• Journal of Photoscience
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• v.8 no.1
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• pp.9-12
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• 2001

The photoisomerization behavior of benzylideneacetophenones, known as chalcones, was studied. We synthesized the chalcone derivatives that have ether groups at 4 and 4＇ positions. Due to the electron donating ability of the ether oxygen, the bond order of the single bond between two phenyl ring of the chalcone strengthened, which eventually increased the rotational barrier of the single bond. The rotational barrier of the single bond is about 20-22 kcal/mole. Thermal recovery of this process took about 1 min. The UV-visible spectra of these chromophores exhibit two characteristic absorption peaks at 276 nm and 340 nm. The relative intensity of the peaks varies depending on the alkyl chain length of the substituent. Photo-irradiation with the 365 nm light monotonously decreases the 340 nm peak. However, the photo-irradiation with 254 nm light induce two competing processes and produced rather complicated absorption profile.

• The Journal of Korean Academy of Prosthodontics
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• v.37 no.1
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• pp.42-50
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• 1999

This study investigated the effects of surface treatment for filling resins on the surface texture of denture resin teeth by the use of scanning electron microscope. This study also evaluated the bond strength of filling resins to denture resin teeth. The denture resin teeth in this study was Endura Posterio(Shofu Co., Japan). The ailing resins used were Coe-cure(Coe Co., USA), Vertex RS (Dentimax Ziest, Holland), and light cured resin Z-100(3M Co., USA). The test sample were divided into 3 parts. Group 1 : Sandblasted with $50{\mu}m$ Aluminum oxide. Group 2 : Treated with #60 silicone carbide paper Group 3 : Treated with monomer brush application. Control Group : No Treatment. The results were as follows ; 1. The bond strength of filling resins to denture resin teeth is increased by surface treatment. 2. Regardless of the filling resins, there was a significant difference with # 60 silicone carbide paper treated group. 3. Regardless of each group, the bond strength according to the filling resins were decreased in the following order: Vertex RS, Coe-cure and Z-100.

• Journal of Welding and Joining
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• v.20 no.5
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• pp.120-126
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• 2002

Ni-5%Al alloy powder is widely used as the bond coating powder to improve the adhesive strength between the substrate and coating. The important properties in the bond coating are the deposition efficiency and surface roughness. In this study, it was tried to optimize the plasma spray parameters to maximize the deposition efficiency and surface roughness. In the first step, spray current and hydrogen gas flow rate were optimized in order to increase the deposition efficiency. In the next step, the seven plasma spray variables were selected and optimized to improve both the deposition efficiency and surface roughness using the Taguchi experimental method. By these optimization, the deposition efficiency was improved from about 10 % at the frist time to 51.2 % by the optimization of spray current and hydrogen gas flow rate and finally to 65.2 % by the Taguchi experimental method. The average surface roughness was increased from about $12.9\mu\textrm{m}$ to $15.4\mu\textrm{m}$.

• Bulletin of the Korean Chemical Society
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• v.7 no.5
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• pp.391-395
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• 1986

MNDO calculations were carried out to determine reactant complexes and transition states of the $S_N2$ reactions of $CH_3X\;+\;Y^-\;{\to}\;CH_3Y\;+\;X^-$ where X = F, Cl, CN and Y = CN, OH, F, Cl. The leaving group ability was found to vary inversely with the activation barrier, which in turn was mainly ascribable to the deformation energies accompanied with bond stretching of C-X bond and inversion of $CH_3$ group. The nucleophilicity was shown to be in the order $Cl^->F^->OH^->CN^-$ but the effect on the activation barrier was relatively small compared with that of the leaving group. The bond breaking and bond formation indices and energy decomposition analysis showed that the TS for the reaction of $CH_3$Cl occurs in the early stage of the reaction coordinate relative to that of $CH_3$F. It has been shown that the potential energy surface (PES) diagrams approach can only accommodate thermodynamic effects but fails to correlate intrinsic kinetic effects on the TS structure.

• International Journal of Fuzzy Logic and Intelligent Systems
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• v.6 no.4
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• pp.331-334
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• 2006

Original Support Vsctor Machines (SVMs) by Vapnik were used for binary classification problems. Some researchers have tried to extend original SVM to multiclass classification. However, their studies have only focused on classifying samples into nominal categories. This study proposes a novel multiclass SVM model in order to handle ordinal multiple classes. Our suggested model may use less classifiers but predict more accurately because it utilizes additional hidden information, the order of the classes. To validate our model, we apply it to the real-world bond rating case. In this study, we compare the results of the model to those of statistical and typical machine learning techniques, and another multi class SVM algorithm. The result shows that proposed model may improve classification performance in comparison to other typical multiclass classification algorithms.

