• Title/Summary/Keyword: Conductive Properties

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Integrated Interpretation of ERT Data from the Mineralized Zone in Geumpung Mine (금풍광산 광화대에 대한 전기비저항 토모그래피탐사 자료의 복합해석)

  • Jung, Yeon-Ho;Byun, Joong-Moo
    • Geophysics and Geophysical Exploration
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    • v.10 no.4
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    • pp.322-331
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    • 2007
  • In this study, electrical resistivity tomography (ERT) were conducted to find the mineralized zone at the Geumpung mine in Dojeon-ri, Susan-myeon, Jecheon-si, Chungcheongbuk-do. The deviation of the inclined borehole was measured to obtain the exact positions of the electrodes for correcting apparent resistivity values from ERT. Geophysical loggings such as resistivity and natural gamma were conducted to obtain the properties of the material near the borehole. Measurements of the physical properties of the cores, such as porosity, water content, density, susceptibility, resistivity were performed to analyze the correlation between physical properties and resistivity. Grade analysis for core sample was also conducted to identify relationship between grade and resistivity. Rock property analysis shows that the resistivity is more dominated by susceptibility and grade than by porosity and water content in the mineralized zone. The results of ERT are well consistent with geophysical logging data and geologic column. So ERT is powerful method to identify conductive mineralized zone.

Electrical Properties of Eco-Friendly RuO2-Based Thick-Film Resistors Containing CaO-ZnO-B2O3-Al2O3-SiO2 System Glass for AlN Substrate (Electrical Properties of Eco-Friendly RuO2-Based Thick-Film Resistors Containing CaO-ZnO-B2O3-Al2O3-SiO2 계 유리가 적용된 질화알루미늄 기판용 RuO2계 친환경 후막저항의 전기적 특성 연구)

  • Kim, Min-Sik;Kim, Hyeong-Jun;Kim, Hyung-Tae;Kim, Dong-Jin;Kim, Young-Do;Ryu, Sung-Soo
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.467-473
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    • 2010
  • The objective of this study is to prepare lead-free thick film resistor (TFR) paste compatible with AlN substrate for hybrid microelectronics. For this purpose, CaO-ZnO-$B_2O_3-Al_2O_3-SiO_2$ glass system was chosen as a sintering aid of $RuO_2$. The effects of the weight ratio of CaO to ZnO in glass composition, the glass content and the sintering temperature on the electrical properties of TFR were investigated. $RuO_2$ as a conductive and glass powder were dispersed in an organic binder to obtain printable paste and then thick-film was formed by screen printing, followed by sintering at the range between $750^{\circ}C$ and $900^{\circ}C$ for 10 min with a heating rate of $50^{\circ}C$/min in an ambient atmosphere. The addition of ZnO to glass composition and sintering at higher temperature resulted in increasing sheet resistance and decreasing temperature coefficient of resistance. Using $RuO_2$-based resistor paste containing 40 wt%glass of CaO-20.5%ZnO-25%$B_2O_3$-7%$Al_2O_3$-15%$SiO_2$ composition, it is possible to produce thick film resistor on AlN substrate with sheet resistance of $10.6\Omega/\spuare$ and the temperature coefficient of resistance of 702ppm/$^{\circ}C$ after sintering at $850^{\circ}C$.

Fabrication and Characterization of Lead Oxide (PbO) Film for High Efficiency X-ray Detector (고효율 X선 검출기 적용을 위한 PbO 필름 제작 및 특성 연구)

