• Title/Summary/Keyword: Carbon dioxide (CO2)

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A Study on Characteristics of Indoor- Air-Quality in Interior Space Equipped with System Air-Conditioner (시스템 에어컨 설치 공간의 실내공기질 특성에 관한 연구)

  • Lee, Sang-Won;Kim, Jong-Min;Yeum, Seung-Won;Cho, Dae-Gun;Choi, Jae-Boong;Kim, Seok-Woo
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.20 no.5
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    • pp.304-313
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    • 2008
  • This paper investigates the indoor-air-quality (IAQ) characteristics of the interior space equipped with system air-conditioner. The behaviors of individual variables such as temperature, humidity and concentration of carbon dioxide ($CO_2$) that influence on IAQ of the interior space were characterized under various cooling conditions by numerical and experimental studies. The numerical analysis predicting the temperature behavior of the interior space was conducted, and its results showed a good agreement with the experimental ones. The $CO_2$ concentration and humidity were measured and their time dependent behaviors were monitored and analyzed. From the results, it was found that there existed the differences of the time-dependent behaviors of IAQ variables according to the locations. In addition, it is demonstrated that the large discharge angle of $45^{\circ}$ made the temperature profile more irregular and the high discharge flow of 5.34 m/s produced similar temperature profiles at three different sensing locations. Finally, the humidity of interior space was less sensitive to the changes of the air cooling conditions than the case of temperature and the $CO_2$ concentration increase mainly depended on the number of individuals inside the space.

Preparation of Activated Carbon Fiber-Ceramic Composites and Its Physical Properties (활성탄소섬유-세라믹복합체의 제조 및 물성)

  • 이재춘;박민진;김병균;신경숙;이덕용
    • Journal of the Korean Ceramic Society
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    • v.34 no.1
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    • pp.56-62
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    • 1997
  • The PAN (Polyacrylonitrile) based carbon fiber-ceramic composites (CFCC) were prepared from mixtures of short carbon fibers, phenolic resin and ceramic binder. The effects of carbonization temperature of a pre-cursor fiber, the stabilized PAN fiber, on the specific surface area and the bending strength of the activated CFCC were studied in this work. The precursor fiber was carbonized at 80$0^{\circ}C$ and 100$0^{\circ}C$, respectively. The CFCC were activated at 85$0^{\circ}C$ in carbon dioxide for 10~90 minutes. As the burn-off of the activated CFCC made of the precursor fiber carbonized at 80$0^{\circ}C$ was increased from 37% to 76%, the specific surface area in-creased from 493m2/g to 1090m2/g, and the bending strength decreased from 4.5MPa to 1.4MPa. These values were about two times larger than those of the activated CFCC of which precursor fiber was car-bonized at 100$0^{\circ}C$. The effects of carbonization temperature of a precursor fiber on the specific surface area and bending strength of the activated CCFC were explained by bonding force between carbon fiber and car-bonized phenolic resin as well as by relative shirnkage between carbon fiber and ceramic film.

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Biological conversion of CO2 to CH4 in anaerobic fixed bed reactor under continuous operation (혐기성 고정층 생물반응기의 연속운전을 통한 이산화탄소의 메탄전환)

  • Kim, Jaehyung;Koo, Hyemin;Chang, Wonseok;Pak, Daewon
    • Journal of Energy Engineering
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    • v.22 no.4
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    • pp.347-354
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    • 2013
  • This study was carried out to examine different mole ratio of $H_2/CO_2$ and EBCT using the continuous system in the lab scale throughout biological methods with accumulated hydrogenotrophic methanogen that can convert $CO_2$ to $CH_4$. The experimental-based results with various gas mixtures of mole ratio of 4:1($H_2/CO_2$) and 5:1($H_2/CO_2$), $H_2$ was converted more than 99% conversion rate. In case of $CO_2$, 4:1($H_2/CO_2$) and 5:1($H_2/CO_2$) were $74.45{\pm}0.33%$, $95.8{\pm}10.7%$, respectively, in addition, the study was confirmed that the amount of $H_2$ was more needed than stoichiometric equations, where approach methods are empirical versus theoretical frameworks, for converting total $CO_2$. As such, we have noticed that $H_2$ was used for energy source of hydrogenotrophic methanogen for maintaining life. Regarding the results of the ratio of treatment by retention time, limitation of treatment capacity showed that $H_2$(99.9%) and $CO_2$(96.23%) at EBCT 3.3 hrs indicated stable conversion ratio, as well as appeared that methane production rate and $CO_2$ fixation rate were investigated $1.15{\pm}0.02m^3{\cdot}m^{-3}{\cdot}day^{-1}$ and $2.01{\pm}0.04kg{\cdot}m^{-3}{\cdot}day^{-1}$, respectively.

