• Title/Summary/Keyword: Chemical Additive

Search Result 711, Processing Time 0.028 seconds

Effect of Conductive Additives in La0.8Sr0.2MnO3 Perovskite Electrodes for Oxygen Reduction and Evolution in Alkaline Solution (알칼리용액에서 La0.8Sr0.2MnO3 페롭스카이트 촉매의 산소환원 및 발생반응에서 도전재의 영향)

  • SHIM, JOONGPYO;LOPEZ, KAREEN J.;YANG, JIN-HYUN;SUN, HO-JUNG;PARK, GYUNGSE;EOM, SEUNGWOOK;LEE, HONG-KI
    • Journal of Hydrogen and New Energy
    • /
    • v.27 no.3
    • /
    • pp.276-282
    • /
    • 2016
  • The effects of conductive additives in a $La_{0.8}Sr_{0.2}MnO_3$ perovskite bifunctional electrode for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) were investigated in an alkaline solution. Highly porous carbon black (CB) and Ni powder were added to the bifunctional electrodes as conductive additives. The surface morphologies of electrodes containing CB and Ni were observed by scanning electron microscopy (SEM). The current densities for both ORR and OER were changed by the addition of CB. The conductive additive changed physical properties of bifunctional electrodes such as the sheet conductance, gas permeability and contact angle. It was observed that the air permeability of electrode was most effective to enhance the currents for ORR and OER.

Effect of FeOX Inorganic Additive in SAGD Process for Oil Sand Recovery (고온 고압 스팀을 주입하는 SAGD 공정에서 FeOX 무기첨가제가 오일샌드 회수율에 미치는 영향)

  • Song, Byung Jin;You, Nansuk;Kim, Ji Man;Lee, Chul Wee
    • Applied Chemistry for Engineering
    • /
    • v.25 no.1
    • /
    • pp.113-115
    • /
    • 2014
  • Lab scale simulated steam assisted gravity drainage (SAGD) process devices were used to investigate the effect of inorganic additives for the bitumen recovery from oil sand. An extra heavy oil similar with bitumen and 1.5 mm diameter of the glass bead instead of clay was mixed to simulate the oil sand. In addition, $FeO_X$ synthesized from the inorganic process was introduced as an inorganic additive for improving the recovery. Finally, the steam heat transfer rate of approximately 40% following the introduction of inorganic additives which also increased the recovery rate by about 30%.

Cassava Tops Ensiled With or Without Molasses as Additive Effects on Quality, Feed Intake and Digestibility by Heifers

  • Van Man, Ngo;Wiktorsson, Hans
    • Asian-Australasian Journal of Animal Sciences
    • /
    • v.14 no.5
    • /
    • pp.624-630
    • /
    • 2001
  • Two experiments on the effects of molasses additive on cassava tops silage quality to its feed intake and digestibility by growing Holstein$\times$local crossbred heifers were carried out. Sixteen plastic bags of one meter diameter and two meters length were allocated in a $2{\times}2$ factorial design with four replicates in the ensiling study, with and without the molasses additive and with two storage times (2 and 3 months). The silage produced in the first experiment was used in the feed intake and digestibility study. Six crossbred Holstein heifers, 160-180 kg live weight, were randomly allocated in a $3{\times}2$ change-over design to three treatments: Guinea grass ad libitum, 70% of grass ad libitum with a supplement of non-molasses cassava silage ad libitum, and 70% of grass ad libitum with a supplement of molasses cassava silage ad libitum. Ensiling was shown to be a satisfactory method for preservation of cassava tops. The HCN content was significantly reduced from $840mg\;kg^{-1}$ to 300 or $130mg\;kg^{-1}$, depending on storage period. The tannin content was not significantly changed. Molasses additive resulted in lower pH, Crude Protein (CP), NDF and higher DM content but did not otherwise affect chemical composition. The voluntary feed intake per 100 kg live weight of the heifers was 2.59, 2.65 and 2.91 kg DM of Guinea grass, non-molasses cassava tops silage and molasses cassava tops silage diet, respectively. Crude protein intake was significantly improved in the cassava tops silage diets. The apparent digestibility of DM, OM, CP, NDF and ADF decreased with the silage supplement diets. No significant difference in digestibility was found between the non-molasses and molasses silage diets. The digestibility coefficient of DM, OM, CP, NDF, ADF in non-molasses cassava tops silage and molasses cassava tops silage was 49.4, 52.1, 45.81, 36.6, 27.7 and 49.7, 51.9, 47.55, 28.1, 19.5, respectively. It is concluded that cassava tops can be preserved successfully by ensiling and that cassava tops silage is a good feed resource for cattle.