  • Cho, Sung-Ho;Kang, Sang-Sik;Choi, Chi-Won;Kwun, Chul;Nam, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.329-329
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    • 2007
  • Photoconductive poly crystalline lead oxide coated on amorphous thin film transistor (TFT) arrays is the best candidate for direct digital x-ray detector for medical imaging. Thicker films with lessening density often show lower x-ray induced charge generation and collection becomes less efficient. In this work, we present a new methodology used for the high density deposition of PbO. We investigate the structural properties of the films using X-ray diffraction and electron microscopy experiments. The film coatings of approximately $200\;{\mu}m$ thickness were deposited on $2"{\times}2"$ conductive-coated glass substrates for measurements of dark current and x-ray sensitivity. The lead oxide (PbO) films of $200\;{\mu}m$ thickness were deposited on glass substrates using a wet coating process in room temperature. The influence of post-deposition annealing on the characteristics of the lead oxide films was investigated in detail. X-ray diffraction and scanning electron microscopy, and atomic force microscopy have been employed to obtain information on the morphology and crystallization of the films. Also we measured dark current, x-ray sensitivity and linearity for investigation of the electrical characteristics of films. It was found that the annealing conditions strongly affect the electrical properties of the films. The x-ray induced output charges of films annealed in oxygen gas increases dramatically with increasing annealing temperatures up to $500^{\circ}C$ but then drops for higher temperature anneals. Consequently, the more we increase the annealing temperatures, the better density and film quality of the lead oxide. Analysis of this data suggests that incorporation and decomposition reactions of oxygen can be controlled to change the detection properties of the lead oxide film significantly. Post-deposition thermal annealing is also used for densely film. The PbO films that are grown by new methodology exhibit good morphology of high density structure and provide less than $10\;pA/mm^2$ dark currents as they show saturation in gain (at approximate fields of $4\;V/{\mu}m$). The ability to operate at low voltage gives adequate dark currents for most applications and allows voltage electronics designs.

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Thermal Conductivity Enhancement of Polyimide Film Induced from Exfoliated Graphene Prepared by Electrostatic Discharge Method (정전기 방전에 의해 제조된 흑연박리 그래핀 첨가 폴리이미드 막의 열전도 향상)

  • Lim, Chaehun;Kim, Kyung Hoon;An, Donghae;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.143-148
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    • 2021
  • A thermally conductive 200 ㎛ thick polyimide-based film was made from a polyamic acid (PAA) precursor containing graphene prepared from graphite rod using an electrostatic discharge method in order to improve the thermal conductivity and expand the applicability of polyimide (PI) film. Properties of graphene produced by electrostatic discharge were measured by Raman spectroscopy, transmission electron microscopy and X-ray photoelectron spectroscopy (XPS). As a result of Raman spectrum and XPS analyses of as-prepared graphene, the ID/IG ratio was 0.138 and C/O value was 24.91 which are excellent structural and surface chemical properties. Moreover, thermal conductivities of polyimide films increased exponentially according to graphene contents but when the graphene content exceeded 40%, the polyimide film could not maintain its shape. The thermal conductivity of carbonized PI film made from PAA containing 40 wt% of graphene was 51 W/mK which is greatly enhanced from the pristine carbonized PI film (1.9 W/mK). This result could be originated from superior properties of graphene prepared from the electrostatic discharge method.

Electrical and Optical Properties According to Detachment and Bending of Carbon Nanotube-coated Transparent Tape (카본나노튜브 코팅된 투명 테이프의 탈착과 벤딩에 따른 전기 및 광학적인 특성)

  • Kyoung-Bo Kim;Jongpil Lee;Moojin Kim
    • Journal of Industrial Convergence
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    • v.21 no.8
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    • pp.35-42
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    • 2023
  • Recently, electronic devices with bendable electronic devices based on flexible substrates are being sold, and therefore, the purpose of this study is to evaluate the possibility of flexible substrates of conductive transparent tapes. As a transparent electrode, carbon nanotube (CNT) was formed by the coating method developed by the research team, and samples coated up to 5 times were fabricated. The surface resistance and transmittance of the substrate were measured, and both resistance and transmittance decreased as the number of CNT coatings increased. After the tape was detached from the glass, the surface resistance slightly increased in all samples, and the transmittance increased by about 10% in all measured wavelength ranges because the glass was removed. Next, the tape coated with CNT twice was used to a bending test 20,000 times under the condition of a radius of curvature of 2 mm. The electrical and optical properties before and after bending did not change, which means that there was no change in CNT properties due to bending.

