• Title/Summary/Keyword: Contact state

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Study on Conversion of Carbon Dioxide to Methyl Alcohol over Ceramic Monolith Supported CuO and ZnO Catalysts (세라믹 모노리스에 담지된 CuO와 ZnO계 촉매에 의한 이산화탄소의 메탄올로의 전환에 관한 연구)

  • Park, Chul-Min;Ahn, Won-Ju;Jo, Woong-Kyu;Song, Jin-Hun;Kim, Ki-Joong;Jeong, Woon-Jo;Sohn, Bo-Kyun;Ahn, Byeong Kwon;Chung, Min-Chul;Park, Kwon-Pil;Ahn, Ho-Geun
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.1
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    • pp.97-104
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    • 2013
  • Methyl alcohol is one of the basic intermediates in the chemical industry and is also being used as a fuel additive and as a clean burning fuel. In this study, conversion of carbon dioxide to methyl alcohol was investigated using catalytic chemical methods. Ceramic monoliths (M) with $400cell/in^2$ were used as catalyst supports. Monolith-supported CuO-ZnO catalysts were prepared by wash-coat method. The prepared catalysts were characterized by using ICP analysis, TEM images and XRD patterns. The catalytic activity for carbon dioxide hydrogenation to methyl alcohol was investigated using a flow-type reactor under various reaction temperature, pressure and contact time. In the preparation of monolith-supported CuO-ZnO catalysts by wash-coat method, proper concentration of precursors solution was 25.7% (w/v). The mixed crystal of CuO and ZnO was well supported on monolith. And it was known that more CuO component may be supported than ZnO component. Conversion of carbon dioxide was increased with increasing reaction temperature, but methyl alcohol selectivity was decreased. Optimum reaction temperature was about $250^{\circ}C$ under 20 atm because of the reverse water gas shift reaction. Maximum yield of methyl alcohol over CuO-ZnO/M catalyst was 5.1 mol% at $250^{\circ}C$ and 20 atm.

The Effects of functional foot orthotics on the balance according to Foot Shape (기능성 발보조기의 족부형태별 균형유지에 미치는 영향)

  • Chai, S.W.;Park, K.Y.;Kim, Y.S.
    • Journal of rehabilitation welfare engineering & assistive technology
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    • v.5 no.1
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    • pp.47-52
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    • 2011
  • The functional loot orthoses, when wearing shoes, are in the direct contact with bottom of foots to improve and recover the correctness of abnormal lower limb musculoskeletal imbalance and the primary role of foot and also, it can act to keep the balance and weight of body and support the weakened region, so that it is very helpful to keep body balance for the standing position. In this paper, it was researched that foot orthoses which is accommodable for the function of impact absorption including the gait stability affect on the balanced performances of body in according to the formation and the material of foot part. Taking into account the balanced performances by using the sway velocity, the estimation and comparison of the effects on the balanced performances by each formation and material for foot orthoses was evaluated into significant values(p<0.006) in only the eye-opening posture with Firm state, In this posture, the static process performed by each foot formation reveals in order of normal foot(p<0.010), flat foot(p<0.000) and hollow foot(p<0.003) and then, on the base of each formation of foot part, the result that analyze the effects of the materials of foot orthoses on the balance performance appeared showing that soft materials is more effective on the normal foot and, on the other hand, rigid materials is more effective in balancing on flat foot and hollow foot.

Autohesion Behavior of Brominated-Isobutylene-Isoprene Gum Nanocomposites with Layered Clay (층상점토 충전 브롬화 이소부틸-이소프렌 검 나노복합체의 점착거동)

  • Mensah, Bismark;Kim, Sungjin;Lee, Dae Hak;Kim, Han Gil;Oh, Jong Gab;Nah, Changwoon
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.43-52
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    • 2014
  • The effect of nanoclay (Cloisite 20A) on the self-adhesion behavior of uncured brominated-isobutylene-isoprene rubber (BIIR) has been studied. The dispersion state of nanoclay into the rubber matrix was examined by SEM, TEM and XRD analysis. The thermal degradation behavior of the filled and unfilled samples was examined by TGA and improvement in the thermal stability of the nanocomposites occurred based on the weight loss (%) measurements. Also, addition of nanoclay enhanced the cohesive strength of the material by reinforcement action thereby reducing the degree of molecular diffusion across the interface of butyl rubber. However, the average depth of penetration of the inter-diffused chains was still adequate to form entanglement on either side of the interface, and thus offered greater resistance to peeling, resulting in high tack strength measurements. The improvement in tack strength was only achieved at critical nanoclay loading above 8 phr. Contact angle measurement was also made to examine the surface characteristics. There was no significant interfacial property change by employing the nanoclay.

