• Bulletin of the Korean Chemical Society
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• v.15 no.10
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• pp.857-860
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• 1994

We have calculated the ${\pi}$-electron density, atom self-polarizability, and free valence on each atom of N-(2-chlorobenzyl)-pyridinium, N-(benzyl)-2-chloropyridinium, and N-(2-chlorobenzyl)-2-chloropyridinium salts using a simple Huckel method in order to discuss their intramolecular photocyclization reaction in a qualitative method. Our calculation qualitatively predicts that photocyclization occurs through forming radicals as a reaction intermediate by breaking a C-Cl bond after photoexcitation into a triplet state via intersystem crossing from an initially excited singlet state. We noticed that this C-Cl bond breaking is aided by ${\pi}$-complex formation between a chlorine atom and the ${\pi}$ -electrons of the neighboring ring in the triplet state and a stronger ${\pi}$-complex bond makes C-Cl bond breaking, i.e., radical formation, much easier. A chlorine atom will form a stronger ${\pi}$ -complex bond to a benzyl ring of N-(benzyl)-2-chloropyridinium than a pyridinium ring of N-(2-chlorobenzyl)-pyridinium because the former can donate its ${\pi}$-electron more easily than the latter. The chlorine at position 15 of N-(2-chlorobenzyl)-2-chloropyridinium salt in the excited state also provides its ${\pi}$-electron to the benzyl ring. So this ${\pi}$-electron can increase the bond strength of the $\pi-complex.$ Therefore, the strength of ${\pi}$-complex follows the order of N-(2-chlorobenzyl)-2-chloropyridinium, N-(benzyl)-2-chloropyridinium, and N-(2-chlorobenzyl)-pyridinium salts and thus the radical formation rate. This provides us with an intramolecular photocyclization reaction rate of the same order as given above.

• Transactions of Materials Processing
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• v.10 no.1
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• pp.15-22
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• 2001

The sensitivity method has been utilized to find initial blank shapes which transform into desired shapes after forming. From the information of die shapes, target shape and material properties, the corresponding initial blank which gives final shape after deformation has been found. Drawings of a trapezoidal cup, a cross-shaped cup and an oil pan have been chosen as the examples. At every case the optimal blank shape has been obtained only a few times of modification without any predetermined deformation path. With the predicted optimal blank, both computer simulation and experiment are performed. Excellent agreements are recognized between simulation and experiment at every cases Through the investigation, the sensitivity method is found to be effective in obtaining optimal blank shapes in drawing of complex shapes.

• The Journal of the Petrological Society of Korea
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• v.2 no.2
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• pp.130-138
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• 1993

Kyeonggi Gneiss complex forming Korean Precambrian basement is mainly composed of high-grade metasedimentary rocks, which are generally difficult to determine their absolute ages. We examined the feasibility of successive absolute age determination method for the marbles from this basement. We used hydrochloric acid for the selective dissolution of carbonate minerals from the marbles. Trace element analysis shows that most of Zr and Rb are concentrated in the residues. U in the residue is more abundant than that in HC1-dissolved parts. Pb, Sr, Sm, and Nd are somewhat evenly distributed between HC1-dissolved parts and the residues. }Th shows rather complex behavior. Sr isotopic compositions of the HC1-dissolved parts reveal mixing with Sr from non-carbonate minerals having much higher $^{87}Sr/^{86}Sr$ ratios. We suggest that the most reliable method in the age determination for the marbles of this area is measuring Pb isotopic ratios of the pieces of pure marbles.

• Journal of the Korean Chemical Society
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• v.65 no.2
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• pp.93-105
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• 2021

Mononuclear Cu(II), Ni(II), Co(II), Mn(II), Zn(II), Fe(III), Ru(III), and UO2(II) complexes of 2-hydroxy-4-(p-tolyldiazenyl)benzylidene)-2-(p-tolylamino)acetohydrazide (H2L) were prepared by direct method. The ligand and its complexes were isolated in solid state and characterized by analytical techniques such as elemental and thermal analyses, molar conductance, magnetic susceptibility measurements and spectroscopic techniques such as UV-Visible, IR, 1H-NMR and 13C-NMR. The spectral data indicated that the ligand acted as neutral/monobasic bidentate or monobasic/dibasic tridentate ligand bonded to the metal ions through the oxygen atom of ketonic or enolic carbonyl group, azomethine nitrogen atom and deprotonated/protonated phenolic oxygen atom forming either tetragonally distorted octahedral or octahedral. Antimicrobial activities of the ligand and its complexes were evaluated against Escherichia coli, Bacillus subtilis and Aspergillus niger by well diffusion method. The results of antifungal activity showed that the Fe(III) complex (10) exhibited higher antifungal against Aspergillus niger than the other complexes. However, the results of antibacterial activity revealed that Cu(II) complex (4) is the most active against Escherichia coli while the Cu(II) complex (5) and Fe(III) complex (10) exhibited higher antibacterial effect on Bacillus subtilis than the other complexes.