Electrochemical Properties of PAN-based Carbon Fibers Tow Electrode Using Organic/inorganic Nanocomposite and Its Application of Non-enzymatic Sensor (유/무기 나노 복합체를 이용한 PAN계 탄소섬유 토우 유연 전극의 전기화학적 특성 평가 및 비효소 전기화학 센서의 활용)

  • Min-Jung Song
    • Korean Chemical Engineering Research
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    • v.62 no.3
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    • pp.233-237
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    • 2024
  • This study is about the fabrication of a flexible electrode based on PAN-based carbon fibers tow using organic/inorganic nanocomposite and its application of non-enzymatic sensor. The organic/inorganic nanocomposite was composed of the conductive polymer polyaniline (PANI) and the metal oxide CuO. And glucose was used as the target of the electrochemical sensor. Commercialized CFTs were pretreated through heat treatment for desizing and electrochemical oxidation for activation. This nanocomposite was sequentially synthesized on the pretreated CFT surface using electrochemical polymerization and electrochemical deposition. Finally, the CFT/PANI/CuO NPs electrode was obtained. The electrochemical properties and sensing performance of the CFT/PANI/CuO NPs electrode were analyzed using chronoamperometry (CA), cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The sensitivity of the CFT/PANI/CuO NPs electrode was about 8.352 mA/mM (in a linear range of 0.445~6.674 mM) and 3.369 mA/mM (in a linear range of 6.674~50 mM), respectively. So, the CFT/PANI/CuO NPs electrode exhibited the enhanced sensing performances due to unique properties such as small peak potential separation, low electron transfer resistance, and large specific surface area.

Gravure Offset Printed on Fine Pattern by Developing Electrodes for the Ag Paste (Gravure Offset 인쇄에 의한 미세 전극용 Ag Paste 개발)

  • Lee, Sang-Yoon;Jang, Ah-Ram;Nam, Su-Yong
    • Journal of the Korean Graphic Arts Communication Society
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    • v.30 no.3
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    • pp.45-56
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    • 2012
  • Printing technology is accepted by appropriate technology that smart phones, tablet PC, display(LCD, OLED, etc.) precision recently in the electronics industry, the market grows, this process in the ongoing efforts to improve competitiveness through the development of innovative technologies. So printed electronics appeared by new concept. This technology development is applied on electronic components and circuits for the simplification of the production process and reduce processing costs. Low-temperature process making possible for widening, slimmer, lighter, and more flexible, plastic substrates, such as(flexible) easily by forming a thin film on a substrate has been studied. In the past, the formation of the electrode used a screen printing method. But the screen printing method is formation of fine patterns, high-speed printing, mass production is difficult. The roll-to-roll printing method as an alternative to screen printing to produce electronic devices by printing techniques that were used traditionally in the latest technology and processing techniques applied to precision control are very economical to implement fine-line printing equipment has been evaluated as. In order to function as electronic devices, especially the dozens of existing micro-level of non-dot print fine line printing is required, the line should not break at all, because according to the specifications required to fit the ink transfer conditions should be established. In this study of roll-to-roll printing conductive paste suitable for gravure offset printing by developing Ag paste for forming fine patterns to study the basic physical properties with the aim of this study were to.

Characterization of the Vertical Position of the Trapped Charge in Charge-trap Flash Memory

  • Kim, Seunghyun;Kwon, Dae Woong;Lee, Sang-Ho;Park, Sang-Ku;Kim, Youngmin;Kim, Hyungmin;Kim, Young Goan;Cho, Seongjae;Park, Byung-Gook
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.17 no.2
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    • pp.167-173
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    • 2017
  • In this paper, the characterization of the vertical position of trapped charges in the charge-trap flash (CTF) memory is performed in the novel CTF memory cell with gate-all-around structure using technology computer-aided design (TCAD) simulation. In the CTF memories, injected charges are not stored in the conductive poly-crystalline silicon layer in the trapping layer such as silicon nitride. Thus, a reliable technique for exactly locating the trapped charges is required for making up an accurate macro-models for CTF memory cells. When a programming operation is performed initially, the injected charges are trapped near the interface between tunneling oxide and trapping nitride layers. However, as the program voltage gets higher and a larger threshold voltage shift is resulted, additional charges are trapped near the blocking oxide interface. Intrinsic properties of nitride including trap density and effective capture cross-sectional area substantially affect the position of charge centroid. By exactly locating the charge centroid from the charge distribution in programmed cells under various operation conditions, the relation between charge centroid and program operation condition is closely investigated.

