• Applied Chemistry for Engineering
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• v.32 no.3
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• pp.305-311
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• 2021

Effects of chitosan as a mesopore directing agent of SAPO-34 catalysts were investigated to improve the catalytic lifetime in DTO reaction. The synthesized catalysts were characterized by XRD, SEM, N₂ adsorption-desorption isotherm and NH₃-temperature programmed desorption (TPD). The modified SAPO-34 catalysts prepared by varying the added amount of chitosan showed the same cubic morphology and chabazite structure as the conventional SAPO-34 catalyst. As the added amount of chitosan increased to 3 wt%, the surface area, mesopore volume and concentration of weak acid sites of modified SAPO-34 catalysts increased. The modified SAPO-34 catalysts showed enhanced catalytic lifetime and high selectivity for light olefins in the DTO reaction. In particular, the SAPO-CHI 3 catalyst (3 wt%) exhibited the longest catalytic lifetime than that of the conventional SAPO-34. Therefore, it was confirmed that chitosan was a suitable material as a mesopore directing agent to delay deactivation of the SAPO-34 catalyst.

• Applied Chemistry for Engineering
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• v.26 no.2
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• pp.217-223
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• 2015

Effects of the post-acid treatment of SAPO-34 sample by hydrochloric acid were investigated to enhance the catalytic performance in DTO reaction. Uniformly sized SAPO-34 samples with cubic-like morphology were prepared by hydrothermal method using TEAOH and DEA as the structure directing agents. It was modified in terms of the HCl concentration and treating time. As a result, the total surface area and micropore volume for the well modified samples increased and the total acid site was somewhat decreased along with the erosion of the external surface. Especially, the catalytic lifetime and light olefins selectivity for acid treated SAPO-0.2 M (3 h) samples were considerably enhanced compared with those of untreated SAPO-34 samples. It indicates that the deactivation by coke formation proceeds mainly at the pore entrance on the external surface. Therefore, the acid treatment was confirmed to be a simple method which can significantly improve the catalytic performance by modifying the external surface of SAPO-34 catalyst.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.19 no.5
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• pp.691-697
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• 2010

Reliability-based topology optimization (RBTO) is to get an optimal topology satisfying uncertainties of design variables. In this study, reliability-based topology optimization method is applied to the inner reinforcement of vehicle's hood based on BESO. A multi-objective topology optimization technique was implemented to obtain optimal topology of the inner reinforcement of the hood. considering the static stiffness of bending and torsion as well as natural frequency. Performance measure approach (PMA), which has probabilistic constraints that are formulated in terms of the reliability index, is adopted to evaluate the probabilistic constraints. To evaluate the obtained optimal topology by RBTO, it is compared with that of DTO of the inner reinforcement of the hood. It is found that the more suitable topology is obtained through RBTO than DTO even though the final volume of RBTO is a little bit larger than that of DTO. From the result, multiobjective optimization technique based on the BESO can be applied very effectively in topology optimization for vehicle's hood reinforcement considering the static stiffness of bending and torsion as well as natural frequency.

• Smart Structures and Systems
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• v.11 no.3
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• pp.241-259
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• 2013

This paper presents the optimum load-speed diagram evaluation for a linear micromotor, including multitude cantilever piezoelectric bimorphs, briefly. Each microbeam in the mechanism can be actuated in both axial and flexural modes simultaneously. For this design, we consider quasi-static and linear conditions, and a relatively new numerical method called the smoothed finite element method (S-FEM) is introduced here. For this purpose, after finding an optimum volume fraction for piezoelectric layers through a standard numerical method such as quadratic finite element method, the relevant load-speed curves of the optimized micromotor are examined and compared by deterministic topology optimization (DTO) design. In this regard, to avoid the overly stiff behavior in FEM modeling, a numerical method known as the cell-based smoothed finite element method (CS-FEM, as a branch of S-FEM) is applied for our DTO problem. The topology optimization procedure to find the optimal design is implemented using a solid isotropic material with a penalization (SIMP) approximation and a method of moving asymptotes (MMA) optimizer. Because of the higher efficiency and accuracy of S-FEMs with respect to standard FEMs, the main micromotor characteristics of our final DTO design using a softer CS-FEM are substantially improved.

• Applied Chemistry for Engineering
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• v.26 no.2
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• pp.138-144
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• 2015

Effects of Co/Al and Si/Al molar ratios of cobalt incorporated SAPO-34 catalysts (CoAPSO-34) on their catalytic lifetime were investigated in dimethyl to olefin (DTO) reaction. The property of CoAPSO-34 catalysts was characterized using XRD, SEM, $^{29}Si$ MAS NMR, and $NH_3$-TPD techniques. First, the lifetime of CoAPSO-34 prepared by varying Co/Al molar ratios was improved than that of using the SAPO-34 catalyst, and the optimal Co/Al molar ratio was 0.0025. The total acid site amounts increased from 0.432 to 1.111 mmol/g with increasing Si/Al molar ratios from 0.05 to 0.20 while fixing a Co/Al molar ratio of 0.0025. However, the catalysts with too high acid site amounts were deactivated rapidly with blockages of the pores due to the fast accumulation of polycyclic aromatic hydrocarbons in the cage. Therefore, the CoAPSO-34 catalyst with a proper Si/Al molar ratio of 0.10 was the most superior in terms of the lifetime, which was improved by about 87% as compared with that of the SAPO-34 catalyst.

