Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Some Model Solute Affinity for a Tactic p-HEMA Membranes by K$_D$ Measurement

  • Lee, Eun-Hee (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Jeon, Sang-Il (Department of Chemistry, Korea Advanced Institute of Science and Technology) ;
  • Jhon, Mu-Shik (Department of Chemistry, Korea Advanced Institute of Science and Technology)
  • Published : 1984.10.20
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Abstract

Two series of membranes have been prepared by postcrosslinking highly syndiotactic and isotactic poly (2-hydroxyethyl methacrylate), P(HEMA). The crosslinker used was hexamethylene diisocyante (HMDIC). The distribution coefficients (K$_{D2}$) of the model solutes such as urea (and thiourea), their derivatives, homologous alcohol series and amide sreies in water-swollen tactic P(HEMA) membranes at $25^{\circ}C$ were mesaured. In addition, the concentration effects of acetamide and butyramid were also measured. On the basis of hydrophobic interaction and the structural factors of tactic P(HEMA) membranes, the hydrophobic adsorption of the solutes in the polymer matrix were discussed. The results showed that the more hydrphobic the solute is, the higher the $K_{D2}$ value is. And the polymer conformation also affects the distribution of solvents.

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References

  1. ACS Symposium Series 31 Hydrogcls for Medical and Related Applications J. D. Andrade(ed.)
  2. J. Appl. Polym. Sci. v.27 S. C. Yoon;M. S. Jhon
  3. ACS Adv. Chem. Series 128 Polymerzation Kinetics and Technology G. Borknet;J. J. van Aartsen;N. V. J. Platzer(ed.)
  4. Master's thesis, Dept. of Materials Science and Engineering, University of Utah M. Y. Mah
  5. J. Gen. Physiol. v.54 C. M. Gary-Bobo;R. Dipolo;A. K. Solomon
  6. J. Chem. Soc. D. Reichenberg;W. F. Wall
  7. J. Polym. Sci., Polym. Phys. Ed., v.18 G. A. Russell;A. Hiltner;D. E. Gregonis;A. C. deVisser;J. D. Andrade
  8. J. Bioengineering v.2 K. H Lee;J. G. Jee;M. S. Jhon;T. K. Ree
  9. Bull. Korean Chem. Soc. v.4 J. H. Lee;U. W. Kim;M. S. Jhon
  10. Nature v.185 O. Wichterle;D. Lim
  11. J. Polym. Sci. Polym. Lett. Ed. v.18 A. Haglund;N. V. B. Marsden
  12. J. Amer. Chem. Soc. v.84 I. M. Klotz;J. S. Franzen
  13. The Proteins v.I;II H. A. Scheraga;Neurath(Ed.)
  14. J. Appl. Polym. Sci. v.5 M. F. Refojo
  15. J. Polym. Sci., A-1 v.10 B. D. Ratner;I. F. Miller
  16. Polym. v.19 D. E. Gregonis;G. A. Russell;J. D. Andrade;A. C. deVisser
  17. J. Org. Chem. v.30 G. A. Motimer