• Title/Summary/Keyword: Complex Modulus

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Experimental Study on Development for Separation and Reinforcement Geotextiles with Horizontal Wicking Drain Property (수평방향의 위킹 배수 특성을 지닌 분리·보강용 지오텍스타일 개발을 위한 실험적 연구)

  • Kim, Hong-Kwan;Ahn, Min-Soo
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.4
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    • pp.215-224
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    • 2019
  • According to the recent civil engineering construction work site which is a complex process, development of multi-functional geotextiles is required. In this study, the characteristics of five different modified cross-section fiber yarns for the selection of wicking yarns were analyzed and yarns that can achieve target properties were selected. Experimental prototype geotextiles suitable for horizontal wicking drain property and reinforcement was developed and its tensile strength, 2% secant modulus, vertical water permeability, AOS, friction characteristics by the direct shear method, and vertical/horizontal wicking test were analyzed. These tests are conducted to verify the performance of the geotextiles with horizontal wick drain property, separation and reinforcement developed in this study. As a results of the indoor soil box test, it was confirmed that the geotextiles using the wicking yarn sufficiently exhibited the function of discharging excess pore water in the horizontal direction.

Synthesis and Characterization of High Impact Polystyrene/Organically Modified Layered Silicate Nanocomposites (내충격성 폴리스티렌과 유기화 층상 실리케이트 나노복합체의 합성 및 특성)

  • 김관영;임효진;박상민;이성재
    • Polymer(Korea)
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    • v.27 no.4
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    • pp.377-384
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    • 2003
  • High impact polystyrene/organically modified layered silicate (HIPS/OLS) nanocomposites by in situ polymerization were synthesized to investigate the effect of clay on the particle size and properties of rubber. In the OLS, the montmorillonite having benzyl group showed best dispersion in polystyrene phase. With the addition of clay, the intercalated peak from XRB was confirmed, but the peak gradually shifted to lower angle as rubber concentration increased. Thus, it is speculated that the organoclay disperses better in rubber phase than in polystyrene phase. The average rubber particle size increased and the particle size distribution widened as the amount of clay increased, which may be caused by the increase of the viscosity ratio of rubber to polystyrene phases and the unstable dispersion. The materials having clay showed improved thermal properties from thermogravimetric analysis. Rheological properties such as complex viscosity and storage modulus increased as the amount of clay increased.

AFP mandrel development for composite aircraft fuselage skin

  • Kumar, Deepak;Ko, Myung-Gyun;Roy, Rene;Kweon, Jin-Hwe;Choi, Jin-Ho;Jeong, Soon-Kwan;Jeon, Jin-Woo;Han, Jun-Su
    • International Journal of Aeronautical and Space Sciences
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    • v.15 no.1
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    • pp.32-43
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    • 2014
  • Automatic fiber placement (AFP) has become a popular processing technique for composites in the aerospace industry, due to its ability to place prepregs or tapes precisely in the exact position when complex parts are being manufactured. This paper presents the design, analysis, and manufacture of an AFP mandrel for composite aircraft fuselage skin fabrication. According to the design requirements, an AFP mandrel was developed and a numerical study was performed through the finite element method. Linear static load analyses were performed considering the mandrel structure self-weight and a 2940 N load from the AFP machine head. Modal analysis was also performed to determine the mandrel's natural frequencies. These analyses confirmed that the proposed mandrel meets the design requirements. A prototype mandrel was then manufactured and used to fabricate a composite fuselage skin. Material load tests were conducted on the AFP fuselage skin curved laminates, equivalent flat AFP, and hand layup laminates. The flat AFP and hand layup laminates showed almost identical strength results in tension and compression. Compared to hand layup, the flat AFP laminate modulus was 5.2% higher in tension and 12.6% lower in compression. The AFP curved laminates had an ultimate compressive strength of 1.6% to 8.7% higher than flat laminates. The FEM simulation predicted strengths were 4% higher in tension and 11% higher in compression than the flat laminate test results.

Study on Wear Properties of GCV Materials with DLC Coating (GCV소재의 DLC 코팅 마모특성에 관한 연구)

  • Lee, Soo-Chul;Kim, Nam-Seok;Nam, Ki-Woo;Ahn, Seok-Hwan;Kim, Hyun-Soo
    • Journal of Ocean Engineering and Technology
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    • v.24 no.6
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    • pp.71-75
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    • 2010
  • Although Graphite Compacted Vermicular (GCV) was first observed in 1948, the narrow range for stable foundry production precluded the high volume application of GCV to complex components such as cylinder blocks and heads until advanced process control technologies became available. This, in turn, had to await the advent of modern measurement electronics and computer processors. Following the development of foundry techniques and manufacturing solutions, primarily initiated in Europe during the 1990s, the first series production of GCV cylinder blocks began during 1999. Today, more than 40,000 GCV cylinder blocks are produced each month for OEMs, including Audi, DAF, Ford, Hundai, MAN, Mercedes, PSA, Volkswagen, and Volvo. Given that new engine programs are typically intended to support three to four vehicle generations, the chosen engine materials must satisfy current design criteria and also provide the potential for future performance upgrades without changing the overall block architecture. With at least a 75% increase in the ultimate tensile strength, a 40% increase in the elastic modulus, and approximately double the fatigue strength of either iron or aluminum, GCV is ideally suited to meet current and future of engine design and performance requirements.