High aspect ratio Zinc Oxide nanorods for amorphous silicon thin film solar cells

  • Kim, Yongjun;Kang, Junyoung;Jeon, Minhan;Kang, Jiyoon;Hussain, Shahzada Qamar;Khan, Shahbaz;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.235.2-235.2
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    • 2015
  • The front transparent conductive oxide (TCO) films must exhibit good transparency, low resistivity and excellent light scattering properties for high efficiency amorphous silicon (a-Si) thin film solar cells. The light trapping phenomenon is limited due to non-uniform and low aspect ratio of the textured glass [1]. We present the low cost electrochemically deposited uniform zinc oxide (ZnO) nanorods with various aspect ratios for a-Si thin film solar cells. Since the major drawback of the electrochemically deposited ZnO nanorods was the high sheet resistance and low transmittance that was overcome by depositing the RF magnetron sputtered AZO films as a seed layer with various thicknesses [2]. The length and diameters of the ZnO nanorods was controlled by varying the deposition conditions. The length of ZnO nanorods were varied from 400 nm to $2{\mu}m$ while diameter was kept higher than 200 nm to obtain different aspect ratios. The uniform ZnO nanorods showed higher haze ratio as compared to the commercially available FTO films. We also observed that the scattering in the longer wavelength region was favored for the high aspect ratio of ZnO nanorods and much higher aspect ratios degraded the light scattering phenomenon. Therefore, we proposed our low cost and uniform ZnO nanorods for the high efficiency of thin film solar cells.

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용액공정을 이용한 SiOC/SiO2 박막제조

  • Kim, Yeong-Hui;Kim, Su-Ryong;Gwon, U-Taek;Lee, Jeong-Hyeon;Yu, Yong-Hyeon;Kim, Hyeong-Sun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.36.2-36.2
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    • 2009
  • Low dielectric materials have been great attention in the semiconductor industry to develop high performance interlayer dielectrics with low k for Cu interconnect technology. In our study, the dielectric properties of SiOC /SiO2 thin film derived from polyphenylcarbosilane were investigated as a potential interlayer dielectrics for Cu interconnect technology. Polyphenylcarbosilane was synthesized from thermal rearrangement of polymethylphenylsilane around $350^{\circ}C{\sim}430^{\circ}C$. Characterization of synthesized polyphenylcarbosilane was performed with 29Si, 13C, 1H NMR, FT-IR, TG, XRD, GPC and GC analysis. From FT-IR data, the band at 1035 cm-1 is very strong and assigned to CH2 bending vibration in Si-CH2-Si group, indicating the formation of the polyphenylcarbosilane. Number average of molecular weight (Mn) of the polyphenylcarbosilane synthesized at $400^{\circ}C$ for 6hwas 2, 500 and is easily soluble in organic solvent. SiOC/SiO2 thin film was fabricated on ton-type silicon wafer by spin coating using 30wt % polyphenylcarbosilane incyclohexane. Curing of the film was performed in the air up to $400^{\circ}C$ for 2h. The thickness of the film is ranged from $1{\mu}m$ to $1.7{\mu}m$. The dielectric constant was determined from the capacitance data obtained from metal/polyphenylcarbosilane/conductive Si MIM capacitors and show a dielectric constant as low as 2.5 without added porosity. The SiOC /SiO2 thin film derived from polyphenylcarbosilane shows promising application as an interlayer dielectrics for Cu interconnect technology.

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