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Heteroepitaxial Growth of Single 3C-SiC Thin Films on Si (100) Substrates Using a Single-Source Precursor of Hexamethyldisilane by APCVD

  • Chung, Gwiy-Sang;Kim, Kang-San
    • Bulletin of the Korean Chemical Society
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    • v.28 no.4
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    • pp.533-537
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    • 2007
  • This paper describes the heteroepitaxial growth of single-crystalline 3C-SiC (cubic silicon carbide) thin films on Si (100) wafers by atmospheric pressure chemical vapor deposition (APCVD) at 1350 oC for micro/nanoelectromechanical system (M/NEMS) applications, in which hexamethyldisilane (HMDS, Si2(CH3)6) was used as a safe organosilane single-source precursor. The HMDS flow rate was 0.5 sccm and the H2 carrier gas flow rate was 2.5 slm. The HMDS flow rate was important in obtaing a mirror-like crystalline surface. The growth rate of the 3C-SiC film in this work was 4.3 μm/h. A 3C-SiC epitaxial film grown on the Si (100) substrate was characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), reflection high energy electron diffraction (RHEED), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and Raman scattering, respectively. These results show that the main chemical components of the grown film were single-crystalline 3C-SiC layers. The 3C-SiC film had a very good crystal quality without twins, defects or dislocations, and a very low residual stress.

Optoelectronics Properties of In0.27Ga0.73N/GaN Multi-Quantum-Well Structure (In0.27Ga0.73N/GaN 다중 양자우물 구조에 대한 광전기적 특성)

  • Park, Hun-Bo;Bae, In-Ho;Kim, Ki-Hong
    • Korean Journal of Materials Research
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    • v.17 no.9
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    • pp.489-492
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    • 2007
  • Temperature and injection current dependence of elctroluminescence(EL) spectral intensity of the $In_{0.27}Ga_{0.73}N/GaN$ multi-quantum-well(MQW) have been studied over a wide temperature and as a function of injection current level. EL peaks also show significant broadening into higher photon energy region with the increase of injection current. This is explained by the band-filling effect. When temperature is slightly increased to 300 from 15 K, the EL emission peak showed red-blue-red shift. It can be explained by the carrier localization by potential fluctuation of multiple quantum well and band-gap shrinkage as temperature increase. It is found that a temperature-dependent variation pattern of the EL efficiency under very low and high injection currents show a drastic difference. This unique EL efficiency variation pattern with temperature and current is explained field effects due to the driving forward bias in presence of internal(piezo and spontaneous polarization) fields.

Introducing the Latest 3GPP Specifications and their Potential for Future AMI Applications

  • Koumadi, Koudjo M.;Park, Byong-seok;Myoung, Nogil
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.2
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    • pp.245-251
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    • 2016
  • Despite the exponential throughput improvement in mobile communications systems, their ability to satisfy requirements of state-of-the-art and future applications of advanced metering infrastructure (AMI) is still under investigation. Challenges are mainly due to the inadequacy of third generation partnership project (3GPP) networks to support large amounts of devices simultaneously, while the number of AMI end-devices and the frequency of their data transmission increase with new AMI-based applications. In this introductory survey, innovative and future AMI applications and their communication requirements are first reviewed. Then, we identify challenges of 3GPP long term evolution (LTE) in enabling future AMI applications. More importantly, the latest improvements to LTE-A standard release 12 and 13 are reviewed and analyzed with regards to their potential to improve the quality of LTE-enabled AMI. It is found that 3GPP enhancements on machine type communications (MTC) standards will significantly enhance AMI communications. Beyond MTC specifications, non-MTC-specific enhancements such as carrier aggregation and multi-connectivity for user equipment will also contribute greatly to improving reliability and availability of AMI devices. The paper's focus is towards improved backhaul support for innovative and future AMI applications, beyond traditional automatic meter reading.