Natural Frequency of 2-Dimensional Heaving Circular Cylinder: Frequency-Domain Analysis (상하동요하는 2차원 원주의 고유진동수: 주파수 영역 해석)

  • Lee, Dong-Yeop;Lee, Seung-Joon
    • Journal of the Society of Naval Architects of Korea
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    • v.50 no.2
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    • pp.111-119
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    • 2013
  • The concept of the natural frequency is useful for understanding the characters of oscillating systems. However, when a circular cylinder floating horizontally on the water surface is heaving, due to the hydrodynamic forces, the system is not governed by the equation like that of the harmonic one. In this paper, in order to shed some lights on the more correct use of the concept of the natural frequency, a problem of the heaving circular cylinder is analyzed in the frequency domain. Previously, it was thought that the theory of Ursell (1949) could not be used to get the added mass and wave-making damping for short waves, however, they were obtained by applying an accurate collocation method to the theory in this study. Using the so developed numerical method, we found the added mass and wave-making damping of the circular cylinder for the entire range of the frequency. Then, the MCFR(Modulus of Complex Frequency Response) was used to locate the frequency corresponding to the local maximum of MCFR and we define it as the natural frequency. Comparing our results with the previous investigation, we found that the pressure distribution on the cylinder gets close asymptotically to that of a cylinder in infinite fluid OR close to that of the cylinder, that the approximation of the natural frequency by Lee (2008) is different from our new value only by 0.64%, and that the approximation of the heaving system by an equivalent damped harmonic oscillation is not proper by the reason that is clearly shown from the comparison of the shape of the corresponding MCFRs.

Effect of aggregation on shear and elongational flow properties of acrylic thickeners

  • Willenbacher, N.;Matter, Y.;Gubaydullin, I.;Schaedler, V.
    • Korea-Australia Rheology Journal
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    • v.20 no.3
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    • pp.109-116
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    • 2008
  • The effect of intermolecular aggregation induced by hydrophobic and electrostatic interactions on shear and elongational flow properties of aqueous acrylic thickener solutions is discussed. Complex shear modulus is determined at frequencies up to $10^4$ rad/s employing oscillatory squeeze flow. Extensional flow behavior is characterized using Capillary Break-up Extensional Rheometry. Aqueous solutions of poly(acrylic acid)(PAA)/poly(vinylpyrrolidone-co-vinylimidazole) (PVP-VI) mixtures exhibit unusual rheological properties described here for the first time. Zero-shear viscosity of the mixtures increases with decreasing pH and can exceed that of the pure polymers in solution by more than two orders of magnitude. This is attributed to the formation of complexes induced by electrostatic interactions in the pH range, where both polymers are oppositely charged. PAA/PVP-VI mixtures are compared to the commercial thickener Sterocoll FD (BASF SE), which is a statistical co-polymer including (meth) acrylic acid and ethylacrylate (EA) forming aggregates in solution due to "sticky" contacts among hydrophobic EA-sequences. PAA/PVP-VI complexes are less compact and more deformable than the hydrophobic Sterocoll FD aggregates. Solutions of PAA/PVP-VI exhibit a higher zero-shear viscosity even at lower molecular weight of the aggregates, but are strongly shear-thinning in contrast to the weakly shear-thinning solutions of Sterocoll FD. The higher ratio of characteristic relaxation times in shear and elongation determined for PAA/PVP-VI compared to Sterocoll FD solutions reflects, that the charge-induced complexes provide a much stronger resistance to extensional flow than the aggregates formed by hydrophobic interactions. This is most likely due to a break-up of the latter in extensional flow, while there is no evidence for a break-up of complexes for PAA/PVP-VI mixtures. These flexible aggregates are more suitable for the stabilization of thin filaments in extensional flows.

Preparation of Proton Conducting Anhydrous Membranes Using Poly(vinyl chloride) Comb-like Copolymer (Poly(vinyl chloride) 빗살형 공중합체를 이용한 무가습 수소이온 전도성 전해질막의 제조)

  • Kim, Jong-Hak;Koh, Joo-Hwan;Seo, Jin-Ah;Ahn, Sung-Hoon;Zeng, Xiaolei
    • Membrane Journal
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    • v.19 no.2
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    • pp.89-95
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    • 2009
  • A comb-like copolymer consisting of a poly(vinyl chloride) backbone and poly(hydroxy ethyl acrylate) side chains, i.e. PVC-g-PHEA, was synthesized through atom transfer radical polymerization (ATRP). This comb-like copolymer was crosslinked with 4,5-imidazole dicarboxylic acid (IDA) via the esterification of the -OH groups of PHEA in the graft copolymer and the -COOH groups of IDA. Upon doping with phosphoric acid (PA, $H_3PO_4$) to form imidazole-PA complexes, the proton conductivity of the membranes continuously increased with increasing PA content. A maximum proton conductivity of 0.011 S/cm was achieved at $100^{\circ}C$ under anhydrous conditions. The PVC-g-PHEA/IDA/PA complex membranes exhibited good mechanical properties, i.e. 575 MPa of Young's modulus, as determined by a universal testing machine (UTM). Thermal gravimetric analysis (TGA) shows that the membranes were thermally stable up to $200^{\circ}C$.

