• Title/Summary/Keyword: Base number

검색결과 2,067건 처리시간 0.033초

Isospecific Propylene Polymerization Behavior of Lewis Base Functionalized Unbridged Zirconocences under Bulk Conditions

  • Yoon, Seung Woong;Kim, Hwa Kyu;Kim, Seong Kyun;Kim, Taewon;Lee, Min Hyung;Do, Youngkyu
    • Bulletin of the Korean Chemical Society
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    • 제35권1호
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    • pp.236-242
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    • 2014
  • Isospecific propylene polymerization behavior of meta- and para-Lewis base (E) functionalized unbridged zirconocenes ($[1-(E_n-Ph)-3,4-Me_2C_5H_2]_2ZrCl_2$, E = $NMe_2$, OMe; n = 1 or 2) was investigated under bulk conditions. Catalytic activity of the zirconocenes, and molecular weight and isotacticity of polypropylenes are found to be dependent on the position and number of the Lewis base functional groups in the zirconocenes. All the crude polypropylenes possess a broad molecular weight distribution and multi-melting transitions, indicating an involvement of multi-catalytic active species in the polymerization. The highest [mmmm] value of an isotactic portion of the polypropylenes reached 89%, which is higher than that (85%) from the well-known $C_2$-symmetric EBIZr (rac-$Et(Ind)_2ZrCl_2$) catalyst. These results support that the in situ generated, rigid rac-like cation-anion pair through the Lewis acid-base interactions between the functional groups of zirconocenes and methylaluminoxane anion is effective in the formation of isotactic polypropylene under bulk propylene polymerization conditions.

Base Isolation System이 있는 건물의 지진하중에 대한 동적해석 (Semismic Analysis of Building Structures with Base Isolation System)

  • 이동근;이정석
    • 전산구조공학
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    • 제3권1호
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    • pp.71-81
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    • 1990
  • Base isolation system은 구조물의 기초하부에 설치되며 지진에 의한 구조물의 피해를 감소시켜 준다. 지금까지 많은 공학들에 의해 여러가지 base isolation system이 개발되었으나 실용화된 것은 1970년대에 laminated rubber bearing(LR type)이 개발되고서부터 였다. 최근에는 laminated rubber bearing밑에 미끄럼판을 둔 새로운 base isolation system(SR type)이 개발되었다. 본 연구에서는 isolation system과 구조물의 여러가지 성질에 따른 isolation효과에 대한 연구를 수행하였다. 이 연구의 결과, isolaion system은 지진하중이 작용할 때 건물에 발생하는 피해를 상당히 감소시킴을 알 수 있으며, isolaion system의 주기가 길어짐에 따라 isolation효과는 증가함을 알 수 있다. 그리고 건물의 높이가 증가함에 따라 isolation효과는 줄어든다는 것을 알 수 있다. SR type isolation system이 있는 건물에 지진하중이 작용할 때, 건물내부에서 발생하는 가속도와 층간변위, 그리고 전체변위는 LR type의 경우보다 작으므로 보다 효율적이라는 것을 알 수 있다.

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피복전선의 내부 열화 검출용 센서 개발 (The Development of Diagnostic Sensor for Inner Deterioration of Covered Electric Wire)

  • 김기준
    • 한국전기전자재료학회논문지
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    • 제27권4호
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    • pp.244-249
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    • 2014
  • In this research, it have developed a sensor that could diagnose inner deterioration of covered wires. With this sensor it observed results from simulation, and the attribute required for realization. For simulation it have used FLUX, it have considered all of geometric and electromagnetic information from coil and base metal that influences eddy current sensor's property in order to predict the final result. It assumed there is no mutual inductance in the coil with N number of turns, because equivalent current flows in coil that is continuously connected in eddy current sensor. It assumed circular coil loop draws a circle, always have self inductance, and they are connected in series and overlapped according number of turns (N) in coil, and bobbin configuration. Actual sensor was produced with consideration of inductance and number of turns (N). In conclusion, it were able to test the dependency through results from simulation, actual measurement, and modeling of simulation. It is considered that attributes of respective base metal and structure can be predicted by simulating in advance.

TDMA/TDD 기반 무선 ATM망에서 버스트 트래픽을 위한 접속 제어 프로토콜 (Access Control Protocol for Bursty Traffic in TDMA/TDD-based Wireless ATM Networks)

  • 임인택
    • 한국정보통신학회논문지
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    • 제7권4호
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    • pp.684-690
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    • 2003
  • 본 논문에서는 무선 ATM망에서 비실시간성의 버스트 트래픽을 서비스하기 위한 경쟁기반 예약형 접속 제어 알고리즘과 슬롯 할당 알고리즘을 제안하였다. 제안한 기법에서는 예약요청 패킷의 충돌을 줄이기 위하여 예약요청 패킷 전송을 위한 RAS 미니슬롯의 수와 예약요청 부하를 기반으로 기지국이 전송 확률을 계산하고, 이를 하향 제어채널을 통하여 단말기들에게 방송한다. 전송할 트래픽 버스트가 있는 단말기들은 임의의 RAS 미니슬롯을 선택하여 기지국으로부터 수신한 전송 확률로 단말기 버퍼에 있는 패킷 수를 포함하는 예약요청 패킷을 전송한다. 한편, 슬롯 할당은 성공적으로 수신한 단말기의 버퍼 상태정보를 기반으로 한다. 기지국에서는 단말기들이 요청한 총 슬롯 수에 비례하여 슬롯을 할당한다.