Ionic Conductivity of Anion Receptor Grafted Siloxane Polymers for Solid Polymer Electrolytes

  • Lee, Won-Sil;Kim, Dong-Wook;Lee, Chang-In;Woo, Seong-Ihl;Kang, Yong-Ku
    • Journal of Electrochemical Science and Technology
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    • v.2 no.1
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    • pp.26-31
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    • 2011
  • We have prepared siloxane polymers grafted with trifluoromethane-sulfonylamide and oligoether side chains for solid polymer electrolytes with enhanced ionic conductivity. The grafted trifluoromethane sulfonylamide groups seem to be effective as an anion recepting site to enhance the ionic conductivity of the solid polymer electrolyte. The anion receptor grafted siloxane polymers showed one order of magnitude higher ionic conductivity than the siloxane polymers without anion receptor grafts. The fitting parameter A of the VTF plot which was related to the carrier density of the electrolyte increased with increasing the number of grafted anion receptor. The results of experiment indicate that the anion-complexing site of the anion receptor grafted polymer host effectively traps the anions. The anion receptor grafted polymer was found to be a promising material for lithium polymer batteries.

An Estimation of Springing Responses for Recent Ships

  • Park In-Kyu;Lee Soo-Mok;Jung Jong-Jin;Yoon Myung-Cheol
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.11a
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    • pp.173-178
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    • 2004
  • The estimation of springing responses for recent ships are carried out and application to a ship design are described. To this aim, springing effects on hull girder were re-evaluated including non-linear wave excitations and torsional vibrations of the hull. The Timoshenko beam model was used to calculate stress distribution on the hull girder by the superposition method. The strip method was employed to calculate the hydrodynamic forces and moments on the hull. In order to remove the irregular frequencies, we adopted 'rigid lid' on the hull free surface level and added asymptotic interpolation along the high frequency range. Several applications to the existing ships were carried out. They are Bishop and Price's container ship, S-175 container ship, large container, VLCC and ore carrier. One of them is compared with ship measurement result while another with that of model test. Comparison between analytical solution and numerical one for homogeneous beam type artificial ship shows good agreement. It is found that most springing energy came from high frequency waves for the ships having low natural frequency and North Atlantic route etc. Therefore, the high frequency tail of the wave spectrum should be increased by $\omega^{-3}\;instead\;of\;\omega^{-4}\;or\;\omega^{-5}$ for springing calculation.

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X-ray Photoemission Spectroscopy Study of Cation-Deficient La$_{0.970}$Mn$_{0.970}$O$_3$ System (양이온 결손 La$_{0.970}$Mn$_{0.970}$O$_3$의 X-ray Photoemission Spectroscopy 관측)

  • 정우환
    • Journal of the Korean Ceramic Society
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    • v.36 no.1
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    • pp.50-54
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    • 1999
  • We have measured the x-ray photoemission spectroscopy of cation deficient La0.970Mn0.970O3 as a function of temperature. Detailed results on the chemical shifts and changes in Mn 2p and Lp 3d core levels due to variation of temperature have been obtained. The Mn 2p 3/2 and 1/2 main peaks and La 3d core spectrum shift to lower binding energy levels with increasing temperature. This XPS behavior is correlated with the strength of localization of Mn3+. The Jahn-Teller effect due to Mn3+ besides the conventional random potential effects is likely to localize charge carriers in La-.970Mn0.970O3.

