• Title/Summary/Keyword: Energy Diffusion

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Formation and Growth of Epitaxial $CoSi_2$ Layer by Reactive Chemical Vapor Deposition (반응성 화학기상증착법을 이용한 에피택셜 $CoSi_2$ 박막의 형성 및 성장에 관한 연구)

  • Lee, Hwa-Seong;Lee, Hui-Seung;An, Byeong-Tae
    • Korean Journal of Materials Research
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    • v.10 no.11
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    • pp.738-741
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    • 2000
  • Univorm epitaxial $CoSi_2$layers have been grown in situ on a (100) Si substrate at temperatures near$ 600^{\circ}C$ by reactive chemical vapor deposition of cyclopentadienyl dicarbonyl cobalt, (Co(η(sup)5-C(sub)5H(sub)5) ($CO_2$). The growth kinetics of an epitaxial $CoSi_2$layer on al Si(100) substrate was investigated at temperatures ranging from 575 to $650^{\circ}C$. In initial deposition stage, plate-like discrete $CoSi_2$spikes were nucleated along the <111> directions in (100) Si substrate with a twinned structure. The discrete $CoSi_2$plates with both {111} and (100) planes grew into an epitaxial layer with a flat interface on (100) Si. For epitaxial $CoSi_2$growth on (100) Si, the activation energy of the parabolic growth was found to be 2.82 eV. The growth rate seems to be controlled by the diffusion of Co through the $CoSi_2$layer.

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Characterization of EFG Si Solar Cells

  • Park, S.H.
    • Journal of Sensor Science and Technology
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    • v.5 no.5
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    • pp.1-10
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    • 1996
  • Solar cells made of the edge-defined film-fed growth Si are characterized using current-voltage, surface photovoltage, electron beam induced current, electron microprobe, scanning electron microscopy, and electron backscattering. The weak temperature dependence of the I-V curves in the EFG solar cells is due to a voltage variable shunt resistance giving higher diode ideality factors than the ideal one. The voltage variable shunt resistance is modeled by a modified recombination mechanism which includes carrier tunneling to distributed impurity energy states in the band gap within the space-charge region. The junction integrity and the substrate quality are characterized simultaneously by combining I-V and surface photovoltage (SPV) measurements. The diode ideality factors and the surface photovoltages characterize the junction integrity while the SPV diffusion lengths characterizes the substrate quality. Most of the measured samples show the voltage variable shunt resistance although how serious it is depends on the solar cell efficiency. The voltage variable shunt resistance is understood as one of the most important factors of the degradation of EFG solar cells.

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Development of a Conjunctive Surface-Subsurface Flow Model for Use in Land Surface Models at a Large Scale: Part I. Model Description (대규모 육지수문모형에서 사용 가능한 지표면 및 지표하 연계 물흐름 모형의 개발: I. 모형설명)

  • Choi, Hyun-Il
    • Journal of the Korean Society of Hazard Mitigation
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    • v.8 no.2
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    • pp.59-63
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    • 2008
  • The surface runoff is one of the important components for the surface water balance. However, most Land Surface Models(LSMs), coupled to climate models at a large scale for the prediction and prevention of disasters caused by climate changes, simplistically estimate surface runoff from the soil water budget. Ignoring the role of surface flow depth on the infiltration rate causes errors in both surface and subsurface flow calculations. Therefore, for the comprehensive terrestrial water and energy cycle predictions in LSMs, a conjunctive surface-subsurface flow model at a large scale is developed by coupling a 1-D diffusion wave model for surface flow with the 3-D Volume Averaged Soil-moisture Transport(VAST) model for subsurface flow. This paper describes the new conjunctive surface-subsurface flow formulation developed for improvement of the prediction of surface runoff and spatial distribution of soil water by topography, along with basic schemes related to the terrestrial hydrologic system in Common Land Model(CLM), one of the state-of-the-art LSMs.

Leaching Behavior of Nickel from Waste Multi-Layer Ceramic Capacitor (폐(廢) 적층형(積層形)세라믹콘덴서에 함유(含有)된 니켈의 침출거동(浸出擧動))

  • Kim, Eun-Young;Kim, Byung-Su;Kim, Min-Seuk;Jeong, Jin-Ki;Lee, Jae-Chun
    • Resources Recycling
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    • v.14 no.5 s.67
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    • pp.32-39
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    • 2005
  • Leaching behavior of nickel contained in waste Multi-Layer Ceramic Capacitor (MLCC) was investigated using a batch reactor. The effects of acid type, acid concentration, leaching temperature, particle size, and reaction time on the extraction of nickel metal from waste MLCC were examined. As a result, 97% of nickel contained in waste MLCC was leached out in 30 min at the temperature of $90^{\circ}C$ under the condition of $HNO_3$ concentration 1N, solid/liquid ratio 5 g/L and particle size $-300/+180{\mu}m$. It was also found that a Jander equation was useful to fit well the leaching rate data. The rate of nickel leaching is controlled by pore diffusion in $BaTiO_3$ layer and has an activation energy of 37.6 kJ/mol (9.0 kcal/mol).

