• Title/Summary/Keyword: Ceramic media

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Nitrided LATP Solid Electrolyte for Enhanced Chemical Stability in Alkaline Media (질화 처리된 LATP 고체전해질의 알칼라인 용액내에서의 내화학특성 개선 연구)

  • Seong, Ji Young;Lee, Jong-Won;Im, Won Bin;Kim, Sung-Soo;Jung, Kyu-Nam
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.45-50
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    • 2015
  • In the present work, to increase the chemical stability of the lithium-ion-conducting ceramic electrolyte ($Li_{1+x+y}Al_xTi_{2-x}Si_yP_{3-y}O_{12}$, LATP) in the strong alkaline solution, the surface of LATP was modified by the nitridation process. The surface and structural properties of nitride LATP solid electrolyte were characterized by X-ray diffraction, X-ray photoelectron spectrometer and scanning electron microscopy and ac-impedance spectroscopy, which were correlated to the chemical stability and electrochemical performance of LATP. The nitrided LATP immersed in the alkaline solution for 30 days exhibits the enhanced chemical stability than the pristine LATP. Moreover, a rechargeable hybrid Li-air battery constructed with the nitrided LATP solid electrolyte shows considerably reduced discharge-charge voltage gaps (enhanced the round-trip efficiency) in comparison to the cell constructed with pristine LATP, which indicate that the surface nitridation process can be the efficient way to improve the chemical stability of solid electrolyte in alkaline media.

Application of Phytoremediation for Total Nitrogen and Total Phosphorus Removal from Treated Swine Wastewater and Bio-methane Potential of the Biomass (돈분뇨 처리수 유래 질소와 인 제거를 위한 식물정화법 활용과 바이오매스의 바이오메탄 잠재성 연구)

  • Sudiarto, Sartika Indah Amalia;Choi, Hong Lim;Renggaman, Anriansyah
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.4
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    • pp.21-31
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    • 2015
  • The aim of this study is to determine the removal efficiency of total nitrogen and phosphorus from treated swine wastewater by Phragmites australis and Miscanthus sacchariflorus var Geode Uksae-1, and to determine its biomass total energy value and biomethane potential. Plants were grown with a bedding mixture either soil and sand or soil, sand, and bioceramic. Treeated swine wastewater with Total nitrogen (TN) and Total phosphorus (TP) of 222.78 mg/L and 66.11 mg/L, respectively, was utilized. The TN and TP removal is higher in the bio-ceramic-soil-sand bedding media treatment. The highest TN removal of 96.14% was performed by Miscanthus sacchariflorus var Geode Uksae-1, but the elemental analysis shows that Phragmites australis contains more nitrogen than Miscanthus sacchariflorus var Geode Uksae-1, indicating higher nitrogen uptake. The highest TP removal of 98.12% was performed by Phragmites australis. The cellulose content of the plant grown with the bioceramic-soil-sand bedding was approximately 3-6% higher than that of the plant grown in the soil-sand bedding. Different growing substrates may have an effect on the fiber content of plants. The biomethane potential of the produced biomass of the plants was between 57.01 and $99.25L-CH_4/kg$ VS. The lignin content is believed to inhibit the breakdown of plant biomass, resulting in the lowest methane production in the Phragmites australis grown in the soil-sand bedding media.

무산소-호기공정을 이용한 순환식 생물여과반응기에서 동시 질산화 및 탈질화의 특성 연구

  • Lee, Su-Cheol;Kim, Dong-Jin
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.343-346
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    • 2000
  • This study was carried out to investigate the effects of influent $NH_4^{\;+}-N$ load, C/N ratio and superficial air velocity on the nitrogen removal efficiencies. Laboratory scale upflow biological aerated filter(BAF) was consisted of an anoxic-aerobic filter packed with porous ceramic media and operated with synthetic wastewater. BAFs requires less energy and space for the system when compared to conventional activated sludge process. The influent C/N ratios were varied from 0 to 1 by adjusting acetate. Various superficial air velocity had been applied to investigate aeration effect on nitrogen removal. The BAF reactor showed more than 90% average $NH_4^{\;+}-N$ removal efficiencies at $NH_4^{\;+}-N$ loading in the range of $0.26{\sim}1.33$ kg $NH_4^{\;+}-N/m^3{\cdot}d$ and 62% average T-N removal efficiencies at the C/N ratio of 1. Moreover, average T-N removal efficiencies increased as the superficial air velocity increased, because of the increase $NH_4^{\;+}-N$ removal efficiencies.

