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Ductile Shear Deformation around Jirisan Area, Korea (지리산 일대의 연성전단변형)

  • Ryoo, Chung-Ryul;Kang, Hee-Cheol;Lee, Sang-Won
    • The Journal of the Petrological Society of Korea
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    • v.28 no.2
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    • pp.53-69
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    • 2019
  • In the Jirisan area of the Yeongnam Massif, Korea, several ductile shear zones are developed within Precambrian gneiss complex (Jirisan metamorphic rock complex). The ductile shear zones have a general NS- and NNE-striking foliation with westward dipping directions. The foliation developed in the shear zones cut the foliation in gneiss complex. The stretching lineations are well developed in the foliated plane of the shear zone, showing ENE-trend with gentle plunging angle to the ESE direction. Within shear zone, several millimetric to centimetric size of porphyroclasts are deformed strongly as a sigmoid form by ductile shearing. The sigmoid patterns of porphyroclasts in the shear zones indicate the dextral shearing. The spatial distribution of ductile shear zone is characterized by the dominant NS- and NNE-striking dextral sense in the central and eastern regions respectively. In the western part, it develops in NE-striking dextral sense which is the general direction of the Honam shear zone. The U-Pb concordant ages obtained from the two samples, the strongly sheared leucocratic gneiss, are $1,868{\pm}3.8Ma$ and $1,867{\pm}4.0Ma$, respectively, which are consistent with the U-Pb ages reported around the study area. We supposed that the ductile shearing in the study area is occurred about 230~220 Ma during late stage of the continental collision around Korea and is preceded by granitic intrusion related to subduction during 260~230 Ma, which are supported by compiling the age data from sheared gneiss, deformed mafic dyke intruded gneiss complex, and non-deformed igneous rocks.

Optimization of anode and electrolyte microstructure for Solid Oxide Fuel Cells (고체산화물 연료전지 연료극 및 전해질 미세구조 최적화)

  • Noh, Jong Hyeok;Myung, Jae-ha
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.525-530
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    • 2019
  • The performance and stability of solid oxide fuel cells (SOFCs) depend on the microstructure of the electrode and electrolyte. In anode, porosity and pore distribution affect the active site and fuel gas transfer. In an electrolyte, density and thickness determine the ohmic resistance. To optimizing these conditions, using costly method cannot be a suitable research plan for aiming at commercialization. To solve these drawbacks, we made high performance unit cells with low cost and highly efficient ceramic processes. We selected the NiO-YSZ cermet that is a commercial anode material and used facile methods like die pressing and dip coating process. The porosity of anode was controlled by the amount of carbon black (CB) pore former from 10 wt% to 20 wt% and final sintering temperature from $1350^{\circ}C$ to $1450^{\circ}C$. To achieve a dense thin film electrolyte, the thickness and microstructure of electrolyte were controlled by changing the YSZ loading (vol%) of the slurry from 1 vol% to 5 vol. From results, we achieved the 40% porosity that is well known as an optimum value in Ni-YSZ anode, by adding 15wt% of CB and sintering at $1350^{\circ}C$. YSZ electrolyte thickness was controllable from $2{\mu}m$ to $28{\mu}m$ and dense microstructure is formed at 3vol% of YSZ loading via dip coating process. Finally, a unit cell composed of Ni-YSZ anode with 40% porosity, YSZ electrolyte with a $22{\mu}m$ thickness and LSM-YSZ cathode had a maximum power density of $1.426Wcm^{-2}$ at $800^{\circ}C$.

Stabilization of Nanoemulsion Using PEG-free Surfactant (PEG-free 계면활성제를 사용한 Nanoemulsion의 안정화)

  • Kim, Huiju;Jung, Taek Kyu;Kim, Ja Young;Yoon, Kyung-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.434-447
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    • 2019
  • Polyethylene glycol (PEG) is widely used in cosmetics as a surfactant, detergent and emulsifier. During the manufacturing process, 1,4-dioxane, which is toxic to humans, can be produced as a by-product by dimerization of ethylene oxide. As consumers' interest in cosmetic ingredients has increased, the need for safe emulsion research without PEG ingredients in the personal care market has increased. With increasing consumer interest in cosmetic ingredients, the need for safer emulsion research without the PEG ingredient in the personal care market has increased. In this study, we aimed to develop and stabilize nanoemulsion formulation without PEG. Response Surface Methodology (RSM) was used to develop optimized nanoemulsion formulations. Surfactant content (2~4%), oil content (4~8%) and polyol content (12~24%) were set as independent variables as a result of preliminary experiments for determining independent variables and ranges. The particle size, zeta potential, turbidity, and polydispersity index of the formulation were measured as response variables. As a result of measurement of the prepared nanoemulsion by FIB (Focused ion beam), spherical particles were found to have a size distribution of 100 to 200 nm. The stability of each formulation was evaluated for 30 days at each temperature ($4^{\circ}C$, $25^{\circ}C$, and $45^{\circ}C$). The optimal formulation considering the optimum particle size, turbidity, polydispersity index and zeta potential was found to be surfactant (2%), oil (8%) and polyol (24%).

