• Journal of Electrochemical Science and Technology
• /
• 제9권4호
• /
• pp.339-344
• /
• 2018

The gelling agent used in Zn-air cells plays a role in improving battery life. It prevents the evaporation of water and diffusion of $Zn^{2+}$ ions away from the current collector. Additional functionality was incorporated by replacing some of the gelling agents with new materials. Alcohols with moderate viscosity, namely maltose, sucrose, poly ethylene glycol 600, and 2-hydroxyethyl cellulose, were used to replace some gelling agents in this work. Among these alcohols, poly ethylene glycol 600 and 2-hydroxyethyl cellulose improved the cycle life of full cells. This improved cycle life was attributed to the inhibition of water electrolysis and the improved cycle life of the anode.

• Journal of Industrial and Engineering Chemistry
• /
• 제68권
• /
• pp.146-152
• /
• 2018

Due to their excellent mechanical durability and high electrical conductivity, carbon and silicon composites are potentially suitable anode materials for Li-ion batteries with high capacity and long lifespan. Nevertheless, the limitations of the composites include their poor ionic diffusion at high current densities during cycling, which leads to low ultrafast performance. In the present study, seeking to improve the ionic diffusion using hydrothermal method, electrospinning, and carbonization, we demonstrate the unique design of excavated carbon and silicon composites (EC/Si). The outstanding energy storage performance of EC/Si electrode provides a discharge specific capacity, impressive rate performance, and ultrafast cycling stability.

• 한국대기환경학회:학술대회논문집
• /
• 한국대기환경학회 2000년도 추계학술대회 논문집
• /
• pp.59-60
• /
• 2000

에어로졸을 분리할 수 있는 장비로는 전기적 이동차 분석기(differential mobility analyzer), 싸이클론(cyclone), 습식 충돌기(impinger), 습식 싸이클론(wet cyclone), 확산 배터리(diffusion battery), 관성 임팩터(inertial impactor), 그리고 가상 임팩터(virtual impactor) 등이 있다. 이중 가상 임팩터는 설계 및 제작이 비교적 간편하고, 입자를 분리 및 농축하는데도 좋은 성능을 나타냄으로 널리 사용되어져 왔다. (중략)

• Bulletin of the Korean Chemical Society
• /
• 제32권1호
• /
• pp.191-195
• /
• 2011

This study reports the root cause of the improved rate performance of $LiFePO_4$ after Cr doping. By measuring the chemical diffusion coefficient of lithium ($D_{Li}$) using cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), the correlation between the electrochemical performance of $LiFePO_4$ and Li diffusion is acquired. The diffusion constants for $LiFePO_4$/C and $LiFe_{0.97}Cr_{0.03}PO_4$/C measured from CV are $2.48{\times}10^{-15}$ and $4.02{\times}10^{-15}cm^2s^{-1}$, respectively, indicating significant increases in diffusivity after the modification. The difference in diffusivity is also confirmed by EIS and the $D_{Li}$ values obtained as a function of the lithium content in the cathode. These results suggest that Cr doping facilitates Li ion diffusion during the charge-discharge cycles. The low diffusivity of the $LiFePO_4$/C leads to the considerable capacity decline at high discharge rates, while high diffusivity of the $LiFe_{0.97}Cr_{0.03}PO_4$/C maintains the initial capacity, even at high C-rates.

• 융합정보논문지
• /
• 제11권6호
• /
• pp.219-225
• /
• 2021

배터리 패키지 방식은 안정성의 이유로 각형 패키지 방식이 선호되고 있으나 최근 파우치형 패키지의 안정성 검증에 따라 빠른 확대가 이루어지고 있다. 적층 공정을 이용한 파우치형은 공간 낭비를 줄일 수 있어 배터리 에너지 밀도가 높은 장점이 있으나 생산성이 낮은 단점을 가지고 있다. 따라서 본 논문에서는 조명확산 최소화를 위한 백라이트 조명기구 개선, 스테레오 카메라 위치 관계 변위 모니터링을 위한 기준 확보, 렌즈 풀림 모니터링을 위한 기준 확보를 통하여, 에지 검출 알고리즘 정밀도, 패턴 알고리즘 정밀도, 모션 컨트롤러 재현율을 추출함으로써 위치 결정시의 정확성 및 신뢰성을 확보하는 시스템을 구현을 제안한다. 실험결과 제안한 시스템은 에지 검출에서는 평균 0.032mm, 패턴 알고리즘에서는 0.023mm, 모션 컨트롤러에서는 0.014mm의 오차범위를 보여주고 있어 위치 결정 기구의 정확성과 신뢰성을 확보할 수 있다.

