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Adaptive method for the purification of zinc and arsenic ions contaminated groundwater using in-situ permeable reactive barrier mixture

  • Received : 2020.04.30
  • Accepted : 2020.05.28
  • Published : 2020.06.30

Abstract

This study investigated the purification process of groundwater contaminated with zinc and arsenic using a permeable reactive barrier with a zero-valent iron/pumice mixture. We determined the removal rates of the contaminants for 30 days. In this study, column reactor filled with the zero-valent iron/pumice reactive mixture was used. Experimental results showed that the mixture exhibited an almost complete removal of the zinc and arsenic ions. Arsenic was removed via co-precipitation and adsorption processes while zinc ions were asorbed in active sites.The purification process of water from the metal ionscontinued for 30 days with constant hydraulic conductivity because of the enhanced porosity of the pumice and interparticle distance between the zero-valent iron and pumice. Contaminants removal rates and the remediation mechanism for each reactive system are described in this paper.

Keywords

References

  1. C.M. Lee, S.Y. Hamm, H.T. Jeon, M.S. Kim, H.K. Kim, and K.J. Kim, "Water policy of Korea for supplying safe groundwater in rural areas," Water, Vol. 9, No. 7, pp. 508, July 2017 https://doi.org/10.3390/w9070508
  2. M.A. Rahman, A. Rahman, M.Z.K. Khan, A.M.N. Renzaho, "Human health risks and socio-economic perspectives of arsenic exposure in Bangladesh: A scoping review," Ecotoxicology and Environmental Safety, Vol. 150, pp. 335-343, April 2018. https://doi.org/10.1016/j.ecoenv.2017.12.032
  3. Q. Meng, "Fracking equity: A spatial justice analysis prototype," Land Use Policy, Vol. 70, pp. 10-15, January 2018. https://doi.org/10.1016/j.landusepol.2017.10.021
  4. NIER, Drinking Groundwater Quality Survey and Its Management Policy for the Unserved Areas of Public Water Supply. Incheon: National Institute of Environmental Research (in Korean), 2014.
  5. S.A. Lone, G. Jeelani, A. Mukherjee, P. Coomar, "Geogenic groundwater arsenic in high altitude bedrock aquifers of upper Indus river basin (UIRB), Ladakh," Applied Geochemistry, Vol. 113, pp. 104497, February 2020. https://doi.org/10.1016/j.apgeochem.2019.104497
  6. R. Naidu, and V. Birke, Permeable reactive barrier sustainable groundwater remediation, Boca Raton: CRC Press, 2015.
  7. S. Bilardi, P.S. Calabro, S.Care, N.Moraci, and C. Noubactep, "Improving the sustainability of granular iron/pumice systems for water treatment." Journal of Environmental Management, Vol. 121, pp. 133-141. May 2013. https://doi.org/10.1016/j.jenvman.2013.02.042
  8. J.G. Han, W.I. Yoon, D.H. Jung, Y.S. Kim, J.Y. Lee, "Korean title Column Tests for the Design of PRB System using CFW," Journal of the Korean Geosynthetics Society, Vol. 10, No. 2, pp. 35-43, April 2011. https://doi.org/10.12814/JKGSS.2011.10.2.035
  9. P.S. Calabrò, N. Moraci, and P. Suraci, "Estimate of the optimum weight ratio in zero-valent iron/pumice granular mixtures used in permeable reactive barriers for the remediation of nickel contaminated groundwater," Journal of Hazardous Materials, Vol. 207-208, pp. 111-116, March 2012. https://doi.org/10.1016/j.jhazmat.2011.06.094
  10. M.H. Park, G. Lee, H. Park, S. Jeong, J.Y. Kim, "Adsorption of lead and cadmium from wastewater utilizing nano zero valent iron supported by ground coffee," Journal of the Korean Society of Environmental Engineers, Vol. 40, No. 2, pp. 82-90, April 2018. https://doi.org/10.4491/KSEE.2018.40.2.82
  11. S. Ranjan, B.K. Yadav, and H. Joshi, "Removal of arsenic (III) from aqueous solution using pumice and zeolite supported zero valent iron nanoparticle," Presented at the Proceedings of the American Geophysical Union, Fall meeting 2018, Washington D.C., USA, Dec 13- 2018.
  12. D. Zhou, Y. Li, Y. Zhang, X. Li, Z. Chen, J. Huang, X. Li, G. Flores, and M. Kamon, "Column test-based optimization of the permeable reactive barrier (PRB) technique for remediating groundwater contaminated by landfill leachates," Journal of Contaminant Hydrology, Vol. 168, No. 1, pp. 1-16, November 2014. https://doi.org/10.1016/j.jconhyd.2014.09.003
  13. S. Nasseri, and M. Heidari, "Evaluation and comparison of aluminum-coated pumice and zeolite in arsenic removal from water resources," Iranian Journal of Environmental Health Science & Engineering, Vol. 9, No. 1, pp. 38, December 2012. https://doi.org/10.1186/1735-2746-9-38
  14. R. Rangsivek, M. Jekel, "Removal of dissolved metals by zero-valent Iron (ZVI): Kinetics, Equilibria, processes and implications for stormwater runoff treatment," Water Research, Vol. 39, pp. 4153-4163, October 2005. https://doi.org/10.1016/j.watres.2005.07.040
  15. C. Noubactep, "A critical review on the process of contaminant removal in the $FeO-H_2O$ systems," Environmental Technology, Vol. 9, No.8, pp. 909-920, 2008. https://doi.org/10.1080/09593330802131602
  16. M.N.P. Calabro, "Heavy metals removal and hydraulic performance in zero-valent iron/pumice permeable reactive barriers." Journal of environmental management, Vol. 91, pp. 2336-2341, November 2010. https://doi.org/10.1016/j.jenvman.2010.06.019
  17. S. Bilardi, P.S. Calabro, N. Moraci, "Simultaneous removal of CUII, NIII and ZNII by a granular mixture of zero-valent iron and pumice in column systems" Desalination and Water Treatment, Vol. 55, No. 3, pp 767-776, 2015. https://doi.org/10.1080/19443994.2014.916234