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Synthesis and Characterization of Poly(vinyl alcohol-b-styrene) via Atom Transfer Radical Polymerization and Saponification

  • Li, Guang-Hua;Cho, Chang-Gi
    • Macromolecular Research
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    • v.10 no.6
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    • pp.339-344
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    • 2002
  • Poly(vinyl alcohol-b-styrene) (poly(VA-b-St)) diblock copolymer containing high syndiotactic poly (vinyl alcohol) (PVA) was synthesized by the saponification of poly(vinyl pivalate-b-styrene) (poly(VPi-b-St)). For the block copolymer, poly(vinyl pivalate) (PVPi) with trichloromethyl end group was obtained via telomerization of vinyl pivalate with carbon tetrachloride as a telogen and 2,2-azobisisobutyronitrile (AIBN) as an initiator. Then resulting poly(vinyl pivalate) with trichloromethyl end group was used as an effient macroinitiator for the synthesis of poly(VPi-b-St) using atom transfer radical polymerization (ATRP) in the presence of CuCl/2,2'-bipyridine at 130 $^{\circ}C$. The poly(vinyl pivalate) macroinitiator, poly(VPi-b-St), poly(VA-b-St) were characterized by GPC, FT-IR and $^1$H-NMR. And the analysis showed that integrity of the block copolymer was maintained during saponification reaction.

Randomized Block Size (RBS) Model for Secure Data Storage in Distributed Server

  • Sinha, Keshav;Paul, Partha;Amritanjali, Amritanjali
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.15 no.12
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    • pp.4508-4530
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    • 2021
  • Today distributed data storage service are being widely used. However lack of proper means of security makes the user data vulnerable. In this work, we propose a Randomized Block Size (RBS) model for secure data storage in distributed environments. The model work with multifold block sizes encrypted with the Chinese Remainder Theorem-based RSA (C-RSA) technique for end-to-end security of multimedia data. The proposed RBS model has a key generation phase (KGP) for constructing asymmetric keys, and a rand generation phase (RGP) for applying optimal asymmetric encryption padding (OAEP) to the original message. The experimental results obtained with text and image files show that the post encryption file size is not much affected, and data is efficiently encrypted while storing at the distributed storage server (DSS). The parameters such as ciphertext size, encryption time, and throughput have been considered for performance evaluation, whereas statistical analysis like similarity measurement, correlation coefficient, histogram, and entropy analysis uses to check image pixels deviation. The number of pixels change rate (NPCR) and unified averaged changed intensity (UACI) were used to check the strength of the proposed encryption technique. The proposed model is robust with high resilience against eavesdropping, insider attack, and chosen-plaintext attack.

Hemodynamic Changes on Stellate Ganglion Block Measured by Bioimpedance Method (성상신경절 차단시 Bioimpedance를 이용한 혈액학적 변화의 측정)

  • Kwak, Dong-Myeon;Kim, Si-Oh;Hong, Jung-Gil;Park, Jin-Woong
    • The Korean Journal of Pain
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    • v.9 no.2
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    • pp.336-339
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    • 1996
  • Stellate ganglion block which usually practiced in pain clinics may combined with hemodynamic changes because it blocks sympathetic nerve chains. We measured the hemodynamic changes with NCCOM3-$R7^{(R)}$ (BOMED, U.S.A.) which applicated bioimpedance method in twenty-two patients. Mean arterial pressure, heart rate, cardiac output, ejection fraction and left ventricle end diastolic volume (LEDV) were measured before stellate ganglion block (control), 1, 3, 5, 10 and 20 minutes after stellate ganglion block with 8 ml of 0.25% bupivacaine. The results were as follows: Mean arterial pressure decreased significantly (p<0.05) in 10, 20 minutes after stellate ganglion block comparing to control, but not clinically significant. Heart rate, cardiac output, ejection fraction and LVEDV showed no significant change compared to control value. These results showed that stellate ganglion block is a safe technique without significant hemodynamic changes.

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Development of a Intelligent Welding Carriage for Automation of Curved Block

  • Choi, H.B.;Moon, J.H.;Jun, W.R.;Kim, S.H.
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.626-630
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    • 2005
  • This paper presents a novel Intelligent-Welding-Carriage (IWC) for automation of curved block in shipbuilding. The curved block is usually used in both front and back side of the ship. In curved block root gap is big, $1{\sim}7$ [mm] and inclination, $0{\sim}30$ [deg]. Since available conventional carriage type is limited to use below root gap of 3 [mm], only manual welding is employed in curved block. To adopt an IWC in curved block, it requires control of the welding conditions, i.e., voltage, current and travel speed, with respect to root gap and inclination to achieve good welding quality. In this paper, an IWC is developed for automization of welding operation to accommodate gap and inclination. Kinematics model and dynamics using Lagrangian formulation of the manipulator is introduced. IWC utilizes a database to perform accurate welding. The database is programmed based on numerous experimental test results with respect to gap, inclination, material, travel speed, weaving condition, voltage, and current. Finally, experimental result using PID control is addressed for verify the trajectory tracking accuracy of end-effector.

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Design of the Hydraulic Rotor Block Curvature for a Knuckle Crane According to the Contact Angle (접촉각에 따른 너클 크레인용 유압로터블록의 만곡부 설계)

  • Lee J.M.;Han G.J.;Han D.S.;Lee S.W.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.377-378
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    • 2006
  • The knuckle crane mainly consists of six parts such as swing, main boom, outer boom, extension boom, hydraulic rotor and knuckle. And the hydraulic rotor is connected at the end of extension boom has rotor block, rotor body, rotor vane. In this study, we carried out kinematics analysis of the hydraulic rotor block curvature for a knuckle crane. Then, we showed the formula to establish the radius of a circumscribed circle to form the rotor block curvature. Third, we analyzed the stress at each point of the rotor block curvature according to the contact angle. From the result of this study, we designed the rotor block curvature with a proper contact angle for a knuckle crane to guarantee the stability of hydraulic rotor.