• Bulletin of the Korean Mathematical Society
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• v.51 no.2
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• pp.457-478
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• 2014

In this paper, a 3D autonomous system, which has only stable or non-hyperbolic equilibria but still generates chaos, is presented. This system is topologically non-equivalent to the original Lorenz system and all Lorenz-type systems. This motivates us to further study some of its dynamical behaviors, such as the local stability of equilibrium points, the Lyapunov exponent, the dissipativity, the chaotic waveform in time domain, the continuous frequency spectrum, the Poincar$\acute{e}$ map and the forming mechanism for compound structure of its special cases. Especially, with the help of the Project Method, its Hopf bifurcation of codimension one is in detailed formulated. Numerical simulation results not only examine the corresponding theoretical analytical results, but also show that this system possesses abundant and complex dynamical properties not solved theoretically, which need further attention.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2002.04a
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• pp.46-49
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• 2002

Three-dimensional flow characteristics in a liquid fuel ramjet combustor were investigated using the PIV method. The combustor has two rectangular inlets that loin a 90-degree angle each other. Three cases of test combustors are made in which those inlet angles are 30 degree, 45degree and 60 degree. The experiments were performed in a water tunnel test with the same Reynolds number as Mach 0.3 at the inlet. PIV software was developed to measure the characteristics of the flow field in the combustor. Accuracy of the developed PIV program was verified with a rotating disk experiment and standard data. The characteristics of the internal flows of the combustor are large swirling flows which appear symmetric with respect to the symmetric section. This is attributed to the fact that the flows introduced from the right and left intakes collide with each other, thus forming symmetrically large vortices. A large and complex three-dimensional recirculating flow was measured behind the intakes. An inlet angle of 30 degrees is the most suitable angle as a frame he]der in the performed experimental ranges.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 1998.03a
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• pp.28-31
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• 1998

Wrinkling is one of the major defects in sheet metal products and may be also attributable to the wear of the tool. The initiation and growth of the wrinkles are influenced by many factors such as stress state, mechanical properites of the sheet material, geometry of the body, and contact condition. It is difficult to analyze the wrinkling initiation and growth considering the factors because the effects of the factors are very complex and the wrinkling behavior may show wide variation for small deviation of the factors. In this study, the bifurcation theory is introduced for the finite element analysis of wrinkling initiation and growth, All the above mentioned factors are conveniently considered by finite element method. The finite element formulation is based on the incremental deformation theory and elastic-plastic material modeling. The finite element analysis is carried out using the continuum-based resultant shell elements considering the planar anisotropy of the sheet metal. The proposed method is verified by employing to column buckling problem. And then, the initiation and growth of wrinkling in deep drawing of cylindrical cup are analyzed.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.996-999
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• 2008

Aspheric polymer lens fabrication using isothermal compression molding is presented in this paper. Due to increasing definition of an image sensor, higher precision is required by a lens which can be used as a part of an imageforming optical module. Injection molding is a factory standard method for a polymer optical lens. But achievable precision using injection molding has a formidable limitation due to the machining of complex mold structure and melting and cooling down a polymer melt under high pressure condition during forming process. To overcome the precision requirement and limitation using injection molding method, isothermal compression molding is applied to fabrication of a polymer optical lens. The fabrication condition is determined by numerical simulations of temperature distribution and given material properties. Under the found condition, the lens having a high precision can successfully be reproduced and does not show birefringence which results often in optical degradation.

• Proceedings of the Korean Geotechical Society Conference
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• 1992.10a
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• pp.61-64
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• 1992

Recently, by the lack of fill material, the dredg and fill(hydraulic fill) method is commonly used in reclamation projects. Hydraulic fill method dredges the soil and send it with water through the transportation pipe to the site. The intial state of the hydraulic fill material is accordingly the mixture of water and soil skeleton which settles with time forming a new soil layer. The properties of new soil layer is governed the size of the soil skeleton, the flow velocity of mixing water, salt concentration, the distance from the discharge pipe outlet, and other dredging conditions when settling process occur. In this study, the effects of gradation of derdged soil on the deposition properties (with emphasis on the optimum spacing of the discharge pipes) was investigated by field test. It was found that the soft fine graind soil was forme at 350m from the discharge pipe outlet when the dredged material was classified as CL, while the soft fine grained soil was not formed even at the distance farther than 400m from the diacharge pipe outlet when the dredged material was classified as SM.

• Journal of the Optical Society of Korea
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• v.16 no.2
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• pp.170-173
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• 2012

We present a method that enables dual threshold voltages in a vertical alignment liquid crystal device, through which the gamma shift can be reduced with no subsequent decrease in the contrast ratio. By forming polymer layers, the threshold voltage shift is accomplished through the utilization of the voltage drop effect. We expect that the proposed method can be applied to the conventional 4-domain mode in order to achieve an 8-domain mode without the need for complex driving schemes.