• 제목/요약/키워드: Der p 2

검색결과 195건 처리시간 0.025초

p-Phenylenediamine Dihydroperchlorate의 결정 및 분자구조 (The Crystal and Molecular Structure of p-Phenylenediamine Dihydroperchlorate)

  • 안중태
    • 대한화학회지
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    • 제21권5호
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    • pp.320-329
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    • 1977
  • p-Phenylenediamine dihydroperchlorate의 세포상수는 $a=4.79{\pm}0.02,\;b=9.03{\pm}0.02,\;c=7.12{\pm}0.03{\AA},\;{\alpha}=109.4{\pm}0.2,\;{\beta}=79.6{\pm}0.2,\;r=104.6{\pm}0.2^{\circ},\;Z=1$이며 공간군은 $P\={1}$이다. 구조는 Patterson 및 Fourier법으로 해석하였으며 block diagonal 최소자승법으로 정밀화하였따. 등경사 Weissenberg 사진들에서 얻은 387개의 관측된 반사에 대하여 R값은 0.13이었다. 이 물질의 결정구조에서 수소결합은 아미노기와 과염소산 이온 사이에서 이루어져 있으며 2가지 형이 있다. 첫째것은, 한개의 삼지형 N${\cdot}{\cdot}{\cdot}$O 수소결합이고, 둘째것은, 보통형의 2개의 N${\cdot}{\cdot}{\cdot}$O 수소 결합이다. 한개의 p-phenylenediamine 그룹은 실험오차 내에서 평면이며 12개의 과염소산이온에 결합되어 있다. 그중 10개의 과염소산이온은 수소결합으로 연결되어 있으며 2개는 van der Waals 힘들로 접촉되어 있다. 한개의 과염소산이온은 6개의 p-phenylenediamine과 4개의 과염소산이온에 의하여 둘러싸여 있따. 6개의 p-phenylenediamine 그룹 중 5개는 수소결합이 되어있고 나머지는 van der Waals 힘으로 접촉되어 있다.

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$\cdot$독 문형의 비료설정 시론 (Satzmodelle im Koreanischen und Deutschen im Hinblick auf ihre didaktische Verwertbarkeit)

  • 민춘기
    • 한국독어학회지:독어학
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    • 제7집
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    • pp.85-104
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    • 2003
  • In der vorliegenden Arbeit werden die deutschen Satzmodelle $f\"{u}r$ Zwecke des DaF-Unterrichts in Korea untersucht. Dabei gehen wir davon aus, dass man die deutschen Satzmodelle vergleichend mit den koreanischen neu aufbauen sollte, um sie im Deutschunterricht fur Koraner recht benutzen zu konnen. Dafur haben wir hier zunachst untersucht, wie man die koreanischen Satzmodelle im Hinblick auf den didaktischen Zweck modifizieren muss. Unter $Ber\"{u}cksichtigung$ des dabei erzielten Ergebnisses wurden $anschlie{\ss}end$end die deutschen Satzmodelle rekonstruiert. Im Koreanischen wurden die Satzmodelle ab Ende der 1960er Jahre verschiedenartig untersucht. Zwar gibt es bisher noch keine Arbeit, die Ergebnisse dieser Forschungen zusammenfasst, dennoch versuchen wir hier aus einigen bisherigen Untersuchungen einen begrenzten Rahmen von koreanischen Satzmodellen herauszufinden. Als Resultat haben wir funf grundlegende Satzmolle hergestellt: (1) Subjekt + $Pr\"{a}dikat$, (2) Subjekt + $Pr\"{a}dikativ$ + $Pr\"{a}dikat$, (3) Subjekt + Objektiv + $Pr\"{a}dikat$, (4) Subjekt + Adverbiale + $Pr\"{a}dikat$, (5) Subjekt + Obj. + Obj./$Pr\"{a}dikativ$/Advb. + $Pr\"{a}dikat$. Das Modell (1) $umfa{\ss}t$ drei $Pr\"{a}dikate$, die sich nach den Wortarten unterscheiden: (intransitives) Verb, Adjektiv und Substantiv. Auch beim Fall (5) $k\"{o}nnen$ drei verschiedene Untermodelle nach der $Kombinationsm\"{o}glichkeit$ auftreten: Sub + Obj. + $Pr\"{a}d$., Sub. + Obj. + $Pr\"{a}dikativ$ + $Pr\"{a}d$., Sub. + Obj. + Advb. + $Pr\"{a}d$. Auch im Deutschen kann man ahnlich wie im Koreanischen didaktisch geeignete Satzmodelle herausarbeiten. Auch dabei wurden bisherige Untersuchungen zu den deutschen Satzmodellen herangewgen. Zu der $d\"{a}fur$ $ausgew\"{a}hlten$ Terminologie $geh\"{o}ren$ Subjekt(S), $Pr\"{a}dikat(P)$, $Pr\"{a}dkativerganzung(PE)$, $Objekterg\"{a}nzung(OE)$, $Adverbialerg\"{a}nzung(AE)$. In der deutschen Sprache werden nach den $Valenzm\"{o}glich­keiten$ des $Pr\"{a}dikativteils$ folgende Modelle unterschieden: S + P, S + P + PE, S + P + OE, S + P + AE, S + P + OE + OE/PE/AE. Unter die OE werden okk. OE, dat. OE, $pr\"{a}d$. OE, refl. OE usw. subsumiert. Um die Stichhaltigkeit der in dieser Schrift neu festgestellten Satzmodelle zu $\"{u}berpr\"{u}fen$, sollten sie anhand eines Textkorpus heutiger Texte in weiteren Untersuchungen validiert werden. Ferner ist es zu empfehlen, die Anwendbarkeit der hier vorgestellten Satzrnodelle im Deutschunterricht $f\"{u}r$ Koreaner $gr\"{u}ndlich$ zu testen

