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Synthesis and Spark-plasma Sinetring of Nanoscale Al/alumina Powder by Wire Electric Explosion Process

  • Kim, Ji-Soon;Kim, H. T.;Illyin, A. P.;Kwon, Young-Soon
    • Journal of Powder Materials
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    • v.12 no.5 s.52
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    • pp.351-356
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    • 2005
  • Nanoscale Al powder with thin layer of alumina was produced by Wire Electric Explosion (WEE) process. Spark-Plasma Sintering (SPS) was performed for the produced powder to confirm the effectiveness of SPS like so-called 'surface-cleaning effect' and so on. Crystallite size and alumina content of produced powder varied with the ratio of input energy to sublimation energy of Al wire ($e/e_s$): Increase in ($e/e_s$) resulted in the decrease of crystallite size and the increase of alumina content. Shrinkage curve during SPS process showed that the oxide surface layer could not be destroyed near the melting point of Al. It implied that there was not enough or no spark-plasma effect during SPS for Al/Alumina powder.

Dissolution of Chlorpheniramine Mallate (CMP) from Sustained-Release Tablets Containing CPM in the Coated Film Layer (핵정(核鐘)에 코팅된 필름층 중에 함유되어 있는 말레인산클로르페니라민의 방출특성)

  • Yu, Jei-Man;Shim, Chang-Koo;Lee, Min-Hwa;Kim, Shin-Keun
    • Journal of Pharmaceutical Investigation
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    • v.20 no.2
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    • pp.89-95
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    • 1990
  • Ethylcellulose-PEG 4000 film coated on core tablets was investigated as a potential drug delivery system for the controlled release of chlorpheniramine maleate (CPM). The kinetic analysis of the release data indicated that CPM release followed a diffusion-controlled model, where the quantity released per unit area is proportional to the square root of time. The effect of the film composition, CPM concentration, plasticizer concentration and CPM solubility on the release characteristics were examined. The release rate constant increased as CPM concentration increased. It also increased as the PEG 4000 content in the film increased above 10%(w/w), however, it decreased as the PEG 4000 content increased in the concentration range below 10%(w/w). The release rate constant was not affected by the coated weight on the core tablet. The film-coated tablets which contain CPM only in the coated film layer seemed to be a potential oral drug delivery system for the controlled release of CPM.

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Study on the Accumulation of Iron and Manganese in Relation to the Morphological Characteristics of Paddy Soils (답토양(沓土壤)의 형태적(形態的) 특징(特徵)에 따른 철(鐵) 및 망간의 이동집적(移動集積)에 관(關)한 연구(硏究))

  • Shin, C.S.
    • Applied Biological Chemistry
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    • v.18 no.3
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    • pp.123-144
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    • 1975
  • This study has been carried out to investigate the translocation-illuviation status of iron and manganese, which are striking phenomena in paddy soils, in relation to its morphological characteristics, and to find out a method to identify illuvial layer of iron quantitatively. Determination of active iron and easily reducible manganese content in surface soils of lowland paddy (266 samples) in Korea were conducted. The examination has been made on relationship between morphological, physico-chemical properties of the representative paddy soils (9 series) and iron and manganese content of their horizons. The results are summarized as follows. 1. The poorer the drainage, the higher concentration of active iron and easily reducible manganese were found, and under same drainage condition, the more the sand, the lower the content of them. 2. Irrespective of soil texture and drainage, highly signignificant positive correlation was found between the contents of active iron ($\hat{Y}$) and clay plus silt in surface soils. $$\hat{Y}=0.3929+(0.05352\;X\;clay%)+(0.0001023\;X\;silt%){\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;I$$ No correlation, however, was found between clay content and easily reducible manganese concentration. 3. Significant positive correlation was obtained between active iron ($\hat{Y}$) and total iron (x) content in each profiles of all soil series. Obtained regression equation is as follows; $$\hat{Y}=0.361x-0.480(r=0.651^{**}){\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;{\ldots}\;II$$ On the other hand, easily reducible manganese concentration had a tendency to increase, not significantly, with increasing total manganese concentration. 4. Accumulation of iron and manganese generally can be found in paddy soils, but distinct accumulation was found under moderately well drained fine loamy and clay soils, while surface accumulation occurred under poor drainage without regard to soil texture. 5. Profile description or determination of active iron in each horizon were found to be insufficient to designate illuvial layer of iron. Therefore, identification of illuvial layer of iron based on the ratio of total iron and active iron, and concentration of active iron estimated by the content of clay plus silt (Equation 1 above) was thought to be reasonable. Also, manganese accumulation layer would be estimated by total manganese and easily reducible manganese content and their ratio.

