• Title/Summary/Keyword: Carbon material

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Influence of Heating Rate and Temperature on Carbon Structure and Porosity of Activated Carbon Spheres from Resole-type Phenolic Beads

  • Singh, Arjun;Lal, Darshan
    • Carbon letters
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    • v.10 no.3
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    • pp.181-189
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    • 2009
  • Activated carbon spheres (ACS) were prepared at different heating rates by carbonization of the resole-type phenolic beads (PB) at $950^{\circ}C$ in $N_2$ atmosphere followed by activation of the resultant char at different temperatures for 5 h in $CO_2$ atmosphere. Influence of heating rate on porosity and temperature on carbon structure and porosity of ACS were investigated. Effect of heating rate and temperature on porosity of ACS was also studied from adsorption isotherms of nitrogen at 77 K using BET method. The results revealed that ACS have exhibited a BET surface area and pore volume greater than $2260\;m^2/g$ and $1.63\;cm^3/g$ respectively. The structural characteristics variation of ACS with different temperature was studied using Raman spectroscopy. The results exhibited that amount of disorganized carbon affects both the pore structure and adsorption properties of ACS. ACS were also evaluated for structural information using Fourier Transform Infrared (FTIR) Spectroscopy. ACS were evaluated for chemical composition using CHNS analysis. The ACS prepared different temperatures became more carbonaceous material compared to carbonized material. ACS have possessed well-developed pores structure which were verified by Scanning Electron Microscopy (SEM). SEM micrographs also exhibited that ACS have possessed well-developed micro- and meso-pores structure and the pore size of ACS increased with increasing activation temperature.

Charge-Discharge Properties of Polyaniline-Carbon Composite Electrodes for Supercapacitor (Supercapacitor용 Polyaniline-Carbon Composite전극의 충방전 특성)

  • Kang, Kwang-Woo;Kim, Jong-Uk;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.124-127
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    • 2000
  • The purpose of this study is to research and develop PAn-Carbon composite electrode for Supercapacitor. Supercapacitor cell of PAn-Carbon composite electrode with 1M $LiClO_{4}/IPC$ brings out good capacitor performance below 4.0V. The radius of semicircle of PAn-Carbon composite electrode adding 30wt% Acetylene Black was absolutely small. The total resistance of Supercapacitor cell mainly depended on internal resistance of he electrode. The discharge capacitance of PAn-Carbon on composite with 30wt% Acetylene Black in 1st and 50th cycles was 29 and 31F/g at current density of $1mA/cm^2$. The capacitance of PAn-Carbon composite with 30wt% Acetylene Black capacitor was larger than that of PAn capacitor without Acetylene Black. The coulombic efficiency of supercapacitor at discharge process of 1 and 50 cycles were 94 and 100%. respectively. PAn-Carbon composite Supercapacitor with 30wt.% Acetylene Black content showed good capacitance and stability with cycling.

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Effect of Nano Buffer Layer on Property and Growth of Carbon Thin Film (탄소계 박막의 성장과 특성에 대한 나노 Buffer Layer의 영향)

  • ;Takashi lkuno;Kenjirou Oura
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.1
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    • pp.53-59
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    • 2003
  • Using Platinum-silicide (PtSi) formed between silicon substrate and carbon film, we have improved the field emission of electrons from carbon films. Pt films were deposited on n-Si(100) substrates at room temperature by DC sputter technique. After deposition, these PtSi thin films were annealed at 400 ~ $600^{\circ}C$ in a vacuum chamber, and the carbon films were deposited on those Pt/Si substrates by laser ablation at room temperature. The field emission property of C/Pt/Si system is found to be better than that of C/Si system and it is showed that property was improved with increasing annealing temperature. The reasons why the field emission from carbon film was improved can be considered as follows, (1)the resistance of carbon films was decreased due to graphitization, (2)electric field concentration effectively occurred because the surface morphology of carbon film deposited on Pt/si substrates with rough surface, (3)it is showed that annealing induced reaction between Pt film and Si substrate, as a consequence that the interfacial resistance between Pt film and Si substrate was decreased.

Study on the Heat Performance of CNT/carbon Fiber Plane Heater (탄소계 면상발열체 발열 특성 연구)

  • Ko, Yeongung;Kang, Yeongsik;Chung, Yongsik
    • Textile Coloration and Finishing
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    • v.32 no.1
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    • pp.65-71
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    • 2020
  • Electrical energy is used for heating and cooling because electric cars do not have engines and cooling water. The downside is that when the heating and cooling system is applied to electric vehicles, about 40 percent of the energy is spent on heating and cooling, which is less efficient in winter. This has increased demand for electric vehicle battery efficiency. In this study, the condensation and dispersion of carbon nanotubes were controlled, and carbon fibers and composite slurry were manufactured without binders to manufacture paper. Manufactured by content showed the highest heat generation characteristic at 143℃ with a carbon fiber content ratio of 20wt% and confirmed that the heat temperature rises with increasing pressure. The plane heaters made through this study can be applied to a variety of products other than electric vehicles because they can be simplified by process and high temperature.

