• 제목/요약/키워드: Dispersion behavior

검색결과 492건 처리시간 0.023초

Surface Potential Behavior of Nano $CeO_2$ Particles in Aqueous Media (수계분산매체에서 나노 $CeO_2$ 입자의 계면전위 거동)

  • 이태원;백운규;최성철;이상훈;임형섭;김철진
    • Journal of the Korean Ceramic Society
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    • 제37권7호
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    • pp.721-725
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    • 2000
  • In this study, the dispersion stability of nano-sized CeO2 particles, synthesized by hydrothermal method in aqueous was evaluated from observing the surface potential behavior of CeO2 particle synthesized by solid state reaction. The isoelectric point(IEP) of nano-sized CeO2 synthesized by hydrothermal synthesis was found to be pH 9 contrary to the isoelectric point of micro-sized CeO2 synthesized by solid state reaction at pH 6.7. IEP was shifted to pH 2.0 as the addition of D-3019 from 0.1 to 1.0 wt%. The surface potential of CeO2 particles synthesized by hydrothermal synthesis was reduced as the addition of B-1001 used as a binder without change of IEP because the absorption of B-1001 polymer on the CeO2 particles shifted the shear plane of CeO2 particles outward away from the surface. This surface potential behavior was well correlated with the dispersion stability of slurry.

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An Investigation of Dispersion Behavior of Y2O3 Ceramic Particles in Hypo, Eutectic and Hyper Binary Al-Cu Cast Alloys (아공정, 공정, 과공정 조성의 Al-Cu 주조합금에서의 Y2O3 분말의 분산 거동에 대한 연구)

  • Park, J.J.;Kim, G.H.;Hong, S.M.;Lee, S.H.;Lee, M.K.;Rhee, C.K.
    • Journal of Powder Materials
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    • 제14권2호
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    • pp.123-126
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    • 2007
  • In this work, the dispersion behavior of $Y_2O_3$ particles in binary aluminum (Al)-copper (Cu) cast alloy was investigated with respect to Cu contents of 20 (hypoeutertic), 33 (eutectic) and 40 (hypereutectic) wt.%. In cases of hypo and hypereutectic compositions, SEM images revealed that the primary Al and ${\theta}$ phases were grown up at the beginning, respectively, and thereafter the eutectic phase was solidified. In addition, it was found that some of $Y_2O_3$ particles can be dispersed into the primary Al phase, but none of them are is observed inside the primary 6 phase. This different dispersion behavior of $Y_2O_3$ particles is probably due to the difference in the val- ues of specific gravity between $Y_2O_3$ particles and primary phases. At eutectic composition, $Y_2O_3$ particles were well dispersed in the matrix since there is few primary phases acting as an impediment site for particle dispersion during solidification. Based on the experimental results, it is concluded that $Y_2O_3$ particles are mostly dispersed into the eutectic phase in binary Al-Cu alloy system.

Investigation on Guided Wave Dispersion Characteristics for Metal Thin Films (금속 박막의 유도초음파 분산 특성 연구)

  • Kim, Miso;Cho, Seung Hyun;Jang, Gang-Won;Lee, Seung-Seok;Park, Ik-Keun
    • Journal of the Korean Society for Nondestructive Testing
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    • 제34권3호
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    • pp.233-240
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    • 2014
  • In this study, we investigated the dispersion characteristics of guided waves in thin films. Dispersion curves are essential for understanding not only the behavior of ultrasonic waves, but also the mechanical properties of thin films. Matrix techniques are presented for modeling ultrasonic waves in multilayered structures before being used to calculate the dispersion curves for Al-steel and Al-composite specimens. When compared with the dispersion curves obtained using the commercial program (Disperse), the dispersion curves generated from the transfer matrix method show its validity. These developed methods are used to obtain dispersion curves for Al thin films deposited on a Si substrate. The resulting dispersion curves enable observation of both dispersive and non-dispersive behavior for the guided waves, depending on the thickness of the thin films.