• Journal of Electrochemical Science and Technology
• /
• 제14권2호
• /
• pp.184-193
• /
• 2023

This study investigates the effects of a carbon fiber layer formed on the surface of an etched aluminum current collector on the electrochemical properties of the activated carbon electrodes for an electric double layer capacitor. A particle size analyzer, field-emission SEM, and nitrogen adsorption/desorption isotherm analyzer are employed to analyze the structure of the carbon fiber layer. The electric and electrochemical properties of the activated carbon electrodes using a carbon fiber layer are evaluated using an electrode resistance meter and a charge-discharge tester, respectively. To uniformly coat the surface with carbon fiber, we applied a planetary mill process, adjusted the particle size, and prepared the carbon paste by dispersing in a binder. Subsequently, the carbon paste was coated on the surface of the etched aluminum current collector to form the carbon under layer, after which an activated carbon slurry was coated to form the electrodes. Based on the results, the interface resistance of the EDLC cell made of the current collector with the carbon fiber layer was reduced compared to the cell using the pristine current collector. The interfacial resistance decreased from 0.0143 Ω·cm² to a maximum of 0.0077 Ω·cm². And degradation reactions of the activated carbon electrodes are suppressed in the 3.3 V floating test. We infer that it is because the improved electric network of the carbon fiber layer coated on the current collector surface enhanced the electron collection and interfacial diffusion while protecting the surface of the cathode etched aluminum; thereby suppressing the formation of Al-F compounds.

• Journal of Electrochemical Science and Technology
• /
• 제5권2호
• /
• pp.58-64
• /
• 2014

The surface of an ordered mesoporous silica (OMS) was functionalized using 1H,1H,2H,2H-perfluorooctyltrimethoxysilane at $20^{\circ}C$ and $60^{\circ}C$. It was shown that only elevated temperature allows lyophobic properties on the walls of OMS, eventually preventing pore flooding with nonaqueous electrolytes. The functionalized OMSs (OMS-F) were characterized with various techniques: wettability test, $N_2$ sorption measurement, high-resolution transmission electron microscopy (HR-TEM). Cathodes of $10mg/cm^2$ loading were prepared with a commercial Pt/C catalyst and polyvinylidene fluoride (PVDF, 2.5 wt.%) binder using a typical doctor blade method on a commercial gas diffusion layer (GDL) in the presence or in the absence of OMS-F additives. Subsequent discharge-charge curves were taken in a 1M LiTFSI-TEGDME electrolyte at 60oC in pure oxygen atmosphere. It was found that the discharge capacity was significantly affected by OMS-F: 5 wt.% of additive extended discharge capacity by a factor 1.5. On the other hand, a similar OMS material but synthesized at $20^{\circ}C$ did not show lyophobic properties and deteriorated cathode capacity.

• Journal of Electrochemical Science and Technology
• /
• 제7권2호
• /
• pp.170-178
• /
• 2016

Composited molybdenum oxide and amorphous carbon (MoO₃/C) as anode material for lithium ion batteries has been successfully synthesized by calcining polyaniline (PANI) doped with ammonium heptamolybdate tetrahydrate (AMo). The as prepared electrode material was characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR) and field emission scanning electron microscopy (FE-SEM). The electrochemical performance of the anode was investigated by galvanostatic charge/discharge, cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The MoO₃/C shows higher specific capacity, better cyclic performance and rate performance than pristine MoO₃ at room temperature. The electrochemical of MoO₃/C properties at various temperatures were also investigated. At elevated temperature, MoO₃/C exhibited higher specific capacity but suffered rapidly declines. While at low temperature, the electrochemical performance was mainly limited by the low kinetics of lithium ion diffusion and the high charge transfer resistance.

• 전기학회논문지
• /
• 제65권2호
• /
• pp.264-268
• /
• 2016

Recently, various energy efficiency optimization activities are ongoing globally by integrating conventional grids with ICT (Information and Communication Technology). In this sense, various smart grid projects, which power suppliers and consumers exchange useful informations bilaterally in real time, have been being carried out. The electric vehicle diffusion program is one of the projects and it has been spotlighted because it could resolve green gas problem, fuel economy and tightening environmental regulations. In this paper, the economics of V2G system which consists of electric vehicles and the charging infrastructure is evaluated comparing electric vehicles for V2G with common electric vehicles. Additional benefits of V2G are analyzed in the viewpoint of load leveling, frequency regulation and operation reserve. To find this benefit, electricity sales is modeled mathematically considering depth of discharge, maximum capacity reduction, etc. Benefit and cost analysis methods with the modeling are proposed to decide whether the introduction of V2G systems. Additionally, the methods will contribute to derive the future production and the unit cost of electric vehicle and battery and to get the technical and economic analysis.

• Korean Chemical Engineering Research
• /
• 제48권3호
• /
• pp.283-291
• /
• 2010

리튬이온전지의 음전극으로 사용하기 위해 주로 알카리 수열합성법과 열처리에 의해 제조되는 $TiO_2$ 나노튜브의 전기화학적 특성에 관한 연구결과를 조사하여, 그 충방전 특성을 분석하였다. 현재까지 리튬과 $TiO_2$의 전기화학반응으로 생성되는 $Li_xTiO_2$의 이론용량인 $335mAh\;g^{-1}$(x=1)를 초과하는 최대방전용량 $338mAh\;g^{-1}$(x=1.01)을 $TiO_2(B)$ 상을 갖는 나노튜브가 나타내었다. 이것은 리튬의 자가확산이 활성에너지 0.48 eV 정도로 느리므로 이보다 확산거리가 짧도록 $TiO_2$ 나노튜브의 구조를 조정하여 리튬 수송이 원활하도록 하였기 때문이다. 또한 $TiO_2$ 나노튜브 구조체는 벌크상은 물론 표면에서의 뛰어난 이온저장성 때문에 리튬이온전지의 음전극 소재뿐만 아니라 고출력 특성이 필요한 커페시터 소자의 전극소재로도 활용할 수 있다.