• Polymer(Korea)
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• v.39 no.2
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• pp.293-299
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• 2015

Conductive microcellular foams consisted of polystrene (PS) and polydopamine-coated carbon nanotube (PDA-CNT) were prepared via high internal phase emulsion (HIPE) polymerization and their morphology and electrical conductivity were investigated. CNT as a conductive nanofiller was modified to PDA-CNT by coating with hydrophilic PDA on the surface of CNT to increase aqueous phase dispersion and emulsion stability. It was possible to prepare the HIPEs having higher PDA-CNT content and the resultant foams having improved conductivity due to its good dispersion. The foams showed the morphology of interconnected cell structure. As PDA-CNT content increased, yield stress and storage modulus increased and cell size reduced. The PDA-CNT content showing electrical percolation threshold was ca. 0.58 wt% and the conductivity at PDA-CNT content of 5 wt% was increased to $10^{-3}S/m$.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.416-417
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• 2007

We prepared flexible transparent conducting electrodes by spray coating of single-walled carbon nanotube (SWNT) networks on PET substrate and have demonstrated their use as transparent anodes for flexible organic light emitting diodes (OLEDs). The flexible CNT electrode produced by spray coating method shows relatively low sheet resistance ($150{\sim}220{\Omega}/sq.$) and high transmittance of ~60% even though it was prepared at room temperature. In addition, CNT electrode/PET sample exhibits little resistance change during 2000 bending cycles, demonstrated good mechanical robustness. Using transparent CNT electrode, it is readily possible to achieve performances comparable to commercial ITO-based OLEDs. This indicates that flexible CNT electrode is alternative anode materials for conventional ITO anode in flexible OLEDs.

• Transactions on Electrical and Electronic Materials
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• v.3 no.1
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• pp.23-29
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• 2002

The electronic properties of Carbon Nanotube(CNT) are currently the focus of considerable interest. In this paper, the electronic properties of finite length effect in CNT for the carbon nano-scale device is presented. To Calculate the electronic properties of CNT, Empirical potential method (the extended Brenner potential for C-Si-H) for carbon and Tight Binding molecular dynamic (TBMD) simulation are used. As a result of study, we have known that the value of the band gap decreases with increasing the length of the tube. The energy band gap of (6,6) armchair CNT have the ranges between 0.3 eV and 2.5 eV. Also, our results are in agreements with the result of the other computational techniques.

• Coupled systems mechanics
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• v.6 no.2
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• pp.207-227
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• 2017

In this paper Timoshenko beam theory is employed to investigate the vibration characteristics of functionally graded carbon nanotube-reinforced composite (FG-CNTRC) Beams with a stiff core in thermal environment. The material characteristic of carbon nanotubes (CNT) are supposed to change in the thickness direction in a functionally graded form. They can also be calculated through a micromechanical model where the CNT efficiency parameter is determined by matching the elastic modulus of CNTRCs calculated from the rule of mixture with those gained from the molecular dynamics simulations. The differential transform method (DTM) which is established upon the Taylor series expansion is one of the effective mathematical techniques employed to the differential governing equations of sandwich beams. Effects of carbon nanotube volume fraction, slenderness ratio, core-to-face sheet thickness ratio, different thermal environment and various boundary conditions on the free vibration characteristics of FG-CNTRC sandwich beams are studied. It is observed that vibration response of FG-CNTRC sandwich beams is prominently influenced by these parameters.

• Carbon letters
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• v.24
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• pp.41-46
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• 2017

The microstructure, flexural properties, electrical conductivity, thermal conductivity and electromagnetic interference (EMI) shielding effectiveness (SE) of epoxy composites filled with multi-walled carbon nanotubes (CNTs), exfoliated graphite nanoplatelets (xGnPs) and CNT-xGnP hybrid filler were investigated. The EMI SE of the CNT-xGnP hybrid composite was higher than 25 dB at 100 MHz while that of the xGnP based composite was almost zero. The flexural modulus of the CNT-xGnP based epoxy composite continuously increased to 3.32 GPa with combined filler content up to 10 wt% while that of the CNT based epoxy composites slightly decreased to 1.96 GPa at 4 wt% CNT, and dropped to 1.57 GPa at 5 wt% loading, which is lower than that of epoxy. The CNT and CNT-xGnP samples had the same EMI SE at the same surface resistivity, because samples with the same surface conductivity have the same amount of the charge carriers.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.3
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• pp.355-360
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• 2012

The characteristics of power generation were investigated by changing the electrical conductivity from 10 to 40mS/cm using air-cathode microbial fuel cell, which had graphite fiber fabric(GFF) anode. There were three kinds of cathode used: one was carbon cloth cathode coated with Pt, another was carbon nanotube(CNT) cathode with non-precious catalyst of Fe-Cu-Mn, and the other was carbon nanotube(CNT) cathode without any catalyst. When it was operated in batch mode, power density of 1369.5mW/$m^2$ was achieved at conductivity of 20mS/cm. Power density from MFC with CNT cathode coated with multi-catalyst of Fe-Cu-Mn was shown about 985.55mW/$m^2$, which was 75.1% compared the power density of carbon cloth coated with Pt. This meant that CNT cathode coated with multi-catalyst of Fe-Cu-Mn could be an alternative of carbon cloth cathode.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.489-497
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• 2022