Analytic adherend deformation correction in the new ISO 11003-2 standard: Should it really be applied?

  • Ochsner, A.;Gegner, J.;Gracio, J.
    • Journal of Adhesion and Interface
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    • v.5 no.2
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    • pp.14-26
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    • 2004
  • For reliable determination of mechanical characteristics of adhesively bonded joints used e.g. as input data for computer-aided design of complex components, the thick-adherend tensile-shear test according to ISO 11003-2 is the most important material testing method. Although the total displacement of the joint is measured across the polymer layer directly in the overlap zone in order to minimize the influence of the stepped adherends, the substrate deformation must be taken into account within the framework of the evaluation of the shear modulus and the maximum shear strain, at least when high-strength adhesives are applied. In the standard ISO 11003-2 version of 1993, it was prescribed to perform the substrate deformation correction by means of testing a one-piece reference specimen. The authors, however, pointed to the excessive demands on the measuring accuracy of the extensometers connected with this technique in industrial practice and alternatively proposed a numerical deformation analysis of a dummy specimen. This idea of a mathematical correction was included in the revised ISO 11003-2 version of 2001 but in the simplified form of an analytical method based on Hooke's law of elasticity for small strains. In the present work, it is shown that both calculation techniques yield considerably discordant results. As experimental assessment would require high-precision distance determination (e.g. laser extensometer), finite element analyses of the deformation behavior of the bonded joint are performed in order to estimate the accuracy of the obtained substrate deformation corrections. These simulations reveal that the numerical correction technique based on the finite element deformation modeling of the reference specimen leads to considerably more realistic results.

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Analysis on the Dynamic Characteristics of a Rubber Mount Considering Temperature and Material Uncertainties (온도와 물성의 불확실성을 고려한 고무 마운트의 동특성 해석)

  • Lee, Doo-Ho;Hwang, In-Sung
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.24 no.4
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    • pp.383-389
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    • 2011
  • In this paper, a statistical calibration method is proposed in order to identify the variability of complex modulus for a rubber material due to operational temperature and experimental/model errors. To describe temperature- and frequency-dependent material properties, a fractional derivative model and a shift factor relationship are used. A likelihood function is defined as a product of the probability density functions where experimental values lie on the model. The variation of the fractional derivative model parameters is obtained by maximizing the likelihood function. Using the proposed method, the variability of a synthetic rubber material is estimated and applied to a rubber mount problem. The dynamic characteristics of the rubber mount are calculated using a finite element model of which material properties are sampled from Monte Carlo simulation. The calculated dynamic stiffnesses show very large variation.

Natural Frequency of 2-Dimensional Heaving Circular Cylinder: Time-Domain Analysis (상하동요하는 2차원 원주의 고유진동수: 시간 영역 해석)

  • Kim, Ki-Bum;Lee, Seung-Joon
    • Journal of the Society of Naval Architects of Korea
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    • v.50 no.4
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    • pp.224-231
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    • 2013
  • The concept of the natural frequency is useful for understanding the characters of oscillating systems. However, when a circular cylinder floating horizontally on the water surface is heaving, due to the hydrodynamic forces, the system is not governed by the equation like that of the harmonic one. In this paper, in order to shed some lights on the more correct use of the concept of the natural frequency, a problem of the heaving circular cylinder is analyzed in the time domain. The equation of motion, an integro-differential equation, was derived following the fashion of Cummins (1962), and its coefficients including the retardation function were obtained using the numerical solution of Lee (2012). The equation was solved numerically, and the experiment was also carried out in the CNU flume. Using our numerical and experimental results, the natural frequency was defined as its average value given by the motion data excluding those of the initial stage. Our results were then compared with those of the existing investigations such as Maskell and Ursell (1970), Ito (1977) and Yeung (1982) as well as the newly obtained results of Lee (2012). Comparison showed that the natural frequency obtained here agrees well with that of Lee (2012), which was found through the frequency domain analysis. It was also shown that the approximation of heaving motion by a damped harmonic oscillation, which was regarded as suitable by most previous investigators, is not physically suitable for the reason that can be clearly shown through comparing the shape of MCFRs(Modulus of Complex Frequency Response). Furthermore, we found that although the previous approximations yield the damping ratio significantly different from our result the magnitude of natural frequency is not much different from our result.