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Precise Deterioration Diagnosis and Restoration Stone Suggestion of Jungdong and Banjukdong Stone Aquariums in Gongju, Korea (공주 중동 및 반죽동 석조의 정밀 손상도 진단과 복원석재 제안)

  • Jo, Young Hoon;Lee, Myeong Seong;Choi, Gi Eun;Lee, Chan Hee
    • Korean Journal of Heritage: History & Science
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    • v.44 no.3
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    • pp.92-111
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    • 2011
  • This study focus on the restoration stone selection of break-out part based on material characteristics analysis and the conservational safety diagnosis using various nondestructive techniques for Jungdong and Banjukdong Stone Auariums. As a result, the original rocks of the stone aquariums body are porphyritic granodiorite with magnetite-series having igneous lineation, microcline phenocryst, veinlet and basic xenolith. As a result of the provenance presumption of the host rock, a rock around Gamgokri area in Nonsan City was identified the genetically same rock. Therefore, the rock is appropriate for restoration materials of the break-out part. The deterioration assessment showed that the stone aquariums were highly serious scaling, scale off and blackening. Particularly, the front face of Banjukdong stone aquarium needs reinforcement of structural crack (760mm) caused from igneous lineation of biotite. Blackening contaminants on the stone aquariums surface occurred by combining iron oxide, manganese oxide and clay mineral. Also, major factors of efflorescence contaminants were identified as calcite (Jungdong stone aquariums) and gypsum (Banjukdong stone aquariums). The physical characteristics of stone aquariums appeared that the original and new stone is third (moderately weathered) and second grade (slightly weathered), respectively. This study sets up an integrated conservation system from material analysis to restoration stone selection and conservational safety diagnosis of Jungdong and Banjukdong stone aquariums.

Soil Properties of Granitic Weathered Soils in the Landslide-prone Areas in Seoul (서울지역 화강암 풍화토 토층지반의 토질특성)

  • Kim, Kyeong-Su
    • The Journal of Engineering Geology
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    • v.29 no.1
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    • pp.23-35
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    • 2019
  • Landslides occur due to heavy rainfall in the summer season. Some of water may infiltrate into the ground; it causes a high saturation condition capable of causing a landslide. Soil properties are crucial in estimating slope stability and debris flow occurrence. The main study areas are Gwanaksan, Suraksan and Bukhansan (Mountain) in Seoul. A total of 44 soil samples were taken from the study area; and a series of geotechnical tests were performed. Physical and mechanical properties were obtained and compared based on region. As a result, among well-graded soils, they are classified as a clayey sand. Coarse-grained and fine-grained contents are approximately 95% and 5%, respectively, with very low amount of clay content. Density, liquid limit and dry unit weight are ranged in $2.62{\sim}2.67g/cm^3$, 27.93~38.15% and $1.092{\sim}1.814g/cm^3$. Cohesion and internal friction angle are 4 kPa and $35^{\circ}$ regardless of mountain area. Coefficient of permeability is varied between $3.07{\times}10^{-3}{\sim}4.61{\times}10^{-2}cm/sec$; it means that it results in great seepage. Permeability is inversely proportional to the uniformity coefficient and is proportional to the effective particle size. In the formal case, there was a difference by mountain area, while in the latter, the tendency was almost similar.

Changes in sedimentary structure and elemental composition in the Nakdong Estuary, Korea (낙동강 하구역 퇴적구조 및 원소조성 변화에 관한 연구)

