• 대한화학회지
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• 제37권7호
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• pp.689-691
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• 1993

• 대한치과기공학회지
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• 제31권4호
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• pp.15-23
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• 2009

The aim of this study was to evaluate the bond strength of using a Au bonding agent applied on cp-Ti and nonprecious metal-gold-ceramic system. Metallic frameworks(diameter: 5mm, height: 20mm)(N=56, n=7per group) cast in Ni-Cr alloy, Co-Cr alloy and cp-Ti were obtained using acrylic templates and airborne particle abraded with $110{\mu}m$ aluminum oxide. Au bonding agent was applied on wash opaque firing as intermediate layer. SEM and SEM/EDS line profile were performed on the cutting the cross-section of the metal substrate-porcelain with intermediate Au coating. Groups were tested using shear bond strength(SBS) testing at 0.5mm/min. The mean SBS values for the ceramic-Au layer-metal combination were significantly higher than those ceramic-metal combination. While ceramic-Au layer-cp-Ti combinations failed to increase bond strength instead of using a titanium bonding porcelain. The appication of using Au intermediate layer significantly improve the bond strength combination with metal-ceramic system.

• Journal of Periodontal and Implant Science
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• 제42권6호
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• pp.248-255
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• 2012

Purpose: The aim of the present study was to evaluate the biological response of alkali- and heat-treated titanium-8tantalum-3niobium surfaces by cell proliferation and alkaline phosphatase (ALP) activity analysis. Methods: Commercial pure titanium (group cp-Ti) and alkali- and heat-treated titanium-8tantalum-3niobium (group AHT) disks were prepared. The surface properties were evaluated using scanning electron microscopy, energy dispersed spectroscopy and X-ray photoelectron spectroscopy (XPS). The surface roughness was evaluated by atomic force microscopy and a profilometer. The contact angle and surface energy were also analyzed. The biological response of fetal rat calvarial cells on group AHT was assessed by cell proliferation and ALP activity. Results: Group AHT showed a flake-like morphology microprofile and dense structure. XPS analysis of group AHT showed an increased amount of oxygen in the basic hydroxyl residue of titanium hydroxide groups compared with group cp-Ti. The surface roughness (Ra) measured by a profilometer showed no significant difference (P>0.05). Group AHT showed a lower contact angle and higher surface energy than group cp-Ti. Cell proliferation on group AHT surfaces was significantly higher than on group cp-Ti surfaces (P<0.05). In comparison to group cp-Ti, group AHT enhanced ALP activity (P<0.05). Conclusions: These results suggest that group AHT stimulates osteoblast differentiation.

• 대한치과기공학회지
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• 제28권1호
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• pp.61-66
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• 2006

Titanium alloys have been used for dental materials due to it's very good biocompatibility. Ti-6Al-4V alloy instead of pure titanium is being widely used as biomaterials has some characteristics such as high fatigue strength, tensile strength and corrosion resistance. But it has been reported recently that the vanadium element expresses cytotoxicity and carcinogenicity and the aluminium element is related with dementia of Alzheimer type and neurotoxicity. The Ti-Nb alloys has designed and examined corrosion resistance. Ti-3wt.%Nb($\alpha$type), Ti-20wt.%Nb(${\alpha}+{\beta}$type) and Ti-40wt.%Nb($\beta$type) alloys were melted by vacuum arc furnace. The corrosion resistance of Ti alloys was evaluated by potentiodynamic polarization test in the solution of 0.9% NaCl and 5% HCl. The results can be summarized as follows: 1) For the corrosion test in the solution of 0.9% NaCl and 5% HCl, the corrosion behaviour of Ti-Nb alloys was similar to ASTM grade 2 CP Ti. 2) The corrosion resistance of Ti-20Nb alloy was better than that of CP-Ti, Ti-3Nb, Ti-40Nb alloy in 0.9% NaCl and 5% HCl, solutions.

• 한국재료학회지
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• 제15권5호
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• pp.353-360
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• 2005

Surface treatment play an important role in nucleating calcium phosphate deposition on surgical Ti implant. Therefore, the purpose of this study is to examine whether the precipitation of apatite on cp-Ti and Ti alloys are affected by surface modification in HCl and $H_2O_2$ solution. Specimens were then chemically treated with a solution containing 0.1 M HCl and 8.8M $H_2O_2$ at $80^{\circ}C$ for 30 mins, and subsequently heat-treated at $400^{\circ}C$ for 1 hour. All specimens were immersed in the HBSS with pH 7.4 at $36.5^{\circ}C$ for 15 days, and the surface was examined with XRD, SEM, EDX ana XPS. Also, pure Ti, Ti-6Al-4V and Ti-6Al-7Nb alloy specimens with and without surface treatment were implanted in the abdominal connective tissue of mice for 4 weeks. All specimens chemically treated with HCl and $H_2O_2$ solution have the ability to form a apatite layer in the HBSS which has inorganic ion composition similar to human blood plasma. The average thickness of the fibrous capsule surrounding the specimens implanted in the connective tissue was $38.57\;{\mu}m,\;62.27\;{\mu}m\;and\;45.64\;{\mu}m$ in the cp-Ti, Ti-6Al-4V ana Ti-6Al-7Nb alloy specimens with the chemical treatment respectively, and $52.20\;{\mu}m,\;75.62\;{\mu}m\;and\;66.56\;{\mu}m$ in the commercial specimens of cp-Ti, Ti-6Al-4V and Ti-6Al-7Nb without any treatment respectively. The results of this evaluation indicate that the chemically treated cp-Ti, Ti-6Al-4V ana Ti-6Al-7Nb alloys have better bioactivity and biocompatibility compared to the other metals tested.

