• Title/Summary/Keyword: Capacity retention

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Impact of Application Rate of Non-ionic Surfactant Mixture on Initial Wetting and Water Movement in Root Media and Growth of Hot Pepper Plug Seedlings (비이온계 계면활성제 혼합물의 처리농도가 상토의 수분 보유 및 고추 플러그묘의 생장에 미치는 영향)

  • Choi, Jong-Myung;Moon, Byung-Woo
    • Horticultural Science & Technology
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    • v.29 no.1
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    • pp.16-22
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    • 2011
  • In developing soil wetting agent using polyoxyethylene nonylphenyl ether (PNE) and polyoxyethylene castor oil (1:1; v/v), the effect of application rates on changes in concentration of PNE, initial wetting of peatmoss + perlite (7:3) medium, and growth of hot pepper (Capsicum annuum L. 'Knockwang') plug seedlings were investigated. The elevation of application rates of wetting agent increased the amount of water retained by the root media. The treatment of 2.5 $mL{\cdot}L^{-1}$ showed similar water retention to + control ($AquaGro^L$ 3.0 $mL{\cdot}L^{-1}$). Most of the liquid wetting agent (LWA) incorporated during the medium formulation leached out in the first and second irrigation, then it decreased gradually until 10 times in irrigation. In investigation of the influence of LWA on position of water infiltrating into root media, the vertical water movements in treatments of 0.5, 1.0, and 1.5 $mL{\cdot}L^{-1}$ were much faster than those in 0.0 $mL{\cdot}L^{-1}$ (-control), but relative speed of water movement decreased by the elevation in application rate of LWA to 2.0 or 2.5 $mL{\cdot}L^{-1}$. The evaporative water loss of root media that to contained various rate of LWA and irrigated to reach container capacity was the fastest in -control among the treatments and it delayed as the application rate of LWA was elevated. The plant height of 22.2 cm in 0.5 $mL{\cdot}L^{-1}$ and stem diameter of 3.26 mm in 1.0 $mL{\cdot}L^{-1}$ were the highest among the treatments tested. The treatment of 1.0 $mL{\cdot}L^{-1}$ also had the heaviest fresh and dry weights such among treatments tested as 3.08 g and 0.861 g per plant, respectively. The elevated application rate over than 1.5 $mL{\cdot}L^{-1}$ resulted in decreased seedling growth. The results mentioned above indicate that optimum application rate of LWA is 1.0 $mL{\cdot}L^{-1}$.

A Study on the New Development for Determination of Dead Time in GC-OTC/FID (GC-OTC/FID에서 Dead Time 결정을 위한 새로운 방법 개발에 대한 연구)

  • Oh, Doe Seok;Kim, Sung Wha;Ko, Eun Ah;Jeon, Hyung Woo
    • Journal of the Korean Chemical Society
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    • v.63 no.4
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    • pp.246-252
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    • 2019
  • In the system of GC-OTC/FID (Gas chromatography-Open Tubular Column/Flame Ionization Detector), DMSO (Dimethyl sulfide) solvent was used to separate the polar solvents (Alcohols). In this system DMSO was eluted later than the separated polar solvents. At this system to calculate chromatographic factors [adjusted retention time ($t_R^{\prime}=t_R-t_O$), capacity factor{$k^{\prime}=(t_R-t_O)/t_O$} and separation factor {${\alpha}=(t_{R2}-t_O)/(t_{R1}-t_O)$}], dead time($t_O$) is necessary, but the method to calculate it has not been reported yet. Therefore, we have tried to develop $t_O$. To calculate $t_O$, we conversed DMSO retention time (DMSO $t_R$) to logarithm ($f(x)={\log}\;t_{R(DMSO)}{\rightarrow}t_O$, $t_O={\log}$ 9.551=0.980). To confirm the optimization of the developed method, we compared with $CH_4\;t_R$ and ${\ln}\;t_{R(DMSO)}$. Both of the values calculated by $CH_4\;t_R$ and ${\ln}\;t_{R(DMSO)}$ were not suitable in the calculation k' and ${\alpha}$. The developed method in this study{${\log}\;t_{R(DMSO)}$} has satisfied both of the values k' criteria (1${\alpha}(1<{\alpha}<2)$. The developed calculation method in this study was easy and convenient, therefore it can be expected to be applied to these similar systems.