  • Kim, Yunji;Kang, Jeongwon;Park, Seonyoung
    • Journal of Wetlands Research
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    • v.23 no.3
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    • pp.213-223
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    • 2021
  • To understand the sedimentary environment of Scirpus planiculmis habitat (Myeongji and Eulsuk tidal flats) in the Nakdong Estuary, this study analyzed the statistical parameters (sorting, skewness, and kurtosis) of grain size data and the major (Al, Fe, Mn, Mg, Ca, Na, K, Ti, and P), minor (Li, Sc, V, Cr, Co, Ni, Cu, Zn, Sr, Zr, Cs, Pb, Th, and U), and rare earth elements (REEs) in sediment cores. For Myeongji, the sediment structure of the upper part of the cores was poorly sorted, more finely skewed, and more leptokurtic due to construction of the West gate. By contrast, the Eulsuk cores all differed due to the contrasting floodgate operation patterns of the West and East gates. The linear discriminate function (LDF) results corresponded to the statistical parameters for grain size. At the Eulsuk tidal flat (sites ES05 and ES11), elemental distributions were representative of Al-, Fe- and Ca-associated profiles, in which the elements are largely controlled by the accumulation of their host minerals (such as Na- and K-aluminosilicate and ferromagnesium silicate) and heavy detrital minerals at the sites. Detrital minerals including the aluminosilicates are major factors in the elemental compositions at ES05, diluting the REE contents. However, clay minerals and Fe-oxyhydroxides, as well as REE-enriched heavy minerals, appeared to be controlling factors of the elemental composition at ES11. Therefore, the mineral fractionation process is important in determining the elemental composition during sedimentation, which reflects the depositional condition of riverine-saline water mixing at both sites.

Properties of Pohang Mudstone with High Porosity According to Water Immersion (수침에 따른 공극률이 큰 포항 이암의 특성)

  • Kim, Byung-Soo;Lee, Yun-Jae;Kim, Tae-Hyung;Kim, Byeong-Jun
    • Journal of the Korean Geotechnical Society
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    • v.37 no.11
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    • pp.83-92
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    • 2021
  • In this study, effective porosity measurement, electron microscope (SEM) observation, X-ray diffraction analysis (XRD), slaking, swelling, and unconfined compression strength according to water immersion were analyzed to evaluate the properties of mudstone with high porosity in Pohang. As a result of the test for 16 square samples (5 cm), the effective porosity was 14.67% on average, higher than porosity of general mudstone, and electron microscope observation confirmed that the porosity was actually high. As a result of X-ray diffraction analysis, the swelling clay mineral content was 2.3~4.1%, which was lower than the results of previous studies in Pohang. The slake durability index was 37.73~87.73%, showing low to medium durability, which was lower than the results of previous studies. It was confirmed that the swelling property rapidly expanded to 1.79~1.82% of maximum swelling strain in the major axis direction for 30 minutes. As the properties of decreasing the unconfined compression strength according to water immersion, the samples rapidly weathered after 10 minutes of water immersion, and the strength decreased. It was confirmed that the results of previous studies related to mudstone in Pohang were different. This is judged to be due to the high porosity of mudstone in study.

Interpretation of Firing Temperature and Material Similarity for Potteries from Ancient Tombs in Songpa Area, Seoul (서울 송파 지역 고분 출토 토기의 재료학적 동질성 및 소성온도 해석)

  • Lee, Gyu Hye;Yun, Jung Hyun;Lee, Chan Hee
    • Conservation Science in Museum
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    • v.28
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    • pp.17-34
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    • 2022
  • This study seeks to identify the material characteristics of earthenware excavated from the Bangi-dong Ancient Tomb No. 3 and the articulated stone-mound tomb of the Seokchon-dong ancient tombs in the Songpa region, and analyze the homogeneity and the firing temperature of the materials used at each excavated site. The remains have been studied relatively recently, and the groups of tombs in which they were found demonstrate the transition of ancient Korean burial systems, and at the same time, provide important archaeological data about those in power at the time. The earthenware pottery excavated from the two sites examined in the study were buried at different times, and it is assumed that they were made by procuring weathered soil of similar gneiss, judging from the behavior of the compatible and incompatible elements and the weathering tendency found by examining the main components. In addition, the examination of the mineral composition and microstructure of clay indicates that the earthenware from Seokchon-dong was fired at 950 degrees Celsius or lower at a relatively early stage. On the other hand, the earthenware from Bangi-dong Tomb No. 3 was confirmed to have experienced temperatures below 850 degrees Celsius and above 1,000 degrees Celsius. However, it is difficult to interpret the difference as the result of the changes in firing temperature throughout the eras. It is expected that it will be possible to interpret the changes in earthenware manufacturing techniques by comparing more diverse earthenware potteries and ancient soils.

