• 센서학회지
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• 제30권6호
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• pp.384-387
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• 2021

Cyclic voltammetry (CV) is a powerful electrochemical measurement technique that can determine redoxable substances in a solution. The advantage of CV is that we can observe redox behavior over a wide potential range in a short time. Because of its practicality and versatility, CV is used not only in electrochemistry but also in various fields of chemistry, such as inorganic chemistry, organic chemistry, and biochemistry. As technology advances and the popularity of CV grows, the need for trained electrochemists also increases. However, most students do not receive formal training in these technologies as part of their curriculum. There are few concise and accessible resources for learning CV. Therefore, this manuscript provides a brief introduction to cyclic voltammetry to aid readers in collecting and interpreting useful data from cyclic voltammograms.

• 전기화학회지
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• 제16권4호
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• pp.217-224
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• 2013

본 연구에서는 금 나노입자로 전착된 전극위에 3-MPA로 개질된 자가조립 단층 전극의 순환전위법의 특성을 조사하였다. 또한 전극 주변에서 전자와 이온의 이동현상을 해석하였다. 반무한 확산모델을 채택하여, 물질전달 지배계에 대하여 지배방정식과 경계조건을 유도하였다. 자가조립단층 전극에 대한 순환전위법의 수치해를 구하기 위하여, 양함수 유한차분법을 적용하여 MATLAB 프로그램을 작성하여 해를 구현하였다. 자가조립으로 개질된 전극에 대한 본 CV 용 프로그램은 3-MPA으로 개질된 금 나노입자 SAM 전극의 순환전위법 실험결과를 잘 설명하고 있음을 확인할 수 있었다.

• 전기화학회지
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• 제7권1호
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• pp.9-15
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• 2004

Cyclic voltammetry and chronocoulometry have been used for characterization of catechol violet (CV) at the hanging mercury drop electrode in acetic acid-sodium acetate buffer solution. At pH 2.94 a nearly symmetric cyclic voltammetric wave due to an irreversible weak adsorption of CV on mercury was obtained at concentration of $0.53{\mu}mol\;dm ^{-3}$. Under these conditions, CV adsorbes in a monolayer. Upon increasing the concentration, the symmetry of the wave decreases; it can be attributed to a mixed diffusion adsorption process. The amount of the adsorbed catechol violet on the HMDE expressed as surface concentration as well as the surface areaf occupied by one molecule$(\sigma)$ were calculated. It was found that the values obtained for f and o utilizing cyclic voltammetric and chrono-coulometry are almost identical. A 1:1 and 1:2 Th (IV)-CV complexes are formed on addition of thorium (IV) to catechol violet. These complexes are adsorbed and reduced on the HMDE at more negative potentials than the peak potential of free CV, Using the square-wave (SW) technique, the adsorptive cathodic stripping voltammetry, ACSV, of these complexes was studied. It was found that the SW-ACSV of Th(IV)-CV can be applied to the determination of thorium at the nanomole level. Optimum conditions and the analytical method of determination were presented and discussed.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2009년도 하계학술대회 논문집
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• pp.486-486
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• 2009

In this paper, the current-voltage (I-V) curves, such as linear sweep voltammetry (LSV) and cyclic voltammetry (CV), were employed to evaluate the effect of electrolyte concentration on the electrochemical reaction trend. From the I-V curve, the electrochemical states of active, passive, transient and trans-passive could be characterized. And then, we investigated that how this chemical affect the process of voltage-induced material removal in electrochemical mechanical polishing (ECMP) of Copper. The scanning electron microscopy (SEM) and energy dispersive spectroscopy EDS) analyses were used to observe the surface profile. Finally, we monitored the oxidation and reduction process of the Cu surface by the repetition of anodic and cathodic potential from cyclic voltammetry (CV) method in acid- and alkali-based electrolyte. From these analyses, it was important to understand the electrochemical mechanisms of the ECMP technology.

• Journal of Electrochemical Science and Technology
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• 제11권1호
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• pp.14-25
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• 2020

Li ion battery (LIB) is one of the most remarkable energy storage devices currently available in various applications. With a growing demand for high-performance batteries, the role of electrochemical analysis for batteries, especially, electrode reactions are becoming very important and crucial. Among various analytical methods, cyclic voltammetry (CV) is very versatile and widely used in many fields of electrochemistry. Through CV, it is possible to know electrochemical factors affecting the reaction voltage and reversibility, and furthermore, quantitative analysis on Li⁺ diffusivity as well as intercalation and capacitive reactions, and also anionic redox reaction. However, the explanation or interpretation of the results of CV is often deficient or controversial. In this mini-review, we briefly introduce the principle of cyclic voltammetry and its applications in LIB to bring a better understanding of the electrochemical reaction mechanisms involved in LIB.

