• Title/Summary/Keyword: Detailed Kinetics

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Electrical Impedance Spectroscopy(EIS) Measurements to Evaluate Corrosion of Steel/Concrete System (교류 임피던스기법을 이용한 철근부식 측정에 관한 실험적 연구)

  • Jung, Si-Young;Kim, Byoung-Kook;Choi, Oan-Chul
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.659-662
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    • 2005
  • Electrochemical impedance spectroscopy (EIS) has been extensively used to try to evaluate the corrosion state of the steel/concrete system. This technique is attractive because, in theory, used in a wide range of frequencies, it can give detailed information about the mechanisms and kinetics of the electrochemical reactions. Impedance measurements were performed using potential control and measuring the corresponding current response. One-year-old southern exposure test. specimens were used in the current study. The effectiveness of corrosion inhibiting additives was evaluated. The corrosion current densities estimated by impedance measurements were confirmed by those determined using linear polarization techniques. The purpose of this study was to evaluate the long-term-performance potential of the corrosion inhibitors in chloride contaminated reinforce concrete.

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Flame Propagation within Hydrogen Premixed Gas mixture According to Ignition Condition (점화 조건에 따른 수소 예혼합기에서의 화염 전파)

  • Han, Cho-Young;Kim, Jeong-Soo;Lee, Kyun-Ho;Kim, Byung-Kyo
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.350-355
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    • 2003
  • Flame onset and propagation within hydrogen premixed gas mixture are numerically investigated in an rectangular enclosure. A detailed chemistry for hydrogen reaction is applied to anticipate the thermochemical behavior of intermediate species appropriately. To facilitate computation, 10 species and 16 elementary reaction steps for hydrogen combustion are taken into account. On the basis of 30 % of hydrogen concentration in hydrogen-air mixture, the effects of position and quantity of ignition sources on the flame evolution are analyzed. From the simulation results, the means that can lessen the possible hazard caused by flame propagation are suggested.

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Three-Dimensional Numerical Analysis of Spinning Detonation Wave (Spinning Detonation 파의 3차원 수치 해석)

  • Cho, Deok-Rae;Choi, Jeong-Yeol;Won, Su-Hee
    • 한국연소학회:학술대회논문집
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    • 2006.04a
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    • pp.205-212
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    • 2006
  • Three-dimensional numerical study was carried out for the investigation of the detonation wave structures propagating in tubes. Fluid dynamics equations and conservation equation of reaction progress variable were analyzed by a MUSCL-type TVD scheme and four stage Runge-Kutta time integration. Chemical reaction was modeled by using a simplified one-step irreversible kinetics model. The variable gas properties between unburned and burned states were considered by using variable specific heat ratio formulation. The unsteady computational results in three-dimension show the detailed mechanisms of rectangular and diagonal mode of detonation wave instabilities resulting same cell length but different cell width in smoked-foil record. The results for the small reaction constant shows the spinning mode of three-dimensional detonation wave dynamics, which was rarely observed in the previous numerical simulation of the detonation waves.

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탄화수소/산소 혼합기체가 채워진 관 내부를 전파하는 데토네이션 파의 해석과 가시화

  • Choe Jeong Yeol
    • 한국가시화정보학회:학술대회논문집
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    • 2004.04a
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    • pp.29-36
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    • 2004
  • A numerical study is carried out on the detonation wave propagation through a T-shaped flame tube, which represents a crucial part of the combustion wave ignition (CWI) system aimed for simultaneous ignition of multiple combustion chambers by delivering detonation waves. The formulation includes the Euler equations and an induction-parameter model. The reaction rate is treated based on a chemical kinetics database obtained from a detailed chemistry mechanism. A second-order implicit time integration and a third-order TVD algorithm are Implemented to solve the theoretical model numerically. A total of more than two-million grid points are used to provide direct insight into the dynamics of the detonation wave. Several important phenomena including detonation wave propagation, degeneration, and re-initiation are carefully examined. Information obtained can be effectively used to facilitate the design and optimization of the flame tubes of CWI systems.

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A Numerical Study on Combustion Characteristics of HCCI Engine with Stratification Condition of EGR Exhaust Gases (EGR 배기가스의 성층화 조건에 따른 HCCI 엔진의 연소 특성에 관한 수치해석 연구)

  • Lee, Won-Jun;Lee, Seung-Ro;Lee, Chang-Eon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.6
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    • pp.46-52
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    • 2011
  • Homogeneous charge compression ignition (HCCI) is the best concept able to provide low NOx and PM in diesel engine emissions. This new alternative combustion process is mainly controlled by chemical kinetics in comparison with the conventional combustion in internal combustion engine. However, HCCI engine's operation have an excessive rate of pressure rising during the combustion process. In this study, stratification condition of EGR exhaust gases was used to reduce the pressure rising during the combustion process in HCCI engine. Also, combustion characteristics and emissions characteristics were investigated using the detailed diesel surrogate reaction mechanism.

