• Title/Summary/Keyword: Disperse dyes

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Isolation and Identification of Fungi for Decolorization of Synthetic Dyes

  • Lee, Jang-Hoon;Nam, Youn-Ku;Kwon, Hyuk-Ku
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2005.12a
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    • pp.95-102
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    • 2005
  • For decolorization of synthetic dyes, Isolate fungi were investigated for the decolorization of 8 industrial dyes. One fungus isolated from textile wastewater collected from Banweol industrial complex, Korea showed excellent ability for removing synthetic dyes. Internal Transcribed Spacers (ITS) sequencing result was confirmed as the new Basidomycetes species. HUE05-1 The optimal decolorizaton conditions were pH5, 30$^{\circ}C$ and aerobic condition. HUE05-1 was completely decolorized all dyes in both solid and liquid condition. The result is decolorization effect at Reactive Orange 16; 97.12%, Reactive Blue 19; 92.09%, Reactive Blue 49; 97.04%, Reactive Yellow 145; 95.53%, Acid Orange 10; 99.18%, Acid Violet 43; 98.73%, Acid Blue 350; 94.71%, Disperse Blue 106; 90.07%.

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각종 white rot fungi에 의한 분산염료의 색제거 비교

  • Lee, Hyeon-Uk;Son, Dong-Chan;Im, Dong-Jun
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.402-405
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    • 2000
  • Batch culture system and continuous culture system were used to investigate the removal of disperse dye using several white rot fungi. White rot fungi used in the study were Coriolus hirsutus IFO 4917, Lenzites betulina IFO 6266, Coriolus versicolor IFO 30340 and Phanerochaete chrysosporium IFO 31249. The results of the batch culture experiment showed that white rot fungi used in this study had excellent dye removal abilities. Phanerochaete chrysosporium IFO 31249 was especially effective on the removal of disperse dyes. And continuous treatment of disperse red-60 was studied under bioreactor with vertical matrix using Phanerochaete chrysosporium IFO 31249. The removal efficiency of disperse red-60 were more than 95% in 0.20 ${\sim} 1.50 $hr^{-1}$ dilution rate and 90% in $1.83h^{-1}$ dilution rate.

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The Effects of Polar Compounds on the Rate of Dye Exhaustion in Solvent Dyeing (용제염색에서 극상 화합물이 염착속도에 미치는 영향)

  • 이대수;안태환
    • Textile Coloration and Finishing
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    • v.2 no.1
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    • pp.21-30
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    • 1990
  • In order to obtain high dye uptake initially, polyethylene terephthalate (PET) filaments were dyed with C.I.Disperse Orange 3 and Red 1 in mixed solvents of tetrachloroethylene acidic solvent, ethyl alcohol and tetrachloroethylene basic solvent, DMF. The dyeing behavior in the mixed solvent of tetrachloroethylene and basic solvent, DMF, the initial uptake of disperse dyes increased rapidly. The shrinkage of PET increased when the solubility parameter values of PET fiber and mixed solvent approached graduately.

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Kinetics and Mechanism for Alkaline Hydrolysis of Dinitrothiophene Disperse Dye(C. I. Disperse Green 9) (디니트로티오펜계 분산염료인 C. I. Disperse Green 9의 알칼리 가수분해 반응속도 및 반응메카니즘)

  • Park, Geon-Yong;Kim, Jae-Hyoun
    • Textile Coloration and Finishing
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    • v.19 no.4
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    • pp.18-25
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    • 2007
  • Kinetics and mechanism for alkaline hydrolysis of C. I. Disperse Green 9(G-9) of dinitrothiophene disperse dye were investigated. As soon as G-9 contacted with alkali, instant and continuous decreases of color strength of G-9 followed with increasing time. The hydrolysis rate of G-9 increased with increasing alkali, and it was found that alkali appeared first order dependence. The observed rate constants obtained from hydrolysis of various amount of dye were similar values, and calculation of initial rates showed that G-9 hydrolyzed by first order reaction for dye. Therefore it was confirmed that the overall reaction was second order, $SN_2$ of nucleophilic substitution reaction. Increasing temperature enhanced the hydrolysis of G-9. From the results of hydrolysis performed at various temperatures, it was obtained that activation energy(Ea) was 12.6 kcal/mole, enthalpy of reaction(${\triangle}H$) was 12.0 kcal/mole, and entropy of reaction(${\triangle}S$) was $29.8J/mol{\cdot}K$.

