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A Theoretical and Experimental Study of Physical Adsorption of Gases on Uniform Flat Solid Surface

  • Lee, Jo-Woong;Chang, Sei-Hun;Yoon, Jae-Shin
    • Bulletin of the Korean Chemical Society
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    • v.10 no.3
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    • pp.292-297
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    • 1989
  • In this work we have experimentally observed the physisorption isotherms for nitrogen, TMS, cyclohexane, benzene, and n-hexane adsorbed on flat aluminum foil surface and have analyzed them theoretically on the basis of the theory proposed by Chang et al. The results show that the theory by Chang et al. can provide a useful means to describe the physisorption of gases on uniform flat solid surface which is essentially important for analysis of the pore volume distribution in porous solid surface. We have also discussed the application of the results obtained in this work to the analysis of pore volume distribution in porous alumina we reported previously.

Observation of Rotational Cooling of CN($B^2{\Sigma}^+$) Radical Generated in a Supersonic Expansion

  • Lee, Sang-Kuk;Choi, Iek-Soon;Kim, Un-Sik
    • Bulletin of the Korean Chemical Society
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    • v.15 no.5
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    • pp.353-356
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    • 1994
  • The $CN(B^2{\Sigma}^+)$ radical was produced in a jet using an electric dc discharge of the precursor $CH_3CN$ with inert carrier gases. The rotationally resolved Fourier transform emission spectra of the 0-0 band of the $(B^2{\Sigma}^+{\to}X^2{\Sigma}^+)$ transition of CN have exhibited different distribution of the intensity for the carrier gases He and Ar, respectively. From the analysis of intensity distribution in the spectra, the mechanism for rotational cooling process of CN radical in a supersonic expansion has been suggested.

Some Model Solute Affinity for a Tactic p-HEMA Membranes by K$_D$ Measurement

  • Lee, Eun-Hee;Jeon, Sang-Il;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.5
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    • pp.175-178
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    • 1984
  • Two series of membranes have been prepared by postcrosslinking highly syndiotactic and isotactic poly (2-hydroxyethyl methacrylate), P(HEMA). The crosslinker used was hexamethylene diisocyante (HMDIC). The distribution coefficients (K$_{D2}$) of the model solutes such as urea (and thiourea), their derivatives, homologous alcohol series and amide sreies in water-swollen tactic P(HEMA) membranes at $25^{\circ}C$ were mesaured. In addition, the concentration effects of acetamide and butyramid were also measured. On the basis of hydrophobic interaction and the structural factors of tactic P(HEMA) membranes, the hydrophobic adsorption of the solutes in the polymer matrix were discussed. The results showed that the more hydrphobic the solute is, the higher the $K_{D2}$ value is. And the polymer conformation also affects the distribution of solvents.

Fundamental Morphological Study of 16 Genera of Chironomid Larvae in Korea

  • Lee, Dong Ju;Park, Jae-won;Kwak, Ihn-Sil
    • Korean Journal of Ecology and Environment
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    • v.54 no.2
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    • pp.125-129
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    • 2021
  • Chironomids are a large group of invertebrates that live in various aquatic habitats. The distribution range of these invertebrates has become varied due to anthropogenic impacts; as such, their distribution can be used as an indicator of environmental health. Adult chironomids are well known in South Korea; however, the larvae have rarely been studied due to difficulties associated with morphological classification. To address this lack of information, we collected larvae from four important rivers in South Korea and summarized their taxonomic morphological characteristics. The antennae, mandible, and mentum were used for larval taxonomic characterization. In this study, we describe the basic morphological features and key pictorial features of 20 species of chironomids, representing 16 genera.

ON GENERIC SUBMANIFOLDS OF LP-SASAKIAN MANIFOLDS WITH CONCURRENT VECTOR FIELDS

  • Ghosh, Sujoy;Jun, Jae-Bok;Sarkar, Avijit
    • Communications of the Korean Mathematical Society
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    • v.36 no.2
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    • pp.361-375
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    • 2021
  • The object of the present paper is to deduce some important results on generic submanifolds and also generic product of LP-Sasakian manifolds with concurrent vector fields. Also, we provide a necessary and sufficient condition for which the invariant distribution D and anti-invariant distribution D of M are Einstein. Also, we deduce an interesting necessary and sufficient condition for submanifolds of LP-Sasakian manifolds to be totally umbilical submanifolds. Especially we deal with the generic submanifolds admitting a Ricci soliton in LP-Sasakian manifolds endowed with concurrent vector fields.