Analysis of Behavior Characteristics of Instantaneous Input of Pollutant in River (하천에 순간 유입된 오염물질의 거동 특성 분석)

  • Yoon, Sei-Eui;Ko, Jae-Hyung;Kim, Soo-Youl
    • Journal of Korea Water Resources Association
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    • 제36권4호
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    • pp.575-586
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    • 2003
  • In case of continuous input of a pollutant, dispersion characteristics do not change much with changing dispersion coefficient, but that of an instantaneous input is very sensitive to the changes of dispersion coefficient. The characteristics of behavior of instantaneous input of a pollutant at the downstream of Han river were analyzed in this paper Field measurement of hydraulic and water quality factors at the downstream of Han river were conducted at low flow condition. The hydraulic factors were used to estimate the longitudinal dispersion coefficient, and the reasonable empirical equations for longitudinal dispersion coefficient at the downstream of Han river were suggested. The measured concentrations of BOD were closely matched with the calculated ones from RMA-4 model. In case of instantaneous input, range of dispersion, transport pathway and the traveltimes of the first and maximum concentration with variation of the longitudinal dispersion coefficients and water levels of downstream boundary were evaluated in this paper.

Impact of target spectra variance of selected ground motions on seismic response of structures

  • Xu, Liuyun;Zhou, Zhiguang
    • Earthquakes and Structures
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    • 제23권2호
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    • pp.115-128
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    • 2022
  • One common method to select input ground motions to predict dynamic behavior of structures subjected to seismic excitation requires spectral acceleration (Sa) match target mean response spectrum. However, dispersion of ground motions, which explicitly affects the structural response, is rarely discussed in this method. Generally, selecting ground motions matching target mean and variance has been utilized as an appropriate method to predict reliable seismic response. The goal of this paper is to investigate the impact of target spectra variance of ground motions on structural seismic response. Two sets of ground motions with different target variances (zero variance and minimum variance larger than inherent variance of the target spectrum) are selected as input to two different structures. Structural responses at different heights are compared, in terms of peak, mean and dispersion. Results show that increase of target spectra variance tends to increase peak floor acceleration, peak deformation and dispersions of response of interest remarkably. To short-period structures, dispersion increase ratios of seismic response are close to that of Sa of input ground motions at the first period. To long-period structures, dispersions of floor acceleration and floor response spectra increase more significantly at the bottom, while dispersion increase ratios of IDR and deformation are close to that of Sa of input ground motions at the first period. This study could further provide useful information on selecting appropriate ground motion to predict seismic behavior of different types of structures.

Dispersion Polymerization of Styrene Employing Lyophilic Comonomer in the Absence of Stabilizer: Synthesis of Impurity-free Microspheres

  • Han, Hye-Kyung;Lee, Jeong-Woo;Hong, Jin-Ho;Shim, Sang-Eun
    • Macromolecular Research
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    • 제17권7호
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    • pp.469-475
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    • 2009
  • We investigated the feasibility of dispersion polymerization without any stabilizer, which has been considered essential for ensuring colloidal stability. By employing small amounts of a lyophilic comonomer, 4-vinyl pyridine, styrene was successfully polymerized by dispersion polymerization in aqueous alcohol without stabilizer to afford stable poly(styrene-co-4-vinyl pyridine) copolymer microspheres. The stable microspheres were produced in the 4-vinyl pyridine range of 2-15 wt% to styrene. Without 4-vinyl pyridine, severely coagulated particles were obtained, implying that the poly(4-vinyl pyridine) moiety endowed colloidal stability. The polymerization kinetics, behavior, and properties of the ultimate particles showed general features of dispersion polymerization. The study results suggest that stabilizer- tree dispersion polymerization is possible, thereby facilitating the synthesis of impurity(stabilizer)-tree polymer particles.

