• Title/Summary/Keyword: Corrosion Speed

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A Study on the Damage Suppression of Diesel Engine Cylinder Liners under Vibratory Cavitation (디젤기관 실린더라이너의 진동캐비테이션 손상 억제에 관한 연구)

  • Jeong, Ki-Cheol;Hwang, Jae-Ho;Lim, Uh-Joe
    • Journal of Fisheries and Marine Sciences Education
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    • v.10 no.2
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    • pp.226-238
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    • 1998
  • With the advent of high speed and high output diesel engines, cavitation erosion-corrosion of wet cylinder liners is one of the most prevalent types of failure. The cavitation erosion-corrosion at cylinder liners in water cooled diesel engines is considered to be to the collapse of cavitation bubbles attributed to the cylinder liner vibration. To suppress cavitation damage in cylinder liner, the addition of an inhibitor would be more general method and innovations such as the improvement in the geometric design of the equipment or the selection of suitably resistant construction materials are necessary. In this study, photomicrographs from vibratory facility cavitation specimens and from an eroded liner of a field diesel engine are compared. The behavior of cavitation bubbles grown in fluid is observed under vibration conditions by taking direct photographs with high speed camera. In order to determine the contributions of pure cavitation erosion and of pure corrosion to the total cavitation damage are be studied by following an experimental programme which includes three types of test: (1)pure cavitation erosion test, (2)pure corrosion test, and (1)cavitation erosion-corrosion test. Also cavitation damage under vibratory cavitation is reduced by using flow in tap water.

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Crevice Corrosion Study of Materials for Propulsion Applications in the Marine Environment

  • Deflorian, F.;Rossi, S.;Fedel, M.;Zanella, C.;Ambrosi, D.;Hlede, E.
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.288-295
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    • 2015
  • The present work addresses crevice and galvanic corrosion processes occurring at the cylinder head gasket/cylinder head interface and cylinder head gasket/cylinder liner interface of four-stroke medium-speed diesel engines for marine applications. The contact between these systems and the marine environment can promote formation of demanding corrosion conditions, therefore influencing the lifetime of the engine components. The electrochemical behavior of various metals and alloys used as head gasket materials (both ferrous alloys and copper alloys) was investigated. The efficacy of corrosion inhibitors was determined by comparing electrochemical behavior with and without inhibitors. In particular, crevice corrosion has been investigated by electrochemical tests using an experimental set-up developed starting from the requirements of the ASTM G-192-08, with adaptation of the test to the conditions peculiar to this application. In addition to the crevice corrosion resistance, the possible problems of galvanic coupling, as well as corrosive reactivity, were evaluated using electrochemical tests, such as potentiodynamic measurements. It was possible to quantify, in several cases, the corrosion resistance of the various coupled materials, and in particular the resistance to crevice corrosion, providing a basis for the selection of materials for this specific application.

Effect of Phosphate-based Inhibitors on Pipe Corrosion of Drinking Water Supply (상수도 배급수관망의 부식방지를 위한 인산염계 방청제 적용에 관한 연구)

  • 이윤진;남상호
    • Journal of Environmental Health Sciences
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    • v.29 no.3
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    • pp.65-71
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    • 2003
  • The injection concentration of corrosion inhibitor increases under the pH 7, temperature of 2$0^{\circ}C$, and alkalinity of 35 mg/l (as CaCO$_3$), the corrosion rate gradually decreased. When the corrosion inhibitor of 10 mg/l is injected, the corrosion rate for carbon steel pipe, galvanized steel pipe, and copper pipe reduces for 37, 66 and 61 % respectively that it is more efficient on galvanized steel pipe and copper pipe. As a result of examination of corrosion rate at pH 6, 7, and 8 when injecting 10 mg/l of corrosion inhibitor under the conditions of 2$0^{\circ}C$ in water temperature and 35 mg/l (as CaCO$_3$) in alkalinity, the efficiency of the corrosion inhibitor increases as the pH increases. For carbon steel pipe, it does not show much a difference with the change of the pH condition, but galvanized steel pipe and copper pipe clearly show the corrosion rate depending on the change of the pH condition. The efficiency of corrosion inhibitor is low as the concentration of residual chlorine is high, but it does not show a great influence at 0.4 mg/l or less. For each pipe type, in the case of carbon steel pipe, the range of increase of corrosion speed following the residual chloride is higher than the other pipe types. In the meantime, the effect following the residual chlorine in copper pipe is low.

