• Journal of The Korean Society of Grassland and Forage Science
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• v.43 no.1
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• pp.50-55
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• 2023

The present study investigated the effects of forage cutting and baler mixing on the chemical compositions, fermentation indices, and aerobic stability of whole crop rice (WCR) haylage. The WCR ("Youngwoo") was harvested at 48.4% dry matter and ensiled into a 300 kg bale silo with forage cutting (whole crop without cutting vs. 5 cm of cutting length). The WCR forages were ensiled without baler mixing process (CON) or with (MIX). The concentrations of dry matter, crude protein, ether extract, crude ash, neutral detergent fiber, and acid detergent fiber of whole crop rice before ensiling were 48.4, 9.70, 2.57, 6.11, 41.2, and 23.5%, respectively. The forage cutting did not affect the chemical compositions, fermentation indices, microbes, and aerobic stability of WCR haylage (p>0.05). The CON haylages tend to be higher in NDF content (p<0.10). The MIX haylages had lower in lactate (p=0.019), and lactate:acetate ratio (p<0.001). The MIX haylages had higher in lactic acid bacteria (LAB) (p=0.010). Therefore, this study concluded that the fermentation quality of WCR haylage improved by baler mixing, but had no effects by forage cutting.

• Journal of the Geological Society of Korea
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• v.54 no.5
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• pp.579-584
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• 2018

It is crucial to determine a mixing ratio using an end-member mixing analysis when there is seawater intrusion. In this study, an error from the calculation of the mixing ratio between seawater and freshwater based on the principles of uncertainty was determined. I present the errors in the calculated mixing ratios as a function of the chemical difference between the mean seawater concentrations and standard deviations. The error is caused by: (1) the mixing ratio between seawater and freshwater; (2) the difference between the mean concentration and the standard deviation; and (3) the difference of the tracer concentration between freshwater and seawater (inversely). In particular, the error may determine hydrogeochemical process (either precipitation or dissolution) when a value of ionic delta (difference between measured and theoretical concentration) is close to zero during cation exchange by seawater intrusion.

• Journal of the Optical Society of Korea
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• v.10 no.3
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• pp.130-142
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• 2006

Lab-on-a-chip technology is attracting great interest because the miniaturization of reaction systems offers practical advantages over classical bench-top chemical systems. Rapid mixing of the fluids flowing through a microchannel is very important for various applications of microfluidic systems. In addition, highly sensitive on-chip detection techniques are essential for the in situ monitoring of chemical reactions because the detection volume in a channel is extremely small. Recently, a confocal surface enhanced Raman spectroscopic (SERS) technique, for the highly sensitive biological analysis in a microfluidic sensor, has been developed in our research group. Here, a highly precise quantitative measurement can be obtained if continuous flow and homogeneous mixing condition between analytes and silver nano-colloids are maintained. Recently, we also reported a new analytical method of DNA hybridization involving a PDMS microfluidic sensor using fluorescence energy transfer (FRET). This method overcomes many of the drawbacks of microarray chips, such as long hybridization times and inconvenient immobilization procedures. In this paper, our recent applications of the confocal Raman/fluorescence microscopic technology to a highly sensitive lab-on-a-chip detection will be reviewed.

• Journal of Institute of Convergence Technology
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• v.4 no.2
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• pp.51-54
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• 2014

Energy storage not only reduces the mismatch between supply and demand but also improves the performance and reliability of energy systems. The different forms of energy that can be stored, including mechanical, electrical and thermal energy. Phase change materials (PCM) are latent heat storage materials. A large number of phase change materials (organic, inorganic and eutectic) are available in any required temperature range. We concentrated on eutectic materials and made a eutectic by mixing urea and choline chloride. Heat capacity ($C_p$) is one of the most important properties to be considered when a process is developed using the eutectic and currently DSC (Differential Scanning Calorimetry) has been proved as an effective technique to measure the heat capacity. This study focused on measuring heat capacity ($C_p$) of the mixing urea and choline chloride by DSC.

• Journal of the Korean Chemical Society
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• v.15 no.4
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• pp.177-181
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• 1971

Free radicals of lysozyme produced by $Ti-H_2O_2$ system were studied in aqueous solution at room temperature using ESR with a continuous flow-mixing. The spectra, each consisting of a doublet with 5.5 G splitting and a broad resonance covering 80 G splitting are closely similar in shape to that for solid irradiated in vacuum at $77^{\circ}K$ and observed at room temperature immediately on warming. The result is assumed to indicate that the secondary protein radical components formed within 0.01 second, dead time of the mixing chamber, and initiated by hydrogen atom abstraction at ${\alpha}$-carbon atom of peptide chain in liquid solution at room temperature are identical to those resulting from the initial formation of a mixture of positive holes and negative ions by ionization processes as well as radical fragments by the rupture of chemical bonds in the solid during similar time at the same temperature. A broad resonance is observed with considerable amplitude on the high field side of the doublet, which is quite dissimilar to the spectra of irradiated solid lysozyme. This resonance was tentatively attributed to the polypeptide free radical in which unpaired electrons are localized on side chain.