Study on Material Fracture and Debris Dispersion Behavior via High Velocity Impact (고속충돌에 따른 재료 파괴 및 파편의 분산거동 연구)

  • Sakong, Jae;Woo, Sung-Choong;Kim, Jin-Young;Kim, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • 제41권11호
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    • pp.1065-1075
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    • 2017
  • In this study, high velocity impact tests along with modeling of material behavior and numerical analyses were conducted to predict the dispersion behavior of the debris resulting from a high velocity impact fracture. For the impact tests, two different materials were employed for both the projectile and the target plate - the first setup employed aluminum alloy while the second employed steel. The projectile impacts the target plate with a velocity of approximately 1 km/s were enforced to generate the impact damages in the aluminum witness plate through the fracture debris. It was confirmed that, depending on the material employed, the debris dispersion behavior as well as the dispersion radii on the witness plate varied. A numerical analysis was conducted for the same impact test conditions. The smoothed particle hydrodynamics (SPH)-finite element (FE) coupled technique was then applied to model the fracture and damage upon the debris. The experimental and numerical results for the diameters of the perforation holes in the target plate and the debris dispersion radii on the witness plate were in agreement within a 5% error. In addition, the impact test using steel was found to be more threatening as proven by the larger debris dispersion radius.

Dispersion stability of polyelectrolyte-wrapped carbon black particles in a highly fluorinated solvent

  • Yoon, Hyeon Ji;Choe, Jun Ho;Jin, Hyoung-Joon
    • Carbon letters
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    • 제26권
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    • pp.25-30
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    • 2018
  • The dielectric medium used in electrophoretic displays (EPDs) is required to be an environmentally friendly solvent with high density, low viscosity, and a large electric constant. Hydrofluoroether, a highly fluorinated solvent with eco-friendly characteristics, is regarded as a viable alternative medium for EPDs, owing to the similarity of its physical properties to those of the conventional EPD medium. Surface modification of particles is required, however, in order for it to disperse in the charged solvent. Also, positive/negative charges should be present on the particle surface to enable electrophoretic behavior. In this study, carbon black particles wrapped with positively charged nitrogen (N-CBs) were fabricated by a simple hydrothermal process using a poly(diallyldimethylammonium chloride) solution as a black coloring agent for the EPD. The dispersion behavior of N-CBs was investigated in various solvents.

Behavior of Gaseous Volatile Organic Compounds Considered by Density-Dependent Gas Advection (밀도차에 의해 발생하는 이송을 고려한 휘발성 유기화합물 가스의 거동)

  • 이창수;이영화
    • Journal of Environmental Science International
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    • 제11권12호
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    • pp.1321-1326
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    • 2002
  • A numerical model is investigated to predict a behavior of the gaseous volatile organic compounds and a subsurface contamination caused by them in the unsaturated zone. Two dimensional advective-dispersion equation caused by a density difference and two dimensional diffusion equation are computed by a finite difference method in the numerical model. A laboratory experiment is also carried out to compare the results of the numerical model. The dimensions of the experimental plume are 1.2m in length, 0.5m in height, and 0.05m in thickness. In comparing the result of 2 methods used in the numerical model with the one of the experiment respectively, the one of the advective-dispersion equation shows better than the one the diffusion equation.

Flow and Diffusion of Lower Han River Considering Tidal Elevation in Yellow Sea (서해안 조위를 고려한 한강 하류부의 흐름 및 확산)

  • Seo, Il-Won;Song, Chang-Geun;Lee, Myung-Eun
    • 한국방재학회:학술대회논문집
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    • 한국방재학회 2008년도 정기총회 및 학술발표대회
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    • pp.199-202
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    • 2008
  • It is well-known fact that tidal difference between the ebb and flow in Yellow Sea is about 9 m so that it has largest value in the world. This wide range of tide level enables Yellow Sea water to intrude into main stream of Han River. However, the study of the tidal reach of Han River has not been carried out thoroughly since North and South Koreas share this region so that topography data and physical measurement are lacking. In this study, to examine the reverse flow and dispersion behavior by tidal effect at the tidal reach of Han River, 2-D river analysis models were applied. RMA-2 was applied to calculate the horizontal velocities and water surface elevation. With the results of velocities and water depth, RAM4, which is 2-D advection-dispersion model based on FEM was simulated to analyze the horizontal transport behavior of BOD.

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