In this study, the fluidity, mechanical properties and microstructure of cement pastes with carbon nanotube (CNT) were experimentally investigated. The 6 types of cement paste mixes with different PCE:CNT and w/b had been manufactured, and several tests including flow, compressive strength, absorption and water porosity were performed on cement pastes with or without CNT.Additionally, microstructural observations such as x-ray diffraction (XRD) and scanning electron microscopy (SEM) were carried out to examine hydrates formed in cement paste with CNT. As a result, it was found that the performance of cement pastes with CNT was better compared to that of control cement paste (OPC) due to both of hydration acceleration effect and filling effect. Furthermore, the SEM images clearly showed that CNT can bridge cracks formed in cement matrix. Conclusively, it is believed that the CNT, if mixed appropriately, could be an option as nono-materials to improve performance of concrete structures.

• Tribology and Lubricants
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• v.36 no.5
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• pp.290-296
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• 2020

When two layers of carbon nanotube (CNT) arrays are loaded to mate, the free ends of individual CNTs come into contact at the interface of the two layers. This leads to a higher contact resistance due to a smaller contact region. However, when the free CNT ends of one array penetrate into the mating array, the contact region increases, effectively lowering the contact resistance. To explore the penetration of mating CNTs, we perform molecular dynamic simulations of a simple unit cell model, incorporating four CNTs in the lower array layer coupled with a single moving CNT on the upper layer. The interaction with neighboring CNTs is modelled by long-range carbon bond order potential (LCBOP I). The model structure is optimized by energy minimization through the conjugate gradient method. A NVT ensemble is used for maintain a room temperature during simulation. The time integration is performed through the velocity-Verlet algorithm. A significant vibrational motion of CNTs is captured when penetration is not available, resulting in a specific vibration mode with a high frequency. Due to this vibrational behavior, the random behaviors of CNT motion for predicting the penetration are confirmed under the specific gap distances between CNTs. Thus, the probability of penetration is examined according to the gap distance between CNTs in the lower array and the aspect ratio of CNTs. The penetration is significantly affected by the vibration mode due to the van der Waals forces between CNTs.

• Composites Research
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• v.25 no.5
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• pp.159-163
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• 2012

The coating of metal surface with carbon nanotubes(CNTs) has been studied for the heat transfer enhancement of the boiling and condensation of refrigerant. The multiwalled carbon nanotube/copper oxide(CuO) composite powder, which has been surface modified by dispersant and polyvinyl alcohol solution, was ultrasonically sprayed and sintered on a copper wafer. In this paper, experiments were performed to assess the characterization and comparison of the carbon nanotube before and after sinterning and the morphology changes of the CNT/CuO-coated surface by using different dispersants. The dispersants used are THF (Tetrahydrofuran), SDBS(Dodecylbenzenesulfonic acid sodium salt), SDS(Sodium dodecy sulfate). The samples were examined by scanning electron microscopy(SEM), thermogravimetric analysis(TGA), differential scanning calorimeter(DSC) and Raman spectroscopy.

• Korean Journal of Materials Research
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• v.22 no.5
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• pp.237-242
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• 2012

We report on the NO gas sensing properties of Al-doped zinc oxide-carbon nanotube (ZnO-CNT) wire-like layered composites fabricated by coaxially coating Al-doped ZnO thin films on randomly oriented single-walled carbon nanotubes. We were able to wrap thin ZnO layers around the CNTs using the pulsed laser deposition method, forming wire-like nanostructures of ZnO-CNT. Microstructural observations revealed an ultrathin wire-like structure with a diameter of several tens of nm. Gas sensors based on ZnO-CNT wire-like layered composites were found to exhibit a novel sensing capability that originated from the genuine characteristics of the composites. Specifically, it was observed by measured gas sensing characteristics that the gas sensors based on ZnO-CNT layered composites showed a very high sensitivity of above 1,500% for NO gas in dry air at an optimal operating temperature of $200^{\circ}C$; the sensors also showed a low NO gas detection limit at a sub-ppm level in dry air. The enhanced gas sensing properties of the ZnO-CNT wire-like layered composites are ascribed to a catalytic effect of Al elements on the surface reaction and an increase in the effective surface reaction area of the active ZnO layer due to the coating of CNT templates with a higher surface-to-volume ratio structure. These results suggest that ZnO-CNT composites made of ultrathin Al-doped ZnO layers uniformly coated around carbon nanotubes can be promising materials for use in practical high-performance NO gas sensors.