• 제어로봇시스템학회논문지
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• 제10권11호
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• pp.981-990
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• 2004

Specialized propulsors for naval applications have numerous opportunities in terms of research, design and fabrication of an appropriate propulsor. One of the most important components of any propulsor is the actuator that provides the mode of locomotion. Ionomeric electro-active polymer may offer an attractive solution for locomotion of small propulsors. A common ionomeric electro-active polymer, ionic Polymer-Metal Composites (IPHCs) give large true bending deformations under low driving voltages, operate in aqueous environments, are capable of transduction and are relatively well understood. IPMC fabrication and operation are presented to further elucidate the use of the material for a propulsor. Various materials, including IPMCs, are investigated and a simplified propulsor model is explored.

• Smart Structures and Systems
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• 제4권5호
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• pp.549-563
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• 2008

The ability of an electroactive polymer, IPMC (Ionic Polymer Metal Composites,) to produce electric charge under mechanical deformations may be exploited for the development of next generation of energy harvesters. Two different electrode types (gold and platinum) were employed for the experiments. The sample was tested under dynamic conditions, produced through programmed shaking. In order to evaluate the potential of IPMC for dry condition, these samples were treated with ionic liquid. Three modes of mechanical deformations (bending, tension and shear) were analyzed. Experimental results clearly indicate that IPMCs are attractive applicants for energy harvesting, with inherent advantages like flexibility, low cost, negligible maintenance and virtually infinite longevity. Besides, preliminary energy harvesting model of IPMC has been formulated based upon the work of previous investigators (Newbury 2002, Newbury and Leo 2002, Lee, et al. 2005, Konyo, et al. 2004) and the simulation results reciprocate experimental results within acceptable error.

• Smart Structures and Systems
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• 제20권4호
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• pp.499-508
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• 2017

The ionic polymer-metal composite (IPMC) is an electroactive polymer material and has a promising potential as actuators for propulsion and locomotion in underwater systems. In this paper a physics based model is used to analyse the actuation dynamics of the IPMC propulsor. Moreover, proportional-integral (PI) controller is used for position control of the tip displacement of IPMC propulsor. PI parameter tuning is performed using particle swarm optimization (PSO) algorithm. Several performance indices have been used as an objective function to optimize the error of the system. Finally, the best tuning method is found out by comparing the results under various performance indices.

• 센서학회지
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• 제4권4호
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• pp.81-87
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• 1995

A novel biomaterial capable of incorporating biotinylated biomolecule has been synthesized. Our strategy is to biotinylate one-dimensional electroactive polymers and use a bridging streptavidin protein on Langmuir-Blodgett (LB) organized films. These copolymers are derivatized with long alkyl chains and biotin moieties to bind, respectively, to the hydrophobic surface and the biotinylated species, through the biotin and streptavidin complexation. We utilize the polymer assembly approach to attach a signal transducing biomolecule biotinylated phycoerythrin (B-PE) into this novel biomaterial by binding the unoccupied biotin binding sites on the bound streptavidin (4 sites total). The pressure-area isotherm of the protein injected monolayer showed area expansion. A characteristic fluorescent emission peak at 576nm was detected from the monolayer transferred onto a solid substrate. These observations demonstrated the promise of the organized thin polymer assemblies for their application to the sensor system.

• 공업화학
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• 제16권1호
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• pp.1-8
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• 2005

일반적으로 큰 유전상수 또는 높은 전기전도도를 갖는 입자들을 점도가 낮은 절연유체에 분산시킨 전기유변유체는 외부 전기장하에서 급격하고 또한 가역적으로 변화를 한다. 현재까지 알려진 여러 종류의 전기응답성 물질들 중에서 본 총설에서는 zeolite, MCM-41/polyaniline 복합체 및 SBA-15/polyaniline 복합체 등에 중점을 두어 이러한 무기재료를 이용한 전기유변유체의 합성 및 그들의 전기유변유체적 특성을 다룬다.

• Bulletin of the Korean Chemical Society
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• 제27권11호
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• pp.1910-1912
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• 2006

• Journal of Biosystems Engineering
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• 제27권3호
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• pp.249-258
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• 2002

The fourteen different electrodes coated with polymeric lipid membrane were evaluated to selectively monitor the sweet, salty, sour and bitter tastes, and umami. The polymeric lipid membrane consisted of the three components, or polymer matrix, plasticizer and electroactive material, the compositional ratio of which was 1:1.25:1. Herein, the 14 different electroactive materials were used. Sucrose, NaCl, citric acid, caffeine and MSG were used as standard materials of sweet, salty, sour and bitter tastes, and umami. The linear responses of each electrode regarding 5 tastes were analyzed by means of the correlation coefficient between electric potential difference and concentration of a taste material when the linearity was based on a linear model and a thermodynamic model, respectively. As fur salty taste, the electrode coated with valinomycin had a selective linearity at the significance level of 0.01. For monitoring sweet taste, the electrode with oleylamine and the electrode with the mixture of tai-n-octylmethylammonium chloride and dioctylphosphate (2:8) showed the significant linearities at the levels of 0.05 and 0.10, respectively.