• Journal of Dental Rehabilitation and Applied Science
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• v.21 no.1
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• pp.59-67
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• 2005

The bond strength of denture base resin and resin teeth, is an important factor in the long term prognosis of dentures. The purpose of this study is to find an appropriate combination of commercial denture base resin and artificial resin teeth according to shear bond strength. In this study, the shear bond strength of various denture base resins (Vertex $RS^{(R)}$(Dentimax Ziest, Holland), $PERform^{(R)}$(Hedent GmbH., Germany), SR $IVOCAP^{(R)}$(Ivoclar AG, Schaan, Liechtenstein)) and resin teeth (SR Orthosit PE(Ivoclar AG, Schaan, Liechtenstein), $Trubyte^{(R)}$ $Biotone^{(R)}$(Dentsply, U.S.A.)) was evaluated. 1. In comparison of denture resin, the shear bond strength increased in the order of $IVOCAP^{(R)}$, $PERform^{(R)}$, Vertex $RS^{(R)}$. 2. In resin teeth, $Trubyte^{(R)}$ $Biotone^{(R)}$ showed higher strength, but there was no statistical difference between the groups. 3. According to loading direction, the lingual showed higher strength, but there was no statistical difference. 4. When using SR Orthosit PE, SR $IVOCAP^{(R)}$ showed significantly higher shear bond strength(p<0.05). 5. Fracture tendancy showed more cohesive fractures(59) than adhesive failures(13). $IVOCAP^{(R)}$ showed the most superior results statistically. $Trubyte^{(R)}Biotone^{(R)}$ showed the highest shear bond strength. When using the SR Orthosit PE, it is thought that $IVOCAP^{(R)}$ would present the most superior results.

• Journal of the Korea Concrete Institute
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• v.25 no.5
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• pp.573-581
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• 2013

In this paper, an experimental investigation of bond properties between steel fiber reinforced concrete and glass fiber reinforced polymer reinforcements was performed. The experimental variables were diameter of reinforcements, volume fraction of steel fiber, cover thickness and compressive strength of concrete. Bond failure mainly occurred with splitting of concrete cover. Main factor for splitting of concrete is tension force occurred by the displacement difference between reinforcements and concrete. Therefore, in order to prevent the bond failure between reinforcements and concrete, capacity of tensile strength of concrete cover should be upgraded. As a results of test, volume fraction of steel fiber significantly increases the bond strength. Cover thickness changes the failure mode. Diameter of reinforcements also changes the failure mode. Generally, diameter of reinforcement also affects the bond properties but this effect is not significant as volume fraction of fiber. Increase of compressive strength increases the bond strength between concrete and reinforcement because compressive strength of concrete directly affects the tensile strength of concrete.

• Journal of the korean academy of Pediatric Dentistry
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• v.34 no.3
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• pp.420-429
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• 2007

The purpose of this study was to compare the micro ensile bond strength to bovine dentin of several adhesives (SM, Scotch $Bond^{TM}$ Multipurpose; SB, $Adper^{TM}$ Single Bond 2; SE, $Clearfil^{(R)}$ SE Bond; AQ, AQ $Bond^{TM}$; TS, $Clearfil^{(R)}$ tri-S Bond). Except SM and SB, they have a simplified one- or two-step application protocols in compare with the dentin adhesives conventional three-step protocols. For the microtensile bond strength test, the labial surfaces of bovine incisors were used. Following exposure of dentin layer, according to their manufacturer's directions, each dentin adhesives were applied and composite resin blocks were constructed. The teeth were sectioned for specimen and tested microtensile bond strength. Also observed the fracture mode of interface. The obtained results were as follows : 1. The microtensile bond strength values ranged from 51.34 to 24.04 MPa on dentin(in decreasing order, SE, SM, SB, AQ and TS). 2. The highest microtensile bond strength was by SE and SM on bovine dentin, and the lowest by AQ and TS. 3. SM, SB and SE showed cohesive failures and adhesive failure but AQ, TS presented almost adhesive failures. In summary, microtensile bond strengths of single-step adhesives (AQ and TS) on bovine dentin were significantly lower than those of multi-step adhesives (SM, SB and SE) (p<0.05).

• The Journal of Korean Academy of Prosthodontics
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• v.32 no.2
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• pp.212-224
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• 1994

The purpose of this study was to evaluate and compare film thickness of five kinds of resin luting cements [Comspan, Panavia Ex, Maryland bridge adhesive, All-bond C & B cementation kit, and Super-bond C & B]. Zinc-phosphate cement and glass-ionomer cement were used as the control group. In order to measure the film thickness the methods used were in broad compliance with ADA Specification No. 8, a tapered-die system that simulates clinical conditions more closely, and the connected tapered-die system that simulates bridge conditions. The inorganic filler size of resin cements was also examined with scanning electron micrographs. The results were obtained as follows ; 1. The film thickness of resin cements was increased in the order of Comspan, Panavia Ex, Super-bond C & B, Maryland bridge adhesive, and All-bond C & B cementation kit. Maryland bridge adhesive and All-bond C & B cementation kit showed significantly higher film thickness than the control group(p<0.01). 2. For all resin cements, there was a significant difference of film thickness between the ADA method and the tapered-die system. Generally, the tapered-die system demonstrated lower film thickness than the ADA method(p<0.01). 3. There was no significant difference in film thickness between the tapered-die system and the tapered-die bridge system in all resin cements(p<0.01). 4. The scanning electron microscope showed that the cement with larger filler had a tendency to be higher in film thickness.

• Journal of the korean academy of Pediatric Dentistry
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• v.32 no.2
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• pp.191-199
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• 2005

This study was experienced in order to obtain the shear bond strength of orthodontic bracket adhesives under the blood contamination that can be occurred during the procedure of bracket bonding under window opening surgery. As a result of this study, shear bond strength of all glass ionomer groups were lower than resin cement groups. However, the strength of uncontaminated and post-contaminated group of glass ionomer was strong enough to perform an orthodontic forced eruption. This study revealed that during a window opening surgery, glass ionomer without etching procedure is available in order to bond a bracket if surface of teeth is not pre-contaminated by blood before the adhesive application. Both simple procedure and less adhesives remnant after bonding failure could make light-cured glass ionomer cement the ultimate choice for racket bonding.