• Title/Summary/Keyword: Contamination process

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Evaluation of Groundwater Quality in Crystalline Bedrock Site for Disposal of Radioactive Waste (방사성폐기물 처분을 위한 결정질 기반암의 지하수 수질 평가)

  • Lee, Jeong-Hwan;Jung, Haeryong;Cheong, Jae-Yeol;Park, Joo-Wan;Yun, Si-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.4
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    • pp.275-286
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    • 2014
  • This study evaluated the evolution stage and origin of chemical components of 12 boreholes at crystalline bedrock using multivariate statistical and groundwater quality analyses. Groundwater types are mostly belonged to Na(Ca)-$HCO_3$ and Ca-$HCO_3$ types, indicating that directly reaction of cation exchange ($Ca^{2+}{\rightarrow}Na^+$) prevailed. The degree of groundwater evolution is included the range from low to intermediate stage based on field and laboratory analytical conditions. As a result of multivariate statistical analysis, a typical indicator of groundwater contamination, $NO_3$-, has the positive correlation with $Na^+$ and $Cl^-$. The origin of sea spary ($Cl^-$) has the positive correlation with $Na^+$, $SO{_4}^{2-}$, $Mg^{2+}$, and $K^+$, while not correlation with $Ca^{2+}$, $Fe^{2+}$, $HCO_3{^-}$, $F^-$, and $SiO_2$. The concentration of $Cl^-$ and $NO_3{^-}$ belongs to general quality of groundwater and not exceeds over the Korean standard for drinking water. And the negative values of saturation index of minerals are calculated with chemical components in groundwater. Therefore, most of chemical components of groundwater in the study area are originated from natural process between rock and groundwater, whereas some of components are derived from sea spary and anthropogenic sources related to agricultural activities.

Classification of Metal Scraps Using Laser Induced Breakdown Spectroscopy (레이저유도붕괴분광법을 이용한 폐금속 분류)

  • Shin, Sungho;Lee, Jaepil;Moon, Youngmin;Choi, Jang-Hee;Jeong, Sungho
    • Resources Recycling
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    • v.27 no.1
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    • pp.31-37
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    • 2018
  • To enhance the recycling rate of used metal resources, it is strongly desired to develop a metal sorting system that can automatically identify metal type from mixed metal scraps and sort them separately. Laser-induced breakdown spectroscopy(LIBS) is a technique that enables real time classification of different metals based on multi-elemental and in-air analysis. In this work, we report the results of LIBS elemental analysis of field scrap samples acquired from a recycling company. By applying multivariate analysis, it was found that the LIBS signals of five different metals could be perfectly classified if surface contamination was removed. The classification accuracy degraded for LIBS signals including contaminant emission, which however could be overcome by performing the multivariate analysis using properly selected emission lines of higher correlation only. The significant improvement in classification accuracy and process speed by the selection of proper emission lines demonstrated the feasibility of LIBS technique as an industrial tool for metal scrap sorting.

Applicability of SRSL(Self-Recovering Sustainable Liner) to the Landfill Final Cover System (SRSL(Self Recovering Sustainable Liner)재의 매립지 최종복토층에 대한 활용성 검토)

  • Kwon, Oh-Jung;Seo, Min-Woo;Hong, Soo-Jung;Park, Jun-Boum;Park, Soo-Young
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.453-460
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    • 2004
  • To prevent penetration of rainwater into the landfill site is the main purpose of the final cover in landfill sites. Conventional designs of landfill covers uses geotextiles such as geomembrane and GCL, and clay liners to lower the permeability of final covers of landfill sites. However, differential settlement and the variation of temperature in landfill sites cause the development of cracks or structural damage inside the final cover and it is also difficult to obtain clay - the main material of the compacted clay liner in Korea. Thus the former final cover system that suggests geomembrane and GCL or compacted clay liner has several limitations. Therefore, an alternative method is necessary and one of them is the application of SRSL(self-Recovering Sustainable Liner) material. SRSL is two different layers consist of individual materials that react with each other and form precipitates, and with this process lowers the permeability of the landfill final cover. SRSL generally is made up of two layers, so that when a internal crack occurs the reactants of the two layers migrate towards the crack and heal it by forming another liner. In this study the applicability of SRSL material for landfill final cover was examined by performing; (1) jar test to verify the formation of precipitate in the mixture of each reactants, (2) falling head test considering the field stress in order to confirm the decrease of permeability or prove that the hydraulic condctivity is lower than the regulations, (3) compression tests to judge weather if the strength satisfies the restricts for landfills, (4) freeze/thaw test to check the applicability of SRSL for domestic climate. In addition, the application of waste materials in the environmental and economical aspect was inspected, and finally the possibility of secondary contamination due to the waste materials was examined by performing elution tests.

