• Title/Summary/Keyword: Cement-paste

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Experimental Study on the Development of EMP Shielded Concrete Using Industrial By-products (산업부산물을 사용한 EMP차폐 콘크리트 개발에 관한 실험적 연구)

  • Min, Tae-Beom;Kim, Hyeong-Cheol;Choi, Hyun-Kuk;Roh, Jeong-Heon;Kim, Kuk-Joo;Park, Young-Jun
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.6
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    • pp.477-484
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    • 2019
  • The purpose of this study is to present basic data for developing concrete with EMP shielding as the structure materials when constructing an EMP shielded building structure. In order to use metal-based recycled aggregates with excellent conductivity and easy procurement for EMP shielding concrete, an evaluation of the stability evaluation and EMP shielding performance was performed. Through the stability evaluation, it was found that the coarse aggregate stability criterion was satisfied, but the oxidized slag did not satisfy the fine aggregate stability criterion, the oxidized slag is not satisfied. In addition, as a result of fresh concrete, the workability is increased and the air volume is decreased. The compressive strength is increased due to the high density and coarse granularity of the recycled aggregates, which increased the cement paste and adhesion, thereby increasing the compressive strength. The results of an EMP shielding test show that aggregates with high shielding performance are electronic arc furnace(EAF) Oxidizing Slag and Cooper Slag. The shielding performance is expected to increase if the average particle size of aggregate is small or uniformly distributed.

Setting Time and Strength Characteristics of Cement Mixtures with Set Accelerating Agent for Shotcrete (숏크리트용 급결제를 첨가한 시멘트 모르타르의 응결 및 강도특성)

  • Kim Jin-Cheol;Ryu Jong-Hyun
    • Journal of the Korea Concrete Institute
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    • v.16 no.1 s.79
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    • pp.70-78
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    • 2004
  • Although set accelerating agents are used generally in New Austrian Tunneling Method, the standards for test methods and quality of set accelerating agents are not prescribed domestically. In this study, the proprieties of the various standards and the characteristics of set accelerating agents for shotcrete were evaluated. The alkali contents of set accelerating agents based on silicate, aluminate and cement were higher than those of alkali-free ones. From the result, it is thought that the quality control of aggregate should be enhanced and that the number of test cycle of alkali-aggregate reaction should be increased. The setting times of cement paste with set accelerating agents based on silicate and alkali-free ones were different largely with mixing methods. Compressive strength of mortar with set accelerating agents based on silicate, aluminate and cement at one day satisfied the specifications of Korea Concrete Institute. However, the strength ratio compared to control mix at 28 days showed as $50{\~}65\%$ except for the alkali-free set accelerating agents. As a results of setting time and strength test, the establishment of domestic standards that can reflect the characteristics of materials and construction methods of tunnels and that can increase quality of set accelerating agents is required immediately.

The Effects of Na2CO3 on Early Strength of High Volume Slag Cement (대량치환 슬래그 시멘트의 초기강도에 미치는 Na2CO3의 영향)

  • Kim, Tae-Wan;Hahm, Hyung-Gil
    • Journal of the Korea Concrete Institute
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    • v.28 no.3
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    • pp.349-356
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    • 2016
  • This report presents the results of an investigation on the early strength development of pastes high volume slag cement (HVSC) activated with different concentration of sodium carbonate ($Na_2CO_3$). The ordinary Portland cement (OPC) was replaced by ground granulated blast furnace slag (GGBFS) from 50% to 90% by mass, the dry powders were blended before the paste mixing. The $Na_2CO_3$ was added at 0, 2, 4, 6, 8 and 10% by total binder (OPC+GGBFS) weight. A constant water-to-binder ratio (w/b)=0.45 was used for all mixtures. The research carried out the compressive strength, ultrasonic pulse velocity (UPV), water absorption and X-ray diffraction (XRD) analysis at early ages(1 and 3 days). The incase of mixtures, V5 (50% OPC + 50% GGBFS), V6 (40% OPC + 60% GGBFS) and V7 (30% OPC + 70% GGBFS) specimens with 6% $Na_2CO_3$, V8 (20% OPC + 80% GGBFS) and V9 (10% OPC + 90% GGBFS) specimens with 10% $Na_2CO_3$ showed the maximum strength development. The results of UPV and water absorption showed a similar tendency to the strength properties. The XRD analysis of specimens indicated that the hydration products formed in samples were CSH and calcite phases.