Convective heat transfer of MWCNT / HT-B Oil nanofluid inside micro-fin helical tubes under uniform wall temperature condition

  • Kazemia, M.H.;Akhavan-Behabadi, M.A.;Nasr, M.
    • Advances in nano research
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    • 제2권2호
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    • pp.99-109
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    • 2014
  • Experiments are performed to investigate the single-phase flow heat transfer augmentation of MWCNT/HT-B Oil in both smooth and micro-fin helical tubes with constant wall temperature. The tests in laminar regime were carried out in helical tubes with three curvature ratios of 2R/d=22.1, 26.3 and 30.4. Flow Reynolds number varied from 170 to 1800 resulting in laminar flow regime. The effect of some parameters such as the nanoparticles concentration, the dimensionless curvature radius (2R/d) and the Reynolds number on heat transfer was investigated for the laminar flow regime. The weight fraction of nanoparticles in base fluid was less than 0.4%. Within the applied range of Reynolds number, results indicated that for smooth helical tube the addition of nanoparticles to the base fluid enhanced heat transfer remarkably. However, compared to the smooth helical tube, the average heat transfer augmentation ratio for finned tube was small and about 17%. Also, by increasing the weight fraction of nanoparticles in micro-fin helical tubes, no substantial changes were observed in the rate of heat transfer enhancement.

회주철 판형 주조품의 공정 셀 수와 칠 깊이에 미치는 두께, 기본 원소 및 접종제의 영향 (Effects of Thickness, Base Element and Inoculants on the Number of Eutectic Cells and Chill Depth of Gray Cast Iron Plate Casting)

  • 김태형;오정혁;권해욱
    • 한국주조공학회지
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    • 제31권3호
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    • pp.137-144
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    • 2011
  • The effects of thickness, base element and inoculants on the number of eutectic cells and chill depth of gray cast iron plate casting were investigated. Meanwhile the number of eutectic cells increased by inoculation, chill depth decreased. The former decreased and the latter increased by holding the melt at the temperature range between 1,450 and $1,500^{\circ}C$. The former was more for the thinner casting with the thickness of 5 mm than the other. The result of thermal analysis coincided well with the change of macrostructure. The former increased and the latter decreased with the increased contents of carbon, silicon and the silicon content by inoculation. The former decreased and the latter increased with increased manganese content. The performance of the Superseed Extra was the best among 5 inoculants.

치과용 Co-Cr 합금의 제성질에 미치는 Boron과 Silicon의 영향 (Effect Boron and Silicon on Various Properties of Dental Cobalt-Chromium Alloys)

  • 정종현
    • 대한치과기공학회지
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    • 제14권1호
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    • pp.119-132
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    • 1992
  • This paper aims to investigate the effect of B and Si upon the mechanical properties, microstructure and corrosion resistance of Co-Cr base alloy. Ten groups of alloy ingot ingot with various contents of B and Si were remelted by high frequency electrical induction furnace and cast into tensile specimen of ADA Specification No. 14 Tensile and hardness test were carried out by Amsler and Rockwell hardness tester(R-30N), respectively. The microstructures of specimen were observed by SEM. The results obtained are summarized as follows : 1. As B content is increased, tensile strength, yield strength and Rockwell hardness number(R-30N) are also increased significantly, while the elongation is decreased significantly. 2. As Si contect os increased, no significant chang in tensile strength is noticed, yield strength is slightly decreased, but Rockwell hardness number(R-30N) is moderately in creased, Elongation marks maxium value with 1% Si content while with more than 1% Si it is decreased. 3. As B content is increased corrosion resistance is decreased and is at best with 1.5% B content. Corrosion resistance is increased with the increase of Si content and the alloys with Si over 3.0% showed corrosion resistance. 4. As B content increased, precipitates are increased in number at grain boundaries. The grain size tends to become coarse with the increase of Si content. 5. Co rich-Cr alloy is present through matrix whereas at the grain boundaries Cr base precipitates are primarily formed.