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Application of Au-Sn Eutectic Bonding in Hermetic Rf MEMS Wafer Level Packaging (Au-Sn 공정 접합을 이용한 RF MEMS 소자의 Hermetic 웨이퍼 레벨 패키징)

  • Wang Qian;Kim Woonbae;Choa Sung-Hoon;Jung Kyudong;Hwang Junsik;Lee Moonchul;Moon Changyoul;Song Insang
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.3 s.36
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    • pp.197-205
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    • 2005
  • Development of the packaging is one of the critical issues for commercialization of the RF-MEMS devices. RF MEMS package should be designed to have small size, hermetic protection, good RF performance and high reliability. In addition, packaging should be conducted at sufficiently low temperature. In this paper, a low temperature hermetic wafer level packaging scheme for the RF-MEMS devices is presented. For hermetic sealing, Au-Sn eutectic bonding technology at the temperature below $300{\times}C$ is used. Au-Sn multilayer metallization with a square loop of $70{\mu}m$ in width is performed. The electrical feed-through is achieved by the vertical through-hole via filled with electroplated Cu. The size of the MEMS Package is $1mm\times1mm\times700{\mu}m$. By applying $O_2$ plasma ashing and fabrication process optimization, we can achieve the void-free structure within the bonding interface as well as via hole. The shear strength and hermeticity of the package satisfy the requirements of MIL-STD-883F. Any organic gases or contamination are not observed inside the package. The total insertion loss for the packaging is 0.075 dB at 2 GHz. Furthermore, the robustness of the package is demonstrated by observing no performance degradation and physical damage of the package after several reliability tests.

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Ion Exchange Phenomena of $Cs^{+1},\;Sr^{+2},\;and\;Th^{+4}$ on Ion Exchange Resin in Loading and Elution Process ($Cs^{+1},\;Sr^{+2}$$Th^{+4}$가 동시에 이온교환수지에 흡착 및 탈착시의 이온교환현상)

  • Park, Chong-M.;Walter, Meyer
    • Journal of Radiation Protection and Research
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    • v.11 no.2
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    • pp.104-113
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    • 1986
  • The ion exchange behaviour of the $Cs^{+1},\;Sr^{+2},\;and\;Th^{+4}$ in the system of $Cs^{+1},\;Sr^{+2},\;Th^{+4},\;and\;7Cl^{-}-H^{+}$ from Dowex HCR-W2, was examined in the loading and elution processes. $Th^{+4}$ was slowly adsorbed through the entire contact time between resin and solution and $Cs^{+1}\;and\;Sr^{2+}$ were adsorbed fast for the first few minutes of contact time. Because of the strong affinity of $Th^{+4}$, the longer contact time was allowed, the less amount of $Cs^{+1}\;and\;Sr^{2+}$ was adsorbed on the resin. The peak concentration of the resin phase $Cs^{+1}$ in the solution concentration of $Cs^{+1}:Sr^{+2}:Th^{+4}$ in the ratio of 2 : 2 : 1 in normality with total normality of 0.1N was produced at about 4 minutes of contact time and the peak time for $Sr^{+2}$ was 20 minutes. The loaded ions were eluted using hydrochloric acid. The loaded $Cs^{+1}$ was eluted at the low eluent concentration of less than 0.1N with less than 5% contamination of $Sr^{+2}$. The loaded $Th^{+4}$ was eluted at the high eluent concentration of greater than 1N. The best eluent concentration for eluting $Th^{+4}$ was 4N.