A Study on Nitrification of Raw Waters Containing Linear Alkyl Sulfate in Biological Activated Carbon (생물활성탄을 이용한 Linear Alkyl Sulfate함유 원수에서의 질산화에 관한 연구)

  • Park, Seong Sun;Chang, Ji Soo;Yu, Myong Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.3
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    • pp.116-126
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    • 1995
  • The purpose of this study was to investigate the removal of ammonium nitrogen by biological nitrification in raw water containing LAS using BAC. At batch teats, LAS removal by ozone followed the first order reaction, and the rate constants(k) by ozone dose 1, 3mg/min.L were $0.040min^{-1}$, $0.062min^{-1}$ respectively. Therefore, the more ozone was dosed, the higher LAS was removed The reaction between ozone and ammonium nitrogen also followed the first order, and rate constants(k) at pH7,8 and 9 were $8.9{\times}10^{-4}min-1$, $3.8{\times}10^{-3}min^{-1}$, and $2.9{\times}10^{-2}min^{-1}$ respectively at ozone dose of 3mg/min.L . Therefore, ammonium nitrogen was little removed by ozone under neutral pH of 7. The continuous flow apparatus had four sets composed of a ozone contacter and a GAC column. Through continuous filtration test for 50days, the following conclusions were derived; (1) LAS was removed 23%, 30% respectively by ozone dose 1, 3mg/L, and was not detected in all column effluents during the period of experiment. Therefore, it appeared that adsorption capacities of each column still remained. (2) Ammonium nitrogen concentration after ozone contact varied little in raw Water because pH of raw water was from 6 to 7, and was transfered to nitrite and nitrate within GAC columns as the result of staged nitrification. After 30days, nitrite was not detected in all column effluents due to biological equilbrium between nitro semonas and nitrobacter Average removals of ammonium nitrogen in each column after the lapse of 30days were the following; ${\cdot}$ column A (ozone dose 3mg/L, EBCT 9.5min): about 100% ${\cdot}$ column B (ozone dose 1mg/L, EBCT 9.5min): 91% ${\cdot}$ column C (ozone dose 3mg/L, EBCT 14.2min): about 100% ${\cdot}$ column D (ozone dose 0mg/L, EBCT 9.5min): 53% Though column A and C reached nitrification of about 100%, column C (longer EBCT than column A) was more stable than column A. (3) After backwash, nitrification reached steady state within 5 to 8 hours. Therefore, nitrification was not greatly affected by backwash. (4) According to the nitrification capacity in depth of column A, C, where 100% nitrification occured. LAS was removed within 20cm, while ammonium nitrogen required more depth to be removed by nitrification.

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Rotordynamic Analysis of a Dual-Spool Turbofan Engine with Focus on Blade Defect Events (블레이드 손상에 따른 이축식 터보팬 엔진의 동적 안정성 해석)

  • Kim, Sitae;Jung, Kihyun;Lee, Junho;Park, Kihyun;Yang, Kwangjin
    • Tribology and Lubricants
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    • v.36 no.2
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    • pp.105-115
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    • 2020
  • This paper presents a numerical study on the rotordynamic analysis of a dual-spool turbofan engine in the context of blade defect events. The blades of an axial-type aeroengine are typically well aligned during the compressor and turbine stages. However, they are sometimes exposed to damage, partially or entirely, for several operational reasons, such as cracks due to foreign objects, burns from the combustion gas, and corrosion due to oxygen in the air. Herein, we designed a dual-spool rotor using the commercial 3D modeling software CATIA to simulate blade defects in the turbofan engine. We utilized the rotordynamic parameters to create two finite element Euler-Bernoulli beam models connected by means of an inter-rotor bearing. We then applied the unbalanced forces induced by the mass eccentricities of the blades to the following selected scenarios: 1) fully balanced, 2) crack in the low-pressure compressor (LPC) and high pressure compressor (HPC), 3) burn on the high-pressure turbine (HPT) and low pressure compressor, 4) corrosion of the LPC, and 5) corrosion of the HPC. Additionally, we obtained the transient and steady-state responses of the overall rotor nodes using the Runge-Kutta numerical integration method, and employed model reduction techniques such as component mode synthesis to enhance the computational efficiency of the process. The simulation results indicate that the high-vibration status of the rotor commences beyond 10,000 rpm, which is identified as the first critical speed of the lower speed rotor. Moreover, we monitored the unbalanced stages near the inter-rotor bearing, which prominently influences the overall rotordynamic status, and the corrosion of the HPC to prevent further instability. The high-speed range operation (>13,000 rpm) coupled with HPC/HPT blade defects possibly presents a rotor-case contact problem that can lead to catastrophic failure.