Optimization of Operating Parameters and Components for Water Electrolysis Using Anion Exchange Membrane (음이온 교환막 알칼리 수전해를 위한 운전 조건 및 구성요소의 최적화)

  • Jang, Myeong Je;Won, Mi So;Lee, Kyu Hwan;Choi, Sung Mook
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.159-165
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    • 2016
  • The hydrogen has been recognized as a clean, nonpolluting and unlimited energy source that can solve fossil fuel depletion and environmental pollution problems at the same time. Water electrolysis has been the most attractive technology in a way to produce hydrogen because it does not emit any pollutants compared to other method such as natural gas steam reforming and coal gasification etc. In order to improve efficiency and durability of the water electrolysis, comprehensive studies for highly active and stable electrocatalysts have been performed. The platinum group metal (PGM; Pt, Ru, Pd, Rh, etc.) electrocatalysts indicated a higher activity and stability compared with other transition metals in harsh condition such as acid solution. It is necessary to develop inexpensive non-noble metal catalysts such as transition metal oxides because the PGM catalysts is expensive materials with insufficient it's reserves. The optimization of operating parameter and the components is also important factor to develop an efficient water electrolysis cell. In this study, we optimized the operating parameter and components such as the type of AEM and density of gas diffusion layer (GDL) and the temperature/concentration of the electrolyte solution for the anion exchange membrane water electrolysis cell (AEMWEC) with the transition metal oxide alloy anode and cathode electrocatalysts. The maximum current density was $345.8mA/cm^2$ with parameter and component optimization.

Effects of Alloying Elements on Hardening of 13Cr Stainless Steels Using Plasma Nitriding Process (플라즈마질화처리에 의한 13Cr 스테인리스강의 표면경화특성에 미치는 질화물형성원소첨가의 영향)

  • ;;;;中田一博
    • Journal of Welding and Joining
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    • v.16 no.1
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    • pp.88-97
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    • 1998
  • The surface characteristics of 13Cr stainless steel systems by plasma nitriding were investigated. The plasma nitriding for the 13Cr steels, in which the nitriding forming elements such as Ti, V, W, Nb, Al, Zr and Si were added about 2~3wt.%, respectively, was performed. In all nitrided specimens, .epsilon.-F $e_{2-3}$N, UPSILON.'-F $e_{4}$N and CrN were detected as the nitrides with the a-Fe in the nitrided layer. VN and .betha.- $W_{2}$N were also detected in 13Cr-3V and 13Cr-3W alloys. The growth of the nitrided layer was controlled by the diffusion process. The thickness of the nitrided layer was similar in the 13Cr-2Nb and 3Zr specimens to that of 13Cr(BM) specimen, while the others exhibited the thinner layer. The activation energy for the growth of the nitrided layer in the temperature range of 773-873K was about 130kJ/mol in 13Cr(BM), 13Cr-2Ti, 3W, 3Al, 3Zr and 3Si alloys. The hardness of the nitrided specimens was significantly increased above Hv1000, comparing to the non-nitrided specimen. The specimens with the nitrided forming elements revealed much higher hardness values and, especially, 13Cr-3Al, 3V and 3Si specimens were significantly hardened up to Hv1300.v1300.0.

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A Study on the Thermoacoustic Oscillation of an Air Column (기주의 열음향진동에 관한 연구)

  • 권영필;이병호
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.2
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    • pp.253-261
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    • 1987
  • Thermoacoustic oscillation of an air column induced by heated wires is investigated analytically and experimentally. Acoustic power generation from a single heater wire is estimated based on the result of heat transfer analysis and expressed in terms of the efficiency factor indicating the conversion efficiency from heat to acoustic energy. It is shown that the efficiency factor becomes maximum when the wire radius is the order of the coustic boundary layer thickness and the flow velocity is close to the thermal diffusion velocity. Onset condition of the column oscillation is obtained by equating the acoustic power generation at the heater to the power loss due to thermoviscous dissipation at the tube wall and the convection and radiationloss at the open ends of the tube. In estimating the acoustic power generation, the heater is treated as a stretched single wire by correcting the flow velocity to take into account the interactions between adjacent heater wires. Experiment is performed by using a spiral heater of 1mm diameter in an air column of 37mm diameter. The heat input to drive the oscillation is measured and compared with the theoretical prediction. A good agreement is found between the theory and experiment, which is regarded as a substantial verification of the present analysis.