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Determination of Self-Disposal date by the Analysis of Radioactive Waste Contamination for 1131I Therapy Ward (131I 치료입원실 폐기물 방사능 오염도 분석 및 자체처분가능일자 산출)

  • Kim, Gi-sub;Jung, Haijo;Park, Min-seok;Jeon, Gjin-seong
    • The Korean Journal of Nuclear Medicine Technology
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    • v.17 no.1
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    • pp.3-6
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    • 2013
  • Purpose: The treatment of thyroid cancer patients was continuously increased. According to the increment of thyroid cancer patients, the establishment of iodine therapy site was also increased in each hospital. This treatment involves the administration of radioactive iodine, which will be given in the form of a capsule. Therefore, protections and managements for radioactive source pollution and radiation exposure should be necessary for radiation safety. Among the many problems, the problem of disposing the radioactive wastes was occurred. In this study, The date for self-disposal for radioactive wastes, which were contaminated in clothes, bedclothes and trash, were calculated. Materials and Methods: The number of iodine therapy ward was 15 in Korea Institute of Radiological Medical and Sciences. Recently, 8 therapy wards were operated for iodine therapy patients and others were on standby for emergency treatment ward of any radiation accidents. Radioactive wastes, which were occurred in therapy ward, were clothes, bedclothes, bath cover for patients washing water and food and drink which was leftover by patients. Each sample was hold into the marinelli beaker (clothes, bedclothes, bath covers) and 90 ml beaker (food, drink, and washing water). The activities of collected samples were measured by HpGe MCA device (Multi Channel Analysis, CANBERRA, USA) Results: The storage period for the each kind of radioactive wastes was calculated by equation of storage periods based on the measurement outcomes. The average storage period was 60 days for the case of clothes, and the maximum storage period was 93 days for patient bottoms. The average storage period and the maximum storage period for the trash were 69 days and 97 days, respectively. The leftover foods and drinks had short storage period (the average storage period was 25 days and maximum storage period was 39 days), compared with other wastes. Conclusion: The proper storage period for disposing the radioactive waste (clothes, bedclothes and bath cover) was 100 days by the regulation on self-disposal of radioactive waste. In addition, the storage period for disposing the liquid radioactive waste was 120 days. The current regulation for radioactive waste self-disposing was not suitable for the circumstances of each radioactive therapy facility. Therefore, it was necessary to reduce the leftover food and drinks by adequate table setting for patients, and improve the process and regulation for disposing the short-half life radioactive wastes.

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Study on the Drying Method of Velvet Antler using Microwave Oven (전자레인지를 이용한 녹용의 건조방법)

  • 성시흥
    • Journal of Animal Environmental Science
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    • v.8 no.3
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    • pp.177-182
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    • 2002
  • Drying process is very important for commercialization of velvet antlers. So far, artificial drying has mostly depended on experience of farmers resulting in low efficiency of drying, deterioration during drying, and contamination by dust and bacteria. Various drying techniques for high-quality production have currently been commercialized in some developed countries, and one of them is a drying technique using microwave. In this study, application of the technique using an electronic (microwave) oven for drying of velvet antler was investigated. The results of this study are as follows. 1. It was found that the drying period was significantly affected by cornification of velvet antlers. Accordingly, it can be assumed that the velvet antlers should partly be sliced to save drying period and required drying energy. 2. It was also found that the drying speed was changeable according to tempering period and even with same drying period. The tempering period should be controlled according to processing rate. 3. The results indicated that a repeated drying of 2-min drying and 3-min tempering is the most effective when a microwave oven was used. 4. The results also showed that the drying technique using microwave of electronic oven can be effectively used for drying of velvet antlers. 5. Only drying and tempering periods were examined in this study, however, ingredient change of deer antler after drying is necessary to be investigated in the future.