Estimation of the Shadow Price of Carbon Dioxide Emissions, the Potential Reduction, and Substitution Possibility for fuels in the Chinese Fossil-fueled Power Generation Sector (중국 화력발전산업의 CO2 암묵가격 및 잠재감축량, 연료에 대한 대체가능성 분석)

  • Jin, Yingmei;Lee, Myunghun
    • Environmental and Resource Economics Review
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    • v.22 no.1
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    • pp.77-98
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    • 2013
  • China, the world's largest $CO_2$ producer, is likely to be obligated to reduce greenhouse gas emissions under the post-Kyoto protocol. This paper estimates a Shephard input distance function for the Chinese fossil-fueled power generation sector to measure the shadow price of $CO_2$ emissions, technical efficiency, and indirect Morishima elasticities of substitution between inputs. Empirical results show that, on average, it costs approximately 3.2 US dollars per year to reduce $CO_2$ emissions by one ton over the period 1981-2009. This finding indicates that Chinese power sector is expected to benefit from selling emission permits to other countries such as Korea and Japan, given that our estimate for China is lower than the ones previous literatures estimated for the power sector in these countries. The maximum attainable average $CO_2$ reduction potential amounts to approximately 25 million tons per year by improving technical efficiency. Capital is substitutable with both coal and oil and capital is relatively more readily substituted for these fuels.

Global Regulation of Gene Expression in the Human Gastric Pathogen Helicobacter pylori in Response to Aerobic Oxygen Tension Under a High Carbon Dioxide Level

  • Park, Shin Ae;Lee, Na Gyong
    • Journal of Microbiology and Biotechnology
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    • v.23 no.4
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    • pp.451-458
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    • 2013
  • The human gastric pathogen Helicobacter pylori (Hp) has been considered a microaerophile. However, we recently reported that, when supplied with 10% $CO_2$, Hp growth is stimulated by an atmospheric level of $O_2$, suggesting that Hp is a capnophilic aerobe. In this study, we investigated the effects of aerobic $O_2$ tension on Hp cells by comparing gene expression profiles of cultures grown under microaerobic and aerobic conditions in the presence of 10% $CO_2$. The results showed that overall differences in gene expression in Hp cells grown under the two $O_2$ conditions were predominantly growth-phase-dependent. At 6 h, numerous genes were down-regulated under the aerobic condition, accounting for our previous observation that Hp growth was retarded under this condition. At 36 h, however, diverse groups of genes involved in energy metabolism, cellular processes, transport, and cell envelope synthesis were highly up- or down-regulated under the aerobic condition, indicating a progression of the cultures from the log phase to the stationary phase. The expression of several oxidative stress-associated genes including tagD, katA, and rocF was induced in response to aerobic $O_2$ level, whereas trxA, trxB, and ahpC remained unchanged. Altogether, these data demonstrate that aerobic $O_2$ tension is not detrimental to Hp cells but stimulates Hp growth, supporting our previous finding that Hp may be an aerobic bacterium that requires a high $CO_2$ level for its growth.

