• The Journal of Korean Institute of Communications and Information Sciences
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• v.30 no.11A
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• pp.1012-1020
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• 2005

In this paper, we propose a novel applying method of Mobile IPv6 service into the UMTS to solve the mapping problems in the GGSN TFT packet filter. The mobility management tables or the GGSN should be maintained as the same as the MN and the CN. Our proposed scheme copes with the problem when the RO procedure is not normally performed by using Mobile IPv6 signaling packets in the GGSN and adding a function block in the UMTS. To show the performance of our proposed algorithm, we accomplish the simulations of measuring the delay time in the cases of success and failure of the RO procedure. Also, the amount of transmission is observed when the packet transmission is assured in the case of the successful RO procedure.

• Journal of the Korean Chemical Society
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• v.9 no.2
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• pp.101-105
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• 1965

Spectrophotometric method for the determination of Co(Ⅱ) is developed based on the fact that Co(Ⅱ) forms a stable red complex with 7-nitroso-8-hydroxyquinoline-5-sulfonate at pH 4. 5. The absorbance is measured at 528$m{\mu}$, $25^{\circ}C$. Beer's law is followed in the concentration range of 0. 3 to 6. 0 p.p.m. of Co(Ⅱ) and molar extinction coefficient of the complex was $1.1{\times}10^4$. Of the diverse ions checked, Fe(Ⅱ), Fe(Ⅲ), Cu(Ⅱ), Mn(Ⅱ), Hg(Ⅰ), CN-, EDTA interfere. The composition of the complex is found to be 3:1 ligand to metal species by mole ratio and continuous variation methods.

• Proceedings of the Korea Water Resources Association Conference
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• 2010.05a
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• pp.576-580
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• 2010

NRCS의 유출곡선지수 산정법(CN; Runoff Curve Number method)은 유역내의 토지 이용 및 토지 피복, 토양특성, 수문학적 조건 등을 이용하여 총 강우량으로부터 유효 유출량을 계산하는 방법으로서 이론의 간편성과 적용성으로 인하여 여러 분야에 적용되고 있다. 그러나, 유출곡선지수의 특성상 지역적인 특성에 따라 차이가 발생할 수 밖에 없음에도 국내에서는 대부분 미국 NEH(National Engineering Handbook)에서 제시한 기준을 이용하고 있는 실정이다. 이에 대하여 본 연구에서는 국내 유역의 강우-유출 특성을 반영한 유출곡선지수를 산정하고 강우에 따른 직접 유출량을 모의하기 위한 방법을 연구하였다. 이를 위하여 보청천 유역의 관측 강우-유출 자료에 Hawkins et al(1993)등이 제시한 점근 유출곡선지수방법을 적용하고 이를 국가수자원관리종합정보시스템(WAMIS)에서 제시한 값과 비교하였다. 또한 유역의 대표 유출곡선지수에 대한 회귀식을 유도하고 이를 이용하여 보청천 유역의 하계 유출을 모의하고 그 결과를 비교 분석 하였다. 연구결과 대표 유출곡선지수식을 이용한 유역의 직접유출 모의결과가 단일 유출곡선지수시의 모의결과보다 더 우수한 결과를 나타내었다.

• Journal of the Korean Electrochemical Society
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• v.16 no.3
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• pp.145-150
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• 2013

In this study, the electrochemical investigation of various electrodes for reverse electrodialysis using potassium ferrocyanide and potassium ferricyanide as a redox system was carried out. Cyclic voltammetry was the employed method for this electrochemical study. From the results of cyclic voltammograms for various electrode materials, i.e., Au, Vulcan supported Pt, activated carbon, carbon nanofiber, Vulcan, the Vulcan electrode showed the lowest overpotential, but the Pt electrode having slightly higher overpotential obtained slightly higher anodic and cathodic current densities for the $Fe(CN)_6{^{4-}}/Fe(CN)_6{^{3-}}$ redox couple. The cyclic voltammograms for the Vulcan electrode confirmed very good electrochemical reversibility and kinetic behavior. As a result, among the electrode materials, the Vulcan electrode is the most promising electrode material for reverse electrodialysis.

• Bulletin of the Korean Chemical Society
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• v.6 no.6
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• pp.362-366
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• 1985

The hydrogen atom transfer reaction between substituted methane, $CH_3X,$ and its radical, $CH_2X(X=H,F,CH_3,CN,OH\;and\;NH_2$ was studied by MINDO/3 method. The transition state(TS) structure and energy barriers were determined and variation of the transition state and of the reactivity due to the change of X were analyzed based on the potential energy surface characteristics. It was found that the greater the radical stabilization energy. the looser the TS becomes; the TS occurs at about 15% stretch of the C-H bond, which becomes longer as the radical stabilization energy of $CH_2X$ increasers. The intrinsic barrier, ${\Delta}E*_{x.x},$ of the reaction with X was found to increase in the order $H The degree of bond stretch of the C-H bond stretch of the C-H bond at the TS also had the same order indicating that the homolytic bond cleavage of the C-H bond is rate-determining. Orbital interactions at the TS between LUMO of the fragment $C{\ldots}H{\ldots}C$ and the symmetry adapted pair of nonbonding, $n{\pm}(=n_1{\pm}n_2),$ or pi orbitals of the two X atoms were shown to be the dominant contribution in determining tightness or looseness of the TS. The Marcus equation was shown to apply to the MINDO/3 barriers and energy changes of the reaction.

