• Title/Summary/Keyword: Electronic transition

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A Zero-Current-Transition Synchronous Buck Converter Using Auxiliary Circuit with Soft-Switching (소프트 스위칭 방식의 보조 회로를 활용한 영전류 천이형 싱크로너스 벅 컨버터)

  • Lee, Eui-Cheon;Choi, Hyun-Chil
    • The Transactions of the Korean Institute of Power Electronics
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    • v.18 no.4
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    • pp.359-366
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    • 2013
  • This paper proposes a zero-current-transition(ZCT) synchronous buck converter using auxiliary circuit with soft-switching for light weight and high efficiency. In this scheme, an auxiliary circuit is added to the conventional synchronous rectifier buck converter and used to achieve soft-switching condition for both the main switch and synchronous switch. In addition, the switch in the auxiliary circuit operates under soft-switching conditions. Thus, the proposed converter provides a higher efficiency. The basic operations, in this paper, are discussed and design guidelines are presented. The usefulness of the proposed converter is verified on a 200KHz, 20 W prototype converter.

Interband Transition and Confinement of Charge Carriers in CdS and CdS/CdSe Quantum Dots

  • Man, Minh Tan;Lee, Hong Seok
    • Applied Science and Convergence Technology
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    • v.24 no.5
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    • pp.167-171
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    • 2015
  • Quantum-confined nanostructures open up additional perspectives in engineering materials with different electronic and optical properties. We have fabricated unique cation-exchanged CdS and CdS/CdSe quantum dots and measured their first four exciton transitions. We demonstrate that the relationship between electronic transitions and charge-carrier distributions is generalized for a broad range of core-shell nanostructures. These nanostructures can be used to further improve the performance in the fields of bio-imaging, light-emitting devices, photovoltaics, and quantum computing.

Vibronic Emission Spectrum of Jet-Cooled o-Tolunitrile in a Corona Excited Supersonic Expansion

  • Park, Chan-Ho;Lee, Gi-Woo;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • v.27 no.6
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    • pp.881-885
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    • 2006
  • We have employed a technique of corona excited supersonic expansion to generate electronically excited but jet-cooled o-tolunitrile. The vibronically well-resolved emission spectrum of the jet-cooled o-tolunitrile in the $S_{1}\rightarrow S_{0}$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. The electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined from the analysis of the spectra observed.

Assignment of Vibronic Emission Spectra of Jet-Cooled m-Tolunitrile

  • Park, Chan Ho;Lee, Sang-Kuk
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1377-1380
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    • 2006
  • The technique of corona-excited supersonic expansion was applied to produce electronically excited but rovibrationally cooled m-tolunitrile. The well-resolved vibronic emission spectrum of the jet-cooled m-tolunitrile in the $S_1\;\rightarrow \;S_0$ transition was recorded in the uv region using a Fourier transform spectrometer equipped with a Quartz-uv beam splitter. From an analysis of the spectrum observed, it was confirmed that the electronic transition and vibrational mode frequencies in the ground electronic state were accurately determined.

A study on the improvement of thermostability and dielectric breakdown strength for packaging and impregnating epoxy composite materials for electrical machines and apparatus (전기 기기용 봉지 및 함침 에폭시 복합 재료의 내열성 및 절연파괴 특성 개선에 관한 연구)

  • 김명호;김재환
    • Electrical & Electronic Materials
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    • v.7 no.6
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    • pp.527-533
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    • 1994
  • In this study, it was studied on dielectric breakdown strength and thennostability properties due to the structure variation of matrix resin and treatment of coupling agent of epoxy insulating materials. The interpenetrating network structure was formed by simultaneous heating curing the epoxy resin with single network structure and the methacrylic acid resin. Also inner structure was observed and the glass transition temperature was measured on these three type specimens. Dielectric breakdown properties were investigated by applying DC, AC and impulse voltage. As a result, the glass transition temperature and the dielectric breakdown strength of specimen with interpenetrating network structure was more higher than another two type specimens.

