• Journal of the Korean Society of Safety
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• v.26 no.5
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• pp.59-64
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• 2011

This paper presents the research results performed to develope the shrinkage-free grout with high early strength. Alumina cement and anhydrite were utilized as the expensive tool to gain the shrinkage-free grout. The compressive strength, length change, and ettringite formation of the grout were investigated with compressive test, length change test, and X-ray diffraction. The more anhydrite was added into the grout, the larger the early expansion of the grout. In addition, the more anhydrite formated the more ettringite. From this study, It was conformed that the grout mixture with shrinkage-free property and high early strength is the mixture with the ratio of alumina cement and anhydrite of 40:60 by weight.

• Journal of the Korean Ceramic Society
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• v.47 no.5
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• pp.357-364
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• 2010

This study was performed to get basic information about properties of high blaine slag cement(HSC) to use shotcrete(or sprayed concrete and mortar). Particle size distribution, setting time and compressive strength test, analysis like as SEM, DSC thermal analysis, XRD was carried out to investigate principle properties of HSC. Setting time of HSC was delayed slightly, but influence of accelerators was more bigger than ordinary portland cement(OPC). Compressive strength of HSC at 28 days was more higher than OPC regardless of using accelerators. Results of analysis showed early period hydration products of HSC is more small and located widely, because of the interface of between cement particle and water is increased as specific surface of cement increase. From the SEM observation and analysis of DSC and XRD results, aluminates accelerators bring on some hydration products like as calcium aluminium hydrates, alkali free accelerators increases ettringite and monosulfates. Aluminates accelerators has a advantage of setting time and early strength, alkali free accelerators increases strength after 7 days.

• Journal of the Korean Ceramic Society
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• v.19 no.1
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• pp.19-23
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• 1982

The technique to determine the components in the supersulphated slag cement is discussed by several selective extraction analyses. Accordingly, the rate of hydration reaction of supersulphated slag cement could be quantitatively measured by the following 3 kinds of the selective extraction analyses. (1) Determination of unreacted slag - a salicylic acid, acetone.methanol solution (2) Determination of free $CaSO_4$ - a half saturated lime water (3) Determination of free $Ca(OH)_2$ - glycerine.alcohol solution

• Geomechanics and Engineering
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• v.38 no.4
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• pp.353-366
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• 2024

Organic soils pose significant challenges in geotechnical engineering due to their high compressibility and low stability, which can result in issues like differential settlement, rutting, and pavement deformation. This study explores effective methods for stabilizing organic soils. Rather than conventional ordinary Portland cement (OPC), the focus is on using environmentally friendly calcium sulfoaluminate (CSA) cement, known for its rapid setting, high early strength development, and environmental benefits. Mechanical behavior is analyzed through 1-D free swell, unconfined compressive strength (UCS), and bender element (BE) tests. Microstructural analyses, including Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM), characterize the soil mixed with CSA cement. Experimental results demonstrate improved soil properties with increasing cement dosage and curing periods. A notable strength increase is observed in soil samples with 15% cement content, with UCS doubling after 7 days. This trend aligns with shear wave velocity results from the BE test. SEM and FTIR spectroscopy reveal how CSA cement hydration forms hydrated calcium silicate gel and ettringite, enhancing soil properties. CSA cement is recommended for reinforcing organic subgrade soil due to its eco-friendly nature and rapid strength gain, contributing to improved durability.

• Journal of the Korean Geotechnical Society
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• v.29 no.5
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• pp.29-38
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• 2013

The G-class cement is commonly used in practice for geothermal well cementing in order to protect a steel casing that is designed to transport hot water/steam from deep subsurface to ground surface during operating a geothermal power plant. In order to maintain optimal performance of geothermal wells, physical properties of the cementing material should be satisfactory. In this paper, relevant factors (i.e., groutability, uniaxial compression strength, thermal conductivity and free fluid content) of the G-class cement were experimentally examined with consideration of various water-cement (w/c) ratios. Important findings through the experiments herein are as follows. (1) Groutability of the G-class cement increases by adding a small dose of retarder. (2) There would be a structural defect caused when the w/c ratio is kept higher in order to secure groutability. (3) Thermal conductivity of the G-class cement is small enough to prevent heat loss from hot steam or water to the outer ground formation during generating electricity. (4) The G-class cement does not form free water channel in cementing a geothermal well. (5) The Phenolphthalein indicator is applicable to the distinction of the G-class cement from the drilling mud.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.05a
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• pp.147-148
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• 2016

Generally, the vegetable oil contains glycerin esther and free fatty acid. When the vegetable oil reacts with concrete, the glycerin esther from oil induces saponification by reacting with and hydrolyzing calcium hydroxide from cement hydration. As a result of this saponification, it has been reported the expansion of concrete. although the free fatty acid from vegetable oil, as an acid, can decompose the concrete by producing soluble salt from calcium hydroxide or CSH, the hydration products of cement, there was no report on the harmful oil type for concrete. therefore, in this research, the property change of cement mortar incorporating fly ash was analyzed experimentally by immerging various types of vegetable oils.

• Journal of Korean Tunnelling and Underground Space Association
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• v.5 no.1
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• pp.23-31
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• 2003

Since the mid of 1990, permanent shotcrete tunnel linings such as Single-shell and NMT have been constructed in many countries for reducing the construction time and lowing construction costs instead of conventional in-situ concrete linings. Among essential technologies for successful application of permanent shotcrete linings, high performance shotcrete having high strength, high durability and better pumpability has to be developed in advance as an integral component. This paper presents the idea and first experimental attempts to increase early strength and bond strength of wet-mixed Steel Fiber Reinforced Shotcrete (SFRS) in spring water condition. In order to increase early behavior of SFRS, a new approach using high-early strength cement with alkali-free liquid accelerator has been investigated. From the test results, wet-mix SFRS with high-early strength cement and alkali-free accelerator exhibited excellent early compressive strength improvement compared to the ordinary portland cement and good bond strength even under spring water condition.

• Cement Symposium
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• no.31
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• pp.247-253
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• 2004

• Cement Symposium
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• s.36
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• pp.150-155
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• 2009

• Restorative Dentistry and Endodontics
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• v.43 no.2
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• pp.19.1-19.10
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• 2018

Objectives: This study investigated the effect of continuous application of 10-methacryloyloxydecyldihydrogen phosphate (MDP)-containing primer and luting resin cement on bond strength to tribochemical silica-coated yttria-stabilized tetragonal zirconia polycrystal (Y-TZP). Materials and Methods: Forty bovine teeth and Y-TZP specimens were prepared. The dentin specimens were embedded in molds, with one side of the dentin exposed for cementation with the zirconia specimen. The Y-TZP specimen was prepared in the form of a cylinder with a diameter of 3 mm and a height of 10 mm. The bonding surface of the Y-TZP specimen was sandblasted with silica-coated aluminium oxide particles. The forty tribochemical silica-coated Y-TZP specimens were cemented to the bovine dentin (4 groups; n = 10) with either an MDP-free primer or an MDP-containing primer and either an MDP-free resin cement or an MDP-containing resin cement. After a shear bond strength (SBS) test, the data were analyzed using 1-way analysis of variance and the Tukey test (${\alpha}=0.05$). Results: The group with MDP-free primer and resin cement showed significantly lower SBS values than the MDP-containing groups (p < 0.05). Among the MDP-containing groups, the group with MDP-containing primer and resin cement showed significantly higher SBS values than the other groups (p < 0.05). Conclusions: The combination of MDP-containing primer and luting cement following tribochemical silica coating to Y-TZP was the best choice among the alternatives tested in this study.