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Performance Evaluation of Sintered Metal Filter in LILW Vitrification Facility (중.저준위 방사성폐기물 유리화설비에서 금속필터 적용성평가)

  • Park, Seung-Chul;Kim, Byong-Ryol;Hwang, Tae-Won
    • Journal of Energy Engineering
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    • v.15 no.3 s.47
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    • pp.146-153
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    • 2006
  • A performance test of the stainless steel based sintered metal filter was conducted on the low and intermediate level radioactive waste (LILW) vitrification process. The applicability of the metal filter was based on the test results as well. The baseline pressure drop of the metal filter was evaluated similar to the ceramic filter. During the test, when the flow rate of off-gas was $110Nm^{3}/h$, the total baseline pressure drop was shown as $92mmH_{2}O$. The total pressure drop was attributed to the filter media and the residual dust layer and the value of each was $25mmH_{2}O\;and\;67mmH_{2}O$ respectively. The SEM-EDS spectrum and micrograph of the metal filter specimen showed, no corrosion and no physical damage both at the skin membrane and at the support layer. And most of the baseline pressure drop was caused by the deposition of dust on the surface of the membrane. In conclusion, even though the filter exposure time was short at the test, the performance of the stainless steel based metal filter was acceptable for the treatment of LILW vitrification process.

Microbial Immobilization, Characterization and Isolation of Nitrogen Oxidizing Bacteria (암모니아 및 아질산성 질소 산화세균의 분리 및 특성)

  • Lee, Yong-Seok;Yoo, Ju-Soon;Chung, Soo-Yeol;Park, Choon-Soo;Choi, Yong-Lark
    • Applied Biological Chemistry
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    • v.46 no.1
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    • pp.1-6
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    • 2003
  • Abstract: In order to improve the system for biological nitrogen oxidizing process in sewage and wastewater, a bacterium having high abilities to oxidize of nitrogen was isolated from wastewater and polluted soils. The strain was identified to Bacillus sp. CH-N, based on the physiological and biochemical properties. Characteristics and oxidizing ability of both ammonia and nitrite were examined for the strain, Bacillus sp. CH-N. The strain showed the oxidizing rate about 80% to 90% on the sewage and wastewater after 48 h culture. The nitrogen oxidizing rate was increased in proportion to the initial concentration of glucose. The microorganism, Bacillus sp. CH-N cell immobilized on ceramic carrier were evaluated for the oxidation of ammonia in culture media.

SINTERED $Al_{2}O_{3}$-TiC SUBSTRATE FOR THIN FILM MAGNETIC HEAD

  • Nakano, Osamu;Hirayama, Takasi
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 1998.04b
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    • pp.6-6
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    • 1998
  • In 1957, the first magnetic disk drive compatible with a movable head was introduced as an external file memory device for computer system. Since then, magnetic disks have been improved by increasing the recording density, which has brought about the development of a high performance thin film magnetic head. The thin film magnetic head has a magnetic circuit on a ceramic substrate using IC technology. The physical property of the substrate material is very important because it influences the tribology of head/disk interface and also manufacturing process of the head. $Al_{2}O_{3}$-TiC ceramics, so called ALTIC, is known to be one of the best substrate materials which satisfies this property requirement. Even though the head is not in direct contact with the disk, frequent instantaneous contacts are unavoidable due to its high rotating speed and the close gap between them. This may cause damage in the magnetic recording media and, thus, it is very important that the magnetic head has a good wear resistance. $Al_{2}O_{3}$-TiC ceramics has an excellent tribological property in head/disk interface. Manufacturing process of thin film head is similar to that of IC, which requires extremely smooth and flat surface of the substrate. The substrate must be readily sliced into the heads without chipping. $Al_{2}O_{3}$-TiC ceramics has excellent machineability and mechanical properties. $Al_{2}O_{3}$-TiC ceramics was first developed at Nippon Tungsten Co. as cutting tool materials in 1968, which was further developed to be used as the substrate materials for thin film head in collaboration with Sumitomo Special Metals Co., Ltd. in 1981. Today, we supply more than 60% of the substrates for thin film head market in the world. In this paper, we would like to present the sintering process of $Al_{2}O_{3}$-TiC ceramics and its property in detail.

