• Title/Summary/Keyword: Energy barrier

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A Study on the Effects of the Thickness of Top Coat on the Thermal Stresses of a Sprayed Thermal Barrier Coating (용사 열차폐 코팅층의 두께가 열응력에 미치는 영향)

  • 김형남;양승한
    • Proceedings of the KWS Conference
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    • 2004.05a
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    • pp.223-225
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    • 2004
  • Based on the principle of complementary energy an analytical method is developed for determining thermal stress distribution in an thermal barrier coating. This method gives the stress distributions which satisfy the stress-free boundary conditions at the edge. Numerical examples are given in order to verify the method and to investigate the thickness effects of the ZrO$_2$-8wt%Y$_2$O$_3$ top coat on the integrity of thermal barrier coating consisted of IN738LC substrate and MCrAlY bond coat.

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Impact Ionization Rates of Electron in GaAs/AlGaAs Qunantum Well Using EMC Simulation (EMC Simulation을 이용한 GaAs/AlGaAs 양자 우물 내 전자의 충돌 이온화율)

  • 윤기정;홍창희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.11a
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    • pp.221-225
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    • 1994
  • We described the impact ionization rates of electron in GaAs/AlGaAs MQH(multi- quantum well) using EMC(ensenble Monte Carlo) simulation. Hot electron energy of injected into quantum well is increasing nearly liearly due to the applied electric field to the barrier of MQM inspite of various Al mole fraction in AlGaAs or barrier width. Impact ionization rates are decreasing exponentially by increasing Al mole fraction, and they have peak vague due to the barrier width.

Design Optimization of Safety Barrier Consisting of Steel Rail and CFRP Post (강재 레일과 CFRP 기둥으로 이루어진 방호울타리의 최적화 설계)

  • Kim, Jung Joong;Kim, Seung-Eock
    • Journal of the Korean Society for Advanced Composite Structures
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    • v.4 no.2
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    • pp.25-30
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    • 2013
  • In this study a hybrid safety barrier system consisting of steel rail and carbon fiber reinforced polymer (CFRP) post is considered. W hile CFRP post is selected for impact energy reflection due to its high strength, steel rail is selected for impact energy absorption due to its high ductility. A numerical model considering the elastoplastic behavior of steel is formulated to simulate the dynamic responses of the hybrid system subject to an impact load. A hybrid roadside guard rail system of steel rail and CFRP post is proposed and analyzed with a case study. The numerical model for the hybrid roadside guard rail system is used to find optimized design of the proposed hybrid system.

Adaptive method for the purification of zinc and arsenic ions contaminated groundwater using in-situ permeable reactive barrier mixture

  • Njaramba, Lewis Kamande;Nzioka, Antony Mutua;Kim, Young-Ju
    • International Journal of Advanced Culture Technology
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    • v.8 no.2
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    • pp.283-288
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    • 2020
  • This study investigated the purification process of groundwater contaminated with zinc and arsenic using a permeable reactive barrier with a zero-valent iron/pumice mixture. We determined the removal rates of the contaminants for 30 days. In this study, column reactor filled with the zero-valent iron/pumice reactive mixture was used. Experimental results showed that the mixture exhibited an almost complete removal of the zinc and arsenic ions. Arsenic was removed via co-precipitation and adsorption processes while zinc ions were asorbed in active sites.The purification process of water from the metal ionscontinued for 30 days with constant hydraulic conductivity because of the enhanced porosity of the pumice and interparticle distance between the zero-valent iron and pumice. Contaminants removal rates and the remediation mechanism for each reactive system are described in this paper.

Cross-Interaction Constant and Intrinsic Reaction Barrier

  • Lee, Ik Chun;Lee, Hae Hwang
    • Bulletin of the Korean Chemical Society
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    • v.22 no.7
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    • pp.732-738
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    • 2001
  • The cross second-derivative of the activation energy,${\theta}$G${\neq}$ , with respect to the two component thermodynamic barriers, ${\theta}$G˚X and ${\theta}$G$^{\circ}C$Y, can be given in terms of a cross-interaction constant (CIC), $\betaXY(\rhoXY)$, and also in terms of the intrinsic barrier,${\theta}$G${\neq}$ , with a simple relationship between the two: $\betaXY$ = $-1}(6${\theta}$G${\neq}$).$ This equation shows that the distance between the two reactants in the adduct (TS, intermediate, or product) is inversely related to the intrinsic barrier. An important corollary is that the Ritchie N+ equation holds (for which $\betaXY$ = 0) for the reactions with high intrinsic barrier. Various experimental and theoretical examples are presented to show the validity of the relationship, and the mechanistic implications are discussed.