Effect of Ambient Air Pollution on Years of Life Lost from Deaths due to Injury in Seoul, South Korea (대기오염물질이 손상으로 인한 손실수명연수에 미치는 영향: 서울특별시를 중심으로)

  • Sun-Woo Kang;Subin Jeong;Hyewon Lee
    • Journal of Environmental Health Sciences
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    • v.49 no.3
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    • pp.149-158
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    • 2023
  • Background: Injury is one of the major health problems in South Korea. Few studies have evaluated both intentional and unintentional injury when investigating the association between exposure to air pollutants and injury. Objectives: We aimed to explore the association between short-term exposure to ambient air pollution and years of life lost (YLLs) due to injury. Methods: Data on daily YLLs for 2002~2019 were obtained from the the Death Statistics Database of the Korean National Statistical Office. This study estimated short-term exposure to particulate matter with an aerodynamic diameter of <10 ㎛ (PM10), particulate matter with an aerodynamic diameter of <2.5 ㎛ (PM2.5), sulfur dioxide (SO2), nitrogen dioxide (NO2), carbon monoxide (CO), and ozone (O3). This time series study was conducted using a generalized additive model (GAM) assuming a Gaussian distribution. We also evaluated a delayed effect of ambient air pollution by constructing a lag structure up to seven days. The best-fitting lag was selected based on smallest generalized cross validation (GCV) value. To explore effect modification by intentionality of injury (i.e., intentional injury [self-harm, assault] and unintentional injury), we conducted stratified subgroup analyses. Additionally, we stratified unintentional injury by mechanism (traffic accident, fall, etc.). Results: During the study period, the average daily YLLs due to injury was 307.5 years. In the intentional injury, YLLs due to self-harm and assault showed positive association with air pollutants. In the unintentional injury, YLLs due to fall, electric current, fire and poisoning showed positive association with air pollutants, whereas YLLs due to traffic accident, mechanical force and drowning/submersion showed negative associations with air pollutants. Conclusions: Injury is recognized as preventable, and effective strategies to create a safe society are important. Therefore, we need to establish strategies to prevent injury and consider air pollutants in this regard.

A Study for Developing an Operating Mode-Based Emission Model for Korea (한국형 운행 모드 기반 배출량 산정 모형 개발에 관한 연구)

  • HU, Hyejung;FREY, Christopher;YOON, Chunjoo;YANG, Choongheon;KIM, Jinkook
    • Journal of Korean Society of Transportation
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    • v.34 no.2
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    • pp.180-190
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    • 2016
  • Atmospheric pollutants such as Nitrogen Oxides(NOx), Carbon Monoxide(CO), Carbon Dioxide($CO_2$), Particulate Matter(PM) and Hydrocarbons(HC) come from vehicle exhaust gases. Emission curves based on average travel speeds have been employed for estimating on-road emissions as well as evaluating environmental impacts of transportation plans and policies in Korea. Recently, there is a growing interest in estimation methods of vehicle emissions considering relationship between vehicle dynamic driving characteristics and emissions, and incorporating such emission estimators into traffic simulation models. MOVES Lite, a simplified version of MOVES, is one of the estimation methods. In this study, the authors performed a study to develop an adaptable version of MOVES Lite for Korea, called MOVES Lite-K. Vehicle types, driving characteristics, emission rates, and emission standards of Korea were reflected in MOVES Lite-K. The characteristics of emission calculation of MOVES Lite-K and NIER emission curves were compared and the adaptability of MOVES Lite-K were examined.

Testing for Convergence in Carbon Dioxide Emissions : Using a Dynamic Panel Analysis and Panel Unit Root Test (이산화탄소 배출량의 수렴성 검정 : 다이나믹 패널 분석과 패널 단위근 검정을 이용하여)

  • Cho, Sungtaek;Cho, Yongsung
    • Environmental and Resource Economics Review
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    • v.18 no.1
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    • pp.53-73
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    • 2009
  • This study examines the existence of ${\beta}$-convergence of carbon dioxide emissions in 24 countries over the period 1971~2002. For that purpose, The model of economic growth developed by Barro and Sala-i-Martin (1995) is extended and conducted Dynamic panel analysis and unit root testing by employing the panel stationarity test of Levin et al. (2002) and 1m et al. (2003). A dynamic panel estimation is well known method including capacity to control for both the endogeneity problem and the unobserved country-specific effects problem. Dynamic panel estimation method has been widely used in similar empirical studies. therefore, we also used the dynamic panel estimation method in our estimation. The result show that evidence of ${\beta}$-convergence exists among both the Obligatory GHG reduction countries (Annex) and the Non-obligatory GHG reduction countries (Non-Annex). but China discharge amount of $CO_2$ gas more than any other country. This fact can cause some bias in overall test. and so we reexamined test of convergence for Non-annex countries excluding china. As expected, in the Non-annex countries excluding china, I couldn't find any evidence of convergence.