Study on The Measurement of Corrosion Product Concentration in The Feed Water System of A Power Plant (발전소 급수계통 부식생성물 농도 측정에 관한 연구)

  • Moon, Jeon Soo;Lee, Jae Kun
    • Corrosion Science and Technology
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    • v.10 no.4
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    • pp.151-155
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    • 2011
  • The iron oxide particles could be resulted from the corrosion of the circulating water system of a power plant. Because it may be one of the trouble materials which affect the power generation efficiency due to the deposition on steam generator tube and turbine blade, the continuous observation of its concentration is very important. The laser induced break-down detection (LIBD) technology was applied to monitor continuously the concentration of corrosion products with the detection limit of ppb level. The measurement system consists of a Nd:YAG pulsed laser, a polarizing beam splitter, a flow-type sample cell, an acoustic emission sensor, a high speed data acquisition board, a personal computer, etc.. The performance test results confirmed that this technology can be effective to monitor the corrosion product concentration of the circulating water system of a power plant.

Analysis of activated colloidal crud in advanced and modular reactor under pump coastdown with kinetic corrosion

  • Khurram Mehboob;Yahya A. Al-Zahrani
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4571-4584
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    • 2022
  • The analysis of rapid flow transients in Reactor Coolant Pumps (RCP) is essential for a reactor safety study. An accurate and precise analysis of the RCP coastdown is necessary for the reactor design. The coastdown of RCP affects the coolant temperature and the colloidal crud in the primary coolant. A realistic and kinetic model has been used to investigate the behavior of activated colloidal crud in the primary coolant and steam generator that solves the pump speed analytically. The analytic solution of the non-dimensional flow rate has been determined by the energy ratio β. The kinetic energy of the coolant fluid and the kinetic energy stored in the rotating parts of a pump are two essential parameters in the form of β. Under normal operation, the pump's speed and moment of inertia are constant. However, in a coastdown situation, kinetic damping in the interval has been implemented. A dynamic model ACCP-SMART has been developed for System Integrated Modular and Advanced Reactor (SMART) to investigate the corrosion due to activated colloidal crud. The Fickian diffusion model has been implemented as the reference corrosion model for the constituent component of the primary loop of the SMART reactor. The activated colloidal crud activity in the primary coolant and steam generator of the SMART reactor has been studied for different equilibrium corrosion rates, linear increase in corrosion rate, and dynamic RCP coastdown situation energy ratio b. The coolant specific activity of SMART reactor equilibrium corrosion (4.0 mg s-1) has been found 9.63×10-3 µCi cm-3, 3.53×10-3 µC cm-3, 2.39×10-2 µC cm-3, 8.10×10-3 µC cm-3, 6.77× 10-3 µC cm-3, 4.95×10-4 µC cm-3, 1.19×10-3 µC cm-3, and 7.87×10-4 µC cm-3 for 24Na, 54Mn, 56Mn, 59Fe, 58Co, 60Co, 99Mo, and 51Cr which are 14.95%, 5.48%, 37.08%, 12.57%, 10.51%, 0.77%, 18.50%, and 0.12% respectively. For linear and exponential coastdown with a constant corrosion rate, the total coolant and steam generator activity approaches a higher saturation value than the normal values. The coolant and steam generator activity changes considerably with kinetic corrosion rate, equilibrium corrosion, growth of corrosion rate (ΔC/Δt), and RCP coastdown situations. The effect of the RCP coastdown on the specific activity of the steam generators is smeared by linearly rising corrosion rates, equilibrium corrosion, and rapid coasting down of the RCP. However, the time taken to reach the saturation activity is also influenced by the slope of corrosion rate, coastdown situation, equilibrium corrosion rate, and energy ratio β.

