• Journal of Korean Society for Atmospheric Environment
• /
• v.31 no.6
• /
• pp.538-547
• /
• 2015

Test activated carbon fiber (ACF) was prepared from Polyacrylonirile (PAN) through oxidation and chemical activation. Immersion of ACF precursors in the aqueous KOH solution enhanced the surface structure, as examined by BET pore analysis. Specific surface area increased greatly from less than $70m^2/g$ to $1226m^2/g$ with 4 M KOH, and total pore volume also rose up to $0.483cm^3/g$. In particular, it was found that micropores favorable for $CO_2$ molecule capture occupied more than 95%. Maximum $CO_2$ adsorption capacity was 3.59 mmol/g at 298 K. Low depth of pores in the present ACF may facilitate the molecules' desorption for its regeneration.

• Journal of Ocean Engineering and Technology
• /
• v.22 no.6
• /
• pp.88-94
• /
• 2008

The concentration of atmospheric carbon dioxide (CO2), which is one of the major greenhouse gases, continues to rise with the increase in fossil fuel consumption. In order to mitigate global warming the amount of CO2 discharge to the atmosphere must be reduced. Carbon dioxide capture and storage (CCS) technology is now regarded as one of the most promising options. To complete the carbon cycle in a CCS system, a huge amount of captured CO2 from major point sources such as power plantsshould be transported for storage into the marine or ground geological structures. Since 2005, we have developed technologies for marine geological storage of CO2,including possible storage site surveys and basic design of CO2 transport and storage process. In this paper, the design parameters which will be useful to construct on-shore and off-shore CO2 transport systems are deduced and analyzed. To carry out this parametric study, we suggested variations in thedesign parameters such as flow rate, diameter, temperature and pressure, based on a hypothetical scenario. We also studied the fluid flow behavior and thermal characteristics in a pipeline transport system.

• Journal of Korean Society of Environmental Engineers
• /
• v.37 no.3
• /
• pp.175-181
• /
• 2015

Activated carbon impregnated with polyethyleneimine (PEI) was evaluated as a functionalized adsorbent for $CO_2$ capture. The $CO_2$ adsorption characteristics of the adsorbents was undertaken using GC/TCD, BET surface area and FT-IR. A series of adsorbents were synthesized by impregnating 10, 30, 50 wt% of PEI on activated carbons and were investigated $CO_2$ adsorption capacity at high and low adsorption temperature. The $CO_2$ adsorption capacity at $20^{\circ}C$ and $100^{\circ}C$ was as follow: AC > PEI(10)-AC > PEI(30)-AC > PEI(50)-AC at $20^{\circ}C$ and PEI(10)-AC > PEI(30)-AC > PEI(50)-AC > AC at $100^{\circ}C$. Adsorption capacities of amine functionalized AC was lager than virgin AC at high temperature due to chemisorption by amino-group content. From the results, the PEI(10)-AC showed one of the most promising adsorbents for $CO_2$ capture from flue gas at high temperature.

• Carbon letters
• /
• v.2 no.2
• /
• pp.113-119
• /
• 2001

The advanced method for $CO_2$capture is currently one of the most important environmental issues in worldwide and it is therefore necessary to have available technologies, which minimize the discharge of $CO_2$ including Carbon-14 from nuclear facilities into the atmosphere. A key aspect of this work is to provide the technically principal data required to improve a $CO_2$ removal system for the utilization of regenerative sorbent use, specifically include suggestions regarding its modified column design (parallel dual-bed assembly), stop-restart operation and the economic feasibility of sorbent use. The removal performance of soda lime and the effects of relative humidity (RH) and packing bed-depth (BD) on $CO_2$ removal were investigated. In a single-bed, it revealed that the utilization of soda lime for $CO_2$ removal at line velocity of 13 cm/sec and bed depth of 12 cm increased with the increased relative humidity up to 85%. However, in the parallel dual-bed assembly applied with the stop-restart operation, a maximum utilization rate of soda lime for $CO_2$ removal was obtained even at 55% of RH and 8 cm of BD, specifically the utilization rate of soda lime by using this $CO_2$ removal assembly was about two-fold superior to that in a single-bed.

• Tunnel and Underground Space
• /
• v.26 no.1
• /
• pp.12-23
• /
• 2016

For a successful accomplishment of Carbon Capture Sequestration (CCS) projects, appropriate injection conditions should be designed and optimized for site specific geological conditions. In this study, we evaluated the effect of injection conditions such as injection temperature and injection rate on the geomechanical stability of CCS system in terms of TOUGH-FLAC simulator, which is one of the well-known T-H-M coupled analysis methods. The stability of the storage system was assessed by a shear slip potential of the pre-existing fractures both in a reservoir and caprock, expressed by mobilized friction angle and Mohr stress circle. We demonstrated that no tensile fracturing was induced even in the cold CO2 injection, where the injected CO2 temperature is much lower than that of the reservoir and tensile thermal stress is generated, but shear slip of the fractures in the reservoir may occur. We also conducted a scenario analysis by varying injected CO2 volume per unit time, and found out that it was when the injection rate was decreasing in a step-wise that showed the least potential of a shear slip.