Soil Physiochemical Properties in Leaf-yellowing Black Locust (Robinia Pseudo-acacia L.) Stands (아까시나무 황화현상 발생임분의 토양 이화학적 특성)

  • Lee, Seung-Woo;Byun, Jae-Kyoung;Ji, Dong-Hun;Kwon, Young-Dae
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.6
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    • pp.409-414
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    • 2009
  • In 1970's Black locust(Robinia pseudoacacia) had been widely planted Korea as an important forest greening species for erosion control afforestation. Since 2000, however, the tree's leaf-yellowing symptom has often been observed at a limited region and then spreaded out over the country in 2006. This study was conducted to study soil physiochemical properties of black locust stands with and without the leaf-yellowing symptom in Osan, Gyeonggi province. Most of soils in sampling sites were mostly slightly eroded, dry, and moderately dry. Available soil depth(16cm) and total soil depth(26cm) in leaf-yellowing (LY) site were significantly lower than in non leaf-yellowing (Non-LY) site's soil depths which were 30cm and 56cm, respectively. And solid phase proportion and bulk density in soils were lower in LY site than in non-LY site soils, while soil liquid phase proportion was also low. It could reflect that LY site soils might have a lower air and moisture movement in the rhizosphere of black locust stand compared with non-LY site soils. Soil acidity in both sites was very strong acid, soil pH (4.42) of LY site was slightly lower than non-LY site's (pH 4.54). Content of available phosphorous, exchangeable $Ca^{2+}$ and $Mg^{2+}$ and percent base saturation were less than LY site. These results indicated that soil physiochemical condition in LY site, more deteriorated than non-LY site, should adversely affect the retention and supply capacity of soil nutrients and moisture. Therefore the black locust may be more sensitive to other environmental stresses.

Biological conversion of CO2 to CH4 in anaerobic fixed bed reactor under continuous operation (혐기성 고정층 생물반응기의 연속운전을 통한 이산화탄소의 메탄전환)

  • Kim, Jaehyung;Koo, Hyemin;Chang, Wonseok;Pak, Daewon
    • Journal of Energy Engineering
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    • v.22 no.4
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    • pp.347-354
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    • 2013
  • This study was carried out to examine different mole ratio of $H_2/CO_2$ and EBCT using the continuous system in the lab scale throughout biological methods with accumulated hydrogenotrophic methanogen that can convert $CO_2$ to $CH_4$. The experimental-based results with various gas mixtures of mole ratio of 4:1($H_2/CO_2$) and 5:1($H_2/CO_2$), $H_2$ was converted more than 99% conversion rate. In case of $CO_2$, 4:1($H_2/CO_2$) and 5:1($H_2/CO_2$) were $74.45{\pm}0.33%$, $95.8{\pm}10.7%$, respectively, in addition, the study was confirmed that the amount of $H_2$ was more needed than stoichiometric equations, where approach methods are empirical versus theoretical frameworks, for converting total $CO_2$. As such, we have noticed that $H_2$ was used for energy source of hydrogenotrophic methanogen for maintaining life. Regarding the results of the ratio of treatment by retention time, limitation of treatment capacity showed that $H_2$(99.9%) and $CO_2$(96.23%) at EBCT 3.3 hrs indicated stable conversion ratio, as well as appeared that methane production rate and $CO_2$ fixation rate were investigated $1.15{\pm}0.02m^3{\cdot}m^{-3}{\cdot}day^{-1}$ and $2.01{\pm}0.04kg{\cdot}m^{-3}{\cdot}day^{-1}$, respectively.

Study on the Thickness Effect of the Separator for Lithium Secondary Batteries (리튬이차전지용 분리막의 두께에 따른 특성 연구)

  • Kim, Sang Woo;Seok, Ji-Hoo;Kim, Byung-Hyun Daniel;Cho, Hee-Min;Cho, Kuk Young
    • Journal of the Korean Electrochemical Society
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    • v.17 no.1
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    • pp.7-12
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    • 2014
  • There is increasing demand on the reducing the weight and the volume of the major components in lithium secondary battery to improve energy density. Separator not only provides pathway for lithium ion movement but also prevents direct contact between anode and cathode. Herein we fabricated polyethylene separator by varying biaxial stretching ratio to obtain membrane thickness of 16, 12, and $9{\mu}m$. Mechanical and thermal properties of the separator with different thickness were investigated. Also rate capability and charge-discharge cycle property up to 500 cycles were studied using coin type full-cell with $LiCoO_2$ and graphite as a cathode and an anode, respectively. All the cells using separator with different thickness demonstrated excellent capacity retention after 500cycles (around 80%). Considering the rate capability, cell using separator with thickness of $9{\mu}m$ showed best performance. Interestingly, separator thickness of $9{\mu}m$ was more resistant to heat contraction compared to that of $16{\mu}m$ separator.