Effect of Solution Temperature on the Cavitation Corrosion Properties of Carbon Steel and its Electrochemical Effect

  • Jeon, J.M.;Yoo, Y.R.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.325-334
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    • 2021
  • In the open system (vessel and pipe), the maximum corrosion rate of carbon steel at ca. 80 ℃ was obtained due to the decrease of dissolved oxygen by increasing the solution temperature. Effect of temperature on the cavitation damage can be explained through several mechanisms. Moreover, when cavitation occurs on the surface of metal and alloys, whether cavitation is erosion or corrosion is still controversial. This work focused on the effect of solution temperature on the corrosion of carbon steel under cavitation in an open system, Tests were performed using an electrochemical cavitation corrosion tester in 3.5% NaCl solution and the effect of solution temperature of carbon steel was discussed. Cavitation corrosion rate can be increased by cavitation, but when the temperature increases, a dissolved oxygen content reduces at a very high speed and thus the maximum cavitation corrosion temperature changed from 80 ℃ to 45 ℃. Below the maximum cavitation temperature, the electrochemical effect was more dominant than the mechanical effect by increasing temperature, but over the maximum cavitation temperature, the mechanical effect was more dominant than the electrochemical effect by increasing temperature.

Effect of Load and Sliding Speed on Corrosive Wear of Metals in Seawater

  • Kawazoe, T.;Ura, A.;Nakashima, A.;Moritaka, H.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.245-246
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    • 2002
  • The objective of this study is to evaluate corrosive wear resistance of metals used for bearings and gears in seawater. Sliding wear test of ferrous and copper materials against $Al_2O_3$ were carried out in artificial seawater using an electrochemical potentiostat. As the results, the wear rate and the coefficient of friction of the copper materials are lower than those of the ferrous materials. The corrosive wear of stainless steel is remarkably affected by normal load and sliding speed in view of tribological characteristics including adhesion and corrosion products.

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Effects of Hardness on Sliding Wear Behavior of Tempered Bearing Steel (베어링강의 미끄럼 마모거동에 미치는 Tempering 경도의 영향)

  • Lee, Han-Young
    • Tribology and Lubricants
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    • v.29 no.6
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    • pp.360-365
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    • 2013
  • In this study, sliding wear tests were conducted to investigate the effects of tempered hardness on the sliding wear behavior of bearing steel. At a sliding speed of 0.3 m/s, the wear resistance of bearing steel with a tempered hardness of HRC 54 was superior to that with HRC 62. It was found that bearing steel with HRC 54 showed a strong tendency for the occurrence of oxidation wear at that speed, compared to that with HRC 62. This would be due to the troostitic structure of bearing steel with HRC 54, which is highly susceptible to corrosion. In this context, it is considered that sliding wear behavior could be affected by the corrosion resistance of the material.

A Study on Flow-Accelerated Corrosion of SA106 Gr.C Weldment (SA106 Gr.C강 용접재에서의 유체가속부식(FAC) 현상 연구)

  • Zheng Yugui
    • Journal of Welding and Joining
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    • v.19 no.3
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    • pp.334-341
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    • 2001
  • The chemical and geometric effects of weld on flow-accelerated corrosion (FAC) of SA106 Gr.C low alloy steel pipe in 3.5wt% NaCl and simulated feedwater of nuclear power plant have been investigated by using rotating cylinder electrode. Polarization test and weight loss test were conducted and compared at rotating speed of 2000rpm (3.14m/s) with the variables of chemical and geometric parameters. The results showed that the chemical effects were relatively larger than the geometric effects, and the welded parts were the local anode and preferentially corroded, which could be explained by the differences between microstructural and compositional parameters. On the other hand, under active corrosion conditions, the heat affected zone were severely corroded and microstructural effects became the important role in the whole process.

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Effect of Hydrodynamic Condition on the Electrochemical Behavior of Various Metals in 3.5 wt% NaCl Solution

  • Pan, Szu-Jung;Hadinata, Samuel-Sudibyo;Kao, Ruey-Chy;Tsai, Wen-Ta
    • Corrosion Science and Technology
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    • v.14 no.5
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    • pp.218-225
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    • 2015
  • The electrochemical behaviors of various metals with and without diamond-like-carbon (DLC) coating in 3.5 wt% NaCl solution were investigated. The effect of hydrodynamic conditions was focused by employing a rotating disc electrode (RDE). The experimental results showed that each bare metal had a more positive corrosion potential and a higher corrosion rate due to enhanced oxygen transport at the higher rotating speed of the RDE. DLC coating caused a substantial increase in the corrosion resistance of all metals studied. However, localized corrosion was still found in the DLC-coated metal at sites where deposition defects existed. Surface morphology examination was performed after the electrochemical test to confirm the roles of hydrodynamic conditions and DLC coating.