Gait analysis methods and walking pattern of hemiplegic patients after stroke (뇌졸중환자의 보행분석방법과 보행특성)

  • Han, Jin-Tae;Bae, Sung-Soo
    • PNF and Movement
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    • v.5 no.1
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    • pp.37-47
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    • 2007
  • Objective : A large proportion of stroke survivors have to deal with problems in gait. Proper evaluation of gait must be undertaken to understand the sensorimotor impairment underlying locomotor disorders post stroke. Methods : The characteristics of gait pattern with post stroke are reviewed in this paper. In particular, temporal distance parameters, kimematics, kinetics, as well as energy cost, EMG are focused. Results : The technology for gait analysis is moving rapidly. The techniques of 3D kinematic and kinetic analysis can provide a detailed biomechanical description of normal and pathological gait. This article reviews gait analysis method and characteristics of post stroke. Finally current method of gait analysis can provide further insight to understand paretic gait and therapeutic direction.

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A Numerical Study of Combustion Characteristics for HCCI Engine with Detailed Diesel Surrogate Chemical Mechanism (Diesel Surrogate 상세 반응 기구를 이용한 HCCI 엔진의 연소 특성에 관한 수치해석 연구)

  • Lee, Won-Jun;Lee, Seung-Ro;Lee, Chang-Eon
    • Journal of the Korean Society of Combustion
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    • v.16 no.2
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    • pp.9-15
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    • 2011
  • Homogeneous charge compression ignition(HCCI) is the best concept able to provide low NOx and PM in diesel engine emissions. This new alternative combustion process is mainly controlled by chemical kinetics in comparison with the conventional combustion in internal combustion engine. In this paper, combustion characteristics of HCCI engine with suggested diesel surrogate(heptane/toluene mixture fuel) reaction mechanism were numerically investigated by heptane/toluene mixture ratio and EGR ratio. As results, the ignition timing became faster with increasing of heptane, and an initial oxidation and the ignition timing of the mixture fuel were affected by heptane and toluene, respectively.

Design of Hardward Diagnostic System for Reactor Internal Structures Using Neutron Noise (중성자 신호이용 원자로 내부 구조물 감시시스템 하드웨어 설계)

  • Park, Jong-Beom;Park, Jin-Ho;Hwang, Choong-Hwan;Kim, Soo-Hong
    • Proceedings of the KIEE Conference
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    • 2001.07d
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    • pp.2166-2168
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    • 2001
  • Reactor Noise is defined as the fluctuations of measured instrumentation signals during full-power operation of reactor which have informations on reactor system dynamics such as neutron kinetics. The Reactor internal structures which consist of many complex components are subjected to flow-induced vibration due to high temperature and pressure in reactor coolant system. The above flow-induced vibration causes degradation of structural integrity of the reactor and may result in loosing mechanical binding component which might impact other equipment and component or cause flow blockage. It is important to analyze reactor noise signal for the early detection of potential problem or failure in order to diagnosis reactor integrity in the point of view of safety and plant economics. Detailed design of hardware diagnostic system reactor internal structures using neutron noise(RIDS).

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Three-dimensional Detonation Cell Structures in a Circular Tube

  • Cho, D.R.;Won, S.H.;Shin, Edward J.R.;Choi, J.Y.
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.597-601
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    • 2008
  • Three-dimensional structures of detonation wave propagating in circular tube were investigated. Inviscid fluid dynamics equations coupled with a conservation equation of reaction progress variable were analyzed by a MUSCL-type TVD scheme and four stage Runge-Kutta time integration. Variable-$\gamma$ formulation was used to account for the variable properties between unburned and burned states and the chemical reaction was modeled by using a simplified one-step irreversible kinetics model. The computational code was parallelized based on domain decomposition technique using MPI-II message passing library. The computations were carried out using a home made Windows based PC cluster having 160 AMD AthloxXP and Athlon64 processor. The computational domain consisted of through a roundshaped tube with wall conditions. As an initial condition, analytical ZND solution was distributed over the computational domain with disturbances. The disturbances has circumferential large gradient. The unsteady computational results in three-dimension show the detailed mechanisms of multi-cell mode of detonation wave instabilities resulting diamond shape in smoked-foil record.

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Analysis of Core Disruptive Accident Energetics for Liquid Metal Reactor

  • Suk, Soo-Dong;Dohee Hahn
    • Nuclear Engineering and Technology
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    • v.34 no.2
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    • pp.117-131
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    • 2002
  • Core disruptive accidents have been investigated at Korea Atomic Energy Research Institute(KAERI) as part of the work to demonstrate the inherent and ultimate safety of conceptual design of the Korea Advanced Liquid Metal Reactor(KALIMER), a 150 MWe pool- type sodium cooled prototype fast reactor that uses U-Pu-Zr metallic fuel. In this study, a simple method and associated computer program, SCHAMBETA, was developed using a modified Bethe-Tait method to simulate the kinetics and thermodynamic behavior of a homogeneous spherical core over the period of the super-prompt critical power excursion induced by the ramp reactivity insertion. Calculations of the energy release during excursions in the sodium-voided core of the KALIMER were subsequently performed using the SCHAMBETA code for various reactivity insertion rates up to 100 S/s, which has been widely considered to be the upper limit of ramp rates due to fuel compaction. Benchmark calculations were made to compare with the results of more detailed analysis for core meltdown energetics of the oxide fuelled fast reactor. A set of parametric studies were also performed to investigate the sensitivity of the results on the various thermodynamics and reactor parameters.