• 제목/요약/키워드: Carbon/carbon-based materials

검색결과 1,325건 처리시간 0.03초

Nonlinear stability of non-axisymmetric functionally graded reinforced nano composite microplates

  • Loghman, Abbas;Arani, Ali Ghorbanpour;Barzoki, Ali Akbar Mosallaie
    • Computers and Concrete
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    • 제19권6호
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    • pp.677-687
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    • 2017
  • The nonlinear buckling response of nano composite anti-symmetric functionally graded polymeric microplate reinforced by single-walled carbon nanotubes (SWCNTs) rested on orthotropic elastomeric foundation with temperature dependent properties is investigated. For the carbon-nanotube reinforced composite (CNTRC) microplate, a uniform distribution (UD) and four types of functionally graded (FG) distribution are considered. Based on orthotropic Mindlin plate theory, von Karman geometric nonlinearity and Hamilton's principle, the governing equations are derived. Generalized differential quadrature method (GDQM) is employed to calculate the non-linear buckling response of the plate. Effects of FG distribution type, elastomeric foundation, aspect ratio (thickness to width ratio), boundary condition, orientation of foundation orthotropy and temperature are considered. The results are validated. It is found that the critical buckling load without elastic medium is significantly lower than considering Winkler and Pasternak medium.

Geometric structure and electronic behavior of Rh decorating effect on zigzag CNTs (n=7-12): A DFT study

  • Cui, Hao;Zhang, Xiaoxing;Zhou, Yongjian;Zhang, Jun
    • Carbon letters
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    • 제26권
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    • pp.61-65
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    • 2018
  • Comprehensive calculations of the Rh decoration effect on zigzag CNTs with n ranging from 7 to 12 were conducted in this work to understand the effect of Rh doping on geometric structures and electronic behaviors upon metallic and semiconducting CNTs. The obtained results indicated that Rh dopant not only contributes to the deformation of C-C bonds on the sidewall of CNTs, but also transforms the electron distribution of related complexes, thereby leading to a remarkable increase of the conductivity of pure CNTs given the emerged novel state within the energy gap for metallic CNTs and the narrowed energy gap for semiconducting CNTs. Our calculations will be meaningful for exploiting novel CNT-based materials with better sensitivity to electrons and higher electrical conductivity compared with pure CNTs.

Karl Fischer를 통한 전력케이블용 반도전 Composite 특성 연구 (A Study on the Property of Semiconductive Shield Composite through Karl Fischer Method in Power Cable)

  • 양훈;박대희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2008년도 Techno-Fair 및 합동춘계학술대회 논문집 전기물성,응용부문
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    • pp.187-188
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    • 2008
  • In this paper, we have investigated water content of semiconductive shield materials for power cables, EEA(Ethylene Ethyl Acrylate) is used polymer matrix. And filler is used CNT(Carbon Nanotube) and CB(Carbon Black). EEA, CNT and CB is favor moisture. In case of EEA, it has polyolefin resin that strong polarity combination. To research water content, experimental method used KF(Karl Fischer). KF method is Electrochemical titration based on chemical reaction. As a result, specification by KEPCO(Korea Electric Power Corporation) is lower than 800ppm. CNT and CB ratio of 80 versus 20 is best specimen that had lowest moisture content. It seem likely to increase crosslinking rate, CNT between CB.

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The Memory Effects of a Carbon Nanotube Nanodevice

  • Lee Chi-Heon;Kim Ho-Gi
    • Transactions on Electrical and Electronic Materials
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    • 제4권4호
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    • pp.26-29
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    • 2003
  • To discover electrical properties of individual single wall nanotube(SWNT), a number of SWNT-based tubeFETs have been fabricated. The device consists of a single semiconducting SWNT on an insulating substrate, contacted at each end by metal electrodes. It presents high transconductances, and charge storage phenomenon, which is the operations of injecting electrons from the nanotube channel of a tubeFET into charge traps on the surface of the $SiO_2$ gate dielectric, thus shifting the threshold voltage. This phenomenon can be repeated many times, and maintained for the hundreds of seconds at room temperature. We will report this phenomenon as the memory effects of the SWNT, and attempt to use this property for the memory device.

Size dependent effect on deflection and buckling analyses of porous nanocomposite plate based on nonlocal strain gradient theory

  • Khazaei, Pegah;Mohammadimehr, Mehdi
    • Structural Engineering and Mechanics
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    • 제76권1호
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    • pp.27-56
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    • 2020
  • In this paper, the deflection and buckling analyses of porous nano-composite piezoelectric plate reinforced by carbon nanotube (CNT) are studied. The equations of equilibrium using energy method are derived from principle of minimum total potential energy. In the research, the non-local strain gradient theory is employed to consider size dependent effect for porous nanocomposite piezoelectric plate. The effects of material length scale parameter, Eringen's nonlocal parameter, porosity coefficient and aspect ratio on the deflection and critical buckling load are investigated. The results indicate that the effect of porosity coefficient on the increase of the deflection and critical buckling load is greatly higher than the other parameters effect, and size effect including nonlocal parameter and the material length scale parameter have a lower effect on the deflection increase with respect to the porosity coefficient, respectively and vice versa for critical buckling load. Porous nanocomposites are used in various engineering fields such as aerospace, medical industries and water refinery.

