• Title/Summary/Keyword: Constant rate model

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Estimated Photodegradation Properties of Acetanilide Using AOPWIN (AOPWIN을 이용한 Acetanilide의 광부해 특성 평가)

  • 권민정;최윤호;송상환;박혜연;구현주;전성환;나진균;박광식
    • Environmental Analysis Health and Toxicology
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    • v.16 no.3
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    • pp.139-142
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    • 2001
  • Acetanilide is a High Production Volume Chemical, which is produced about 2,300 tons/year in Korea as of 1998 survey. Most is used as an intermediate for synthesis of pharmaceuticals and dyes, and the chemical is one of seven chemicals of which human and environmental risk are being assessed by National Institute of Environmental Research under the frame of OECD SIDS program. The Atmospheric Oxidation Program for Microsoft Windows (AOPWIN) is used to estimates the rate constant for the atmospheric, gas-phase reaction between photochemically produced hydroxyl radicals and organic chemicals. It is also used to estimates the rate constant for the gas-phase reaction between ozone and olefinic/acetylenic compounds. The rate constants estimated by the program are then used to calculate atmospheric half-lives for organic compounds based upon average atmospheric concentrations of hydroxyl radicals and ozone. AOPWIN requires only a chemical structure to make these predictions. Structures are entered into AOPWIN by SMILES (Simplified Molecular Input Line Entry System) notations. In this study, one of environmental fate/distribution of the chemical elements, photodegradation of acetanilide was estimated using AOPWIN model based on SMILES notation and chemical name data.

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Glass Dissolution Rates From MCC-1 and Flow-Through Tests

  • Jeong, Seung-Young
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.257-258
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    • 2004
  • The dose from radionuclides released from high-level radioactive waste (HLW) glasses as they corrode must be taken into account when assessing the performance of a disposal system. In the performance assessment (PA) calculations conducted for the proposed Yucca Mountain, Nevada, disposal system, the release of radionuclides is conservatively assumed to occur at the same rate the glass matrix dissolves. A simple model was developed to calculate the glass dissolution rate of HLW glasses in these PA calculations [1]. For the PA calculations that were conducted for Site Recommendation, it was necessary to identify ranges of parameter values that bounded the dissolution rates of the wide range of HLW glass compositions that will be disposed. The values and ranges of the model parameters for the pH and temperature dependencies were extracted from the results of SPFT, static leach tests, and Soxhlet tests available in the literature. Static leach tests were conducted with a range of glass compositions to measure values for the glass composition parameter. The glass dissolution rate depends on temperature, pH, and the compositions of the glass and solution, The dissolution rate is calculated using Eq. 1: $rate{\;}={\;}k_{o}10^{(ph){\eta})}{\cdot}e^{(-Ea/RT)}{\cdot}(1-Q/K){\;}+{\;}k_{long}$ where $k_{0},\;{\eta}$ and Eaare the parameters for glass composition, pH, $\eta$ and temperature dependence, respectively, and R is the gas constant. The term (1-Q/K) is the affinity term, where Q is the ion activity product of the solution and K is the pseudo-equilibrium constant for the glass. Values of the parameters $k_{0},\;{\eta}\;and\;E_{a}$ are the parameters for glass composition, pH, and temperature dependence, respectively, and R is the gas constant. The term (1-Q/C) is the affinity term, where Q is the ion activity product of the solution and K is the pseudo-equilibrium constant for the glass. Values of the parameters $k_0$, and Ea are determined under test conditions where the value of Q is maintained near zero, so that the value of the affinity term remains near 1. The dissolution rate under conditions in which the value of the affinity term is near 1 is referred to as the forward rate. This is the highest dissolution rate that can occur at a particular pH and temperature. The value of the parameter K is determined from experiments in which the value of the ion activity product approaches the value of K. This results in a decrease in the value of the affinity term and the dissolution rate. The highly dilute solutions required to measure the forward rate and extract values for $k_0$, $\eta$, and Ea can be maintained by conducting dynamic tests in which the test solution is removed from the reaction cell and replaced with fresh solution. In the single-pass flow-through (PFT) test method, this is done by continuously pumping the test solution through the reaction cell. Alternatively, static tests can be conducted with sufficient solution volume that the solution concentrations of dissolved glass components do not increase significantly during the test. Both the SPFT and static tests can ve conducted for a wide range of pH values and temperatures. Both static and SPFt tests have short-comings. the SPFT test requires analysis of several solutions (typically 6-10) at each of several flow rates to determine the glass dissolution rate at each pH and temperature. As will be shown, the rate measured in an SPFt test depends on the solution flow rate. The solutions in static tests will eventually become concentrated enough to affect the dissolution rate. In both the SPFt and static test methods. a compromise is required between the need to minimize the effects of dissolved components on the dissolution rate and the need to attain solution concentrations that are high enough to analyze. In the paper, we compare the results of static leach tests and SPFT tests conducted with simple 5-component glass to confirm the equivalence of SPFT tests and static tests conducted with pH buffer solutions. Tests were conducted over the range pH values that are most relevant for waste glass disssolution in a disposal system. The glass and temperature used in the tests were selected to allow direct comparison with SPFT tests conducted previously. The ability to measure parameter values with more than one test method and an understanding of how the rate measured in each test is affected by various test parameters provides added confidence to the measured values. The dissolution rate of a simple 5-component glass was measured at pH values of 6.2, 8.3, and 9.6 and $70^{\circ}C$ using static tests and single-pass flow-through (SPFT) tests. Similar rates were measured with the two methods. However, the measured rates are about 10X higher than the rates measured previously for a glass having the same composition using an SPFT test method. Differences are attributed to effects of the solution flow rate on the glass dissolution reate and how the specific surface area of crushed glass is estimated. This comparison indicates the need to standardize the SPFT test procedure.