Effects of Applying Microbial Additive Inoculants to Spent Mushroom Substrate (Flammulina velutipes) on Rumen Fermentation and Total-tract Nutrient Digestibility in Hanwoo Steers (팽이버섯 부산물 발효에 따른 한우 거세우 반추위 성상 및 소화율에 미치는 영향)

  • Baek, Youl-Chang;Jeong, Jin-Young;Oh, Young-Kyoon;Kim, Min-Seok;Lee, Sung-Dae;Lee, Hyun-Jeong;Do, Yoon-Jung;Ahmadi, Farhad;Choi, Hyuck
    • Korean Journal of Organic Agriculture
    • /
    • v.25 no.3
    • /
    • pp.569-586
    • /
    • 2017
  • We inoculated a spent mushroom substrate from Flammulina velutipes (SMSF) with a microbial additive and assessed the effects on chemical composition, ruminal fermentation parameters, and total-tract nutrient digestibility. In Exp. 1, three cannulated Hanwoo steers were used in an in situ trial to determine the degradation kinetics of dry matter (DM) and crude protein (CP). In Exp. 2, three Hanwoo steers were randomly assigned to experimental diets according to a $3{\times}3$ Latin square for a 3-week period (2 weeks for adaptation and 1 week for sample collection). Experimental diets included the control diet (3.75 kg/d formulated concentrate mixture + 1.25 kg/d rice straw), SMSF diet (3.19 kg/d formulated concentrate mixture + 1.25 kg/d rice straw + 0.56 kg/d SMSF), and inoculated SMSF (ISMSF) diet (3.19 kg/d formulated concentrate mixture + 1.25 kg/d rice straw + 0.56 kg/d ISMSF). The chemical composition of ISMSF did not differ from that of SMSF. Microbial additive inoculation decreased pH (P<0.05) and improved preservation for SMSF. The percentages of DM, neutral detergent fiber (NDF), and acid detergent fiber (ADF) in ISMSF were slightly lesser than those in SMSF. Ruminal fermentation characteristics and total-tract nutrient digestibility were not affected by diet. Overall, microbial additive inoculation improved preservation for SMSF and may allow improved digestion in the rumen; however, the total digestible nutrients (TDN) of SMSF and ISMSF diets were slightly lesser than the control diet. The ISMSF can be used as an alternative feedstuff to partially replace formulated concentrate feed.

The Effect of Additives on the Performance of Aqueous Organic Redox Flow Battery Using Quinoxaline and Ferrocyanide Redox Couple (수계 유기 레독스 흐름 전지 성능에서의 첨가제 효과)

  • Chu, Cheonho;Lee, Wonmi;Kwon, Yongchai
    • Korean Chemical Engineering Research
    • /
    • v.57 no.6
    • /
    • pp.847-852
    • /
    • 2019
  • In this study, the effect of additives on the performance of aqueous organic redox flow battery (AORFB) using quinoxaline and ferrocyanide as active materials in alkaline supporting electrolyte is investigated. Quinoxaline shows the lowest redox potential (-0.97 V) in KOH supporting electrolyte, while when quinoxaline and ferrocyanide are used as the target active materials, the cell voltage of this redox combination is 1.3 V. When the single cell tests of AORFBs using 0.1 M active materials in 1 M KCl supporting electrolyte and Nafion 117 membrane are implemented, it does not work properly because of the side reaction of quinoxaline. To reduce or prevent the side reaction of quinoxaline, the two types of additives are considered. They are the potassium sulfate as electrophile additive and potassium iodide as nucleophilie additive. Of them, when the single cell tests of AORFBs using potassium iodide as additive dissolved in quinoxaline solution are performed, the capacity loss rate is reduced to $0.21Ah{\cdot}L^{-1}per\;cycle$ and it is better than that of the single cell test of AORFB operated without additive ($0.29Ah{\cdot}L^{-1}per\;cycle$).