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A design of HomePNA2.0 PHY. (10Mbps급 HomePNA2.0 PHY. 회로 설계)

  • 박성희;구기종;김종원
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.27 no.12C
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    • pp.1282-1287
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    • 2002
  • In this Paper, we present the design of 10Mbps HomePNA(Home Phoneline Networking Alliance) PHY which is Home Network Technology using phone-line. It is connected with external interface through MII(Media Independent Interface) and AFE(Analog Front End) Interface. 10Mbps HomePNA PHY is composed with Management Block IEEE 802.3 CSMA/CD MAC(Media Access Control) Block Modulator block and Demodulator block. For their verification, we designed a prototype FPGA PCB board using XPC860T made in Motorola. We verified HomePNA frame data transmission using a driver program based Linux kernel. we verified rate negotiation by HomepNA 2.0 Link Layer Protocol.

Development of a Intelligent Welding Carriage for Automation of Curved Block (곡 블록 자동화를 위한 지능형 용접 캐리지 개발)

  • Choi HeeByoung;Moon JongHyun;Jun WanLyul;Kim Sehwan
    • Special Issue of the Society of Naval Architects of Korea
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    • 2005.06a
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    • pp.171-176
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    • 2005
  • This paper presents a novel Intelligent-Welding-Carriage (IWC) for automation of curved block in shipbuilding. The curved block is usually used in both front and back side of the ship. In curved block root gap is big, 1-7 (mm) and inclination, 0-30 (deg). Since available conventional carriage type is limited to use below root gap of 3 (mm), only manual welding is employed in curved block. To adopt an IWC in curved block, it requires control of the welding conditions, i.e., voltage. current, weaving speed, dwell time and travel speed, with respect to root gap and inclination to achieve good welding qualify. In this paper, an IWC is developed for automization of welding operation to accommodate gap and inclination. Kinematics model and dynamics using Lagrangian formulation of the manipulator is introduced. IWC utilizes a database to perform accurate welding. The database is programmed based on numerous experimental test results with respect to gap, inclination, material, travel speed, weaving condition, voltage, and current. Finally, experimental result using PID control is addressed for verifying the trajectory tracking accuracy of end-effector.

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Development of CMOS Sigma-Delta DAC Chip for Using ADSL Modem (ADSL 모뎀용 CMOS 시그마-델타 DAC 칩 개발)

  • Bang, Jun-Ho;Kim, Sun-Hong
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.52 no.4
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    • pp.148-153
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    • 2003
  • In this paper, the low voltage 3V Sigma-Delta Digital Analog Converter(DAC) is designed for using in the transmitter of ADSL analog front-end. We have developed the CMOS DAC according to ANSI T1.413-2(DMT) standard specifications of the chip. The designed 4th-order DAC is composed of three block which are 1-bit DAC, 1st-order Switched-Capacitor filter and analog active 2nd-order Resistor-Capacitor(RC) filter. The HSPICE simulation of the designed DAC showing 65db SNR, is connected with 1.1MHz continuous lowpass filter. And also, we have performed the circuits verification and layout verification(ERC, DRC, LVS) followed by fabrication using TSMC 2-poly 5-metal p-substrate CMOS $0.35{\mu}m$ processing parameter. Finally, the chip testing has been performed and presented in the results.

OFDM-Based STBC with Low End-to-End Delay for Full-Duplex Asynchronous Cooperative Systems

  • Jiang, Hua;Xing, Xianglei;Zhao, Kanglian;Du, Sidan
    • ETRI Journal
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    • v.35 no.4
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    • pp.710-713
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    • 2013
  • We propose a new space-time block coding (STBC) for asynchronous cooperative systems in full-duplex mode. The orthogonal frequency division multiplexing (OFDM) transmission technique is used to combat the timing errors from the relay nodes. At the relay nodes, only one OFDM time slot is required to delay for a pair-wise symbol swap operation. The decoding complexity is lower for this new STBC than for the traditional quasi-orthogonal STBC. Simulation results show that the proposed scheme achieves excellent performances.

Cross Layer Optimal Design with Guaranteed Reliability under Rayleigh block fading channels

  • Chen, Xue;Hu, Yanling;Liu, Anfeng;Chen, Zhigang
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.7 no.12
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    • pp.3071-3095
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    • 2013
  • Configuring optimization of wireless sensor networks, which can improve the network performance such as utilization efficiency and network lifetime with minimal energy, has received considerable attention in recent years. In this paper, a cross layer optimal approach is proposed for multi-source linear network and grid network under Rayleigh block-fading channels, which not only achieves an optimal utility but also guarantees the end-to-end reliability. Specifically, in this paper, we first strictly present the optimization method for optimal nodal number $N^*$, nodal placement $d^*$ and nodal transmission structure $p^*$ under constraints of minimum total energy consumption and minimum unit data transmitting energy consumption. Then, based on the facts that nodal energy consumption is higher for those nodes near the sink and those nodes far from the sink may have remaining energy, a cross layer optimal design is proposed to achieve balanced network energy consumption. The design adopts lower reliability requirement and shorter transmission distance for nodes near the sink, and adopts higher reliability requirement and farther transmission distance for nodes far from the sink, the solvability conditions is given as well. In the end, both the theoretical analysis and experimental results for performance evaluation show that the optimal design indeed can improve the network lifetime by 20-50%, network utility by 20% and guarantee desire level of reliability.