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Synthesis and Optical Properties of CaMoO4:RE3+ (RE=Eu, Dy) Phosphors (CaMoO4:RE3+ (RE=Eu, Dy) 형광체의 제조와 광학 특성)

  • Cho, Shinho
    • Journal of the Korean Vacuum Society
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    • v.22 no.2
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    • pp.79-85
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    • 2013
  • Rare earth ions, either $Eu^{3+}$ or $Dy^{3+}$-doped $CaMoO_4$ phosphors were synthesized by using the solid-state reaction method. The crystalline structure of all the phosphor powders, irrespective of the type and concentration of activator ions, was found to be a tetragonal system with the main diffraction peak at (112) plane. For $Eu^{3+}$-doped $CaMoO_4$ phosphors, the grain particles showed an increasing tendency and the pebble-like patterns with a very homogeneous size distribution in the range of 0.01~0.10 mol of $Eu^{3+}$ ions concentration, and the excitation spectra were composed of a broad band centered at 311 nm and weak multiline peaked in the range of 360~470 nm. The dominant emission spectrum was the strong red emission centered at 618 nm due to the $^5D_0{\rightarrow}^7F_2$ transition of $Eu^{3+}$ ions. For $Dy^{3+}$-doped $CaMoO_4$ powders, excitation spectra showed a charge transfer band centered at 303 nm and relatively weak bands resulting from the transitions of $Dy^{3+}$ ions and the main yellow emission spectrum was observed at 578 nm, which was assigned to the $^4F_{9/2}{\rightarrow}^7H_{13/2}$ transition of $Dy^{3+}$ ions.

Dielectric and Pyroelectric Properties of Dy-doped BSCT Thick Films by Screen-printing Method

  • Noh, Hyun-Ji;Lee, Sung-Gap;Nam, Sung-Pill
    • Journal of Electrical Engineering and Technology
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    • v.4 no.4
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    • pp.527-530
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    • 2009
  • $(Ba_{0.57}Sr_{0.33}Ca_{0.10})TiO_3$(=BSCT) powders, prepared by the sol-gel method, were doped using $MnCO_3$ as the acceptor and $Dy_2O_3$ as the donor. This powder was mixed with an organic vehicle. BSCT thick films were fabricated by the screen-printing techniques on the alumina substrate. The structural and dielectric properties of BSCT thick films were investigated with variation of the $Dy_2O_3$ amount. As a result of the differential thermal analysis (DTA), the exothermic peak was observed at around $670^{\circ}C$ due to the formation of the polycrystalline perovskite phase. All the BSCT thick films showed the XRD patterns of a typical polycrystalline perovskite structure. The average grain size of BSCT thick films decreased with an increasing amount of $Dy_2O_3$. The relative dielectric constant and dielectric loss of the BSCT thick film doped $Dy_2O_3$ 0.1mol% were 4637.4 and 1.6% at 1kHz, respectively.

Photoluminescence and Thermal Characteristics of SrAl2O4:Eu+2, Dy+3 Phosphors Synthesized with Various Aluminum Compounds (SrAl2O4:Eu+2, Dy+3 장잔광 형광체 합성에 있어서 알루미늄 화합물에 따른 열적거동 및 발광특성 변화)

  • Lee, Young-Ki;Lee, You-Kee
    • Korean Journal of Materials Research
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    • v.17 no.11
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    • pp.612-617
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    • 2007
  • Both photoluminescence and thermal characteristics for $SrAl_2O_4:Eu^{+2},\;Dy^{+3}$ phosphors synthesized with various aluminum compounds (${\alpha}-Al_2O_3$, ${\gamma}-Al_2O_3$, amorphous-$Al_2O_3$ and $Al(OH)_3)$ were investigated in this study. The formation temperature of the host $SrAl_2O_4$ crystal is changed by these various aluminum compounds, as a result of the different thermal decomposition temperature of $SrCO_3$ phase. Among these compounds, the amorphous-$Al_2O_3$ phase shows the lowest formation temperature of the host $SrAl_2O_4$ crystal. The PL emission and excitation spectra of $SrAl_2O_4:Eu^{+2},\;Dy^{+3}$ phosphor are not affected by these aluminum compounds. After the removal of the Xenon lamp excitation (360 nm), however, the excellent longphosphorescent property of the phosphor is obtained by the amorphous-$Al_2O_3$ phase, although the decay time for all phosphors decrease exponentially.

The development of Dy free MAGFINE and its applications to Motors

  • Honkura, Yoshinobu
    • Proceedings of the Korean Magnestics Society Conference
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    • 2013.12a
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    • pp.95-95
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    • 2013
  • The NdFeB magnet can be classified into the sintered magnet and bonded magnet. The former has superior magnet characteristics but the degree of freedom in shape is highly restricted, whereas the latter has a high degree of freedom, but its magnet characteristics are inferior to the former. When a NdFeB magnet is used at the elevated temperature, part of Nd must be replaced with a high priced Dy to increase its coercive force. For these reasons, a Dy free and high performance NdFeB bonded magnet is desired strongly. The author successfully developed a Dy free NdFeB anisotropic bonded magnet based on discovery of new phenomena called as d-HDDR reaction and its mass production process such as a thermally balanced hydrogen reaction furnace, micro capsuled powder, compression molding / injection molding under magnetic field, magnetic die and so on. Applied to DC brush seat motor for automotive use, the motor has become 50% small in size and weight. The commercialization of a half sized motor for automotive use has been realized up to the market share of 30%. At present, its commercialization is extending to various types of motors such as power tool, ABS motor, wiper motor, window motor, electric bike power motor, and compressor motor. It is expected that the applications will be increasingly enlarged to EV motor, wind generator, EPS motor, washing machine, and glass cutting machine. This innovative technology has realized Dy free high performance magnet and mudt make big contribution to not only rare element strategies but also energy conservation.