2003 Asia Pacific Microwave Conference (2003아시아 태평양 마이크로파 학술회의)

  • 김동일;이혁재;박동철;명로훈;윤상원;조영기;남상욱;윤영중;이해영
    • Proceedings of the Korea Electromagnetic Engineering Society Conference
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    • 2004.01a
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    • pp.1-226
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    • 2004
  • I. Title APMC'03(2003 Asia Pacific Microwave Conference) II. Objecuve $\bigcirc$Investigation of new trend in the field of microwave engineering $\bigcirc$Establishment of R&D track for wireless and high speed communication III. Scope of investigation $\bigcirc$R&D trend in various microwave engineering areas-Solid state Devices and circuits-Electromagnetic Field Theory-EMI&EMC-Phased & Active Array Antennas-Scattering & Propagation $\bigcirc$Discussions with various technical topics-New research & development topics-Establishment of wireless & high speed communications IV. Results During the conference, very active academic exchange were possible between Korean and foreign microwave engineering scholars. It was also possible to introduce the level and activities of Korean microwave engineering researches to foreign countries. Also, it was good opportunity to contact foreign scholars and researchers for valuable academic discussion using technical paper presentations and inquiries.

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Hepatitis C Virus - Proteins, Diagnosis, Treatment and New Approaches for Vaccine Development

  • Keyvani, Hossein;Fazlalipour, Mehdi;Monavari, Seyed Hamid Reza;Mollaie, Hamid Reza
    • Asian Pacific Journal of Cancer Prevention
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    • v.13 no.12
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    • pp.5917-5935
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    • 2012
  • Background: Hepatitis C virus (HCV) causes acute and chronic human hepatitis infection and as such is an important global health problem. The virus was discovered in the USA in 1989 and it is now known that three to four million people are infected every year, WHO estimating that 3 percent of the 7 billion people worldwide being chronically infected. Humans are the natural hosts of HCV and this virus can eventually lead to permanent liver damage and carcinoma. HCV is a member of the Flaviviridae family and Hepacivirus genus. The diameter of the virus is about 50-60 nm and the virion contains a single-stranded positive RNA approximately 10,000 nucleotides in length and consisting of one ORF which is encapsulated by an external lipid envelope and icosahedral capsid. HCV is a heterogeneous virus, classified into 6 genotypes and more than 50 subtypes. Because of the genome variability, nucleotide sequences of genotypes differ by approximately 31-34%, and by 20-23% among subtypes. Quasi-species of mixed virus populations provide a survival advantage for the virus to create multiple variant genomes and a high rate of generation of variants to allow rapid selection of mutants for new environmental conditions. Direct contact with infected blood and blood products, sexual relationships and availability of injectable drugs have had remarkable effects on HCV epidemiology. Hundreds of thousands of people die each year from hepatitis and liver cancer caused by HCV virus infection. Approximately 80% of patients with acute hepatitis C progress into a chronic disease state leading to serious hepatic disorders, 10-20% of which develop chronic liver cirrhosis and hepatocellular carcinoma. The incubation period of HCV is 6-8 weeks and the infection is often asymptomatic so it is very hard to detect at early stages, making early treatment very difficult. Therefore, hepatitis C is called a "silent disease". Neutralizing antibodies are produced against several HCV proteins during infection but the virus mutates to escape from antibodies. Some patients with chronic hepatitis C may have some symptoms such as fatigue, muscle aches, nausea and pain. Autoimmune and immunecomplex-mediated diseases have also been reported with chronic HCV infection.