Properties of Cement Matrix Using Vegetable Activated Carbon (식물성 활성탄을 활용한 시멘트 경화체의 특성)

  • Lee, Jae-Hoon;Park, Chae-Wool;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.138-139
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    • 2020
  • With the rapid progress of industrialization, indoor air quality is a very important factor for modern people who spend most of their day indoors. The recent issue of fine dust and radon on the portal site's popularity search shows that interest in indoor air quality has increased. Fine dust causes respiratory diseases, and radon causes severe lung cancer. The new material was tested using plant activated carbon, palm activated carbon and bamboo activated carbon. Both palm activated carbon and bamboo activated carbon are porous materials and generate smooth physical adsorption. As a result of the experiment, both the activated carbon tends to gradually decrease in strength and fluidity as the replacement ratio increases. The reason for this is that both activated carbons have the property of absorbing moisture, so it is judged that the strength is lowered by absorbing moisture necessary for curing. In the case of fluidity, it is judged that the fluidity is reduced by absorbing the moisture required for the flow. In the future, if the problem of the color of the finished cured body is compensated, it will be possible to manufacture a functional finishing board to replace the existing interior finishing material.

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Characteristics of CMP-PLA Heatsink Materials with Carbon Nanotube Contents (탄소나노튜브 양에 따른 CMP-PLA 방열 소재의 특성)

  • Kim, Young-Gon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.12
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    • pp.924-927
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    • 2013
  • In this study, we proposed CMP-PLAs to replace the Al heat sinks as heat sink materials, and investigated heat dissipation characteristics of the LED lighting devices using them. The crystallinity of the proposed CMP-PLA heat sinks decreased with increasing carbon nanotube contents in CMP-PLA. However, the thermal conductivity was improved with the increase of the carbon nanotube contents. The heat dissipation characteristics of the LED lighting devices using CMP-PLA heat sinks was improved with increasing carbon nanotube contents in CMP-PLA. For the LED lighting devices using CMP-PLA heat sinks with 40% carbon nanotube contents, the initial temperature measured at the heat sink plate was $27^{\circ}C$, which increased as time, and it was saturated around $56^{\circ}C$ after an hour. The LED lighting devices using CMP-PLA heat sinks are expected to be functional materials that can reduce their weight and improve their electric properties, compared to those using existing Al heat sinks.

Electrosorption of Uranium Ions in Liquid Waste

  • Lee, Hye-Young;Jung, Chong-Hun;Oh, Won-Zin;Park, Jin-Ho;Shul, Yong-Gun
    • Carbon letters
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    • v.4 no.2
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    • pp.64-68
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    • 2003
  • A study on the electrosorption of uranium ions onto a porous activated carbon fiber (ACF) was performed to treat uraniumcontaining lagoon sludge. The result of the continuous flow-through cell electrosorption experiments showed that the applied negative potential increased the adsorption kinetics and capacity in comparison to the open-circuit potential (OCP) adsorption for uranium ions. Effective U(VI) removal is accomplished when a negative potential is applied to the activated carbon fiber (ACF) electrode. For a feed concentration of 100 mg/L, the concentration of U(VI) in the cell effluent is reduced to less than 1 mg/L. The selective removal of uranium ions from electrolyte was possible by the electrosorption process.

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The Simulation of Pulsed Laser Ablation - One-dimensional CCP Model - (레이저 어블레이션 시뮬레이션 - 1 차원 비대칭 용량결합형 모델 -)

  • So, Soon-Youl;Chung, Hae-Deok;Park, Gye-Choon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04c
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    • pp.22-26
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    • 2008
  • In this paper, we developed a hybrid simulation model of carbon laser ablation under the Ar plasmas consisted of fluid and particle methods. Three kinds of carbon particles, which are carbon atom, ion and electron emitted by laser ablation, are considered in the computation. In the present simulation, we adopt capacitively coupled plasma with asymmetrical electrodes. As a result, in Ar plasmas, carbon ion motions were suppressed by a strong electric field and were captured in Ar plasmas. Therefore, a low number density of carbon ions were deposited upon substrate. In addition, the plume motions in Ar gas atmosphere was also discussed.

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Structural Phases of Potassium Intercalated into Carbon Nanotubes (탄소 나노튜브 내부에 삽입된 칼륨 구조)

  • 변기량;강정원;송기오;최원영;황호정
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.3
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    • pp.249-258
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    • 2004
  • We investigated structural phases of potassium intercalated into carbon nanotubes using a structural optimization process applied to atomistic simulation methods. As the radius of carbon nanotubes increased, structures were found in various phases from an atomistic strand to multishell packs composed of coaxial cylindrical shells and in helical, layed, and crystalline structures. Numbers of helical atom rows composed of coaxial tubes and orthogonal vectors of a circular rolling of a triangular network could explain multishell phases of potassium in carbon nanotubes.

Mechanical Properties of Carbon Fiber Reinforced Porous Concrete for Planting

  • Park Seung-Bum;Kim Jeong-Hwan
    • KCI Concrete Journal
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    • v.14 no.4
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    • pp.161-169
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    • 2002
  • The mechanical properties of fiber reinforced porous concrete for use as a planting material were investigated in this study. Changes in physical and mechanical properties, subsequent to the addition of carbon fiber and silica fume, were studied. The effects of recycled aggregate were also evaluated. The applicability as planting work concrete material was also assessed. The results showed that there were no remarkable changes in the void and strength characteristics following the increase in proportion of recycled aggregate. Also, the mixture with 10% silica fume was found to be the most effective for strength enforcement. The highest flexural strength was obtained when the carbon fiber was added with $3\%$. It was also noticed that PAN-derived carbon fiber was superior to Pitch-derived ones in view of strength. The evaluation of its usage for vegetation showed that the growth of plants was directly affected by the existence of covering soil, in case of having the similar size of aggregate and void.

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