Dyeing Properties of PET/Dyeable PP Double Knit Fabric (PET/가염PP 이종 편성물의 염색 특성)

  • Chang, Young-Min;Lee, Jin-Ah;Park, Jong-Ho;Koh, Joon-Seok;Jung, Young-Jin;Kim, Sung-Dong
    • Textile Coloration and Finishing
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    • v.20 no.2
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    • pp.53-58
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    • 2008
  • New dyeable PP fiber and several products from it has been developed through dispersing polyester copolymer into PP resin by a Korean synthetic fiber manufacturer and its colleagues. The dyeing properties of PET/dyeable PP double knit fabric were examined with three different types of disperse dye in this study. It was found that the disperse dye, exhausted on dyeable PP at early stage of dyeing, migrated to PET at elevated dyeing temperature when two fibers were dyed in the same dye bath. The ratios of dye distribution between two substrates dyed at $120^{\circ}C$ and $130^{\circ}C$ showed no difference. S type disperse dyes showed good build-up properties and acceptable color fastness while high light fastness type exhibited the lowest amounts of exhaustion but excellent color fastness. It might be concluded that the most appropriate dye for PET/dyeable PP double knit fabric was S type, and that some color difference between PET side and dyeable PP side was unvoidable.

Dyeing Properties of Polyurethane-impregnated PET Knit

  • Park, Jong-Ho;Kim, Sung-Dong
    • Textile Coloration and Finishing
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    • v.20 no.5
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    • pp.35-40
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    • 2008
  • Dyeing and washing fastness properties of polyurethane-impregnated polyester (PU-impregnated PET), and the distribution of two disperse dyes between PET and PU film were studied to investigate the effect of PU portion to exhaustion and washing fastness. Dyeing properties of PU-impregnated PET were quite different with those of PET: PU-impregnated PET absorbed disperse dye linearly from the early stage of dyeing to equilibrium, and it exhibited excellent build-up property up to 4 %owf dyeing. The absorbed dye on PU film at early dyeing stage migrated to more substantive PET at the temperature higher than $115^{\circ}C$. The amount of exhausted dye on PET portion was larger than on PU film and the distribution ratio was $2.08{\sim}2.34$. The grade of washing fastness of PU-impregnated PET was the same as or lower by $0.5{\sim}1$ grade than PU film whose washing fastness was lower by $0.5{\sim}1$ than PET.

Preparation and Characterization of Microcapsule for non-aqueous dyeing (비수계 염색용 마이크로캡슐의 제조 및 성질)

  • 최창남;박원규;변수진;이기영
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.327-332
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    • 2003
  • In this study, the polyurethane microcapsules for non-aqueous dyeing containing iron oxide and disperse dyes were prepared by in-situ polymerization method using hexamethylene diisocyanate(HDI) with ethylene glycol(EG). And the size, shape, and particle size distribution of microcapsules prepared were investigated. The size and shape of microcapsule were observed by optical microscope and scanning elecron microscope. The particle size distribution was analyzed by particle size analyzer. The microcapsule size and its distribution were largely effected by the existance of surface active agent in the system. When a surfactant did not exist in the system, the size distribution of microcapsules prepared was much uneven. By adding a surfactant, this phenomenon was disappeared. And the size of microcapsule was also effeced by the hydrophobicity of core material(disperse dye). It was considered due to the difference of dispersity of core materials. And the size of microcapsule prepared was inversely proportional to the stirring speed.