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Comparison of Combustion Characteristics With and Without Water Tube Simulating Heat Exchanger in Two Sections Porous Media Burner (2단 다공성 매체버너에서 열교환기를 모사한 수관 유무에 따른 연소 특성 비교)

  • Lee, Hui-Do;Kim, Jae-Hyeon;Lee, Kee-Man
    • Journal of the Korean Institute of Gas
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    • v.23 no.5
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    • pp.24-34
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    • 2019
  • In this study, the experimental studies were conducted to analyzing characteristics of combustion and flame stabilizing according to with and without water tube in boiler. The burner has consisted of SiC foam where has the location of submerged flame between a ceramic board acting as flash-back arrestor. Porous burner is also insulated to minimize heat loss in the radial direction. In the condition of fixed equivalence ratio, the flame mode was divided into three stability zones by the flow rate. The main factor for blow-off and flash-back depends on mixture flow rate. Consequently, the case of burner with water-tube has higher NOx emissions than without case. This result explains that the presence of water-tube makes the heat loss resistant to ambient temperature with increasing of NOx. This tendency was proved by predicting the relationship between O2 emission and NO production rate, and by analysing temperature profiles.

Chinese Porcelain Lacquer Painting Art : Primary Analysis on Convergence of Porcelain Decoration and Raw Lacquer (중국 칠도예술: 도자장식과 생칠의 융합에 대한 선행적 분석)

  • Bai, JuanJuan;Sun, Yue;Kim, Won-Suk;Ro, Hae-Sin;Kim, Sung-Min
    • Journal of Digital Convergence
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    • v.17 no.10
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    • pp.405-410
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    • 2019
  • This study is an primary analysis on convergence of porcelain lacquer painting art which is composed of porcelain art and raw lacquer technic. As a part of ceramic art, this study suggest 3 ways of porcelain lacquer decoration with understanding of its history and contemporary status. Lacquer technic gives stability for surface paintings and it also has various media to express its beauty. Porcelain lacquer decoration art contains artistic value and pragmatic purpose for daily life usage. These days, due to unavailability for mass production, it tends to be tried for art work purposes. However this artistic technic and value can be applied to porcelain goods, so that it will raise aesthetic pleasure and cultural diversity.

A Study on the Color Image of Environment Shape Objects in University -Focusing on the Case of Kongju University- (대학 내 공공 환경조형물 색채 감성이미지 분석 연구 -공주대학교 사례를 중심으로-)

  • Kim, Hye-Jin;Chung, Ji-Bok;Choi, Jung-In
    • Journal of Digital Convergence
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    • v.17 no.6
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    • pp.349-354
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    • 2019
  • The purpose of this study is to measure and analyze color image scale when viewing the public objects installed in Kongju National University and the installation environment, and preferred colors and color image scale in the color planning. The research was conducted with the analysis of the sculpture installed in the school and the questionnaire for the students. As a result of the study, suggestions were made for points to be considered for user's perception of environmental sculptures in the school and when constructing the sculpture. This study approaches the color of the public environment sculpture installed in the school academically, and proposes factors to be considered in the color planning stage in the future. Therefore, it is expected that this study will provide appropriate guidelines for the installation and planning of the sculpture in the school.

TEM analysis of IBAD/RABiTS substrates prepared by Tripod polishing (Tripod polishing을 이용한 IBAD/RABiTS 기판의 TEM 분석)

  • Choi, Soon-Mee;Chung, Jun-Ki;Yoo, Sang-Im;Park, Chan;Oh, Sang-Soo;Kim, Cheol-Jin
    • Progress in Superconductivity and Cryogenics
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    • v.8 no.1
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    • pp.9-14
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    • 2006
  • Sample preparation plays a critical role in microstructure analysis using TEM. Although TEM specimen has been usually prepared by jet-polishing or Ar-ion beam milling technique. these methods could not be applied to YBCO CC which is composed of IBAD or RABiTS substrates, several buffet layers, and YBCO superconducting layer because of big difference in mechanical strengths between the metallic phase and oxide phases. To obtain useful cross-sectional information such as interface between the phases or second phases in YBCO CC, it is prerequisite to secure the large area of thin section in the cross-sectional direction. The superconducting layer or the buffer layers are relatively weak and fragile compared to the metallic substrate such as Ni-5wt%W RABiTS of Hastelloy-based IBAD, and preferential removal of weak ceramic phases during polishing steps makes specimen preparation almost impossible. Tripod polisher and small jig were home-made and employed to sample preparation. The polishing angle was maintained <$1^{\circ}$ throughout the polishing steps using 2 micrometers attached to the tripod plate. TEM specimens with large and thin area could be secured and used for RABiTS/IBAD substrate analyses. In some cases, additional Ar-beam ion milling with low beam current and impinging angle was used for less than 30 sec. to remove debris or polishing media attacked to the specimens.