• Title/Summary/Keyword: Combustion product

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Covalently-Bonded Solid Solution Formed by Combustion Synthesis

  • Ohyanagi, Manshi;Munir, Zuhair A.
    • The Korean Journal of Ceramics
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    • v.6 no.3
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    • pp.250-257
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    • 2000
  • The feasibility of synthesizing SiC-AlN solid solution by field-activated combustion synthesis was demonstrated. At lower fields of 8-16.5V/cm, composites of AlN-rich and SiC-rich phases were synthesized, but at fields of 25-30 V/cm, the product was a 2H structure solid solution. Combustion synthesis of the solid solution by nitridation of aluminum with silicon carbide under a nitrogen gas pressure of 4-8 MPa was also investigated. The maximum combustion temperature and wave propagation velocity were found to be influenced by the electric field in the field-activated combustion synthesis, and by the green density and nitrogen pressure in the combustion nitridation. In both cases the formation of solid solutions is complete within seconds, considerably faster than in conventional methods which require hours.

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Fire Characteristics of Flaming and Smoldering Combustion of Wood Combustibles Considering Thickness (목재 가연물의 두께에 따른 화염연소와 훈소상태에서의 화재특성)

  • Kim, Sung-Chan;Nam, Dong-Gun
    • Fire Science and Engineering
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    • v.29 no.4
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    • pp.67-72
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    • 2015
  • A series of fire tests was conducted to examine the fire characteristics of flaming and smoldering combustion of engineered wood products, which have been widely used for furniture and finishing materials in buildings. The engineered wood products of MDF, plywood, and chipboard were ignited by a radiant cone heater with incident heat flux of $50kW/m^2$. During the fire test, key parameters representing the fire characteristics such as the heat release rate, yield rate of combustion product, and effective heat of combustion were quantified in terms of thickness. The tests show two peak points of HRRPUA due to lateral fire propagation in the initial stage, followed by later fire penetration through the specimen thickness. The mass loss rate of flaming combustion was 5 times higher than that of smoldering combustion, while the CO yield rate of smoldering combustion was 10 times higher than that of flaming combustion. This study can contribute to the understanding of fire behavior of wood combustibles and provide useful data for fire analysis.

Design Point Operating Characteristics of an Oxidizer Rich Preburner (산화제 과잉 예연소기 설계점 운영 특성)

  • Moon, Ilyoon;Moon, Insang;Kang, Sang Hun;Ha, Seong-Up;Lee, Soo Young
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.4
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    • pp.81-88
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    • 2013
  • It was designed and tested at the design point that an oxidizer rich preburner for a staged combustion liquid rocket engine propelled by kerosene and LOx. The oxidizer rich preburner was designed as some of LOx injected from the mixing head was burned with kerosene and the rest of LOx injected from injection holes in the regenerative cooling chamber was vaporized by combustion gas. The preburner is operated at OF ratio of 60 and combustion pressure of 20 MPa. The Preburner has a honey-comb type mixing head with simplex swirl injectors, a turbulence ring improving combustion stability and uniformity of product gas temperature distribution, and a nozzle simulating the duct. With the combustion test results at the design point, the oxidizer rich preburner showed high combustion stability and uniformity of product gas temperature distribution.

An Experimental Study on Combustion Characteristics of Regenerative Gas Burner (축열버너의 연소특성에 대한 실험적 연구)

  • Yang, J.B.;Kim, W.B.;Noh, D.S.
    • Journal of the Korean Society of Combustion
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    • v.5 no.1
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    • pp.99-108
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    • 2000
  • Regenerative burner is a product of new combustion technology for realizing higher thermal efficiency and lower emissions, moreover utilizing very high preheated air temperature up to $1,000^{\circ}C$. In this study the experimental study was carried out to find out a combustion characteristics breaking the old combustion concept. From the variation of configuration of gas nozzle and hot test on the temperature distribution and NOx, CO, it was found out that the performance of regenerative burner was better than that of existing burner, mainly due to the effect of internal gas recirculation.

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The Effect of Some Additives on the Components of Cigarette Smoke (첨가제가 담배 연기성분에 미치는 영향)

  • Ra Do-Young;J도 Byong-Kwon;Lee Chang-Kook;Cho Si-Hyung;Lee Dong-Wook
    • Journal of the Korean Society of Tobacco Science
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    • v.27 no.1 s.53
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    • pp.40-50
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    • 2005
  • The influence of tobacco additives on the composition of the combustion products in mainstream smoke is discussed. The effect of additives on the chemical composition of smoke have been further evaluated in order to discover additives that would alter the chemical composition of smoke. Tobacco was uniformly treated at a 1-5$\%$ level with 8 classes of additives. Group M treated with alkali metal salt and group S, F, O give lower tar, nicotine and CO values than the control. Group AN treated with natural antioxidant gives higher tar and CO values than the control. The increases are most probably due to the high transfer rate of the ingredients to smoke. M3 and P1 reduced above the $50\%$ of TSNA from the smoke. M4 and P1 reduced above the $50\%$ of HCN from the smoke. These results suggest that tobacco additives alter pyrolysis or combustion product distribution and provide fundamental data to lead the development of a RRP(reduced risk product).