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Phase transformation of $REBa_2Cu_3O_{7-x}$ (RE=Nd, Gd, Dy) Superconductor during Continuous Cooling and Isothermal Heat Treatment (등온열처리와 냉각에 따른 $REBa_2Cu_3O_{7-x}$ (RE=Nd, Gd, Dy) 초전도체의 상변화)

  • O, Yong-Taek;Shin, Dong-Chan;Han, Young-Hee;Sung, Tae-Hyun;Jeong, Nyeon-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05a
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    • pp.42-45
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    • 2003
  • The phase transformation of $REBa_2Cu_3O_{7-x}$ (RE=Nd, Gd, Dy) was investigated using isothermal heat-treatment and continuous cooling in air. During continuous cooling, the $REBa_2Cu_3O_{7-x}$ (RE=123) superconducting phase with well-distributed $REBa_2Cu_3O_{7-x}$ (RE-211) was obtainde at a cooling rate of $0.001^{\circ}C$/s. Single phase RE-123 (Nd, Gd, Dy) was stable at $1050^{\circ}C$, $1050^{\circ}C$, and $950^{\circ}C$ during isothermal heat-treatment, respectively. Above these temperatures the RE-211 phase existed within the RE-123 grains. The RE-123, RE-211, $BaCu_2Od_2$, and CuO phases coexisted at $50^{\circ}C$ below the partial melting temperature for each respective rare-earth RE-123.

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Ion Exchange Separation and Spectrofluorometric Determination of Lanthanides in Nuclear Grade Material (이온 질환수지 및 형광분석법에 의한 핵급물질 중희토류원소의 분리정량)

  • Ki-Soo Cho;In-Suck Suh
    • Nuclear Engineering and Technology
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    • v.15 no.2
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    • pp.142-148
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    • 1983
  • Distribution coefficients between cation exchange resin (Dowex 50W$\times$8) and $\alpha$-hydroxyisobutric acid ($\alpha$-HIBA) are measured in order to separate traces of Sm, Eu, Gd and Dy from nuclear material. Individual separations are performed by pH gradient technique with 0.40M $\alpha$-HIBA from 3.40 to 3.60 in cation exchange resin after a group separation. Each of separated elements is determined with a fluorometric method except Gd by colorimetry. The results are applied to analyze Sm, Eu, Gd and Dy in magnesium diuranate (yellow cake).

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Development of a current collection performance simulation program(CaPoDyS 4.0) based on the Windows environment (윈도우 환경을 가진 집전성능 시뮬레이션 프로그램(CaPoDyS 1.0) 개발)

  • Kwon, Sam-Young;Lee, Ki-Won
    • Proceedings of the KIEE Conference
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    • 2001.07b
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    • pp.1223-1225
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    • 2001
  • This paper describes the simulation algorithms and user interfaces of the self-developed CaPoDyS which is to simulate the dynamic interaction between catenary and pantograph based on FEM. Also, the reliability of the simulation results are discussed through comparing with the ERRI report.

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Oscillation of Certain Second Order Damped Quasilinear Elliptic Equations via the Weighted Averages

  • Xia, Yong;Xu, Zhiting
    • Kyungpook Mathematical Journal
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    • v.47 no.2
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    • pp.191-202
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    • 2007
  • By using the weighted averaging techniques, we establish oscillation criteria for the second order damped quasilinear elliptic differential equation $$\sum_{i,j=1}^{N}D_i(a_{ij}(x){\parallel}Dy{\parallel}^{p-2}D_jy)+{\langle}b(x),\;{\parallel}Dy{\parallel}^{p-2}Dy{\rangle}+c(x)f(y)=0,\;p>1$$. The obtained theorems include and improve some existing ones for the undamped halflinear partial differential equation and the semilinear elliptic equation.

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Structural and Photoluminescence Properties of BaMoO4:RE (RE=Sm, Eu, Tb, Dy, Tm) Phosphors (BaMoO4:RE (RE=Sm, Eu, Tb, Dy, Tm) 형광체의 구조 및 발광 특성)

  • Gang, Min-Ji;Jo, Sin-Ho
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.105-106
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    • 2012
  • 고상반응법을 사용하여 다양한 활성제 이온 (Eu, Sm, Tb, Tm, Dy)을 도핑한 $BaMoO_4$ 형광체 분말을 제조하였다. 합성한 형광체의 결정 구조는 활성제 종류에 관계없이 $2{\theta}=26.34^{\circ}$에서 주 피크를 갖는 정방정계이었다. 발광스펙트럼의 경우에 첨가한 활성제이온에 따라 다양한 색상을 발생하였다.

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A Study of Hydrogen Desorption in Dy2Co7-H System (Dy2Co7-H System에서 수소(水素)의 Desorption에 관한 연구(硏究))

  • Nam, ln-Tak
    • Journal of Industrial Technology
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    • v.1
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    • pp.47-51
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    • 1981
  • A Kinetic model of desorption of hydrogen in $Dy_2Co_7-H$ system has been suggested and rate equation of each step of the model has been compared with experimental results. The reat controlling step was hydrogen recombination in metal surface. The activation energy of over-all reaction was about 23kcal/mole.

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