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The constituents of Korean cannabis (한국산대마의 성분에 대한 연구)

  • 이창기
    • YAKHAK HOEJI
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    • v.17 no.1
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    • pp.21-26
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    • 1973
  • The constituents of Korean cannabis were studied comparatively with foreign orgins. Especially, tetrahydrocannabinol(THC), the active constituents of cannabis were analyzed by the technique of thin layer chromatography and colorimetry. The results are as follows ; (1) THC content in Korean cannabis is comparatively higher than that in foreign samples. (2) THC is contained most abundantly in male flowers, abundantly in female tops and leaves and some in barks. (3) There is a tendency that the THC content increase gradually with growth of plants, being highest during unripe nad decrease with maturity of the tops. (4) Korean cannabis contains THC, cannabinol, cannabidiol, cannabidiolic acid and other cannandiolic compounds. Distribution of chemical components of Korean cannabis, compared with those of foreign ones, is remarkably different. (5) The THC content of Spanish cannabis cultivated tentatively in Korea is similar to that of Korean cannabis.

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Effects of Ga contents on the performance of CIGS thin film solar cells fabricated by co-evaporation technique (Ga 조성이 동시진공 증발법으로 제조된 CIGS 태양전지 특성에 미치는 영향)

  • Jung, Sung-Hun;Yun, Jae-Ho;Ahn, Se-Jin;Yoon, Kyung-Hoon;Kim, Dong-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.438-440
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    • 2008
  • Effects of Ga contents of CIGS absorber layer on the performance of thin films solar cells were investigated. As Ga content increased, the grain size of CIGS films decreased presumably because Ga diffusion during 2nd stage of co-evaporation process is more difficult than In diffusion. Performances of corresponding solar cell show systematic dependence on Ga content in which open circuit voltage increases and short circuit current and fill factor decrease as Ga contents increases. At a optimal condition of Ga/(In+Ga)=0.27, the solar cell shows a conversion efficiency of 15.6% with $V_{OC}$ of 0.625 V, $J_{SC}$ of 35.03 mA/$cm^2$ and FF of 71.3%.

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Electrical Contact Characteristics of Ag-SnO2 Materials with Increased SnO2 Content

  • Chen, Pengyu;Liu, Wei;Wang, Yaping
    • Journal of Electrical Engineering and Technology
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    • v.12 no.6
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    • pp.2348-2352
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    • 2017
  • The electrical contact characteristics including temperature rise, contact resistance and arc erosion rate of the $Ag-SnO_2$ materials with increased $SnO_2$ content were investigated during the repeated make-and-break operations. The thickness of arcing melting layer reduces by half and the arc erosion rate decreases more than 70% under 10000 times operations at AC 10 A with the $SnO_2$ content increasing from 15 wt.% to 45 wt.%, on one hand, temperature rise and contact resistance increase obviously but could be reduced to the same order of conventional $Ag-SnO_2$ materials by increasing the contact force. The microstructure evolution and the effect of $SnO_2$ on the arc erosion, contact resistance were analyzed.