Defect Detection of the Wall Thinning Pipe of the Nuclear Power Plant Using Infrared Thermography (적외선열화상을 이용한 원자력발전소 감육 배관의 결함 검출)

  • Kim, Kyeong-Suk;Chang, Ho-Sub;Hong, Dong-Pyo;Park, Chan-Joo;Na, Sung-Won;Kim, Kyung-Su;Jung, Hyun-Chul
    • Journal of the Korean Society for Nondestructive Testing
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    • v.30 no.2
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    • pp.85-90
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    • 2010
  • The infrared energy is emitted in the infrared wavelength range that corresponds to the surface temperature of a object which has temperature that is over the absolute the temperature(OK). The infrared thermography (IRT) is a non-destrnctive testing method that provides thermal video for the user in real-time by converting the infrared quantity that is detected by the infrared detector into temperature. The pipes of nuclear power plant(NPP) could be thinned by the corrosion and fatigue and the defect could lead to a big accident. For this reason, the effective non-destructive testing method is necessary. In this study, the relationship between the measured temperature and the defect depth or size of NPP pipes were recognized and that was applied to detect the wall thinning defects of NPP pipes.

Surface Rendering in Abdominal Aortic Aneurysm by Deformable Model (복부대동맥의 3차원 표면모델링을 위한 가변형 능동모델의 적용)

  • Choi, Seok-Yoon;Kim, Chang-Soo
    • The Journal of the Korea Contents Association
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    • v.9 no.6
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    • pp.266-274
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    • 2009
  • An abdominal aortic aneurysm occurs most commonly in older individuals (between 65 and 75), and more in men and smokers. The most important complication of an abdominal aortic aneurysm is rupture, which is most often a fatal event. An abdominal aortic aneurysm weakens the walls of the blood vessel, leaving it vulnerable to bursting open, or rupturing, and spilling large amounts of blood into the abdominal cavity. surface modeling is very useful to surgery for quantitative analysis of abdominal aortic aneurysm. the 3D representation and surface modeling an abdominal aortic aneurysm structure taken from Multi Detector Computed Tomography. The construction of the 3D model is generally carried out by staking the contours obtained from 2D segmentation of each CT slice, so the quality of the 3D model strongly defends on the precision of segmentation process. In this work we present deformable model algorithm. deformable model is an energy-minimizing spline guided by external constraint force. External force which we call Gradient Vector Flow, is computed as a diffusion of a gradient vectors of gray level or binary edge map derived from the image. Finally, we have used snakes successfully for abdominal aortic aneurysm segmentation the performance of snake was visually and quantitatively validated by experts.

Mechanism of MnS Precipitation on Al2O3-SiO2 Inclusions in Non-oriented Silicon Steel

  • Li, Fangjie;Li, Huigai;Huang, Di;Zheng, Shaobo;You, Jinglin
    • Metals and materials international
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    • v.24 no.6
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    • pp.1394-1402
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    • 2018
  • This study investigates the mechanism of MnS precipitation on $Al_2O_3-SiO_2$ inclusions during the solidification of non-oriented silicon steel, especially the influence of the phase structures and sizes of the oxides on the MnS precipitation, by scanning electron microscopy and transmission electron microscopy coupled with energy dispersive spectrometry. The investigation results show that MnS tends to nucleate on submicron-sized $Al_2O_3-SiO_2$ inclusions formed by interdendritic segregation and that it covers the oxides completely. In addition, MnS can precipitate on micron-sized oxides and its precipitation behavior is governed by the phase structure of the oxides. The MnS embryo formed in a MnO-containing oxide can act as a substrate for MnS precipitation, thus permitting further growth via diffusion of solute atoms from the matrix. MnS also precipitates in a MnO-free oxide by the heterogeneous nucleation mechanism. Furthermore, MnS is less prone to precipitation in the $Al_2O_3$-rich regions of the $Al_2O_3-SiO_2$ inclusions; this can be explained by the high lattice disregistry between MnS and $Al_2O_3$.