Study on the Hydration and Strength Properties of Fly-ash Modified Cement Paste and Mortar Using a CSA and Pulp Ash (CSA 및 제지애쉬를 혼합재료 사용한 플라이애쉬 시멘트 모르타르의 수화 및 강도 특성에 관한 연구)

  • Song, Tae-Hyeob;Lee, Sea-Hyun;So, Chee-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.81-88
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    • 2005
  • The fly ash has been widely used in the latest to complement the performance and economical efficiency of the concrete which uses only a normal portland cement, the pulp ash gained through the incineration of paper sludge is possible to be used as the material of concrete because it contains the properties similar to the previous fly ash in ingredients and physical characteristics. Therefore, this research has tested physical characteristics by replacing 20% of fly ash used with the paper ash to solve the problem which lowers the early strength caused when the fly ash was used. As a result, it showed that the fluidity becomes lower and the compressive strength becomes increased by using paper ash. In addition, after mixing the paper ash with the fly ash, it showed that time and heating amount of the 2nd peak of the minor heat of hydration affecting the revelation of strength was equivalent to the combination for normal portland cement, and also indicated that the compressive strength for 3 days is superior to the combination of the fly ash. Therefore, if the paper ash having a regular fineness is used, it was effective in improving the early strength of concrete used the fly ash.

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A STUDY ON THE THERMAL DIFFUSION THROUGH VARIOUS THICKNESS OF BASE AND RESTORATION MATERIALS (수복물(修復物)과 양장재(襄裝材)의 열확산(熱擴散)에 관(關)한 연구(硏究))

  • Yoon, Dong-Ho;Park, Sang-Jin;Min, Byung-Soon;Choi, Ho-Young
    • Restorative Dentistry and Endodontics
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    • v.11 no.1
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    • pp.77-88
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    • 1985
  • The purpose of this study was to examine the thermal diffusion through bases and restorations. The three principle types of base and two restorative materials were included in this study. They were representive brands of a zinc phosphate cement, a zinc oxide-eugenol cement, a calcium hydroxide paste, an amalgam and a composite resin (table 1). The specimens were prepared by placing the bases or restorative materials in laminated plastic molds. 5-mm diameter holes were prepared in the center of square of plastics which were 0.5, 1.0, 2.0, and 3.0mm thick respectively (fig. 1). All materials were manipulated in accordance with manufacturer's recommended proportions. All experimental procedures were carried out dividing them into eight different groups (table 2). Thermal diffusion was measured by means of digital thermometer (DP-100, RKC. instrument Inc. JAPAN) with the surface thermocouple placed on bottom surface of the specimen applying a constant source of heat and cold to the top surface of the each specimen. The thermal stimulus temperature applied on the each specimen surface was in the range of $60^{\circ}C$, $0^{\circ}C$ and $-50^{\circ}C$ respectively. The thermal change were recorded automatically on the multi-Pen recorder (R-16, Rikadenki, Co. JAPAN) connected with thermocouple tips which were centered on the bottom of the specimen. The following results were as follows, 1. Temperature diffusion was highest through amalgam and slowest through the composite resin. 2. As the thickness of restorations increased, the temperature change was decreased. 3. Thermal diffusion was slowest in the presence of zinc oxide-eugenol bases, followed by calcium hydroxide and zinc phosphate cement. 4. The efficiency of the cement bases in providing thermal insulation was dependent on their thickness beneath the restorations. 5. Thermal change was great in the range of $60^{\circ}C$ and $-50^{\circ}C$, but little in the range of $0^{\circ}C$.

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An Experimental Study on Water-Purification Properties in Cement Bricks Using Effective Micro-Organisms and Zeolite (유용 미생물과 제올라이트를 이용한 시멘트 벽돌의 수질 정화 특성에 관한 실험적 연구)

  • Kim, Wha-Jung;Choi, Kil-Jun;Park, Jun-Seok
    • Journal of the Korea Concrete Institute
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    • v.23 no.3
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    • pp.331-338
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    • 2011
  • The purpose of this study is to use organisms or micro-organism functions for eco-friendly water-purification of cement bricks, utilizing bioremediation. Many researches have been performed in the past to improve water quality by using effective micro-organisms in construction materials. In order to purify water using micro-organisms, this research used soybean paste bacteria, an effective micro-organism that was identified through 16S rDNA sequence analysis performed in Daegu S. Environment Protection Institute in addition to Natto bacteria that was studied in the previous research. With these effective micro-organisms with water-purification ability, this study examined their water-purification possibility on cement bricks. This study used Zeolite to immobilize micro-organisms to bricks, and confirmed that the micro-organisms were attached on Zeolite from SEM analysis. The experimental results showed that specific micro-organisms can be used to effectively remove contamination an used to develop eco-friendly construction materials. The study on micro-organisms for material purification shows great promises as a future research topic.