Anti-adherence of Antibacterial Peptides and Oligosaccharides and Promotion of Growth and Disease Resistance in Tilapia

  • Peng, K.S.;She, R.P.;Yang, Y.R.;Zhou, X.M.;Liu, W.;Wu, J.;Bao, H.H.;Liu, T.L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.4
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    • pp.569-576
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    • 2007
  • Four hundred and fifty tilapias ($6.77{\pm}0.23$ g) were assigned randomly to six groups to evaluate the feasibility of the tested antibacterial peptides (ABPs) and oligosaccharides as substitutes for antibiotics. The control group was fed with a commercial tilapia diet; other five groups were fed with the same commercial diet supplemented with konjac glucomannan (KGLM), cluster bean galactomannan (CBGAM), and three animal intestinal ABPs derived from chicken, pig and rabbit at 100 mg/kg respectively. After 21 days of feeding, growth, disease resistance, and in vivo anti-adherence were determined. Furthermore, the inhibitory effect of tested agents on adhesion of Aeromonas veronii biovar sobria (A.vbs) strain BJCP-5 to tilapia enteric epithelia in vitro was assessed by cell-ELISA system. As a result, the tested agents supplemented at 100 mg/kg show significant benefit to tilapia growth and disease resistance (p<0.05), and the benefit may be correlated with their interfering in the contact of bacteria with host mucosal surface. Although none of the tested agents did inhibit the growth of BJCP-5 in tryptic soy broth at $100{\mu}g/ml$, all of them did inhibit the adhesion of A.vbs to tilapia enteric epithelia in vivo and in vitro. In vitro mimic assays show that three ABPs at low concentrations of $25{\mu}g/ml$ and $2.5{\mu}g/ml$ have the reciprocal dose-dependent anti-adherence effect. The inhibition of ABPs may be correlated with a cation bridging and/or receptor-ligand binding, but not with hydrophobicity. The KGLM and CBGAM inhibited the adherence of BJCP-5 to tilapia enteric epithelia with dose-dependent manner in vitro, and this may be through altering bacterial hydrophobicity and interfering with receptor-ligand binding. Our results indicate that the anti-adherence of the tested ABPs and oligosaccharides may be one of the mechanisms in promoting tilapia growth and resistance to A.vbs.

Effects of Recombinant Baculovirus Infection Conditions on Production of Green Fluorescent Protein in Drosophila S2 Cells (초파리 S2 세포 시스템에서 녹색형광단백질 생산을 위한 재조합 배큘로바이러스의 감염조건들의 영향)

  • Cho, Hye Sook;Kim, Yeon Kyu;Kim, Kyoung Ro;Cha, Hyung Joon
    • Korean Chemical Engineering Research
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    • v.44 no.1
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    • pp.40-45
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    • 2006
  • The baculovirus-insect Drosophila melanogaster S2 cell system combines advantages of conventional baculovirus system and non-lytic S2 cell system because baculoviruses can infect non-permissive cells such as mammalian and Drosophila S2 cells but cannot replicate themselves inside the cells. In the present work, we investigated effects of infection conditions on production of green fluorescent protein (GFP) as a target protein using this baculovirus-S2 cell system. Even though higher MOI and longer baculovirus contact time showed better GFP expression yield during the shorter period, overall protein yield could be lower during the longer period due to the relatively higher cell detachment and lysis (lower cell viability). In addition, maintaining high MOI will be not practical for large-scale cell culture. Therefore, instead of maintaining high MOI, we found that high initial cell number and concentrated (10X) baculovirus volume can confer comparable protein expression even under the moderate MOI condition. Also, we found that the post-infection time that is connected to state of cells after infection was an important factor for production yield.

Removal Characteristics of Geosmin and MIB in BAC Process : Biodegradation and Adsorption (생물활성탄 공정에서 Geosmin과 MIB의 제거 특성 : 생물분해와 흡착)

  • Son, Hee-Jong;Lee, Jeong-Kyu;Kim, Sang-Goo;Park, Hong-Ki;Jung, Eun-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.6
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    • pp.318-324
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    • 2017
  • We evaluated geosmin and MIB biodegradation and adsorption mechanism of biological activated carbon (BAC) and anthracite biofilter. In steady state of BAC process, the geosmin and MIB were completely removed at the 30 min empty bed contact time (EBCT) even though low water temperature ($9^{\circ}C$) in which the activity of attached bacteria decreased. When the water temperature was $26^{\circ}C$, the microbial biomass and activity were higher at the upper layer of the biofilm than at $9^{\circ}C$, and the microbial biomass and activity decreased as the depth was deeper. This is because when the water temperature is high, the biodegradable organic matter (BOM) removal rate in the upper layer is high and the BOM amount that can't be supplied to the lower layer. The Removal rate of geosmin and MIB by BAC process did not show a significant difference compare to activity-inhibited BAC by treated with azide and the biofilter also removed the geosmin and MIB by biological action. It means geosmin and MIB could be removed by competitive relationship between adsorption and biodegradation.