Stabilization of Tocopheryl Acetate of Swollen Micelle by Poloxamer (Poloxamer를 이용한 Swollen Micelle의 Tocopheryl Acetate 안정화)

  • Kim, Mi-Seon;Yoon, Kyung-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.609-622
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    • 2019
  • When the surfactant is dissolved in an aqueous solution, it forms aggregate called micelles (<20 nm) in the solution, and micelles can form the solubilized formulation by supporting the active ingredient therein. Swollen micelles are formulations capable of carrying larger amounts of active ingredient than conventional solubilized formulations at 50~100 nm. Unlike liposomes or nanoemulsions, which require a separate process such as high pressure emulsification, Swollen micelle is a more efficient method of solubilization and particle formation from a productive point of view. In this study, stabilization experiments on swollen micelle formulations were carried out using poloxamer 407, and then optimized formulation experiments for tocopheryl acetate components were performed using Response Surface Methodology (RSM). Tocopheryl acetate, a surfactant that affects solubilization and an active substance, were set as a factor and the correlation between them was confirmed. As the evaluation method, stability and particle size distribution and size were confirmed by temperature and time, and the structure and shape of the swollen micelle carrying the active ingredient were confirmed by FIB. These results show that poloxamer 407 0.500%, octyldodeceth-16 0.387% and tocopheryl acetate 0.945% are the most optimized prescriptions for swollen micelle stabilized with tocopheryl acetate.

A Study on the Estimation of Optimal Unit Content of Binder for the Soil Stabilizer Using the Recycled Resource in DMM (심층혼합공법에서 순환자원을 활용한 지반안정재의 최적 단위결합재량 산정에 관한 연구)

  • Seo, Se-Gwan;Lee, Khang-Soo;Kim, You-Seong;Cho, Dae-sung
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.2
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    • pp.37-44
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    • 2019
  • The compressive strength of the soil stabilizer in the deep mixing method (DMM) depends on kinds of soil, particle size distribution, and water content. Because of this, Laboratory test has to perform to estimate the unit weight of binder to confirm the satisfaction of the design strength. In this study, uniaxial compression strength was measured by mixing the soil stabilizers developed in the previous study with clay in Busan, Yeosu, and Incheon area. And the strength enhancement effect was evaluated comparing with blast furnace slag cement (BFSC). Also, the relationship between the unit content of binder and uniaxial compressive strength was investigated in order to easily calculate the unit weight of binder required to ensure the stability of the ground at the field. As the results of the analysis, the relationship between the unit content of binder and the uniaxial compressive strength are ${\gamma}_B=(108.93+0.0284q_u){\pm}35$ when W/B is 70%, and ${\gamma}_B=(122.93+0.0270q_u){\pm}40$ when W/B is 80%.

A Study on the determination of the optimal resolution for the application of the distributed rainfall-runoff model to the flood forecasting system - focused on Geumho river basin using GRM (분포형 유역유출모형의 홍수예보시스템 적용을 위한 최적해상도 결정에 관한 연구 - GRM 모형을 활용하여 금호강 유역을 중심으로)

  • Kim, Sooyoung;Yoon, Kwang Seok
    • Journal of Korea Water Resources Association
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    • v.52 no.2
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    • pp.107-113
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    • 2019
  • The flood forecasting model currently used in Korea calculates the runoff of basin using the lumped rainfall-runoff model and estimates the river level using the river and reservoir routing models. The lumped model assumes homogeneous drainage zones in the basin. Therefore, it can not consider various spatial characteristics in the basin. In addition, the rainfall data used in lumped model also has the same limitation because of using the point scale rainfall data. To overcome the limitations as mentioned above, many researchers have studied to apply the distributed rainfall-runoff model to flood forecasting system. In this study, to apply the Grid-based Rainfall-Runoff Model (GRM) to the Korean flood forecasting system, the optimal resolution is determined by analyzing the difference of the results of the runoff according to the various resolutions. If the grid size is to small, the computation time becomes excessive and it is not suitable for applying to the flood forecasting model. Even if the grid size is too large, it does not fit the purpose of analyzing the spatial distribution by applying the distributed model. As a result of this study, the optimal resolution which satisfies the accuracy of the bsin runoff prediction and the calculation speed suitable for the flood forecasting was proposed. The accuracy of the runoff prediction was analyzed by comparing the Nash-Sutcliffe model efficiency coefficient (NSE). The optimal resolution estimated from this study will be used as basic data for applying the distributed rainfall-runoff model to the flood forecasting system.