• Journal of the Society of Naval Architects of Korea
• /
• v.61 no.1
• /
• pp.51-60
• /
• 2024

Hi Air Korea and Hanwha ocean are currently developing an Onboard Carbon dioxide Capture System (OCCS) to absorb CO₂ emitted from ship's engine using a sodium hydroxide(NaOH) solution, and converting the resulting salt into a solid form through a chemical reaction with calcium oxide (CaO). The system process involves the following steps; 1)The reaction of CO₂ gas absorption in water, 2)The reaction between carbonic acid (H₂CO₃) and NaOH solution to produce carbonate or bicarbonate, and 3)The reaction between carbonate or bicarbonate and CaO to form calcium carbonate (CaCO₃). And ultimately, the solid material, CaCO₃, is separated and discharged using a separator. The OCCS has been installed on an ship and the test results have confirmed significant reduction effects of CO₂ in the ship's exhaust gas. A portion of the exhaust gas emitted from the engine was transferred to the OCCS using a blower. The flow rate of the transferred gas ranged from 800 to 1384 m³/hr, and the CO₂ concentration in the exhaust gas was 5.1 vol% for VLSFO, 3.7 vol% for LNG and a 12 wt% NaOH solution was used. The results showed a CO₂ capture efficiency of approximately 42.5 to 64.1 vol% and the CO₂ capture rate approximately 48.4 to 52.2kg/hr. Additionally, to assess the impact of the discharged CaCO₃on the marine ecosystem, we conducted "marine ecotoxicity test" and performed Computational Fluid Dynamics (CFD) analysis to evaluate the dispersion and dilution of the discharged effluent.

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.18 no.6
• /
• pp.617-625
• /
• 2012

This study examines the current status and policy development of Carbon Dioxide Capture and Storage(CCS), which is a technology to mitigate climate change, in Korea and foreign countries. It also analyzes IEA CCS regulatory framework as a guideline and provides limitations and implications for marine geological storage in the Republic of Korea. Although CCS master plan is established at national level, related laws are not amended and detailed polices are not yet provided. Established 'Intergovernmental CCS committee' lacks its cooperative mechanism and flexibility. Only limited and segmented economic analyses are performed and funding for large scale of CCS project is not secured. In addition, information sharing is limited and public awareness activities are insufficient. Therefore, this paper provides some policy suggestions on establishing a legal framework based on the 'Marine Environmental Management Act', strengthening the role of intergovernmental CCS committee, conducting CCS economic analysis based on various scenarios, providing economic incentives and public participation strategies, and establishing a specialized agency for information sharing.

• Geophysics and Geophysical Exploration
• /
• v.24 no.3
• /
• pp.78-88
• /
• 2021

Owing to the abnormal weather conditions due to global warming, carbon capture and storage (CCS) technology has attracted global attention as a countermeasure to reduce CO₂ emissions. In the Pohang CCS demonstration project in South Korea, 100 tons of CO₂ were successfully injected into the subsurface CO₂ storage in early 2017. However, after the 2017 Pohang earthquake, the Pohang CCS demonstration project was suspended due to an increase in social concerns about the safety of the CCS project. In this study, to reconfirm the structural suitability of the CO₂ storage site in the Pohang Basin, we employed seismic imaging based on reverse-time migration (RTM) to analyze small-scale ocean-bottom seismic data, which have not been utilized in previous studies. Compared with seismic images using marine streamer data, the continuity of subsurface layers in the RTM image using the ocean-bottom seismic data is improved. Based on the obtained subsurface image, we discuss the structural suitability of the Pohang CO₂ storage site.

• Journal of the Korean Society of Safety
• /
• v.29 no.1
• /
• pp.41-46
• /
• 2014

The design of a 7 degree of freedom motion capture device(MCD) has been presented. The newly designed MCD overcomes the shortcomings of the existing CADEN-7 exoskeleton robot by implementing various ergonomic design. To improve ease of operation, light-weight high-strength materials such as carbon pipes and engineering plastics were used to reduce weight of the MCD and arm-length adjustment mechanism was also added. The MCD showed consistent measurement results in designed experiments involving change of arm posture from nominal configuration to either elbow-side or arm-front configurations. Furthermore, captured motion in more natural tennis swing appeared to agree well with visual observations made.

• Journal of Institute of Convergence Technology
• /
• v.11 no.1
• /
• pp.13-18
• /
• 2021

It is widely accepted that the prevention of global warming requires significant reductions in greenhouse gases, particularly CO₂ emissions. Although fossil fuel-based power plants account for the majority of CO₂ emissions, it is urgent to reduce CO₂ emissions in industries that emit large amounts of CO₂ such as steel, petrochemical, and oil refining. This paper examines the current status of CO₂ emission in the domestic oil refining industry and CO₂ emission sources in each unit process in the oil refining industry. Focusing on the previously developed CO₂ capture process, cases and applicability of greenhouse gas reduction in FCC and hydrogen manufacturing processes, which are major processes constituting the oil refining industry, are reviewed.