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ASSESSMENT OF GAS COOLED FAST REACTOR WITH INDIRECT SUPERCRITICAL $CO_2$ CYCLE

  • Hejzlar, P.;Dostal, V.;Driscoll, M.J.;Dumaz, P.;Poullennec, G.;Alpy, N.
    • Nuclear Engineering and Technology
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    • 제38권2호
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    • pp.109-118
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    • 2006
  • Various indirect power cycle options for a helium cooled gas cooled fast reactor (GFR) with particular focus on a supercritical $CO_2(SCO_2)$ indirect cycle are investigated as an alternative to a helium cooled direct cycle GFR. The balance of plant (BOP) options include helium-nitrogen Brayton cycle, supercritical water Rankine cycle, and $SCO_2$ recompression Brayton power cycle in three versions: (1) basic design with turbine inlet temperature of $550^{\circ}C$, (2) advanced design with turbine inlet temperature of $650^{\circ}C$ and (3) advanced design with the same turbine inlet temperature and reduced compressor inlet temperature. The indirect $SCO_2$ recompression cycle is found attractive since in addition to easier BOP maintenance it allows significant reduction of core outlet temperature, making design of the primary system easier while achieving very attractive efficiencies comparable to or slightly lower than, the efficiency of the reference GFR direct cycle design. In addition, the indirect cycle arrangement allows significant reduction of the GFR &proximate-containment& and the BOP for the $SCO_2$ cycle is very compact. Both these factors will lead to reduced capital cost.

일부 주택에서 집먼지 진드기 알러젠 조사 (A Survey of House Dust Mite Allergen Contamination in House)

  • 손종렬;윤승욱;권보연
    • 한국대기환경학회지
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    • 제22권5호
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    • pp.719-723
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    • 2006
  • House dust mite was the most important cause of allergic asthma and rhinitis. More than 70% of Korean children and about 50% of adult with respiratory allergy were sensitive to house dust mite. This experiment was indoor environment in house and house dust mite existence inquiry. From 23rd December 2005 to 28th February 2006, dust samples were collected from the bedclothes by a vacuum cleaner and air sampler And the levels of Der f1 and Der p1 were determined by ELISA((Enzyme-Linked Immunosorbent Assay). The results were as follows : 1 The dust mites allergy contaminations of bedclothes in house were higher than international standards(2000 ng/g). 2. In type of dust mite, the Korean house the almost have the D. farinae other than D. pteronyeeinus of mite. 3. The Der f1 and Der p1 levels per gram of dust from the bedclothes were 2074.99 ng on average, but they did not exist in air. The concentrations of house dust mite were significantly high in the bedclothes. This results suggest that the bedclothes have enough concentrations of dust mites to develop the sensitization. The control of indoor environment should be emphasized to prevent the sensitization by the repeated exposure to dust mite.

Differential Growth Response of $A_1\;and\;A_2$ Mating Types of Phytophthora infestans on Rye A and V-8 Juice Agar Media Supplemented with Rhizome Powder of Cyperus rotundus

  • Singh, U.P.;Sarma, B.K.;Nishimura, Ruo;Kobayashi, Kiroku;Ogoshi, Akira;Zinkernagel, Volker;Schlenzig, Alexendra;Schober-Butin, Barbel;Aust, H.J.
    • Mycobiology
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    • 제29권3호
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    • pp.164-169
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    • 2001
  • A new medium for studies of diversity among populations of $A_1\;and\;A_2$ mating types of Phytophthora infestans has been evolved. The rye A agar and V-8 juice agar media on which P. infestans grows well have been amended with rhizome powder of Cyperus rotundus. A total of 259 isolates of $A_1\;and\;A_2$ mating types representing Japan, Korea, India, Taiwan, Indonesia, Thailand, China, Nepal, U.K and Medico were screened for their growth response on these two media. Most of the A1 isolates did not grow well on them except Thailand while growth of $A_2$ mating types differed as some grew on it whereas others did not. It is quite likely that the populations of $A_2$ mating types that did not grow well on rhizome-amended medium are of different clonal lineage. This suggests that this medium can be used for the study of diversification among the isolates of the same or both the mating types as well as to detect the newly introduced genetically different isolates of P. infestans in a locality where it was not reported earlier.