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Numerical Analysis of Turbulent Flow and Heat Transfer in a Rectangular Duct with a 180° Bend Degree (직사각단면을 갖는 180°곡관내의 난류 유동및 열전달에 관한 수치해석적 연구)

  • Choi, Y.D.;Moon, C.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.6 no.4
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    • pp.325-336
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    • 1994
  • A numerical simulation of velocity and temperature fields and Nusselt number distributions is performed by using the algebraic stress model (ASM) for the velocity profiles and low Reynolds number ${\kappa}-{\varepsilon}$ model and the algebraic heat flux model(AHFM) for turbulent heat transfer in a $180^{\circ}$ bend with a constant wall heat flux. In the low Reynolds number ${\kappa}-{\varepsilon}$ model, turbulent Prandtl number is modified by considering the streamline curvature effect and the non-equilibrium effect between turbulent kinetic energy production and dissipation rate. Every heat flux term presented in the transport equation of turbulent heat flux is reduced to algebraic expressions in a way similar to algebraic stress model. Also. in the wall region, low Reynods number algebraic heat flux model(AHFM) is applied.

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Control Performance Investigation of MR Fluid Damper using Herschel-Bulkley Shear Model (Herschel-Bulkley 모델을 이용한 MR 댐퍼 승용차의 제어 성능 고찰)

  • 이덕영;황우석
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.323-328
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    • 2002
  • The control performance of a vehicle installed with an MR(magnetorheological) fluid-based damper is investigated on the basis of Herschel-Bulkley shear model. Generally, most of MR fluid damper has been analyzed based on a simple Bingham-plastic shear model. However, the Bingham-plastic shear model can not well describe the behavior of the damper on the condition of high velocity and high current field input. Therefore, in this study, the Herschel-Bulkley shear model in which the constant post-yield plastic viscosity in Bingham model is replaced with a power law model dependent on shear rate is used to assess control performance of a vehicle with MR fluid damper suspension system. This study deals with a two-degree-of-freedom suspension using the MR fluid damper for a quarter car model. The response for the bump input to identify the fastness of MR fluid damper embedded skyhook controller and requested magnetic field are investigated.

