• Title/Summary/Keyword: Chemical phenomena

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Die Finishing Process Using Electro-Chemical Grinding (전해연삭을 이용한 금형의 다듬질 가공특성)

  • 황찬해;정해도
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.2
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    • pp.89-96
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    • 2000
  • This paper describes the characteristic of die finishing to obtain smooth surface using electro-chemical grinding after cutting process. Electro-chemical grinding is possible under lower load and tool wear comparing with those in the mechanical grinding. Conventionally, if the metal bonding material of the grinding wheel is directly t contacted with workpiece, the current is circulated without electrolytic phenomena. Sometimes, electrical discharge is occurred between tool and workpiece. To cope with this problem, the metal-resin bonded pellet was used in this study. This pellet is composed of optimal volume of metal and resin powders and its characteristics are changable with the each volume of powders. Finally, high efficient die finishing is realized using metal resin bonded pellet in electro-chemical grinding.

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The rheology of two-dimensional systems

  • Fuller, G.;Yim, K.S.;Brooks, C.;Olson, D.;Frank, C.
    • Korea-Australia Rheology Journal
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    • v.11 no.4
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    • pp.321-328
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    • 1999
  • This paper discusses the rheology of complex interfaces comprised of amphiphilic materials that are susceptible to flow-induced orientation and deformation. The consequence of the coupling of the film micro-structure to flow leads to nonlinear rheology and surface fluid dynamics. Experimental methods designed to determine the mechanical rheological material functions of fluid-fluid interfaces as well as local, molecular and morphological responses are presented. These include a newly developed interfacial stress rheometer, flow ultraviolet dichroism, and Brewster-angle microscopy. These techniques are applied to a number of complex interfaces ranging from low molecular weight amphiphiles to polymer monolayers. Nonlinear flow phenomena ranging from two-dimensional nematic responses to highly elastic surface flows that manifest surface normal stress differences and elongational viscosities are described.

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Constitutive equation and damping function for entangled polymers

  • Osaki, Kunihiro
    • Korea-Australia Rheology Journal
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    • v.11 no.4
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    • pp.287-291
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    • 1999
  • The tube model theory of entangled polymer presumes that the polymer chain holds its equilibrium contour length under certain conditions of flow; at times longer than a certain characteristic time, ${\tau}_k$, in the stress relaxation process following any flow history; in steady flow of rates smaller than ${{\tau}_k}^{-1}$; etc. Rheological phenomena associated with this presumption are discussed.

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Fabrication of Activated Carbon Fibers from Polyacrylonitrile-Derived Carbon Fibers: Investigating CO2 Adsorption Capability in Relation to Surface Area

  • Seung Geon Kim;Sujin Lee;Inchan Yang;Doo-Won Kim;Dalsu Choi
    • Composites Research
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    • v.36 no.6
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    • pp.402-407
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    • 2023
  • Activated carbon fibers (ACFs) are fibrous form of activated carbon (AC) with higher mechanical strength and flexibility, which make them suitable for building modules for applications including directional gas flow such as air and gas purification. Similarly, ACFs are anticipated to excel in the efficient capture of CO2. However, due to the difficulties in fabricating monofilament carbon fibers at a laboratory scale, most of the studies regarding ACFs for CO2 capture have relied on electrospun carbon fibers. In this study, we fabricated monofilament carbon fibers from PAN-based monofilament precursors by stabilization and carbonization. Then, ACFs were successfully prepared by chemical activation using KOH. Different weight ratios ranging from 1:1 to 1:4 were employed in the fabrication of ACFs, and the samples were designated as ACF-1 to ACF-4, respectively. As a function of KOH ratio, increase in surface area could be observed. However, the CO2 adsorption trend did not follow the surface area trend, and the ACF-3 with second largest surface area exhibited the highest CO2 adsorption capacity. To understand the phenomena, nitrogen content and ultramicropore distribution, which are important factors determining CO2 adsorption capacity, were considered. As a result, while nitrogen content could not explain the phenomena, ultramicropore distribution could provide a reasoning that the excessive etching led ACF-4 to develop micropore structure with a broader distribution, resulting in high surface area yet deteriorated CO2 adsorption.