A Sustainable and Viable Method to Recycle Oyster Shell Waste as an Alternative of Limestone in Limestone Calcined Clay Cement (LC3) (석회석 소성 점토 시멘트(LC3) 내 석회석 대체재로서 굴 패각의 친환경적인 재활용 방안)

  • Her, Sung-Wun;Suh, Heong-Won;Park, Jae-Yeon;Im, Su-Min;Bae, Sung-Chul
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.2
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    • pp.219-226
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    • 2020
  • Over the last decades, great efforts have been devoted to reuse industrial wastes and by-products from various industries as supplementary cementitious materials in order to reduce carbon dioxide(CO2) emission by reducing the use of Portland cement in construction. Oyster shell waste, originating from the fishery industry, is available in huge quantities in certain areas, and is generally discarded or landfilled. In this study, we aimed to reuse oyster shell as an alternative to limestone in limestone calcined clay cement(LC3). The oyster shell calcined clay cement(OC3) paste were produced and were characterized via X-ray diffraction, isothermal calorimetry, compressive strength tests, and thermogravimetry. The results revealed that OC3 pastes exhibited similar strength development and reactivities by pozzolanic reaction with LC3, which implies that oyster shell could be used as a substitute for limestone in LC3.

Experimental Study on the Applicability of Reactivity SiO2 Nano-Materials as Cement Composites (실리케이트계 반응성 나노소재의 시멘트 혼화재로써 적용 가능성에 대한 실험적 연구)

  • Kim, Won-Woo;Moon, Jae-Heum;Baek, Chul-Woo;Yang, Keun-Hyeok
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.4
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    • pp.529-536
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    • 2021
  • In this study, nano-silica and nano-titanium were selected to determine the possibility of applying the binder to reactive nano materials. The basic characteristics of the nano material candidate group were reviewed. and the reactivity of nano materials was reviewed through K-value. The reactivity of the nano silicate materials was measured to be high. Therefore, as a final candidate group, nano silicate materials were selected. The finally selected reactive nano material was reviewed for its usability as a construction binder. The mechanical properties and unit weight of cement paste were reviewed using silica fume and blast furnace slag and nano materials. When cement composites with nano silicate materials, it was confirmed that it was effective in improving the mechanical performance and decrease the unit weight of cement composites.

Self-Healing Property of Hardened Cement Paste (시멘트 페이스트 경화체의 self healing 특성)

  • Kim, Jae Young;Byun, Seung Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.2A
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    • pp.297-304
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    • 2008
  • It is well known that cracks in concrete decrease permeability and durability of concrete because cracks enhance the penetration of water or corrosive chemicals like as chlorides, carbon dioxides, sulfates and some others. But some of cracks in hardened cements may be sealed in case of contacting water. This phenomenon is called "self healing" and it has a close relation to hydration products newly formed on surfaces of cracks. Many studies on self healing in concretes commonly showed that CSH gel has been observed on crack surfaces. And some studies have reported that calcium hydroxides and ettringite were observed as well as CSH gel on crack surfaces. This study was carried out to investigate hydration products formed by self healing process and also examine the influence of waterproof admixture for concretes on self healing of cement. As a result of XRD, DSC, SEM and EDX analysis of crack surfaces, it was found that self healing of cement was related to CSH gel, calcium hydroxides and ettringite. And waterproof admixture increased fibrous (needle-like) hydration products which were in network form. It is estimated that such fibrous products are effective for self healing process of cement system.

Analytical Modeling for Microstructural Permeability Coefficient of (Non)Carbonated Concrete (탄산화 및 비탄산화된 콘크리트의 투수계수의 해석 기법 개발)

  • Yoon, In-Seok
    • Journal of the Korea Concrete Institute
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    • v.21 no.3
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    • pp.255-264
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    • 2009
  • Permeability coefficient of concrete is a substaintial key parameter for understanding the durability performance of concrete and its microstructural densification. Many researches for the issue have been accomplished, however, it is very rare to deal with the theoretical study on permeability coefficient in connection with carbonation of concrete and the the effect of volumetric fraction of cement paste or aggregate on the permeability coefficient. The majority of these researches have not dealt with this issue combined with carbonation of concrete, although carbonation can significantly impact on the permeability coefficient of concrete. The purpose of this study is to establish a fundamental approach to compute the permeability coefficeint of (non)carbonated concrete. When simulating a microstructural characteristics as a starting point for deriving a model for the permeability coefficient by the numerical simulation program for cementitious materials, HYMOSTRUC, a more realistic formulation can be achieved. For several compositions of cement pastes, the permeability coefficient was calculated with the analytical formulation, followed by a microstructure-based model. Emphasis was on the microstructural changes and its effective change of the permeability coefficient of carbonated concrete. For carbonated concrete, reduced porosity was calculated and this was used for calculating the permeability coefficeint. The computational result was compared with experimental outcome.