On-site Conservation Treatment of the Beaker-shaped Pottery from Yori, Hyangnam, Hwaseong (화성 향남 요리 출토 심발형 토기 수습과 보존처리)

  • Kwon, Ohyoung;Ham, Chulhee;Lee, Sunmyoung
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.494-504
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    • 2020
  • Ten historic sites (denoted as A- J in this study) of a tomb were found during the construction of the east-west expressway in District 2 of Hyangnam, Hwaseong, which is implemented by the Gyeonggi-do headquarters of the Korea Land & Housing Corporation. Thetombswere first detected at siteH, and further investigations revealed various tombs from the Three Kingdoms period; artifacts such as gilt-bronze shoes and caps were excavated from wooden coffins in the tombs. The pottery examined in this study was the only pottery artifact excavated from the site. Its raw clay was soft and loose, reddish brown, and had quartz and feldspar particles of < 1 mm, which appeared to have been added as reinforcing agents. The firing temperature of the pottery was estimated to be under 800-870 ℃ as the mica remains and tridimite, which is the phase transition mineral of quartz, was not produced; a slight endothermic peak was also detected because of the hydration of sericite at 800 ℃. The condition of the artifact was severely weakened because of various factors, such as soil pressure from the stratum formed over the site and repeated freezing and thawing. The artifact could not be collected alone, and thus, surrounding soil that had attached to the artifact was also collected; the artifact was transported to the laboratory and conservation treatment was conducted in a safe and systematic manner.

Physical and Mineralogical Properties of Pottery-Making Soils in Korea (국내 도자기용 태토의 토질 및 광물 특성)

  • Kim, Hak Joon;Lee, Yong Cheon;Lee, Yu Jin;Lee, Ho Jeong;Jeong, Chan Ho
    • The Journal of Engineering Geology
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    • v.32 no.4
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    • pp.685-696
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    • 2022
  • Although the use of pottery-making soils has a long history, its use in the pottery industry requires that physical and geotechnical properties of the materials be established to define the suitability for various purposes. The main purpose of this study is to identify the different types of clays and mineral composition and to perform the geotechnical evaluation of the clays for making pottery products. Soils investigated in this study include raw materials used for making Baekja (white porcelains), Chungja (celadons), Buncheong, Sancheong, and Johyung. Pottery-making soils are manufactured by using different types of soils and sold by individual ceramic clay company. This study includes physical tests of soil and chemical analysis of major elements using XRF and XRD instrumentation. Grain size distributions, mineralogical composition, and a range of plasticities of soils for making different types of potteries are presented. Correlations between specific type of pottery clays and geotechnical and mineralogical characteristics are determined by comparing the test results. Since quantitative research using laboratory tests for pottery-making soils are rarely performed in Korea, further research should be done in the future to improve the Korean pottery industry.

Mineralogy and Geochemistry of Shale Deposits in the Lower Anambra Basin, Nigeria: Implication for Provenance, Tectonic Setting and Depositional Environment