• Korean Journal of Plant Tissue Culture
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• v.24 no.2
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• pp.71-75
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• 1997

For the establishment of early selection of heat-tolerant clones through in vitro tuberization of true potato seeds, different temperature treatments for in vitro tuberization were investigated. The ratios of tuberization at 2$0^{\circ}C$ on var. Superior and DTO-33 treated with 5 mg/L of BAP and 500 mg/L of CCC, were 85% and 92%, respectively. At 3$0^{\circ}C$, the ratio of tuberization on DTO-33 was 37%, which revealed strongly heat-tolerant clone. In culture system of in vitro tuberization, the number of tubers per flask at 2$0^{\circ}C$ on non-subculture incubation was more than that on subculture incubation. The condition of non-subculture and short-day treatment for 4 weeks was good for production as 10.6 tubers per flask, which was very similar to that of long-day treatment. On the other hand, tuber diameter on long-day treatment was greater as 11.2 mm than on short-day treatment. Therefore, in vitro tuberization from true potato seeds could be induced under the condition of long-day treatment at darkness.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.19 no.2
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• pp.224-229
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• 2010

This paper presents a reliability-based topology optimization (RBTO) using bi-directional evolutionary structural optimization (BESO). An actual design involves uncertain conditions such as material property, operational load and dimensional variation. Deterministic topology optimization (DTO) is obtained without considering of uncertainties related to the uncertainty parameters. However, the RBTO can consider the uncertainty variables because it has the probabilistic constraints. In this paper, the reliability index approach (RIA) is adopted to evaluate the probabilistic constraint. RBTO based on BESO starting from various design domains produces a similar optimal topology each other. Numerical examples are presented to compare the DTO with the RBTO.

• Bulletin of the Korean Chemical Society
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• v.19 no.3
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• pp.340-344
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• 1998

A facile synthesis of 4,5-(1',2'-diphenylethylenedithio)-1,3-dithiole-2-thione (dPhEDT-DTT) is carried out via a Diels-Alder type [2+4] cycloaddition reaction of 1,3-dithiol-2,4,5-trithione oligomer and t-stilbene. Molecular structure of dPhEDT-DTT is determined by x-ray crystallography: space group P1, a=11.694(3) Å, b=12.117(3) Å, c=14.688(3) Å, α=113.12(2)°, β=102.23(2)°, γ=107.02(2)°, V= 1699.1(7) Å3, Z=2. It turns out that dPhEDT-DTT crystallizes as a racemic compound consisting of (R,R) and (S,S) enantiomers. Coupling reaction of dPhEDT-DTO undergone in neat P(OEt)3 yields TTF(SEt)4 instead of ET derivative. When PR3 (R=OEt, OPh, Ph) is used in benzene, toluene or xylene, however, dPhEDT-DTO is decomposed.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.21 no.1
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• pp.102-110
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• 2022

This paper proposes a solution to the problems of manufacturing cost and processability by applying discrete material and thickness optimization (DMTO) and minimizing the use of high-strength, lightweight materials in the optimization process. A simple infant pop-up seat model was selected as the application target, and the weight reduction effect and variation in strength according to the optimization results were observed. In this study, a simplified finite element model of an infant pop-up seat frame was first constructed. The model was used to perform a static structural analysis to verify the weight and strength of each part. The D-optimal design of the experimental method was then used to observe the influence of each part on the weight and strength. This process was applied using discrete thickness optimization (DTO) (which applies high-strength, lightweight materials and optimizes only the thickness) and DMTO (which considers both the material and thickness). The DTO and DMTO results were compared to verify the design method that determines the major parts and simultaneously considers the material and thickness. Accordingly, in this study, an optimal lightweight design that satisfied the strength standards of the seat frame was derived. Furthermore, discretization parameters were used to minimize the application of high-strength, lightweight materials.

• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.20-27
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• 2021

Effects of the etching treatment of SAPO-34 catalyst were investigated to improve the catalytic lifetime in DTO reaction. The aqueous NH3 solution was a more appropriate treatment agent which could control the degree of etching progress, compared to that of using a strong acid (HCl) or alkali (NaOH) solution. Therefore, the effect on characteristics and lifetime of SAPO-34 catalyst was observed using the treatment concentration and time of aqueous NH3 solution as variables. As the treatment concentration or time of aqueous NH3 solution increased, the growth of erosion was proceeded from the center of SAPO-34 crystal plane, and the acid site concentration and strength gradually decreased. Meanwhile, it was found that external surface area and mesopore volume of SAPO-34 catalyst increased at appropriate treatment conditions. When the treatment concentration and time were 0.05 M and 3 h, respectively, the lifetime of the treated SAPO-34 catalyst was the longest, and was significantly enhanced by ca. 36% (based on DME conversion of > 90%) compared to that of using the untreated catalyst. The model for the etching progress of SAPO-34 catalyst in a mild treatment process using aqueous NH3 solution was also proposed.