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p-Dimethylaminobenzaldehyde 4-(p-Ethoxyphenyl) Thiosemicarbazone구조의 정밀화 (Refinement of the Structure of p-Dimethylaminobenzaldehyde 4-(p-Ethoxyphenyl) Thiosemicarbazone)

  • 서일환;서추명;박영자
    • 한국결정학회지
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    • 제2권1호
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    • pp.12-16
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    • 1991
  • p-dimethylaminobenzaldehyde 4-(p-ethoxyphenyl) thiosemicarbazone, C18H22N4OS의, 단위포상수는 단사정계 a=11.802(2), b=31.962(2), c=9.829(2)A, β=100.12(1)˚, V=3694.8A3이며 F(000)=1472, Mr=342.47, 공간군은 P2₁/c, Z=8, Dx=1.246 Mg m-3, Dm=1.17Mg m-3, μ=0.15mm-1이다. T=294 K에서 Mo Ka(λ=0.71073 A)을 사용하여 최종 R값은 0.0856이다. 비대칭단위내의 두개 분자간의 구조상의 큰차이는 C(9)-N(1)-C(6)-C(7)의 비틀림각이 각각 58.8(8)˚와 1(1)˚인것으로, 각 분자는 길이가 각각 2.613(7)과 2.566(7) A인 N(1)-H(10)'N(3) 분자내 수고결합을 하고 있으며 각 분자는 N(2)원자를 정점으로 하여 V-모양을 하고 있다. 독립적인 두 분자는 두개의 분자간 수소 결합 N(2)-H(11)'S'=3.367(5) A과 N(2')-H(11')'S=3.421(4)A으로 연결되어 이중체(dimer)를 형성하고 있으며 그 이중체들은 van der Waals력으로 결합되어 있다.

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Impact of Physiological Stresses on Nitric Oxide Formation by Green Alga, Scenedesmus obliquus

  • Mallick, Nirupama;Mohn, Friedrich-Helmuth;Rai, Lalchand;Soeder, Carl-J.
    • Journal of Microbiology and Biotechnology
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    • 제10권3호
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    • pp.300-306
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    • 2000
  • The rate of apparent nitric oxide (NO) release, as measured in the exhaust gas of green alga, Scenedesmus obliquus, depended on the light intensity and pH. It doubled after lowering the temperature from $25^{\circ}C{\;}to{\;}15^{\circ}C$ and strongly decreased from $35^{\circ}C{\;}to{\;}42^{\circ}C$. The Scenedesmus cells, deficient in nitrogen or phosphorus, demonstrated a significant increase in NO production following their transfer to nitrate- and phosphate-rich media. The addition of herbicides (DCMU and glyphosate) or toxic concentrations of $Cu^{2+}{\;}or{\;}Fe^{3+}$ produced strong NO peaks, resembling those that occurred after sudden darkening. An increase in the $Ni^{2+}$ concentration to 20 ppm resulted in a gradual increase of NO release from the initial ~1.5 ppbv to>20 ppbv, whereas $Cd^{2+}$ instantaneously suppressed the NO by the cultures of Scenedesmus was not altered by L-NNA, an inhibitor of nitric oxide synthase (NOS), or by its substrate, L-arginine. This seems to exclude the role of NOS in the NO formation under study. Accordingly, it can be assumed that the rate of NO formation is mainly a function of dynamic nitrite pool sizes and environmental factors significantly affect the NO production in algae.

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GaSb결정 성장과 특성에 관한 연구 (A study on the characteristics and crystal growth of GaSb)

  • 이재구;오장섭;정성훈;송복식;문동찬;김선태
    • E2M - 전기 전자와 첨단 소재
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    • 제9권9호
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    • pp.885-890
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    • 1996
  • Undoped p-type and Te doped n-type GaSb crystals were grown by the vertical Bridgman method. The lattice constant of the GaSb crystals was 6.096.+-.000373.angs.. The carrier concentration, the resistivity, and the carrier mobility measured by the van der Pauw method were p.iden.8*10$^{16}$ c $m^{-3}$ , .rho..iden.0.20 .ohm.-cm, .mu.$_{p}$ .iden.400c $m^{2}$ $V^{-1}$ se $c^{-1}$ for p-type, n.iden.1*10$^{17}$ c $m^{-3}$ , .rho..iden.0.15 .ohm.-cm, .mu.$_{n}$ .iden.500c $m^{2}$ $V^{-1}$ se $c^{-1}$ for n-type at 300K. In case of treatment with metal ion of R $u^{+3}$, P $t^{+4}$, the carrier concentration, resistivity and carrier mobility of the GaSb crystals were p.iden.2*10$^{17}$ c $m^{-3}$ , .rho..iden.0.08.ohm.-cm, .mu.$_{p}$ .iden.420c $m^{2}$ $V^{-1}$ se $c^{-1}$ for p-type, n.iden.2.5*10$^{17}$ c $m^{-3}$ , .rho..iden.0.07.ohm.-cm, .mu.$_{n}$ .iden.520c $m^{2}$ $V^{-1}$ se $c^{-1}$ for n-type respectively. GaSb crystals had a tendency to lower resistivity and higher mobility, for surface treatment with metal ion effectively diminished surface recombination centers.s.

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