normal meiosis and syngamy. Seeds produced in this way have identical genotype of their maternal parent. Three different types of agamospermy are recognized: diplospory, apospory, and adventitious (adventive) embryony. $F_1$ hybrid cultivars cannot be used as seed sources in the next ($F_2$) generation because this generation would be extremely variable as a result of genetic segregation. Hybrid vigor is also reduced in the $F_2$ generation. Therefore, parental stocks for hybrid seed production need to be maintained and cross must be continuously repeated. Agamospermic 2n apomixis would make it possible to fix the genotype of a superior variety so that clonal seeds faithfully representing that genotype could be continuously and cheaply produced independent of pollination. That is, $F_1$ hybrid seeds could be produced for many generations without loss of vigor or genotype alteration. Production of apomictic $F_1$ hybrid seed would be simplified because line isolation would not be necessary to produce seed or to maintain parental lines, and the use of male-sterile lines could be avoided. Overall, apomixis would enable a significant reduction in hybrid seed production costs. Additionally, the production of clonal seed is not only important for seed propagated crops, but also for the propagation of heterozygous fruit trees and timbers. Clonal seed would help avoid costly and time-consuming vegetative propagating methods that are currently used to ensure the large-scale production of these plants. Apomixis is scattered throughout the plant kingdom, but few important agricultural crops possess this trait Therefore, most research to date has centered on introgressing the trait of apomixis into agricultural crops such as wheat, maize, and some forage grasses from wild distant relatives by traditional cross breeding. The classical breeding approach, however is slow and often impeded by many breeding barriers. These problems could be surmounted by taking mutagenesis or molecular approach. Arabidopsis thaliana is a tiny sexually reproducing plant and is convenient in constructing and screening in molecular researches. Male-sterile mutants of Arabidopsis are particularly suitable genetic background for mutagenesis and screening for apomictic mutants. Molecular approaches towards isolating the genes controlling the apomictic process are feasible. Direct isolation of genes conferring apomixis development would greatly facilitate the transfer of this trait to wide variety of crops. Such studies are now in progress.

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Double Mutations in eIF4E and eIFiso4E Confer Recessive Resistance to Chilli Veinal Mottle Virus in Pepper

  • Hwang, JeeNa;Li, Jinjie;Liu, Wing-Yee;An, Song-Ji;Cho, Hwajin;Her, Nam Han;Yeam, Inhwa;Kim, Dosun;Kang, Byoung-Cheorl
    • Molecules and Cells
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    • v.27 no.3
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    • pp.329-336
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    • 2009
  • To evaluate the involvement of translation initiation factors eIF4E and eIFiso4E in Chilli veinal mottle virus (ChiVMV) infection in pepper, we conducted a genetic analysis using a segregating population derived from a cross between Capsicum annuum 'Dempsey' containing an elF4E mutation ($pvr1^2$) and C. annuum 'Perennial' containing an elFiso4E mutation (pvr6). C. annuum 'Dempsey' was susceptible and C. annuum 'Perennial' was resistant to ChiVMV. All $F_1$ plants showed resistance, and $F_2$ individuals segregated in a resistant-susceptible ratio of 166:21, indicating that many resistance loci were involved. Seventy-five $F_2$ and 329 $F_3$ plants of 17 families were genotyped with $pvr1^2$ and pvr6 allele-specific markers, and the genotype data were compared with observed resistance to viral infection. All plants containing homozygous genotypes of both $pvr1^2$ and pvr6 were resistant to ChiVMV, demonstrating that simultaneous mutations in elF4E and eIFiso4E confer resistance to ChiVMV in pepper. Genotype analysis of $F_2$ plants revealed that all plants containing homozygous genotypes of both $pvr1^2$ and pvr6 showed resistance to ChiVMV. In protein-protein interaction experiments, ChiVMV viral genome-linked protein (VPg) interacted with both eIF4E and eIFiso4E. Silencing of elF4E and eIFiso4E in the VIGS experiment showed reduction in ChiVMV accumulation. These results demonstrated that ChiVMV can use both eIF4E and eIFiso4E for replication, making simultaneous mutations in eIF4E and eIFiso4E necessary to prevent ChiVMV infection in pepper.

An Exploratory Study on the Relationship between External Causes of Injuries and Regional Safety Grade among Geriatric Injury Patients (노인 손상환자의 손상외인과 지역안전등급 간 관계에 관한 탐색적 연구)

  • Lee, Jeong-Wook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.472-482
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    • 2016
  • The purpose of this study was to determine if a geriatric injury would have a statistically significant relationship with the spatial safety within a specific region. To achieve the objectives of this study, an independent sample t-test and One-way ANOVA were performed to verify difference in mean value of regional safety grade, depending on the injury intentionality, injury location, activities at the time of injury, and injury mechanism, in 6,572 geriatric injury patients by combining the National Hospital Discharge Patients Injury Survey data and regional safety index data. The results of statistical validation suggested that there was no difference in the mean value of regional safety grade by sub-group with respect to the injury intentionality. However, a statistically significant difference was observed in terms of the mean value of regional safety grade in each sub-group with regard to the injury location, activities at the time of injury, and injury mechanism in connection with some areas of the regional safety index. Based on the results of such analysis, we derived and presented 3 implications related to policies and practice for the prevention of geriatric injury and a reduction of its occurrence rate in light of spatial safety after a discussion of the results through a comparison with previous studies that examined individual areas.

Removal of Toxicity from Kraft Pulp Mill Effluents by Activated Sludge Process (활성슬러지 공정에 의한 Kraft 펄프 폐수의 독성 제거)

  • Kim, Yeong-Kwan
    • Journal of Korean Society of Water and Wastewater
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    • v.8 no.3
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    • pp.9-18
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    • 1994
  • Activated sludge pilot plant testing was conducted to determine the ability of a well-designed activated sludge treatment system to remove chromic toxicity from the bleached kraft pulp mill effluent. Removals of conventional(BOD and SS) and nonconventional(resin and fatty acids, color, AOX) pollutants were estimated. The pilot plant was operated at steady state for about 10 weeks at an F/M of 0.28 and a sludge age of 8.4 days. The average MLSS concentration was 4,309mg/l, of which volatile fraction was 57%. During the operation period, the BOD removal reaction rate(k) was determined to be 8.2/day at $30^{\circ}C$. The BOD removal was 84 percent, which was 3 to 6 percent lower than expected for full-scale treatment. The chronic toxicity of the activated sludge effluent was tested by employing both Dinnel and the BML protocols. It was found that the pilot plant could achieve in excess of 90 percent reduction in chronic echinoderm toxicity. The data show slight reduction of color and AOX across the activated sludge system. The pilot system, however, demonstrated on excellent removal of resin and fatty acids.

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