  • Olugbenga Okunlola;Agonsi Udodirim Lydia;Aliyu Ohiani Umaru;Raymond Webrah Kazapoe;Olusegun G. Olisa
    • Economic and Environmental Geology
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    • v.56 no.6
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    • pp.799-816
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    • 2023
  • Mineralogical and geochemical studies of shales within the Lower Anambra Basin was conducted to unravel the depositional environment, provenance, maturity, paleo-weathering conditions, and tectonic settings. Mineralogical studies conducted using X-ray diffraction analysis revealed that the samples were composed of kaolinite, montmorillonite, chlorite, and illite. KaolinIite is the dominant mineral, constituting approximately 41.5% of the bulk composition, whereas the non-clay minerals are quartz, ilmenite, and sillimanite. Geochemical analysis showed a predominance of SiO2, Al2O3, and Fe2O3 contents of the shale samples with mean values of 52.29%, 14.09%, and 6.15% for Imo Shale (IS); 52.31%, 16.70%, and 7.39% for Mamu Shale (MS); 43.21%, 21.33%, and 10.36% for Enugu Shale (ES); 53.35%, 15.64%, and 7.17% for Nkporo Shale (NS); and 51.24%, 17.25%, and 7.78% for Agwu Shale (AS). However, the shales were depleted in Na2O, MgO, K2O, MnO, TiO2, CaO, and P2O5. The trace element ratios of Ni/Co and Cu/Zn of the shale suggest an oxic depositional environment. The average SiO2 vs. Al2O3 ratio of the shales indicated textural maturity. Compared to the PAAS standard, the shales plot below the PAAS value of 0.85, suggesting a high degree of maturity and intensive chemical weathering, further confirmed on a CIA vs. PIA plot. On log (K2O/Na2O) against SiO2 and tectonic setting discriminant function diagrams, the shales plot mostly in the field of passive continental margin tectonic setting. The discriminant function diagrams as well as Al2O3/TiO2 ratio of the shales showed that they were derived from a mixed source (mafic and intermediate igneous rocks).

Origin of limestone conglomerates in the Choson Supergroup(Cambro-Ordovician), mid-east Korea

  • Kwon Y.K.;Chough S.K.;Choi D.K.;Lee D.J.
    • 한국석유지질학회:학술대회논문집
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    • autumn
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    • pp.63-65
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    • 2001
  • The Chosen Supergroup (Cambro-Ordovician), mid-east Korea consists mainly of shallow marine carbonates and contains a variety of limestone conglomerates. These conglomerates largely comprise oligomictic, rounded lime-mudstone clasts of various size and shape (equant, oval, discoidal, tabular, and irregular) and dolomitic shale matrices. Most clasts are characterized by jigsaw-fit (mosaic), disorganized, or edgewise fabric and autoclastic lithology. Each conglomerate layer is commonly interbedded with limestone-dolomitic shale couplets and occasionally underlain by fractured limestone layer, capped by calcareous shale. According to composition, characteristic sedimentary structures, and fabric, limestone conglomerates in the Hwajol, Tumugol, Makkol, and Mungok formations of Chosen Supergroup can be classified into 4 types: (1) disorganized polymictic conglomerate (Cd), (2) horizontally stratified polymictic conglomerate (Cs), (3) mosaic conglomerate (Cm), and (4) disorganized/edgewise oligomictic conglomerate (Cd/e). These conglomerates are either depositional (Cd and Cs) or diagenetic (Cm and Cd/e) in origin. Depositional conglomerates are interpreted as storm deposits, tidal channel fills, or transgressive lag deposits. On the other hand, diagenetic conglomerates are not deposited by normal sedimentary processes, but formed by post-depositional diagenetic processes. Diagenetic conglomerates in the Chosen Supergroup are characterized by autoclastic and oligomictic lithology of lime-mudstone clasts, jigsaw-fit (mosaic) fabric, edgewise fabric, and a gradual transition from the underlying bed (Table 1). Autoclastic and oligomictic lithologies may be indicative of subsurface brecciation (fragmentation). Consolidation of lime-mudstone clasts pre-requisite for brecciation may result from dissolution and reprecipitation of CaCO3 by degradation of organic matter during burial. Jigsaw-fit fabric has been considered as evidence for in situ fragmentation. The edgewise fabric is most likely formed by expulsion of pore fluid during compaction. The lower boundary of intraformational conglomerates of depositional origin is commonly sharp and erosional. In contrast, diagenetic conglomerate layers mostly show a gradual transition from the underlying unit, which is indicative of progressive fragmentation upward (Fig. 1). The underlying fractured limestone layer also shows evidence for in situ fragmentation such as jigsaw-fit fabric and the same lithology as the overlying conglomerate layer (Fig, 1). Evidence from the conglomerate beds in the Chosen Supergroup suggests that diagenetic conglomerates are formed by in situ subsurface fragmentation of limestone layers and rounding of the fragments. In situ subsurface fragmentation may be primarily due to compaction, dewatering (upward-moving pore fluids), and dissolution, accompanying volume reduction. This process commonly occurs under the conditions of (1) alternating layers of carbonate-rich and carbonate-poor sediments and (B) early differential cementation of carbonate-rich layers. Differential cementation commonly takes place between alternating beds of carbonate-rich and clay-rich layers, because high carbonate content promotes cementation, whereas clay inhibits cementation. After deposition of alternating beds and differential cementation, with progressive burial, upward-moving pore fluid may raise pore-pressure in the upper part of limestone layers, due to commonly overlying impermeable shale layers (or beds). The high pore-pressure may reinforce propagation of fragmentation and cause upward-expulsion of pore fluid which probably produces edgewise fabric of tabular clasts. The fluidized flow then extends laterally, causing reorientation and further rounding of clasts. This process is analogous to that of autobrecciation, which can be analogously termed autoconglomeration. This is a fragmentation and rounding process whereby earlier semiconsolidated portions of limestone are incorporated into still fluid portions. The rounding may be due mainly to immiscibility and surface tension of lime-mud. The progressive rounding of the fragmented clasts probably results from grain attrition by fluidized flow. A synthetic study of limestone conglomerate beds in the Chosen Supergroup suggests that very small percent of the conglomerate layers are of depositional origin, whereas the rest, more than $80\%$, are of diagenetic origin. The common occurrence of diagenetic conglomerates warrants further study on limestone conglomerates elsewhere in the world.