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Quality characteristics of frozen brown rice Jeung-pyun dough containing different amounts of acorn flour (도토리가루의 첨가량을 달리하여 제조한 냉동 현미증편반죽의 품질특성)

  • Jeong, Sang-Yeol;Lee, Min-Kyoung;Gwag, Jung Soon;Lee, Sook-Young
    • Food Science and Preservation
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    • v.23 no.3
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    • pp.445-452
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    • 2016
  • In this study, physicochemical properties of acorn flour was investigated, and characteristics of the Jeung-pyun dough added with the acorn flour at various concentrations were evaluated after storage at -$18^{\circ}C$ for 4 weeks and fermentation. Total polyphenolic content, electron donating ability (EDA) of 0.5%, gelatinization onset temperature (To), gelatinization peak temperature (Tp), and gelatinization conclusion temperature (Tc) of acorn flour were 3,525.12 mg%, 16.71%, $68.41^{\circ}C$, $73.83^{\circ}C$, and $82.96^{\circ}C$, respectively. These all values were increased in the Jeung-pyun dough possibly due to addition of the acorn flour. The yeast count was not affected by the addition levels of acorn flour and the frozen storage period before fermentation. The amount of carbon dioxide gas evolved from Jeung-pyun dough during fermentation was significantly changed with the concentration of acorn flour, but it was negligible. The Jeung-pyun added with 6% acorn flour showed an small increase in the amount of carbon dioxide after frozen storage of 1 wk and fermentation. The pH of the fermented Jeung-pyun samples decreased along with the increasing storage period as well as the increasing acorn flour content, ranging from 4.21 to 5.34. Therefore, the frozen Jeung-pyun dough containing 6~15% of acorn flour and stored for 3 weeks was the most desirable among all the tested samples in this study.

Computational Chemistry Study of CO2 Fixation and Cyclic Carbonate Synthesis Using Various Catalysts (촉매를 이용한 이산화탄소 고정화 및 고리형 카보네이트 합성반응에 대한 계산화학적 해석)

  • An, Hye Young;Kim, Min-Kyung;Jeong, Hui Cheol;Eom, Ki Heon;Won, Yong Sun
    • Clean Technology
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    • v.22 no.1
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    • pp.35-44
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    • 2016
  • In this study, a computational chemistry methodology called as molecular modeling was been applied to explain several experiment results mechanistically. The reaction chosen for this study was to remove carbon dioxide, known as a primary greenhouse gas, by an epoxide via the carbon dioxide fixation to produce carbonates. This reaction inherently needs the use of catalysts because it has a significantly high activation barrier (55~59 kcal/mol). Among various types of catalysts, we studied in zeolitic imidazolate framework 90 (ZIF-90)/ionic liquid immobilized ZIF-90 (IL-ZIF-90), polystyrene-supported quaternized ammonium salt, KI/KI-glycine, and dimethylethanolamine (DMEA). First, probable reaction pathways were proposed based on calculated energetics by computational chemistry. The energetics was then used for the thermodynamic interpretation on the activity of catalysts. In the case of ZIF-90/IL-ZIF-90 and KI/KI-glycine, IL-ZIF-90 and KI-glycine showed better yields compared to their counterparts. The calculation proposed interesting results that it is not from the lowering of activation energy but from the unstable intermediates of ZIF-90 and KI-glycine. For DMEA, the calculated activation energy was ~42 kcal/mol, much lower than that of the non-catalytic reaction. A possible reaction pathway was located to confirm the interaction between −NH group from ammonium and oxygen from epoxide for polystyrene-supported quaternized ammonium salt.