Analysis on the buckling of imperfect functionally graded sandwich plates using new modified power-law formulations

  • Zohra, Abdelhak;Benferhat, Rabia;Tahar, Hassaine Daouadji;Tounsi, Abdelouahed
    • Structural Engineering and Mechanics
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    • v.77 no.6
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    • pp.797-807
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    • 2021
  • A new simple solution for critical buckling of FG sandwich plates under axial and biaxial loads is presented using new modified power-law formulations. Both even and uneven distributions of porosity are taken into account in this study. Material properties of the sandwich plate faces are assumed to be graded in the thickness direction according to a modified power-law distribution in terms of the volume fractions of the constituents. Equilibrium and stability equations of FG sandwich plate with various boundary conditions are derived using the higher-order shear deformation plate theory. The results reveal that the distribution shape of the porosity, the gradient index, loading type and functionally graded layers thickness have significant influence on the buckling response of functionally graded sandwich plates.

A semi-analytical solution to spherical cavity expansion in unsaturated soils

  • Tang, Jianhua;Wang, Hui;Li, Jingpei
    • Geomechanics and Engineering
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    • v.25 no.4
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    • pp.283-294
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    • 2021
  • This paper presents a rigorous solution for spherical cavity expansion in unsaturated soils under constant suction condition. The hydraulic behavior that describes the saturation-suction relationship is modeled by a void ratio-dependent soil-water characteristic curve, which allows the hydraulic behavior to fully couple with the mechanical behavior that is described by an extended critical state soil model for unsaturated soil through the specific volume. Considering the boundary condition and introducing an auxiliary coordinate, the problem is formulated to a system of first-order differential equations with three principal stress components and suction as basic unknowns, which is solved as an initial value problem. Parameter analyses are conducted to investigate the effects of suction and the overconsolidation ratio on the overall expansion responses, including the pressure-expansion response, the distribution of the stress components around the cavity, and the stress path of the soil during cavity expansion. The results reveal that the expansion pressures and the distribution of the stress components in unsaturated soils are generally higher than those in saturated soils due to the existence of suction.

Experimental investigation of wind flow characteristics over hills and escarpments - A review

  • Wani, Abdul Haseeb;Varma, Rajendra K.;Ahuja, Ashok K.
    • Wind and Structures
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    • v.32 no.4
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    • pp.393-403
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    • 2021
  • A comprehensive knowledge of the wind flow in hilly terrains is of great interest in many engineering applications, be it wind energy distribution for suitable site selection for wind farms, pollution dispersion, forest fire propagation or agrometerological studies. Several researchers have shown that wind flow over a hilly terrain may be significantly different when compared with the wind flow over a flat terrain. Complex hilly terrains may alter the wind speed to a great extent. Therefore, this effect of terrain must be properly assessed by designers and planners to arrive at a proper wind flow distribution. This paper reviews the work done in this area over the past three decades. Wind flow over two-dimensional hills and two-dimensional escarpments investigated in wind tunnels by various researchers is presented in this paper.

Thermoelastic analysis of rectangular plates with variable thickness made of FGM based on TSDT using DQ method

  • Amiri, Majid;Loghman, Abbas;Arefi, Mohammad
    • Geomechanics and Engineering
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    • v.29 no.6
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    • pp.667-681
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    • 2022
  • This paper presents a thermoelastic analysis of variable thickness plates made of functionally graded materials (FGM) subjected to mechanical and thermal loads. The thermal load is applied to the plate as a temperature difference between the top and bottom surfaces. Temperature distribution in the plate is obtained using the steady-state heat equation. Except for Poisson's ratio, all mechanical properties of the plate are assumed to vary linearly along the thickness direction based on the volume fractions of ceramic and metal. The plate is resting on an elastic foundation modeled based on the Winkler foundation model. The governing equations are derived based on the third-order shear deformation theory (TSDT) and are solved numerically for various boundary conditions using the differential quadrature method (DQM). The effects of various parameters on the stress distribution and deflection of the plate are investigated such as the value of thermal and mechanical loads, volume fractions of ceramic and metal, and the stiffness coefficients of the foundation.

2D Kinetic Simulation of Partially Magnetized Capacitively Coupled Plasma Sources (2차원 동역학 시뮬레이션을 활용한 부분적으로 자화된 용량성 결합 플라즈마 전산 모사)

  • Sung Hyun Son;Junbeom Park;Kyoung-Jae Chung
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.1
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    • pp.118-123
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    • 2023
  • Partially magnetized capacitively coupled plasma (CCP) sources are investigated using a two-dimensional kinetic simulation code named EDIPIC-2D. A converging numerical solution was obtained for CCP with a 60 MHz power source, while properly capturing the dynamics of electrons and power absorption over a single RF period. The effects of magnetic fields with different orientations were evaluated. Axial magnetic fields caused changes in the spatial distribution of plasma density, affecting the loss channel. Transverse magnetic fields enhanced stochastic heating near the powered electrode, leading to an increase in plasma density while the significant E×B drift loss compensated for this rise.

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