Effects of Lithium Bis(Oxalate) Borate as an Electrolyte Additive on High-Temperature Performance of Li(Ni1/3Co1/3Mn1/3)O2/Graphite Cells (LiBOB 전해액 첨가제 도입에 따른 Li(Ni1/3Co1/3Mn1/3)O2/graphite 전지의 고온특성)

  • Jeong, Jiseon;Lee, Hyewon;Lee, Hoogil;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.18 no.2
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    • pp.58-67
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    • 2015
  • The effects of electrolyte additives, lithium bis(oxalate)borate (LiBOB), fluoroethylene carbonate (FEC), vinylene carbonate (VC), 2-(triphenylphosphoranylidene) succinic anhydride (TPSA), on high-temperature storage properties of $Li(Ni_{1/3}Co_{1/3}Mn_{1/3})O_2$/graphite are investigated with coin-type full cells. The 1 wt.% LiBOB-containing electrolyte showed the highest capacity retention after high temperature ($60^{\circ}C$) storage for 20 days, 86.7%, which is about 5% higher than the reference electrolyte, 1.15M lithium hexafluorophosphate ($LiPF_6$) in ethylene carbonate/ethyl methyl carbonate (EC/EMC, 3/7 by volume). This enhancement is closely related to the formation of semi-carbonate compounds originated from $BOB^-$ anions, thereby resulting in lower SEI thickness and interfacial resistance after storage. In addition, the 1 wt.% LiBOB-containing electrolyte also exhibited better cycle performance at 25 and $60^{\circ}C$ than the reference electrolyte, which indicates that LiBOB is an effective additive for high-temperature performance of $Li(Ni_{1/3}Co_{1/3}Mn_{1/3})O_2$/graphite chemistry.

High Voltage Performance of the Electrical Double Layer Capacitor with Various Electrolytes (다양한 전해액을 적용한 전기이중층 커패시터의 고전압 특성 연구)

  • Kim, Jung Wook;Choi, Seung-Hyun;Kim, Jeom-Soo
    • Journal of the Korean Electrochemical Society
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    • v.20 no.2
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    • pp.34-40
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    • 2017
  • Electric double layer capacitors (EDLC: electric double layer capacitors) have drew attention as an energy storage device for the next generation because of their outstanding power capability and durability. But their usage is somewhat limited due to low energy density over secondary batteries. One of methods to improve the energy of EDLC is expanding the voltage window of cell operation by increasing the charge cut-off voltage. In this study, $SBP-BF_4$ (spirobipyrrolidinium tetrafluoroborate), $TEA-BF_4$ (tetraethylammonium tetraflouroborate) and $EMI-BF_4$ (1-ethyl-3-methylimidazolium tetrafluoroborate) in AN (acetonitrile) were selected to evaluate the possibility of application at high voltage environment. The LSV (linear sweep voltammetry) measurements showed that the 1.5M SBP-BF4/AN electrolyte was stable over a wide potential window and showed the best electrochemical performance compared to other combinations of electrolytes at high voltage environments (over 3.0 V). Furthermore, TMSP (tris(trimethylsilyl) phosphite) was applied to 1.5M SBP-BF4/AN in order to maintain stable performance at high voltage for the long period of time. The electrolyte with TMSP additive showed the capacity retention of 93% after 10,000 cycles at 3.3 V.

A Study on the Responsibility Judgment and Mental Disorder of Criminal Psychology (책임능력판단에 관한 범죄심리학적 이론과 정신장애 항변 연구)