Analysis of Total Aflatoxin, Ochratoxin A, Zearalenone, Deoxynivalenol and T-2 Toxin Contamination in Nuts (시중유통 견과류의 총아플라톡신, 오크라톡신 A, 제랄레논, 데옥시니발레놀, T-2 독소의 오염도 조사)

  • Hong, JoonBae;Park, Kun Taek
    • Journal of Food Hygiene and Safety
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    • v.34 no.1
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    • pp.58-64
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    • 2019
  • In the current study, 109 commercial nut samples were collected from different Korean markets and analyzed for the contamination of 5 different mycotoxins (aflatoxin, ochratoxin A, deoxynivalenol, zearalenone, and T-2 toxin) using ELISA kits. The results revealed that the most frequently detected mycotoxin was zearalenone (n=36, 33%), followed by aflatoxin (n=31, 28.4%) and ochratoxin A (n=30, 27.5%). Deoxynivalenol and T-2 toxin were also detected in 22 (20.3%) samples, respectively. Among 109 nut samples, 33 samples (30.3%) were contaminated only with one kind of mycotoxin, whereas 43 samples had at least 2 kinds of mycotoxins. Two samples were contaminated with as many as 4 different mycotoxins, and they were both walnuts. Although the monitoring results revealed the amount of aflatoxin contamination was under the safety criteria, there is no current safety guideline for other kinds of mycotoxins or multiple contaminations in Korea. Therefore, further studies should be performed to reveal the distribution of mycotoxin in different foods and propose appropriate safety guidelines for Korean markets.

An Analytical Study on Composite Beam Performance with Post-Fire Temperature Using ANSYS Program (ANSYS를 이용한 화재 후 온도에 따른 합성보 성능에 관한 해석적 연구)

  • Kwak, Sung-Shin;Choi, Byong-Jeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.1
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    • pp.391-400
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    • 2019
  • In the case of fire, a structure loses its original stiffness due to the temperature rise, and the load bearing capacity decreases. The loss of structural strength increases with increasing fire time of the structure. To prevent the collapse of buildings, it is very important to understand whether or not the members are damaged. On the other hand, there is insufficient data to be a guideline for diagnosing and evaluating the residual strength of the members in Korea. Therefore, this study examined the resistance performance by Finite-Element-Analysis of composite beams, which are composite structures among structural members. Composite beam modeling was carried out based on the model used in the Electrical Penetration Room (EPR) in cooperation with KEPCO. The heat transfer analysis and structural analysis of the critical phase were performed using ANSYS, a finite element analysis program. ANSYS was used to perform heat transfer analysis and structural analysis at the static analysis. To analyze the residual performance, the temperature distribution of the composite beam and the maximum displacement result of the heat-affected structure analysis were derived and the experimental data and the structural analysis result data were compared and analyzed.

Estimation of Consolidation Characteristics of Soft Ground in Major River Mouth (주요 강하구 연약지반의 압밀 특성 평가)

  • Lee, JunDae;Kwon, YoungChul;Bae, WooSeok
    • Journal of the Korean GEO-environmental Society
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    • v.20 no.2
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    • pp.69-79
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    • 2019
  • The coastal area forms various sedimentary layers according to the environmental conditions such as the topography and geological features of the upper region of the river, ocean currents, and river mouth. Therefore, identifying the characteristics of the marine clay deposited in the coastal area plays a key role in the investigation of the formation of soft ground. In general, alluvial grounds are formed by a variety of factors such as changes in topography and natural environment, they have very diverse qualities depending on the deposited region or sedimentation conditions. The most important thing for the construction of social infrastructures in soft ground areas is economical and efficient treatment of soft ground. In this study, the author collected data from diverse laboratory and field tests on five areas in western and southern offshore with relatively high reliability, and then statistically analyzed them, thereby presenting standard constants for construction design. Correlation between design parameters such as over consolidation ratio, preconsolidation pressure was analyzed using linear and non-linear regression analyses. Also, proposed distribution characteristics of design parameters in consideration of each region's uncertainty through statistical analyses such as normality verification, outlier removal.

A Study on Penetration Effect of Penetrating Hardener for Prevention of Scattering of Asbestos Building Materials (석면 건축자재의 비산 방지를 위한 침투성 경화제 침투 효과에 관한 연구)

  • Song, Tae-Hyeob;Park, Ji-Sun;Shin, Hyun-Gyoo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.324-330
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    • 2018
  • In accordance with the amendment of the Industrial Safety and Health Act of 2007, Korea completely prohibited the import, distribution and manufacture of asbestos like Europe and Japan. Accordingly, the current problem of asbestos is the safe maintenance and disposal of asbestos construction material, the disposal of asbestos, and the final disposal of asbestos building materials. In the past, Korea used 100,000 tons of asbestos every year, and the building materials using it exceeded 1 million tons per year. These asbestos building materials continued to be used until 2006, and the Ministry predicted that these materials would continue to be maintained until 2044. When the permeable hardening agent is applied to the asbestos building material installed in the pre-pretreatment step for the harmless treatment of the asbestos waste and the dismantling is carried out, the scattering of the asbestos is suppressed in the disassembling step, detoxification treatment conditions can be improved. Therefore, permeable hardeners should be stably penetrated into asbestos building materials. In this study, it is suggested that pre - pretreatment methods for the harmlessization of waste asbestos building materials with medium density level can be presented. In order to efficiently perform pre - treatment for chemical harmlessness in the future, the mixing ratio of permeable hardener and middle water Optimization is the most important factor.