• 한국응용과학기술학회지
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• 제30권1호
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• pp.139-145
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• 2013

The electrochemical analysis of silver ion was performed using cyclic voltammetry (CV) and square-wave (SW) stripping voltammetry, and electrode cell systems were fabricated with graphite pencil electrode (GE) of working, reference and counter electrodes. Also electrolyte was the use of sea water as electrolyte solutions instead of ionic controlled solutions. The optimum analytical conditions for the cyclic and stripping parameters were determined using GE. The results approached the microgram working ranges of SW(ug/L) and CV(ug/L) Ag, and the optimum conditions were applied to frog's tissue and the food samples.

• 공업화학
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• 제23권5호
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• pp.445-449
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• 2012

고분자 전해질막 연료전지의 대량 생산을 위하여 막-전극 접합체(MEA) 활성화 방법의 개발이 중요한 현안이다. 현재 개발된 MEA활성화 방법은 시간이 많이 소요됨으로 인해 수소의 사용량 또한 증가하여 연료전지의 상용화에 큰 걸림돌이 되고 있다. 통상적인 활성화 방법은 활성화 원리를 주로 전해질 수화 관점에서 이해하였다. 반면, 본 논문에서 제안된 순환전압전류(cyclic voltammetry, CV) 활성화 방법은 전해질 및 촉매적 관점에서 별도로 분리하여 이해하였다. 따라서 전해질 관점에서는 상대 습도 100%인 가습된 질소를 공급하여 전극 및 막의 전해질을 수화시키는 과정으로 구성되고, 촉매적 관점에서는 CV 사이클을 수행하여 백금 촉매에 흡착되어 있는 불필요한 오염물질, 또는 산화피막을 제거하는 과정으로 수행된다. CV 활성화법은 2.5 h 내에 활성화가 종료되어 활성화 시간을 크게 단축시킬 수 있을 뿐만 아니라, 수소 사용량도 기존 활성화 방법에 비하여 1/4 이하로 감소시킬 수 있어서 효과적인 연료전지 활성화 방법으로 제안하고자 한다.

• 방사성폐기물학회지
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• 제18권1호
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• pp.1-18
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• 2020

Molten salt solutions consisting of eutectic LiCl-KCl and concentrations of samarium chloride (0.5 to 3.0 wt%) at 500℃ were analyzed using both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The CV technique gave the average diffusion coefficient for Sm³⁺ over the concentration range. Equipped with Sm³⁺ diffusion coefficient, the Randles-Sevcik equation predicted Sm³⁺ concentration values that agree with the given experimental values. From CV measurements; the anodic, cathodic, and half-peak potentials were identified and subsequently used as a parameter to acquire EIS spectra. A six-element Voigt model was used to model the EIS data in terms of resistance-time constant pairs. The lowest resistances were observed at the half-peak potential with the associated resistance-time constant pairs characterizing the reversible reaction between Sm³⁺ and Sm²⁺. By extrapolation, the Voigt model estimated the polarization resistance and established a polarization resistance-concentration relationship.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.123-123
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• 2008

본 논문에서는 Cu의 ECMP 적용을 위해 $HNO_3$ 전해액의 active, passive, transient, trans-passive 영역을 I-V 특성 곡선을 통해 알아보았고, LSV (Linear sweep voltammetry)와 CV (Cyclic voltammetry)법을 통하여 전기화학적 특성을 비교 분석하였다.

• 대한화학회지
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• 제51권5호
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• pp.412-417
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• 2007

DNA를 고정한 탄소나노튜브 페이스트 전극으로 옥시테트라싸이클린 항생제의 분석조건을 연구하였다. 사각 파형 벗김 전압전류법과 순환 전압 전류법을 사용하여 최적조건에서 1-10 ngL?1의 정량 가능 범위에 도달하였다. 벗김법 0.1 mgL?1 농도에서 15번 반복 측정하여 0.068%의 상대표준편차였으며, 벗김법 최적 분석 조건에서 0.4 ngL?1의 검출 한계를 얻었다. 개발된 결과를 양식어류의 세포에서 응용하였다.