NUMERICAL APPROACH FOR QUANTIFICATION OF SELFWASTAGE PHENOMENA IN SODIUM-COOLED FAST REACTOR

  • JANG, SUNGHYON;TAKATA, TAKASHI;YAMAGUCHI, AKIRA;UCHIBORI, AKIHIRO;KURIHARA, AKIKAZU;OHSHIMA, HIROYUKI
    • Nuclear Engineering and Technology
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    • v.47 no.6
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    • pp.700-711
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    • 2015
  • Sodium-cooled fast breeder reactors use liquid sodium as a moderator and coolant to transfer heat from the reactor core. The main hazard associated with sodium is its rapid reaction with water. Sodium-water reaction (SWR) takes place when water or vapor leak into the sodium side through a crack on a heat-transfer tube in a steam generator. If the SWR continues for some time, the SWR will damage the surface of the defective area, causing it to enlarge. This self-enlargement of the crack is called "self-wastage phenomena." A stepwise numerical evaluation model of the self-wastage phenomena was devised using a computational code of multicomponent multiphase flow involving a sodium-water chemical reaction: sodiumwater reaction analysis physics of interdisciplinary multiphase flow (SERAPHIM). The temperature of gas mixture and the concentration of NaOH at the surface of the tube wall are obtained by a numerical calculation using SERAPHIM. Averaged thermophysical properties are used to assess the local wastage depth at the tube surface. By reflecting the wastage depth to the computational grid, the self-wastage phenomena are evaluated. A two-dimensional benchmark analysis of an SWAT (Sodium-Water reAction Test rig) experiment is carried out to evaluate the feasibility of the numerical model. Numerical results show that the geometry and scale of enlarged cracks show good agreement with the experimental result. Enlarged cracks appear to taper inward to a significantly smaller opening on the inside of the tube wall. The enlarged outer diameter of the crack is 4.72 mm, which shows good agreement with the experimental data (4.96 mm).

A Study on the Reactor Configuration and Thermal Conditions for the Growth of High Quality Thin Film of GaN Layer (고품질 질화물 반도체 박막 성장을 위한 반응로 구조 및 열적 조건에 관한 연구)

  • Kim, Jin-Taek;Baek, Byung-Joon;Lee, Cheul-Ro;Pak, Bock-Choon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1632-1639
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    • 2004
  • Numerical calculation has been performed to investigate the transport phenomena in the horizontal reactor which has two different gas inlets for MOCVD(metalorganic chemical vapor deposition). The full elliptic governing equations for continuity, momentum, energy and chemical species are solved by using the commercial code FLUENT. It is investigated how thermal characteristics, reactor geometry, and the operating parameters affect flow fields, mass fraction of each reactants. The numerical simulations demonstrate that flow rate of each species, inlet geometry of the reactor, and its distance from the susceptor as well as the inclination of upper wall of reactor can be used effectively to optimize reactor performance. The commonly used idealized boundary conditions are also investigated to predict flow phenomena in the actual deposition system.

Linear Response Theory for the Mechanical Energy Relaxation of Solid High Polymers at Low Temperature (抵溫에서의 固體 重合體의 力學的 에너지 緩和에 對한 線形反應 理論)

  • Eu, Byung Chan
    • Journal of the Korean Chemical Society
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    • v.20 no.5
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    • pp.340-350
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    • 1976
  • Linear response theory is proposed to be applied for theoretical description of the phenomena in mechanical spectroscopy of solid high polymers below glass transition temperatures. The energy dissipation by sample is given in terms of certain time correlation functions. It is shown that the result leads to the result by Kirkwood on the energy loss and relaxation of cross-linked polymers, if the Liouville operator is replaced by the diffusion equation operator of Kirkwood. An approximation method of calculating the correlation functions is considered in order to show a way to calculate relaxation times. Using the approximation method, we consider a double-well potential model for energy relaxation, in order to see a connection between the present theory and a model theory used in mechanical energy relaxation phenomena of solid polymers containing pendant cyclohexyl groups at low temperature.

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Transmission Electron Microscopy on Memristive Devices: An Overview

  • Strobel, Julian;Neelisetty, Krishna Kanth;Chakravadhanula, Venkata Sai Kiran;Kienle, Lorenz
    • Applied Microscopy
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    • v.46 no.4
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    • pp.206-216
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    • 2016
  • This communication is to elucidate the state-of-the-art of techniques necessary to gather information on a new class of nanoelectronic devices known as memristors and related resistive switching devices, respectively. Unlike classical microelectronic devices such as transistors, the chemical and structural variations occurring upon switching of memristive devices require cutting-edge electron microscopy techniques. Depending on the switching mechanism, some memristors call for the acquisition of atomically resolved structural data, while others rely on atomistic chemical phenomena requiring the application of advanced X-ray and electron spectroscopy to correlate the real structure with properties. Additionally, understanding resistive switching phenomena also necessitates the application not only of pre- and post-operation analysis, but also during the process of switching. This highly challenging in situ characterization also requires the aforementioned techniques while simultaneously applying an electrical bias. Through this review we aim to give an overview of the possibilities and challenges as well as an outlook onto future developments in the field of nanoscopic characterization of memristive devices.

Confirmation of The Fouling Phenomena in CDI Process and The Establishment of Its Removal Process Conditions (CDI 전극 내 파울링 현상 확인 및 제거공정 조건의 확립)

  • Kim, Tae Yeong;Rhim, Ji Won
    • Membrane Journal
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    • v.29 no.5
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    • pp.276-283
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    • 2019
  • In this study, The experiments of the confirmation of the fouling phenomena in CDI process and the establishment of its removal process conditions were carried out. The foulant concentrations of humic acid sodium salt (HA) added to the feed solution were 5, 10, 15 mg/L, respectively. The occurrence of fouling under the certain adsorption/desorption conditions could be confirmed with an increase in adsorption and desorption concentration curve over time. Both the voltage and time in adsorption and desorption processes were changed to eliminate the fouled pollutants. Typically, the fouling removal condition was found at the adsorption condition 1.2 V/5 min and the desorption condition -3 V/2 min, respectively.