• Macromolecular Research
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• v.9 no.3
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• pp.150-156
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• 2001

Polystyrenes(PS) were grafted onto polypropylene(PP) in the PP solution by ultrasonic irradiation-initiated polymerization of styrene. The resulting products consisted of mixtures of homopolymers and PP-PS copolymer because of the homopolymerization of styrene itself and copolymerization with PP. The dependency of the designated polymerization on sonication times was investigated to monitor the evolution lion of the copolymerization. Formation of the PP-PS copolymer was confirmed by FTIR analysis of the reaction products after a proper separation procedure of free PS and PP-PS copolymer. It was found that the tendency for the formation of PP-PS copolymer was closely related with the phase behavior of the PP/styrene mixture which was also influenced by sonication time. In order to verify the effectiveness of the PP-PS copolymer as a compatibilizer for PP/PS blend, melt mixing of PP/PS/PP-PS was performed in a batch mixer. During the mixing, the average torque was higher for the blend containing PP-PS copolymer influencing compatibilization. In accordance with the results from FRIR analysis and torque measurement, the PS domain size remarkably decreased in the PP/PS/PP-PS blend.

• Journal of the Korean Society of Safety
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• v.36 no.3
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• pp.24-30
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• 2021

Heat is generated during the synthesis and mixing process of chemical compounds due to a change in activation energy during the reaction. A runaway reaction occurs when sufficient heat is not removed during the heat control process within a reactor, rapidly increasing the temperature, reaction speed, and rate of heat generation inside the reactor. A risk assessment was executed using an RC-1 (Reaction Calorimeter) during Friedel-Crafts acylation. Friedel-Crafts acylation runs the risk of rapid heat generation during Active Pharmaceutical Ingredient (API) manufacturing; it was used to confirm the risk of a runaway reaction at each synthesis stage and during the mixing process. This study used experimental data to develop a safety efficiency improvement plan to control the risks of runaway and other exothermic reactions, which was implemented at the production site of a chemical plant.

• Journal of the Korean Electrochemical Society
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• v.26 no.1
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• pp.1-10
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• 2023

The cathode, which is one of the four major components of a lithium secondary battery, is an important component responsible for the energy density of the battery. The mixing process of active material, conductive material, and polymer binder is very essential in the commonly used wet manufacturing process of the cathode. However, in the case of mixing conditions of the cathode, since there is no systematic method, in most cases, differences in performance occur depending on the manufacturer. Therefore, LiMn₂O₄ (LMO) cathodes were prepared using a commonly used THINKY mixer and homogenizer to optimize the mixing method in the cathode slurry preparation step, and their characteristics were compared. Each mixing condition was performed at 2000 RPM and 7 min, and to determine only the difference in the mixing method during the manufacture of the cathode other experiment conditions (mixing time, material input order, etc.) were kept constant. Among the manufactured THINKY mixer LMO (TLMO) and homogenizer LMO (HLMO), HLMO has more uniform particle dispersion than TLMO, and thus shows higher adhesive strength. Also, the result of the electrochemical evaluation reveals that HLMO cathode showed improved performance with a more stable life cycle compared to TLMO. The initial discharge capacity retention rate of HLMO at 69 cycles was 88%, which is about 4.4 times higher than that of TLMO, and in the case of rate capability, HLMO exhibited a better capacity retention even at high C-rates of 10, 15, and 20 C and the capacity recovery at 1 C was higher than that of TLMO. It's postulated that the use of a homogenizer improves the characteristics of the slurry containing the active material, the conductive material, and the polymer binder creating an electrically conductive network formed by uniformly dispersing the conductive material suppressing its strong electrostatic properties thus avoiding aggregation. As a result, surface contact between the active material and the conductive material increases, electrons move more smoothly, changes in lattice volume during charging and discharging are more reversible and contact resistance between the active material and the conductive material is suppressed.

• Journal of Environmental Science International
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• v.3 no.1
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• pp.31-38
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• 1994

The diffusion of the pollutants released into atmosphere is dependent on its chemical reaction, topography and micrometeorological characteristics. The purpose of the study is to investigate how much micrometeorological characteristics such as stability, wind speed and mixing height affect the diffusion of the air pollutants. For this purpose, this paper let 1) the basic theory be K-theory, 2) eddy diffusivity and wind speed be dependent on mixing height and stability, and 3) Grout method be used for numeric calculation. The result was 1) the more unstable condition, the higher mixing height and the higher wind speed we, the lower pollutants concentration appears, 2) the most intensive effect on the distribution of the pollutant concentration is the atmospheric stability.

• Journal of computational fluids engineering
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• v.7 no.2
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• pp.1-7
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• 2002

The present study is developed device that effectively mixes raw water and chemicals by using the residual head of fluid in the front pipe of flocculation basin, and performed non-dimensional analysis and presented design standard to apply to water plants that have different equipment capacity. The variables for design are a proper ratio between an outer diameter of deflector and a diameter of pipe, a distance between deflector and orifice and a determination of orifice diameter for an optimal mixing. Numerical study has analyzed flow field on a basis of turbulent intensity in an orifice downstream. As Reynolds number of In-Line Orifice was increased from identical design variable, the turbulent intensity of pipe center was no changed almost.