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Introduction of Clean Techniques for Trace Metal Analysis in Seawater (해수 중의 미량금속 분석을 위한 청결기술의 소개)

  • Kim, Kyung-Tae;Kim, Eun-Soo;Ra, Kong-Tae;Moon, Deok-Soo;Kim, Hyeon-Ju
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.15 no.2
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    • pp.157-164
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    • 2009
  • The metals such as Al, Ag, Au, Cu, Cd, Co, Fe, Ni, Pb, Zn, etc are present at very low concentration in seawater and are classified as so-called trace metals. Whiles some of them are used in metabolism of living organism as a micronutrient, they may show toxic effects on organisms in case of a limited threshold concentration of them Plenty of studies on trace metals have been performed bemuse trace metals have a persistent influence and an adverse effect on marine environment and ecosystem. For long years, when the concentration of trace metals in natural waters such as seawater and fresh water are measured with high precision and accuracy, some systematic errors have been recognized to be present in measurements. Since 1975 in US and European countries, the measured concentration of trace metals in seawater have been found to be lower by factors of 10-1,000 than the previous data of trace metals measurements and the vertical profiles of the measurements have been shown to reflect well-known biological, physical and geochemical processes. These results are attributed to great advances in analytical instrumentation and methodology for trace metals measurements. Precautions against the contamination of samples are required to be taken in the process of sampling, storage, and analysis of samples. However, in Korea, erroneous data of trace metals with regard to ocean and marine environment related survey and investigations are reported The lock of exact understanding and information regarding precautions in sampling, storage and analysis of samples lead to the deterioration of data quality, especially in the analysis of trace metals. The major procedures to obtain the accurate data of trace metals in natural waters are introduced for applying to the study and assessment of marine environments.

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The Effect of Column Process on the Treatment of Municipal Solid Waste Leachate (Column 장치를 이용한 도시쓰레기 침출수의 처리효과)

  • Han, Mun-Gyu;Cho, Ju-Sik;Lee, Hong-Jae;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.11 no.3
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    • pp.201-208
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    • 1992
  • Municipal landfill leachate, a major source of soil contamination and ground water pollution, causes serious environmental problems. To investigate the removal efficiency of pollutants in the leachate by sand, briquet ash, fly ash, and activated carbon columns, COD and some pollutants in the leachate passed through each column for 8 weeks were examined. Average COD removal efficiency for 8 weeks was 83%, 45%, and 43% by activated carbon, briquet ash and fly ash columns, respectively. COD was not effectively reduced by sand column. Average ${NH_4}\;^+$ removal efficiency for 8 weeks was more than 60% by ail columns. Hardness was effectively removed for 8 weeks by fly ash and activated carbon columns. Anoins including $PO_4\;^{3-}$, $CI^-$ and $SO_4^{2-}$ were not removed by all columns.

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Comparison of Pollination Efficiency on Different Pollination Methods in Yellow poplar (Liriodendron tulipifera) (백합나무의 인공교배 방법에 따른 교배 효율성 비교)

  • Ryu, Keun-Ok;Kwon, Hae-Yun;Choi, Hyung-Soon;Kim, In-Sik;Cho, Do-Hyun
    • Journal of Korean Society of Forest Science
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    • v.98 no.6
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    • pp.696-702
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    • 2009
  • Yellow poplar (Liriodendron tulipifera L.) is an insect-pollinated tree species with large, perfect flower, and its seed sets average only about 10 percent naturally. In its controlled pollination, pollination bags are usually taken to prevent unwanted pollination, but bagging is an expensive and time-consuming process. Therefore, this study was conducted to determine the need of pollination bag by estimating how much unintended pollination would occur when different cross methods were applied. Five different pollination methods were applied as follows: 1) natural open pollination (i.e. insect pollination) as a reference, 2) self-pollination; no removing reproductive organs with bagging, 3) open pollination; emasculated(removing sepal, petal and stamen) without bagging, 4) controlled pollination; emasculated with bagging and 5) controlled pollination; emasculated without bagging. Very low value of full seed rate (0.2%) was observed in method 3, it was suggested that removing stamen and petal restrict the activity of pollen vectors like bee. Difference in the full seed rate between method 4 and method 5 was not significant (27.9% versus 24.0%, respectively). Consequently, controlled pollination without bagging might be an alternative method for extensive breeding and mass production of seeds in yellow poplar.