• 대한치과기공학회지
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• 제23권2호
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• pp.223-230
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• 2002

Pure titanium and Ti6Al4V alloy have been mainly used as implant materials but the cytotoxicity of V, neurotoxicity of Al resulting in Alzheimer disease had been reported. This paper was described the influence of composition of Ti-Nb alloys with 3 wt%Nb, 20 wt%Nb on the microstructure and corrosion resistance. Specimens of Ti alloys were melted in vacuum arc furnace and homogenized at $1000^{\circ}C$ for 24hr. The alloys were rolled in $\beta$ and ${\alpha}+{\beta}$ regions. The corrosion resistance of Ti alloys were evaluated by potentiodymic polarization test in 0.9% NaCl and 5% HCl solutions. The results can be summarized as follows: 1. The microstructure was transformed from $\alpha$ phase to ${\alpha}+{\beta}$ phase by adding Nb 2. The hardness of Ti-20Nb alloy was greater than Cp- Ti, Ti-3Nb alloy. 3. The corrosion resistance of Ti-20Nb alloy was better than that of Cp-Ti, Ti-3Nb alloy in 0.9%NaCl and 5%HCl solutions.

• 대한치과기공학회지
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• 제25권1호
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• pp.89-94
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• 2003

The use of titanium alloys as biomaterials is increasing due to their superior biocompatibility and enhanced corrosion resistance compared to conventional stainless steels and cobalt-based alloys. Ti-6Al-4V ($\alpha+\beta$type) alloy instead of pure titanium ($\alpha$type) is being widely used as biomaterials has some characteristics such as high fatigue strength, tensile strength and corrosion resistance. It also has similar characteristics to Ti in inducing bony ingrowth. But it has been reported recently that the vanadium element expresses cytotoxicity and carcinogenicity and the aluminium element is related with dementia of Alzheimer type and neurotoxicity. In order to overcome their detrimental effects, $\beta$-phase stabilizer Nb was chosen in the present study. CP-Ti(ASTM grade 2), Ti-3wt.%Nb($\alpha$type), Ti-20wt.%Nb ($\alpha+\beta$type) and Ti-40 wt.%Nb($\beta$type) alloys were melted by vacuum arc furnace. Biocompatibility of Ti-Nb alloys was evaluated by cytotoxicity test. The results can be summarized as follows: 1. For the cytotoxicity test, Ti-Nb alloys showed excellent biocompatibility compared to CP-Ti(ASTM grade 2), 316L STS and Co-Cr alloys.

• 한국재료학회지
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• 제14권6호
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• pp.432-435
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• 2004

Ti and Ti alloys are important materials for medical and dental applications. The effect of equal channel angular process(ECAP) and addition of Fe in Ti were studied with optical microstructure and corrosion behavior. Fine grains in Ti was obtained after ECAP. Corrosion behavior of commercial pure(CP)-Ti and Ti alloys was studied by open circuit test and polarization curve test(PCT) at $36.5^{\circ}C$ with SBF in biological environment. The corrosion behavior of ECAP-Ti was similar to that of CP-Ti in PCT, but Ti-Fe alloys were observed to become more corrosive with increasing Fe content.

• Journal of Electrochemical Science and Technology
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• 제3권4호
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• pp.185-189
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• 2012

A.c. impedances of mechanically polished CP-Ti specimens were measured at open-circuit potential (OCP) with immersion time and under applied anodic potentials between -0.2 and 1 $V_{Ag/AgCl}$ in 0.1 M NaOH solution. Capacitances of native oxide films ($C_{ox,na}$) grown naturally and capacitances of anodic oxide films ($C_{ox,an}$) formed under applied anodic potentials were obtained to examine the growth of native and anodic oxide films in 0.1 M NaOH solution and how to use $C_{ox,na}$ for the surface area measurement of Ti specimen. $1/C_{ox,na}$ and $1/C_{ox,an}$ appeared to be linearly proportional to OCP and applied potential ($E_{app}$), with proportional constants of 0.086 and 0.051 $uF^{-1}\;V^{-1}$, respectively. The $C_{ox,na}$ also appeared to be linearly proportional to geometric surface area of the mechanically polished CP-Ti fixture specimen, with proportional constants of 11.3 and $8.5{\mu}F\;cm^{-2}$ at -0.45 $V_{Ag/AgCl}$ and -0.25 $V_{Ag/AgCl}$ of OCPs, respectively, in 0.1 M NaOH solution. This linear relationship between $C_{ox,na}$ and surface area is suggested to be applicable for the measurement of real surface area of Ti specimen.

• Environmental Engineering Research
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• 제7권4호
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• pp.227-237
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• 2002

Chemical vapor deposition (CVD), ion beam sputtering (IBS) and sol-gel method were used to prepare TiO$_2$ thin films for degradation of hazardous organic compounds exemplified by 2-chlorophenol (2-CP). The influence of supporting materials and coating methods on the photocatalytic activity of the TiO$_2$ thin films were also studied. TiO$_2$ thin films were coated onto various supporting materials including steel cloth (SS), copper cloth, quartz glass tube (QGT), and silica gel (SG). Results indicate that SS (37 μm)- TiO$_2$ thin film prepared by IBS method improves the photodegradation of 2-CP. Among all supporting materials studied, SS(37 μm) is found to be the best support.