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Modeling of flexible disk grinding process for automation of hand-grinding (수동연삭공정 자동화를 위한 유연성 디스크가공 모델링)

  • Yoo, Song-Min;Kim, Young-Jin
    • Journal of Korean Institute of Industrial Engineers
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    • v.26 no.4
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    • pp.376-383
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    • 2000
  • A flexible disk grinding process model has been implemented with varying disk orientation with respect to workpiece surface along with variable feed rate. Before implementing arbitrary disk orientation and translation, disk angle and feed rate variation have been implemented. The disk angle was changed with constant angular velocity only in the entrance stage. The effect of the variable feed rate was added to the geometric schematic. The feed rate was changed either from the entrance stage or from the between edges stage and process performance was evaluated. Effect of changing both angle end feed rate has been also analyzed. Disk trend showing actual disk deflection has also been visualized.

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LCU-Level Rate Control for HEVC Considering Hierarchical Coding Structure (HEVC의 계층적 부호화 구조를 고려한 LCU 단위의 비트율 제어 기법)

  • Park, Dong-Il;Kim, Jae-Gon;Lim, Sung-Chang;Kim, Jong-Ho;Kim, Hui-Yong
    • Journal of Broadcast Engineering
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    • v.16 no.5
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    • pp.762-772
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    • 2011
  • In this paper, a method of rate control for constant bitrate (CBR) coding of High Efficiency Video Coding (HEVC) is addressed. The existing rate control of H.264/AVC may not provide exact rate control in the case of hierarchical coding structure since it doesn't consider the characteristics of the hierarchical coding structure. It is expected that a rate control is added to the reference software called HM for CBR encoding in the near future. More accurate rate control may be required in a hierarchical structure of random access (RA) mode defined in the common test condition of HM. In this paper, we propose a method of rate control based on quadratic Rate-Distortion (R-D) model considering temporal layers and frame types in hierarchical coding structure for efficient rate control. In the consideration of the trade-off relationship between the bit fluctuation and the average PSNR, both of frame and coding unit (CU) are set as the basic unit of rate control. The performance of the proposed rate control method is verified by simulations along with the trade-off relationships for the both cases of basic unit.

Stress Relaxation Properties of Cucumber under Bending Moment (휨 모멘트에 대한 오이의 응력이완(應力弛緩) 특성(特性))

  • Song, C.H.;Kim, M.S.;Park, J.M.
    • Journal of Biosystems Engineering
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    • v.18 no.3
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    • pp.262-269
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    • 1993
  • Stress relaxation behaviors of the cucumber under bending moment were tested with UTM at three levels of loading rate and initial deflection ratio. Sample cucumber was selected from three cultivars of cucumber, Cheongjangmadi, Baekdadagi, and Gyeousalicheongjang, because these cultivars are the most popular grown cultivars in Korea. When the bending moment was applied to the cucumber sample, the effective span between simple supports was held a constant value of 116mm with consideration of the selected sample length. The objectives of this study were to develop the rheological models such as linear and nonlinear models of the stress relaxation for the cucumber samples, and to investigate the effects of loading rate and initial deflection ratio on the stress relaxation behavior of the cucumber. The results of this study may be summarized as follows : 1. Stress relaxation behavior of the cucumber could be well described by the generalized Maxwell model for each level of deflection ratio. But the stress relaxation behavior of the sample was found to be initial deflection ratio and time dependent, and it was represented the nonlinear viscoelastic model as a function of initial deflection ratio and time. 2. Stress relaxation behavior of the cucumber samples was very highly affected by the loading rate and the initial deflection ratio. The more loading rate and initial deflection ratio resulted in the more initial bending stress and after stress relaxation progressed more rapidly. 3. At the same test conditions, it was found that the stress relaxation rate of Cheongjangmadi was faster than that of other cultivars.