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First-Principles Study of Magnetic Interactions between Transition Metal Ions in ZnO (ZnO내 전이 금속 불순물의 자기적 특성에 관한 제일원리 연구)

  • Lee, Eun-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.6
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    • pp.444-448
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    • 2010
  • Based on first-principles calculations, we study the magnetic properties of Co, Ni, Fe, V, and Mn impurities in ZnO. The stabilities of the ferromagnetic state and the magnetic moment of each impurity largely depend on the amount of doped electron or hole. For lightly doped n-type ZnO, it is found that the doping of Ni ions is the most effective for inducing ferromagnetism, while Fe ions show the most stable ferromagnetic couplings for heavily doped n-type samples. The characteristics of the magnetic interactions of Co ions are similar with those of Fe ions, but Co ions require much larger amount of doped electron than Fe ions to show the ferromagnetic couplings. The ferromagnetic coupling between Mn and V ions is unstable in n-type conditions.

Novel Zero-Voltage-Transition Synchronous Buck Converter for Portable System (휴대용 시스템을 위한 새로운 영전압 천이형 싱크로너스 벅 컨버터)

  • Kim, Nak-Yoon;Choi, Hyun-Chil
    • The Transactions of the Korean Institute of Power Electronics
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    • v.17 no.4
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    • pp.330-336
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    • 2012
  • In this paper, novel zero-voltage-transition(ZVT) synchronous buck converter of pulse-width-modulation(PWM) method is proposed to utilize auxiliary circuit. In this proposed scheme, designed to operate low output voltage for portable system and applied synchronous scheme to improve efficiency. Also proposed circuit is designed to do soft-switching operation in every switch. In this paper, the circuit operation is explained and analysed, and design guidelines are presented. To verify the availability of the proposed circuit, experiment and simulation is carried out.

An Interleaved PWM Buck Converter with a Soft Switching Auxiliary Circuit (소프트 스위칭 형태의 보조 회로를 이용한 인터리브드 벅 컨버터)

  • Lee, Eui-Cheon;Choi, Hyun-Chil
    • The Transactions of the Korean Institute of Power Electronics
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    • v.18 no.6
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    • pp.547-555
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    • 2013
  • This paper proposes the interleaved buck converter using a soft switching auxiliary circuit. In this scheme, an auxiliary circuit is added to the conventional interleaved buck converter and used to achieve soft-switching conditions for both the main switch and freewheeling diode. In addition, the switch in the auxiliary circuit operates under soft-switching conditions. Also, according to the input to output conditions, the main switch achieved zero-current-transition(ZCT) or zero-current & zero-voltage-transition(ZCZVT) at turn on. Thus, the proposed interleaved buck converter provides a higher efficiency. The basic operations, in this paper, are discussed and design guidelines are presented. The usefulness of the proposed converter is verified on a 200kHz, 180W prototype converter.

Development of Laser Material for High Power and High Efficiency (고출력, 고효율 실현을 위한 새로운 레이저매질 개발)

  • 김정호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.15-18
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    • 2001
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(SOL)-D)$_3$] complexes were synthesized by the keto-enol tautomerism reaction of Yb(SOL-H)$_3$ in methanol-d$_4$in methanol-d$_4$in order to reduce the radiationless transition to the ligands. The luminescence properties of Yb(SOL-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$\sub$8/, PO(OCH$_3$)$_3$ and DMSO-d$\sub$6/. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-d$\sub$6/ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$\sub$6/ might be the most appropriate solvent for the liquid laser material of Yb(SOL-D)$_3$ complex.

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Optical Properties of Yb(SOL-D)$_3$ Complex for Laser Material (신 레이저매질 Yb(SOL-D)$_3$착물의 광학적 특성)

  • 김정호;서연호;박용필
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.640-643
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    • 2001
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(SOL-D)$_3$] complexes were synthesized by the keto-enol tautomerism reaction of Yb(SOL-H)$_3$in methanol-d$_4$in order to reduce the radiationless transition to the ligands. The luminescence properties of Yb(SOL-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$and DMSO-d$_{6}$. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-d$_{6}$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of Yb(SOL-D)$_3$complex.complex.

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