• Journal of the Korean Vacuum Society
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• v.4 no.S2
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• pp.131-138
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• 1995

The broad beam ion sources of hot filament plasma type have widely used for modifications of materials and thin films, and the new type intensive current broad beam metal ion source including reactive gaseous ion beams is needed for preparing the hard coating films such as DLC, $\beta-C_3N_4$ Carbides, Nitrides, Borides etc. Now a electorn beam evaporation(EBE) broad beam metal ion source has been developed for this purpose in our lab. CN film has been formed by the EBE ion source. Study of the CN film shows that it has high hardness(HK=5800kgf/$\textrm {mm}^2$)and good adhesion. This method can widely changes the ratio of C/N atom's concentrations from 0.14 to 0.6 and has high coating rate. The low energy pocket ion source which was specially designed for surface texturing of medical silicon rubber was also developed. It has high efficiency and large uniform working zone. Both nature texturing and mesh masked texturing of silicon rubbers were performed. The biocompatibility was tested by culture of monocytes, and the results showed improved biocompatibility for the treated silicon rubbers. In addition, the TiB2 film synthesized by IBED is being studied recently in our lab. In this paper, the results which include the hardness, thickness of the films and the AES, XRD analysis as well as the tests of the oxidation of high temperature and erosion will be presented.

• ETRI Journal
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• v.46 no.3
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• pp.485-500
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• 2024

A hardware architecture is presented to decode (N, K) polar codes based on a low-density parity-check code-like decoding method. By applying suitable pruning techniques to the dense graph of the polar code, the decoder architectures are optimized using fewer check nodes (CN) and variable nodes (VN). Pipelining is introduced in the CN and VN architectures, reducing the critical path delay. Latency is reduced further by a fully parallelized, single-stage architecture compared with the log N stages in the conventional belief propagation (BP) decoder. The designed decoder for short-to-intermediate code lengths was implemented using the Virtex-7 field-programmable gate array (FPGA). It achieved a throughput of 2.44 Gbps, which is four times and 1.4 times higher than those of the fast-simplified successive cancellation and combinational decoders, respectively. The proposed decoder for the (1024, 512) polar code yielded a negligible bit error rate of 10^-4 at 2.7 E_b/N_o (dB). It converged faster than the BP decoding scheme on a dense parity-check matrix. Moreover, the proposed decoder is also implemented using the Xilinx ultra-scale FPGA and verified with the fifth generation new radio physical downlink control channel specification. The superior error-correcting performance and better hardware efficiency makes our decoder a suitable alternative to the successive cancellation list decoders used in 5G wireless communication.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.20 no.2
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• pp.404-411
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• 2019

In this study, the HEC-HMS was applied to determine rainfall-runoff processes for the Gokgyuchun basin. Several sub-basins have large-scale reservoirs for agricultural needs and they store large amounts of initial runoff. Three infiltration methods were implemented to reflect the effect of initial loss by reservoirs: 'SCS-CN'(Scheme I), 'SCS-CN' with simple surface method(Scheme II), and 'Initial and Constant rate'(Scheme III). Modeling processes include incorporating three different methods for loss due to infiltration, Clark's UH model for transformation, exponential recession model for baseflow, and Muskingum model for channel routing. The parameters were calibrated using an optimization technique with trial and error method. Performance measures, such as NSE, RAR, and PBIAS, were adopted to aid in the calibration processes. The model performance for those methods was evaluated at Gangcheong station, which is the outlet of study site. Good accuracy in predicting runoff volume and peak flow, and peak time was obtained using the Scheme II and III, considering the initial loss, whereas Scheme I showed low reliability for storms. Scheme III did not show good matches between observed and simulated values for storms with multi peaks. Conclusively, Scheme II provided better results for both single and multi-peak storms. The results of this study can provide a useful tool for decision makers to determine master plans for regional flood control management.

• Journal of the Korean Applied Science and Technology
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• v.33 no.1
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• pp.67-74
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• 2016

The Prussian Blue Analogue(PBA) has three dimensional structure and the metal - organic framework material, and it has a variety configurations depending on the type of organic ligands. PBA has been receving an attention in the fields of biosensors, optical, catalytic, and hydrogen storage device. Also, it is an environmental friendly substance with a chemical stability. In addition, PBA is widely used in the filed of adsorption art since we can adjust the size of the fine pores. In this study, we synthesized $Mn_3[Fe(CN)_6]_2$, an organometallic framework chains by using a hydrothermal synthesis method. We used $K_4[Fe(CN)_6]$ and $MnCl_2$ as precursors. We also produced a manganese iron oxide, by baking the synthesized material. The effect of the size and shape of the particles was examined by controling pH of the precursor solution, the molar concentration of the precursor, and reaction time as the experimental variables. Synthesized absorbent was analyzed by XRD, SEM, FT-IR, UV-Vis, and TG / DTA to evaluate the adsorption properties of several dyes.

• Journal of the Korean Chemical Society
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• v.42 no.2
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• pp.214-219
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• 1998

Dynorphin B analogues, $[Arg^{11}, D-Ala^{12}]$dynorphin B, $[D-Ala^2, Ala^6, Arg^{11}, D-Ala^{12}]$dynorphin B, and dynorphin B (1-11) were synthesized by solid-phase method. A chloromethylated polystyrene resin cross-linked with 2% divinylbenzene was substituted with Thr in ethanol to contain 1.20 mmol Thr/g of resin. All amino groups of amino acids were protected with t-Boc group and 2,6-dichlorobenzyl and nitro groups were used to protect the side chains of Tyr and Arg, respectively. Stepwise synthetic method was applied for synthesis of the products. Dicyclohexylcarbodiimide (DCC) and 1-hydroxybenzotriazole (HOBT) were used as the coupling reagents. The crude peptides were purified by gel filteration on Sephadex LH-20 column $(2 \times 50 cm)$ using MeOH/MeCN (3/1) and then characterized with HPLC, amino acid analyzer.