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Basic Study for Development of Denitrogenation Process by Ion Exchange(III) - A kinetic study in the batch reactor - (이온교환법에 의한 탈질소 공정개발의 기초연구(III) - 회분식 반응기에서의 반응속도론-)

  • 채용곤;이동환;김승일;윤태경;홍성수;이민규
    • Journal of Environmental Science International
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    • v.9 no.2
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    • pp.165-171
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    • 2000
  • A kinetic study for anion exchange was performed for commercially available Cl- type anion exchange resin in use to remove nitrate in water. The obtained results from the batch reactor were applied to the Langmuir and Freundlich models. The constants for Lagmuir model were qmax =29.82 and b=0.202, and for Freundlich model were K=5.509 and n=1.772. Langmuir model showed betterfit than Frendlich model for the experimental results. Ion exchange reaction rate was also calculated and the the approximate first-order reaction, rate constant k1 was 0.16 L/mg.hr. Effective diffusion coefficient was obtained in the range from $9.67$\times$10^{-8} cm^2/sec$ for initial concentration change, and from $6.09$\times$10^{-7} to 3.98$\times$10^{-6} cm^2/sec$ for reaction temperature change. Activation energy during the diffusion was calculated as 26 kcal/mol.

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Improving Lifetime Prediction Modeling for SiON Dielectric nMOSFETs with Time-Dependent Dielectric Breakdown Degradation (SiON 절연층 nMOSFET의 Time Dependent Dielectric Breakdown 열화 수명 예측 모델링 개선)

  • Yeohyeok Yun
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.16 no.4
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    • pp.173-179
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    • 2023
  • This paper analyzes the time-dependent dielectric breakdown(TDDB) degradation mechanism for each stress region of Peri devices manufactured by 4th generation VNAND process, and presents a complementary lifetime prediction model that improves speed and accuracy in a wider reliability evaluation region compared to the conventional model presented. SiON dielectric nMOSFETs were measured 10 times each under 5 constant voltage stress(CVS) conditions. The analysis of stress-induced leakage current(SILC) confirmed the significance of the field-based degradation mechanism in the low electric field region and the current-based degradation mechanism in the high field region. Time-to-failure(TF) was extracted from Weibull distribution to ascertain the lifetime prediction limitations of the conventional E-model and 1/E-model, and a parallel complementary model including both electric field and current based degradation mechanisms was proposed by extracting and combining the thermal bond breakage rate constant(k) of each model. Finally, when predicting the lifetime of the measured TDDB data, the proposed complementary model predicts lifetime faster and more accurately, even in the wider electric field region, compared to the conventional E-model and 1/E-model.

A RETRIAL QUEUEING MODEL WITH THRESHOLDS AND PHASE TYPE RETRIAL TIMES

  • CHAKRAVARTHY, SRINIVAS R.
    • Journal of applied mathematics & informatics
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    • v.38 no.3_4
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    • pp.351-373
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    • 2020
  • There is an extensive literature on retrial queueing models. While a majority of the literature on retrial queueing models focuses on the retrial times to be exponentially distributed (so as to keep the state space to be of a reasonable size), a few papers deal with nonexponential retrial times but with some additional restrictions such as constant retrial rate, only the customer at the head of the retrial queue will attempt to capture a free server, 2-state phase type distribution, and finite retrial orbit. Generally, the retrial queueing models are analyzed as level-dependent queues and hence one has to use some type of a truncation method in performing the analysis of the model. In this paper we study a retrial queueing model with threshold-type policy for orbiting customers in the context of nonexponential retrial times. Using matrix-analytic methods we analyze the model and compare with the classical retrial queueing model through a few illustrative numerical examples. We also compare numerically our threshold retrial queueing model with a previously published retrial queueing model that uses a truncation method.