• Composites Research
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• 제30권2호
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• pp.126-131
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• 2017

복잡한 형상의 구조 건전성 모니터링을 위해서는 높은 취성 등 기존 센서의 단점을 보완 할 수 있는 매우 유연하고 내구성이 확보된 센서가 필요하다. 본 연구에서는 전기활성고분자의 한 종류인 Polyvinylidene fluoride trifluoroethylene (PVDF-TrFE)를 사용하여 직물센서를 제작하였다. 또한 제작된 직물센서를 복잡한 형상을 가지는 탄소섬유/에폭시 복합재료 구조물에 적용하여 구조 건전성 모니터링을 위한 도구로써 활용 가능성을 평가하였다. 복합재료 구조물의 손상 반응과 파손 메커니즘을 분석하기 위해 다중간헐적 압축시험을 수행하였다. 시험 과정에서 복합재료 구조물에 삽입된 직물센서는 전기적 신호를 발생 (0.05 V-0.25 V)하며 실시간으로 균열발생과 균열위치를 감지해냈다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.11.2-11.2
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• 2011

Polymer based organic photovoltaics have attracted a great deal of attention due to the potential cost-effectiveness of light-weight and flexible solar cells. However, most BHJ polymer solar cells are not thermally stable as subsequent exposure to heat drives further development of the morphology towards a state of macrophase separation in the micrometer scale. Here we would like to show three different approaches for developing new electroactive polymers to improve the thermal stability of the BHJ solar cells, which is a critical problem for the commercialization of these solar cells. For one of the examples, we report a new series of functionalized polythiophene (PT-x) copolymers for use in solution processed organic photovoltaics (OPVs). PT-x copolymers were synthesized from two different monomers, where the ratio of the monomers was carefully controlled to achieve a UV photo-crosslinkable layer while leaving the ${\pi}-{\pi}$ stacking feature of conjugated polymers unchanged. The crosslinking stabilizes PT-x/PCBM blend morphology preventing the macro phase separation between two components, which lead to OPVs with remarkably enhanced thermal stability. The drastic improvement in thermal stabilities is further characterized by microscopy as well as grazing incidence X-ray scattering (GIXS). In the second part of talk, we will discuss the use of block copolymers as active materials for WOLEDs in which phosphorescent emitter isolation can be achieved. We have exploited the use of triarylamine (TPA) oxadiazole (OXA) diblock copolymers (TPA-b-OXA), which have been used as host materials due to their high triplet energy and charge-transport properties enabling a balance of holes and electrons. Organization of phosphorescent domains in TPA-b-OXA block copolymers is demonstrated to yield dual emission for white electroluminescence. Our approach minimizes energy transfer between two colored species by site isolation through morphology control, allowing higher loading concentration of red emitters with improved device performance. Furthermore, by varying the molecular weight of TPA-b-OXA and the ratio of blue to red emitters, we have investigated the effect of domain spacing on the electroluminescence spectrum and device performance.

• Bulletin of the Korean Chemical Society
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• 제31권11호
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• pp.3103-3108
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• 2010

Conducting polymers (CPs) are widely used as matrixes for the entrapment of enzymes in analytical chemistry and biosensing devices. However, enzyme-catalyzed polymerization of CPs is rarely used for immunosensing due to the difficulties involved in the quantitative analysis of colloidal CPs in solution phase. In this study, an enzyme-amplified electrocatalytic immunosensor employing a CP as a redox marker has been developed. A polyanionic polymer matrix, $\alpha$-amino-$\omega$-thiol terminated poly(acrylic acid), was employed for precipitation of CP. The acrylic acid group acts as a polyanionic template. The thiol terminus of the polymer was used to produce self-assembled monolayers (SAMs) on Au electrodes and the amine terminus was employed for immobilization of biomolecules. In an enzymeamplified sandwich type immunosensor, the polyaniline (PANI) produced enzymatically is attracted by the electrostatic force of the matrix polymer. The precipitated PANI was characterized by electrochemical methods.