Dielectric properties of $Bi_{3.25}La_{0.75}Ti_3O_{12}$ thin films with Bi contents (Bi 첨가량에 따른 BLT 박막의 유전특성)

  • 김경태;김창일;강동희;심일운
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.371-374
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    • 2002
  • Bismuth lanthanum titanate thin films with excess Bi contents were prepared onto Pt/Ti/$SiO_2$/Si substrate by metalorganic decomposition (MOD) technique. The structure and morphology of the films were analyzed using X-ray diffraction (XRD) and atomic force microscopy (AFM), respectively. From the XRD analysis, BLT thin films show polycrystalline structure and the layered-perovskite phase was obtained over 10% excess of Bi contents. As a result of ferroelectric characteristics related to the Bi content of the BLT thin film, the remanent polarization and dielectric constant decreased with increasing over Bi content of 10 % excess. The BLT film with Bi content of 10% excess was measured to have a dielectric constant of n9 and dielectric loss of 1.85[%]. The BLT thin films showed little polarization fatigue test up to 3.5 x $10^{9}$ bipolar switching cycling.

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Structural properties of the epoxy resin which adds the Nanofiller (Nanofiller를 첨가한 에폭시 수지의 구조적 특성)

  • Lee, Chang-Gong;Lee, Sung-Gap;Ahn, Byeong-Lib;Won, Woo-Sik;Woo, Hyoung-Gwan;Noh, Hyun-Ji
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1234-1235
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    • 2008
  • To add Nanofiller in the epoxy which is used with the solid insulation material of existing and is a research which observes the improvement of the structural quality to produce the Nanocomposite. Montmorillonite uses with Nanofiller, MMT of the content expense (wt%) which is various and mixed an epoxide and produced sample. According to content of the sample result MMT according to respectively content expense to measure SEM photographing which is the possibility of knowing the minute structure of section with sample where is produced and the tensile strength will be able to observe the change of quality. MMT silicate layer uniformly more in the result and within epoxy matrix, being dispersed, will be able to observe.

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Effects of Microstructure and Surface Oil Film on the Welding in Zr Electroplated steel (전기아연도금 강에서 미세조직 및 표면유막이 용접 spatter에 미치는 영향)

  • 최한철;최수찬;김광연;안덕수;김영우
    • Journal of Surface Science and Engineering
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    • v.30 no.1
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    • pp.13-22
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    • 1997
  • In order to investigate the effects of microstructure Oil film on the welding spatter in Zn electroplated steel, Zn electroplated surface and layer structure with USS-Paddition was observed using XRD, XPS and optical microscopy. Wettability of water drop on the Zn electroplated steel surface was measured using Z.Mei model. Oil absorption test was carried out using Oil pen. Morphology of spot welding and spatter with USS-P addition, applied current, and oil-spray or oil-without was observed using SEM and optical microscopy. Surface morphology of Zn electroplated steel showed finer structure as USS-P content increased. Wettabiliy on the Zn electroplated surface decreased with increasing USS-P content. Size of welding trace increased and spatter occured arround the welding part as applied current increased, whereas spatter disappeared as USS-P content increased and disappeared in case of oil spraying on the Zn electroplated surface.

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Study on tensile performance change by recycled materials of TPO sheet applied to rooftop and artificial ground Rootproofings (옥상 및 인공지반 방근공사에 적용되는 TPO시트의 재생 소재 적용에 따른 인장성능 변화 연구)

  • Kim, Sun-Do;Kim, Jin-Sung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.103-104
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    • 2018
  • Recently, in addition to greening of roof and artificial soil, Rootproofing to prevent damage to the waterproof layer and structures by roots is recognized as an important task. Therefore, various related products and construction methods have been developed and applied in the field. However, in the case of synthetic polymer-based sheets most commonly used in domestic construction sites, Most are produced using 100% new materials that are not suitable for green trends such as resource conservation and environmental protection. Therefore, in this study, we developed TPO sheet using recycled material, which is a technology that can secure eco-friendliness by utilizing recycled resources. As a result of the evaluation of tensile performance of the TPO sheet according to the recycled material content, The tensile strength of the specimens with the recycled content of 50 ~ 70% was the highest, The elongation rate of the specimen with the recycled content of 30 ~ 40% was the best.

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