Effect of Vinylene Carbonate as an Electrolyte Additive on the Electrochemical Properties of Micro-Patterned Lithium Metal Anode (미세 패턴화된 리튬금속 전극의 Vinylene Carbonate 첨가제 도입에 따른 전기화학 특성에 관한 연구)

  • Jin, Dahee;Park, Joonam;Dzakpasu, Cyril Bubu;Yoon, Byeolhee;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
    • /
    • v.22 no.2
    • /
    • pp.69-78
    • /
    • 2019
  • Lithium metal anode with the highest theoretical capacity to replace graphite anodes are being reviewed. However, the dendrite growth during repeated oxidation/reduction reaction on lithium metal surface, which results in poor cycle performance and safety issue has hindered its successful implementation. In our previous work, we solved this problem by using surface modification technique whereby a surface pattern on lithium metal anode is introduced. Although the micro-patterned Lithium metal electrode is beneficial to control Li metal deposition efficiently, it is difficult to control the mossy-like Li granulation at high current density ($>2.0mA\;cm^{-2}$). In this study, we introduce vinylene carbonate (VC) electrolyte additive on micro patterned lithium metal anode to suppress the lithium dendrite growth. Owing to the synergetic effect of micro-patterned lithium metal anode and VC electrolyte additive, lithium dendrite at a high current density is dense. As a result, we confirmed that the cycle performance was further improved about 6 times as compared with the reference electrode.

The Effect of Casting Conditions on Shrinkage and Porosity of A356.2 Alloys (A356.2 합금의 수축과 기공에 미치는 주조 조건의 영향)

  • Jeon, Gyu-Tae;Kim, Ki-Young;Kim, Suk-Jun
    • Journal of Korea Foundry Society
    • /
    • v.37 no.6
    • /
    • pp.193-198
    • /
    • 2017
  • In this study, volumes of shrinkage and porosity of A356.2 alloys during casting were analyzed as a function of melt temperature, pouring diameter, mold temperature, and Sr content. The temperature of the melt barely affected the shrinkage and porosity formation. The pouring diameter determined the pouring rate, and it was proportional to the shrinkage, yet no relationships with the density of porosity were observed. When the mold was heated at $400^{\circ}C$, shrinkage and porosity in the alloy increased above the one in the mold without heating. However, the mold without heating experienced interior shrinkage and the porosity was mainly distributed near interior shrinkage. The addition of Sr to the melt resulted in more shrinkage and less porosity.

Preparation of Aluminum Metalworking Lubricant with Synthesized Malonic Diester (말론산 에스테르 합성 및 이를 이용한 알루미늄 가공용 절삭유의 제조)

  • Lee, Soo;Park, Keun-Ho;Song, Ju-Yeong
    • Journal of the Korean Applied Science and Technology
    • /
    • v.23 no.3
    • /
    • pp.192-198
    • /
    • 2006
  • To provide an aqueous rust inhibitor for metalworking lubricant having low toxicity and excellent rust resistance, we synthesized diester of malonic acid by three consecutive esterifications with over 98% of conversion. This substituted malonic diester could be used as an additive to mineral oil based metalworking lubricant. These metalworking lubricant compositions were showed excellent rust resistance and suitable for various metals and different metalworking processes including hot rolling and cold rolling of aluminum and aluminum alloys.

Characteristics of oyster shell using zeta potential (제타 전위에 의한 참굴 패각의 특성연구)

  • Lee, Seung-Woo;Shin, Na-Young;Choi, Cheong-Song
    • 한국생물공학회:학술대회논문집
    • /
    • 2001.11a
    • /
    • pp.890-893
    • /
    • 2001
  • Zeta potential measurement not only can provide surface information on colloidal biomaterials but more importantly can be used in bioprocess control and products quality control. In this study, zeta potentials for intracrystalline proteins of each layers from oyster shell prepared in 1mM NaCl at different pH were measured. Also, in forming calcite crystals with intracrystalline proteins as an additive extracted from oyster shell, the zeta potentials were measured. These studies were performed to verify the primary role of intracrystalline proteins in controlling the formation, morphological development and crystallography of the biocomposite.

  • PDF

Study on Lubrication Characteristics of Lubrication for Lubricity Improver in Dimethyl Ether (디메틸에테르에 첨가된 윤활성향상제의 윤활특성에 관한 연구)

  • Park, Cheonkyu;Jang, Eunjung;Jung, Choongsub;Lee, Bonghee;Na, Byungki
    • Tribology and Lubricants
    • /
    • v.29 no.2
    • /
    • pp.117-123
    • /
    • 2013
  • Dimethyl ether (DME) has a high cetane number that is suitable for diesel fuel. DME does not contain sulfur or nitrogen, and is an oxygenated fuel so it produces no particulate matter when combusted and is environmentally friendly. DME fuel for diesel engines show excellent material properties such as a lower volumetric heating value, lower boiling point, lower lubricity, and stronger solvent effect than light oil. This study experimentally examined a lubricity improver (LI) for dimethyl ether. A diesel LI based on biodiesel and fatty acid methyl ester was tested among DME LI candidates. The long-term storage stability and physical properties of the optimum LI for DME were determined.