Current Status of the Numerical Models for the Analysis of Coupled Thermal-Hydrological-Mechanical Behavior of the Engineered Barrier System in a High-level Waste Repository (고준위폐기물처분장 공학적방벽시스템의 열-수리-역학적 복합거동 해석 모델 개발 현황)

  • Cho, Won-Jin;Kim, Jin Seop;Lee, Changsoo;Choi, Heui-Joo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.10 no.4
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    • pp.281-294
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    • 2012
  • The current status of the computer codes for the analysis of coupled thermal-hydrological-mechanical behavior occurred in a high-level waste repository was investigated. Based on the reported results on the comparison between the predictions using the computer codes and the experimental data from the in-situ tests, the reliability of the existing computer codes was analyzed. The presented codes simulated considerably well the coupled thermal-hydrological-mechanical behavior in the near-field rock of the repository without buffer, but the predictions for the engineered barrier system of the repository located at saturated hard rock were not satisfactory. To apply the current thermal-hydrological-mechanical models to the assessment of the performance of engineered barrier system, a major improvement on the mathematical models which analyze the distribution of water content and total pressure in the buffer is required.

A Study on the Evaluation of the Daylighting Performance in the Sound Barrier Tunnel (축소모형을 이용한 방음터널의 자연채광 성능평가에 관한 연구)

  • Kim, Oim-Gon;Choi, Jeong-Min;Park, Chang-Seob;Lee, Kyung-Hee
    • Journal of the Korean Solar Energy Society
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    • v.25 no.2
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    • pp.35-43
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    • 2005
  • This study aims to evaluate the natural lighting performance in the sound barrier tunnel. Therefore, to evaluate the daylighting performance, the combinations of 3 tunnel roof types which are flat-roof-type(type A), slope-roof-type(type B), arch-roof-type(type C) and 3 window types which are side-window-type(type 1), one-window-roof type(type 2), two-window-roof type(type 3) are evaluated by experimenting small scaled models. In this 9 cases of experiment, illuminance levels of each case are analyzed and evaluated. The conclusion of this study is that slope-roof-type(B) and arch-roof-type(C) is preferable to flat-roof-type(A) and one-window-roof-type(B) and two-window-roof-type(C) is preferable to side-window-type(A) for daylighting in the sound barrier tunnel.

Variations of Physical Oceanographic Environment Caused by Opening and Closing the Floodgate in Nakdong Estuary (수문개폐에 따른 낙동강 하구둑 하류부의 해양물리환경변화)

  • Kim Ki-Cheol;Yang Han-Soeb;Kim Cha-Kyum;Moon Chang-Ho;Jang Sung-Tae
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.2 no.2
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    • pp.49-59
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    • 1999
  • Nakdong Estuary is complex water system, where sea water and fresh water meet each other. After construction of Nakdong River Barrier, the flow pattern and mixing processes have been changed. Variations of physical oceanographic environment in Nakdong Estuary due to opening and closing the floodgate of Nakdong River Barrier are analysed focusing the movement of outflows from the barrier. Surveys and analysis were made for the three cases. 1. Ordinary times (opening and closing the gate by the tidal period) 2. A period of flood time (opening the gate) 3. A period of water shortage (closing the gate).

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The Design & Analysis of Pulse Separation Device with Thermal Barrier Type for Dual Pulse Rocket Motor (이중펄스 로켓모타의 격막형 펄스분리장치 설계 및 성능평가)

  • Kim, Jinyong;Kwon, Taeha;Lee, Wonbok;Cho, Wonman;Lee, Bangeop;Jung, Gyoodong;Rhee, Youngwoo
    • Journal of the Korea Institute of Military Science and Technology
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    • v.18 no.1
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    • pp.93-99
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    • 2015
  • The dual pulse rocket motor(DPRM) distributes the propellant energy effectively via pulse separation device(PSD) to improve the range and terminal velocity of the missile. There are two types of PSD such as bulk head type and thermal barrier type. A subscale thermal barrier type DPRM was designed, manufactured, and tested. The results showed good understanding of the characteristics of the PSD and will be applied to the design of the full scale DPRM.

Bonding and Antibonding Regions (II). Origin of Barriers to Internal Rotation of $H_2O_2$ and $C_2H_6$ (결합공간과 반결합공간 (제2보). $H_2O_2$$C_2H_6$의 Internal Rotation Barrier의 원천적 요인)

  • Kim Hojing;Lee Duckhwan
    • Journal of the Korean Chemical Society
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    • v.23 no.1
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    • pp.20-29
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    • 1979
  • The origin of barriers to internal rotation of hydrogen peroxide and ethane is investigated by using the concept of Bonding and Antibonding Regions. The strong bond formations between the axial and end atoms on the same side make the real charge densities in these molecules less dependent on conformations than those in the hypothetical molecules having no axial atoms. Thus, the existence of the axial atoms should induce the migration of the transition density from the Bonding region to the Antibonding region. Barrier to internal rotation can be understood in terms of this migration of the transition density to such an extent that the change in nuclear-nuclear repulsion energy becomes the dominating part of the total perturbation energy.

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