Synthesis and Characterization of $Cr_3C_2$ for Plasma-arc Deposit by Combustion Synthesis Process (연소합성법에 의한 Plasma-arc Deposit 용 $Cr_3C_2$ 합성 및 특성에 관한 연구)

  • 장윤식;윤정아;이윤복;박성수;김인술;박흥채;오기동
    • Journal of the Korean Ceramic Society
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    • v.33 no.11
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    • pp.1285-1291
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    • 1996
  • Using Cr2O3 Al and graphite powders as starting materials Cr3C2 was synthesized by combustion synthesis process according to the following reaction : 3Cr3C2 +4C+6Allongrightarrow2Cr3C2 +3Al2O3. The synthesis was conducted at 2 atm in an argon atmosphere. in this study main-product was monolithic phase of Cr3C2 /Cr7C3 mixture and sub-product was slag state of $\alpha$-Al2O3. Single phase of Cr3C2 was obtained when crushed main-product was heat-treated at 120$0^{\circ}C$ for 3h in vacuum state with addition of 2.5wt% C. The obtained Cr3C2 powder can be used as plasma-arc deposit material because the flowability index of powder with the size of 9-50${\mu}{\textrm}{m}$ was 66.

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X-ray Photoelectron Spectroscopy Study of LaFeO3 Powders Synthesized by Solution Combustion (용액연소법으로 제조한 LaFeO3의 XPS 특성)

  • Hwang, Yeon;Kang, Dae-Sik;Park, Mi-Hye;Cho, Sung-Baek
    • Korean Journal of Materials Research
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    • v.18 no.6
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    • pp.313-317
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    • 2008
  • [ $LaFeO_3$ ] powders were synthesized using a method involving solution combustion, and the surface properties of these powders were examined by x-ray photoelectron spectroscopy. As the amount of fuel increased during the synthesis, the $LaFeO_3$ powders became amorphous with a large plate-like shape. It was found that the O 1s spectra were composed of two types of photoelectrons by deconvolutioning the spectra. Photoelectrons with higher binding energy come from adsorbed oxygen ($O^-$) whereas those with lower energy come from lattice oxygen ($O^{2-}$). The ratio of adsorbed and lattice oxygen increased as the ratio of the fuel and nitrate (${\Phi}$) increased. The binding energy of both types of oxygen increased as ${\Phi}$ increased due to the formation of carbonates.

A Study on the Formation Phase of Self-propagating High-temperature Synthesis of Ti-Al-C alloys (Ti-Al-C 합금의 고온 자전 합성 반응시 생성상에 관한 연구)

  • 문종태
    • Journal of Powder Materials
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    • v.2 no.2
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    • pp.149-157
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    • 1995
  • In this study, an attempt was made to fabricate TiAl as well as its in situ composite via combustion synthesis. The processing variable of the combustion synthesis which include aluminum content and the heating rate were found to affect the combustion temperature. The combustion temperature measured, however, was lower than the melting temperature of TiAl and the reaction product were found to include incomplet reaction products. Carbon was added in order to increase the combustion temperature as well as to form in situ reinforcements. The reaction products showed homogeneous microstructures with carbide phases formed within indicating that the addition of carbon increased the combustion temperature above the melting temperature of TiAl.

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A Study on Combustion Characteristics of Turbulent Methane/Oxygen Diffusion Flames (메탄/산소 난류 확산화염의 연소 특성에 관한 연구)

  • Lee, Sang-Min;Kim, Ho-Keun;Kim, Han-Seok;Ahn, Kook-Young
    • 한국연소학회:학술대회논문집
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    • 2004.06a
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    • pp.118-123
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    • 2004
  • The combustion characteristics of 0.03MW turbulent methane/oxygen diffusion flames have been investigated to give basic informations for designing industrial oxyfuel combustors. NOx reduction has become one of the most determining factors in the combustor design since 3-5% nitrogen is intrinsically included from the current oxygen producing processes. Flame lengths and NOx concentrations were measured by varying flow velocities with and without installing quarls. Flame stabilities are significantly enhanced by oxyfuel combustion in contrast to air-fuel combustion. Flame length decreases with increasing fuel or oxygen velocity because of the enhancement of turbulent mixing. NOx concentration was reduced with increasing flo velocities. This can be attributed to the entrainment of inert product gases into flame decreasing flame temperature. The installation of quarl on the burners rather increased NOx concentration since the quarl blocked the entrainment above the nozzles.

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Catalytic combustion of $H_2$/Air mixture using Pt/$Al_2O_3$ coated nickel foam (Pt/$Al_2O_3$가 코팅된 니켈폼을 이용한 수소-공기 예혼합 기체의 촉매 연소)

  • Jin, Jung-Kun;Kwon, Se-Jin
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.37-44
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    • 2007
  • A nickel foam, one of metal foams was seleced as a catalyst support instead of conventional ceramic materials. $Al_2O_3$ was coated on the surface of nickel foam to increase the surface area. $Al_2O_3$ coating process was based on sol-gel process. SEM image was obtained and $Al_2O_3$ coverage was confirmed. Combustion experiments were carried out using SUS combustor and $H_2$/air mixture. Temperatures were measured with different equivalence ratios and $H_2$ flow rates. $H_2$ conversion rates were calculated by the analysis of product gas using gas chromatography. Catalytic combustion of $H_2$ was complete and stable with Pt/$Al_2O_3$ coated nickel foam and influences of water vapor were confirmed during the beginning of combustion.

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