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Outage Analysis of OFDM-Based Cognitive AF Relay Network in the Presence of Narrowband Interference

  • Rajkumar, Samikkannu;Senthilkumaran, V.N.;Thiruvengadam, S.J.
    • ETRI Journal
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    • v.37 no.3
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    • pp.460-470
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    • 2015
  • Orthogonal frequency-division multiplexing (OFDM) is one of the most widely used technologies in current wireless communication systems and standards. Cognitive radio (CR) provides a robust solution to the problem of spectrum congestion as it offers opportunistic usage of frequency bands that are not occupied by primary users. Due to the underlying sensing, spectrum shaping, scaling, and interoperable capabilities of OFDM, it has been adapted as a best transmission technology for CR wireless systems. However, the performance of an OFDM-based CR wireless system is affected by the existence of narrowband interference (NBI) from other users. Further, due to carrier frequency offset in NBI sources, NBI energy may spread over all subcarriers of an OFDM signal. In this paper, a fixed Amplify-and-Forward (AF) relay that operates at a frequency band that is different from that of direct mode is introduced to suppress the effect of NBI. Analytical expressions are derived for outage probability in direct, AF-relay, and incremental relaying modes. The outage performance of the proposed AF relay-based CR network is proven to be better than that of direct mode.

Possible Role of Disorder on Magnetostructural Transition in La1-xBaxMnO3

  • Kim, N.G.;Jung, J.H.
    • Journal of Magnetics
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    • v.12 no.3
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    • pp.103-107
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    • 2007
  • Magnetic field induced structural transition has been systematically investigated for $La_{1-x}Ba_xMnO_3$ with the fine control of carrier doping $(0.15{\leq}x{\leq}0.20)$. Application of a magnetic field results in the suppression of the rhombohedral-orthorhombic transition temperature $(T_s)$ and the increase of insulator-metal transition temperature $(T_{MI})$. Near x = 0.17, where $T_S$ is similar to $T_{MI}$ at zero magnetic field, we found that the $T_S$ smoothly decreased with magnetic field even though it intersected the $T_{MI}$ near 3 T. Also, the magnetostructural phase diagram obtained from the temperature sweep and from the magnetic field sweep is not significantly modified. By comparing the magnetostructural transition in $La_{1-x}Sr_xMnO_3$, we have suggested that the large disorder originated from ionic size differences between La and Ba may weaken the sensitivity of the kinetic energy of $e_g$ electrons on the degree of lattice distortion in $La_{1-x}Ba_xMnO_3$.

Properties of Indium Tin Oxide Transparent Conductive Thin Films at Various Substrate and Annealing Temperature

  • Jeong, Woon-Jo;Kim, Seong-Ku;Kim, Jong-Uk;Park, Gye-Choon;Gu, Hal-Bon
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.1
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    • pp.18-22
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    • 2002
  • ITO thin films with thickness of 3000 $\AA$ were fabricated by rf magnetron sputtering system with a 10 mol % SnO$_2$-90 mol % In$_2$O$_3$target at various substrate temperature and annealing temperature in air. And we investigated structural, electrical and optical characteristics of them. It's resistivity, carrier concentration and Hall mobility was 2$\times$10$\^$-4/ Ωcm, 7$\times$10$\^$20/∼ 9$\times$10$\^$20/ cm$\^$-3/ and 21∼23 cm$^2$/V$.$sec respectively. And it's optical transmittance and energy band gap was above 85 % in the visible range and 3.53 eV respectively.

Performance Analysis on Code-Division Multiple Access in Underwater Acoustic Sensor Network (수중 음향 센서 망에서의 코드 분할 다중 접속 기법에 대한 성능 해석)

  • Seo, Bo-Min;Cho, Ho-Shin
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.35 no.9A
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    • pp.874-881
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    • 2010
  • Acoustic signal, which is a main carrier of underwater communication, attenuates along the traveled path heavily depending on the frequency as well as inter-node distance. In addition, since it has a long propagation delay, the conventional medium access control (MAC) schemes requiring complex signaling procedures and accordingly heavy overhead messages would not be appropriate in underwater communications. In this paper, we propose a code division multiple access (CDMA) scheme as a solution for MAC of underwater communication and evaluate the performance. A hierarchical data-gathering tree topology is considered and a staggered wake-up pattern is employed for the purpose of energy saving. As a performance measure, the data rate at each level of hierarchical topology is derived.