A Study on the Estimation Method of the Environmental Load Intensity for Analyzing GHG Reduction Effect of Han-Ok

  • Kim, Sunghee
    • Architectural research
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    • 제15권3호
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    • pp.143-150
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    • 2013
  • The Korean government recently has rediscovered the potential value of Han-Ok, the Korean traditional house, as an eco-friendly building. In order to objectively verify the environmental performance of Han-Ok as a low carbon green building, this paper suggests the analysis method of GHG emission load of Korean traditional house, based on Life Cycle Assessment, which is commonly abbreviated to "LCA". The environmental impacts caused by building construction and operation can be analyzed through the sum of input and output data from every phase. The study particularly describes the GHG reduction effect by using traditional building materials such as wood products, traditional clay roof tiles, and mud, which are mainly used to construct Han-Ok. Also the study proposes the method for comparative analysis of quantity of GHG emissions in building's entire life cycle so that the data can be used as a reliable basis to optimize the environmental performance of building.

리간드 N-Benzylisonitrosoacetylacetone Imine의 구조 (The Structure of Ligand, N-benzylisonitrosoacetylacetone Imine)

  • 이병교;오대섭;이흥락
    • 대한화학회지
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    • 제32권6호
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    • pp.549-556
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    • 1988
  • 이미 합성된 N-benzylisonitrosoacetylacetone $imine^1$의 유기용매내에서의 구조변화를 측정하기 위하여 여러가지 유기용매에서의 핵자기공명스펙트럼 및 Carbon-13 핵자기공명 DEPT 스펙트럼 등의 분광학적인 자료를 이용하였다. 그 결과 이 시약은 monoxime의 일종으로 용매 중에서 syn- 형과 anti- 형의 기하이성질체가 공존하고 있으며 각각이 토우토메리 현상을 일으키고 있다.

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Influence of MWCNTs on Fracture Toughness of MWCNTs/Nickel-Pitch Fiber/Epoxy Composites

  • Yim, Yoon-Ji;Park, Soo-Jin
    • Composites Research
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    • 제28권6호
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    • pp.361-365
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    • 2015
  • The influence of MWCNTs on fracture toughness properties of MWCNTs/Nickel-Pitch Fibers/epoxy composites (MWCNTs/Ni-PFs/epoxy) was investigated according to MWCNTs content. Nickel-Pitch-based carbon fibers (Ni-PFs) were prepared by electroless nickel-plating. The surface properties of Ni-PFs were determined by scanning electron microscopy (SEM) and X-ray photoelectron spectrometry (XPS). The fracture toughness of MWCNTs/Ni-PFs/epoxy was assessed by critical stress intensity factor ($K_{IC}$) and critical strain energy release rate ($G_{IC}$). From the results, it was found that the fracture toughness properties of MWCNTs/Ni-PFs/epoxy were enhanced with increasing MWCNTs content, whereas the value decreased above 5 wt.%. MWCNTs content. This was probably considered that the MWCNTs entangled with each other in epoxy due to an excess of MWCNTs.

Balanced Ratio of Concrete Beams Internally Prestressed with Unbonded CFRP Tendons

  • Lee, C.;Shin, S.;Lee, H.
    • International Journal of Concrete Structures and Materials
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    • 제11권1호
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    • pp.1-16
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    • 2017
  • The compression or tension-controlled failure mode of concrete beams prestressed with unbonded FRP tendons is governed by the relative amount of prestressing tendon to the balanced one. Explicit assessment to determine the balanced reinforcement ratio of a beam with unbonded tendons (${\rho}^U_{pfb}$) is difficult because it requires a priori knowledge of the deformed beam geometry in order to evaluate the unbonded tendon strain. In this study, a theoretical evaluation of ${\rho}^U_{pfb}$ is presented based on a concept of three equivalent rectangular curvature blocks for simply supported concrete beams internally prestressed with unbonded carbon-fiber-reinforced polymer (CFRP) tendons. The equivalent curvature blocks were iteratively refined to closely simulate beam rotations at the supports, mid-span beam deflection, and member-dependent strain of the unbonded tendon at the ultimate state. The model was verified by comparing its predictions with the test results. Parametric studies were performed to examine the effects of various parameters on ${\rho}^U_{pfb}$.

Microwave-treated Expandable Graphite Granule for Enhancing the Bioelectricity Generation of Microbial Fuel Cells

  • Kim, Minsoo;Song, Young Eun;Li, Shuwei;Kim, Jung Rae
    • Journal of Electrochemical Science and Technology
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    • 제12권3호
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    • pp.297-301
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    • 2021
  • Microbial fuel cells (MFCs) convert chemical energy to electrical energy via electrochemically active microorganisms. The interactions between microbes and the surface of a carbon electrode play a vital role in capturing the respiratory electrons from bacteria. Therefore, improvements in the electrochemical and physicochemical properties of carbon materials are essential for increasing performance. In this study, a microwave and sulfuric acid treatment was used to modify the surface structure of graphite granules. The prepared expandable graphite granules (EGG) exhibited a 1.5 times higher power density than the unmodified graphite granules (1400 vs. 900 mW/m3). Scanning electron microscopy and Fourier transform infrared spectroscopy revealed improved physical and chemical characteristics of the EGG surface. These results suggest that physical and chemical surface modification using sulfuric acid and microwave heating improves the performance of electrode-based bioprocesses, such as MFCs.