  • Rim, Sang-Gon
    • Korean Security Journal
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    • no.10
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    • pp.293-322
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    • 2005
  • The culpability of a person, as determined by due process of law, for any of his actions that are defined as criminal. Determination of such responsibility is a legal function, not a psychiatric one, although a psychiatrist may be called upon to present evidence to the court in order to aid the judge or jury in reaching a decision as to responsibility. Determination of responsibility varies with the laws of the state in which the accused is being tried, but in general all states base their laws on three famous judicial decisions concerning criminal responsibility. 1. the M'Naghten(McNaughton) rule(a. to establish such a defense the accused, at the time the act was committed, must be shown to have been laboring under such defect of reason as not to know the nature and quality of the act he was doing, b. if he did know it, he did or know that what he was doing was wrong). 2. the irresistible impulse test. 3. the Durham decision. Under the Durham test, however, the psychiatrist may give any relevant testmony concerning the mental illness at issue. The psychological and behavioral appearance of a person, in clinical psychiatry this term is commonly used to refer to the results of the mental examination of a patient. The written report of the mental status usually contains specific references to the following areas: I. Attitude and General Behavior (1)General health and appearance. (2)General habits of dress. (3)Personal habits. (4)General mood. (5)Use of leisure time. (6)Degree of sociability. (7)Speech. II. Attitude and Behavior during interview (1)Co-operativeness. (2)Poise. (3)Facial expression. (4)Motor activity. (5)Mental activity. (6)Emotional reactions. (7)Trend of thought. III. Sensorium, mental grasp, and capacity (1)Orientation. (2)Memory and retention. (3)Estimate of intelligence. (4)Abstraction ability. (5)Tests of absurdity, interpretation of proverbs. (6)Judgment.

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Estimation of the Spatial Distribution of Groundwater Recharge by Grid-based Soil Water Balance Method (격자기반의 토양물수지방법에 의한 지하수함양의 공간분포 추정)

  • An Jung-Gi;Lee Yong-Doo;Hwang Jong-Hwan
    • Journal of Soil and Groundwater Environment
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    • v.11 no.1
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    • pp.65-76
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    • 2006
  • This paper outlines the methodology of grid-based water balance for estimating the spatial distribution of recharge, which is applied to Woedo catchment in the northern area of the Jeju Island. The catchment is divided into grids and a daily water balance in each grid is computed for the period of 5 years. Daily rainfall data in each grid is interpolated from the data of 10 rainfall gauging stations. The spatial distributions of parameters such as SCS curve number, soil water retention capacity and crop coefficients are derived from GIS analyses of soil and land use characteristics. The SCS curve number is obtained by calibrating simulated runoffs with respect to the observed runoffs. The results show that the average annual rainfall increases from 1,665 mm/year to 3,382 mm/year in accordance with the topographic elevation, and the average annual recharge varies from 372 mm/year to 2,576 mm/year according to the average annual rainfall increases. Spatial variability of recharge is the highest among the water balance components such as rainfall, direct runoff, evaprotranspiration and recharge because the rate of runoff and evapotranspiration in the area with relatively low rainfall is higher than the other area.

Status of Sediment Dynamics in Lake Takkobu of the Kushiro Mire, Japan, Associated with Forestry and Agricultural Development in the Watershed (산림과 농업 개발로 인한 쿠시로습원 타호부호수의 최근 토사동태)

  • Ahn, Young-Sang
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.5
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    • pp.755-763
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    • 2010
  • Fine sediment loadings from agricultural watersheds have led to habitat degradation in Lake Takkobu, northern Japan. Fifteen lake sediment core samples were obtained and analyzed to develop a chronology using physical sediment characters, $^{137}Cs$, and tephra. The reconstructed sedimentation rates over the past ca 300 years suggested that sedimentation rates increased drastically after land use development. With a natural sedimentation rate of 0.1-1.1 mm $year^{-1}$ until 1898, lake sedimentation accelerated to 0.6-12.8 mm $year^{-1}$ after 1898. The sedimentation rates after land use change, such as forestry, river engineering works, and agricultural development, were about 6-12 times higher than that under natural conditions, leading to accelerated lake shallowing over the last ca 100 years. Sedimentation rates between 1898 and 1963 differed with location in the lake because of spatial variation in the sediment flux from the contributing rivers and their watersheds. The sedimentation rate in the southern zone between 1898 and 1963 was significantly higher than that in the middle and northern zones, reflecting active sediment production associated with forestry for charcoal production and canal construction for transportation in the southern watersheds and wetlands. The sedimentation rate after 1963 did not vary among the three zones, because decreasing sedimentation was found in most of the southern sites whereas an increasing trend was observed in the middle and northern sites. This result can be explained by shallowing of lake-bottom morphology with sedimentation and the resultant reduction of sediment retention capacity in the southern zone. Moreover, the sedimentation rate at sampling sites close to river mouths increased by 5-32 times compared with natural rates before 1898. The Kushiro River, into which Lake Takkobu drains under regular flow conditions, further contributed to an increased sedimentation rate, because water from the Kushiro River flows back into Lake Takkobu during floods.