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매크로셀과 마이크로셀이 중첩된 W-CDMA 무선가입자망에서 마이크로셀의 용량 산정 (Capacity esitmation of microcell in macro/microcell overlaid W-CDMA WLL system)

  • 손성찬;노재성;김수용;조성준
    • 한국통신학회논문지
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    • 제23권9A호
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    • pp.2153-2164
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    • 1998
  • This paper has presented the parameters for the coexistence between two systems in macro/microcell ovelaid W-CDMA WLL (wideband CDMA wireless local loop) and has calculated the capacity of forward/reverse link in microcell. To produce the capacity for analyzing system interference effects, we have shown tables and graphs with the parameters sucyh as RF channel bandwidth of WLL(W), the transmission rate of service message(R), the required signal power to noise power ratio( $E_{b/}$ $N_{0}$) for achieving accepatable error rate, te user number ( $N_{W1}$, $N_{W2}$) of the neighboring system, the signal power to interference power ratio(.GAMMA.$_{C1B}$, .GAMMA.$_{C2B}$) of the neighboring system, the normalized distance(d) between microcell and macrocell base-station, and microcell to macrocell radius ratio ( $R_{d}$). From the results, we have convinced that the capacity of microcell diminishes as increasing the user number ( $N_{W2}$) in macrocell, increasing the microcell radius, and decreasing the normalized distance(d) between microcell and macrocell base-station. Especially, we have known that when $R_{d}$=0.1, $N_{W2}$ must be below 24 at .GAMMA.$_{C2B}$ = 0 dB and below 8 at .GAMMA.$_{C2B}$ = 4 dB for the acceptable capacity raito to be over 80%. Therfore, this paper is usefult to design microcell W-CDMA WLL for accommodating more user number under the interference effects of macrocell W-CDMA WLL and is expected to be reference in power control if base-station.ation.ion.ation.ation.

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BD 빔포밍을 이용한 다중 사용자 기반 거대 안테나 통신 시스템용 안테나 선택 기법 (Antenna Selection Scheme for BD Beamforming-based Multiuser Massive MIMO Communication Systems)

  • 반태원;정방철;박연식
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2013년도 춘계학술대회
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    • pp.433-436
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    • 2013
  • 많은 수의 안테나를 활용하는 Massive MIMO 통신 기술은 부족한 주파수 자원의 효율성을 높이기 위한 핵심기술들 중의 하나로 많은 관심을 끌고 있다. 기존에는 이동통신 시스템의 하향링크에서 단일 사용자 기반의 Massive MIMO 기술에 대하여 많은 연구가 이루어 졌으나, 최근에는 단말 안테나 수의 제한으로 인해 다중 사용자 기반 Massive MIMO에 대한 활발한 연구가 이루어진다. 이렇게 많은 송신 안테나를 사용하는 Massive MIMO 기술은 기지국의 기저대역 (Baseband)과 Radio Frequency와 같은 전송단의 하드웨어 복잡도와 빔포밍 벡터 계산량이 급격히 증가시키는 문제를 야기한다. 이러한 문제점은 기지국에서 전송단의 개수를 송신 안테나 수보다 작게 제한하고, 전체 송신 안테나들 중에서 채널 상태를 고려하여 전송단의 개수에 해당하는 안테나만을 선택하여 데이터를 전송함으로써 큰 성능 저하 없이 해결될 수 있다. 따라서, 본 논문에서는 다중 사용자 기반의 Massive MIMO 시스템에 적용할 수 있는 간단하고 효율적인 안테나 선택 기법을 제안한다. 성능 분석 결과에 따르면, 제안된 방식은 안테나 선택 기법 없이 동일한 수의 안테나를 고정적으로 사용하는 기존 시스템 대비 큰 폭의 성능개선 효과를 나타내었다.

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교과교실제 운영에 따른 공간구성 변화에 대한 현황분석 - 리모델링된 10개 고등학교의 사례 - (A Case Study on The Changes in Space Composition According to Departmental System - Through the 10 Remodeling Cases of High School -)

  • 이동욱;류호섭
    • 교육시설 논문지
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    • 제19권1호
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    • pp.13-24
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    • 2012
  • Recently, many middle and high schools are remodeling the buildings and facilities based on departmental system. This study, through analyzing on 10 remodeling cases of high school, is showing the variation before and after remodeling, space organization types, and the types of school management. This also gives us the information on the number of classrooms and teachers' rooms for each subject, the area and number of home base, and the current state of all these facilities. Furthermore, this study is comparing and analyzing the rate of use of specialized classrooms to the type of management. Through this analysis, we reach the following conclusions. l. However all the cases remodeled their buildings to implement departmental system, the methods of space composition, the numbers of the classrooms, and the status of home base are in various forms. 2. Taken as a whole, there are only few spaces used by departmental system. 3. The spaces for practical subjects such as Science and Art are inadequate than the ones for major subjects such as Languages and Mathematics. 4. A system to assign a room for a teacher records the lowest space usage rate. 5. The area of home base per one student is only $0.48m^2$, and even the area is mostly filled with lockers. The present condition of the 10 high schools which we surveyed shortly after remodeled shows that departmental system is not firmly settled down yet.