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Genesis and Characteristics of the Soil Clay Minerals Derived from Major Parent Rocks in Korea II. Physical and Chemical Properties of the Whole Soils (한국(韓國)의 주요(主要) 모암(母岩)에서 발달(發達)된 토양점토광물(土壤粘土鑛物)의 특성(特性)과 생성학적(生成學的) 연구(硏究) II. 토양(土壤)의 이화학적(理化學的) 특성(特性))

  • Um, Myung-Ho;Kim, Tai-Soon
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.2
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    • pp.79-85
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    • 1991
  • This study reports on the physical and chemical properties of the whole soils (<2mm) derived from five major rocks of granite, granite-gneiss, limestone, shale, and basalt in Korea. The properties were considered from the kind and frequency distribution of rock-forming minerals in the parent rocks. In particle size distribution, sand fractions were high in the soils from granite-gneiss, silt fractions mainly, in the residual soils from limestone, shale, and basalt. And clay fractions were particularly high in the colluvial soil from limestone and the old alluvial soil from basalt. pH, extractable Ca and Mg, and cation exchange capacity of the soils derived from limestone might be considered to be high due to the presence of sand and/or silt-sized calcite and dolomite inherited from the parent rocks. However, the soils derived from granite and granite-gneiss, being abundant in feldspars, quartz, and micas, showed a tendency to the contrary. A soil from shale composing of high quartz tended to have pH. extractable Ca, base saturation, and low exchangeable Al. In total element analysis, the soils derived from parent rocks with high contents of (i) orthoclase and micas, (ii) biotite, primary chlorite, and augite, and (iii) carbonate minerals and plagioclase as a rock-forming mineral showed a tendency to decrease the contents of $K_2O$, $Fe_2O_3$ and MgO, and CaO in comparison with those of their parent rocks.

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