• Title/Summary/Keyword: All Solid State.

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Synthesis and Optical Properties of BaSiO3:RE3+ (RE = Sm, Eu) Phosphors (BaSiO3:RE3+ (RE = Sm, Eu) 형광체의 합성과 광학 특성)

  • Cho, Shinho
    • Korean Journal of Materials Research
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    • v.29 no.6
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    • pp.356-362
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    • 2019
  • $BaSiO_3:RE^{3+}$ (RE = Sm or Eu) phosphor powders with different concentrations of activator ions are synthesized using the solid-state reaction method. The effects of the concentration of activator ions on the structural, photoluminescent, and morphological properties of the barium silicate phosphors are investigated. X-ray diffraction data reveals that the crystal structure of all the phosphors, regardless of the type and the concentration of the activator ions, is an orthorhombic system with a main (111) diffraction peak. The grain particles agglomerate together to form larger clusters with increasing concentrations of activator ions. The emission spectra of the $Sm^{3+}$-doped $BaSiO_3$ phosphors under excitation at 406 nm consist of an intense orange band at 604 nm and three weak bands centered at 567, 651, and 711 nm, respectively. As the concentration of $Sm^{3+}$ increases from 1 to 5 mol%, the intensities of all the emission bands gradually increase, reach maxima at 5 mol% of $Sm^{3+}$ ions, and then decrease significantly with further increases in the $Sm^{3+}$ concentration due to the concentration quenching phenomenon. For the $Eu^{3+}$-doped $BaSiO_3$ phosphors, a strong red emission band at 621 nm and several weak bands are observed. The optimal orange and red light emissions of the $BaSiO_3$ phosphors are obtained when the concentrations of $Sm^{3+}$ and $Eu^{3+}$ ions are 5 mol% and 15 mol%, respectively.

Effect of Calcination Temperature on Ionic Conductivity of All-solid State Battery Electrolytes (하소 온도가 전고체 전지 전해질의 이온전도도에 미치는 영향)

  • Yu Taek Hong;Ji Min Im;Ki Sang Baek;Chan Gyu Kim;Seung Wook Baek;Jung Hyun Kim
    • New & Renewable Energy
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    • v.20 no.2
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    • pp.71-81
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    • 2024
  • In this study, the electrochemical properties of garnet-structured all-solid-state battery electrolytes (Li6.4La3Zr1.4Ta0.6O12, hereafter LLZTO) were assessed by altering the calcination temperature, while maintaining a consistent sintering duration. Among the various heat treatment conditions employed for sample fabrication, the '700_1100' condition, denoting a calcination temperature of 700℃ and a sintering temperature of 1100℃, resulted in the most exceptional ionic conductivity of 4.89 × 10-4 S/cm and a relative density of 88.72% for the LLZTO material. This is attributed to the low calcination temperature of 700℃, leading to reduced grain size and enhanced cohesiveness, thus resulting in a higher sintered density. In addition, a microstructure similar to the typical sintering characteristics observed in Spark Plasma Sintering (SPS) methods was identified in the SEM analysis results under the '700_1100' condition. Consequently, the '700_1100' heat treatment condition was deemed to optimal choice for enhancing ionic conductivity.

Recent Progress and Perspectives of Solid Electrolytes for Lithium Rechargeable Batteries (리튬이차전지용 고체 전해질의 최근 진전과 전망)

  • Kim, Jumi;Oh, Jimin;Kim, Ju Young;Lee, Young-Gi;Kim, Kwang Man
    • Journal of the Korean Electrochemical Society
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    • v.22 no.3
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    • pp.87-103
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    • 2019
  • Nonaqueous organic electrolyte solution in commercially available lithium-ion batteries, due to its flammability, corrosiveness, high volatility, and thermal instability, is demanding to be substituted by safer solid electrolyte with higher cycle stability, which will be utilized effectively in large-scale power sources such as electric vehicles and energy storage system. Of various types of solid electrolytes, composite solid electrolytes with polymer matrix and active inorganic fillers are now most promising in achieving higher ionic conductivity and excellent interface contact. In this review, some kinds and brief history of solid electrolyte are at first introduced and consequent explanations of polymer solid electrolytes and inorganic solid electrolytes (including active and inactive fillers) are comprehensively carried out. Composite solid electrolytes including these polymer and inorganic materials are also described with their electrochemical properties in terms of filler shapes, such as particle (0D), fiber (1D), plane (2D), and solid body (3D). In particular, in all-solid-state lithium batteries using lithium metal anode, the interface characteristics are discussed in terms of cathode-electrolyte interface, anode-electrolyte interface, and interparticle interface. Finally, current requisites and future perspectives for the composite solid electrolytes are suggested by help of some decent reviews recently reported.

Effects of Grooved Surface with Nano-ridges on Silicon Substrate on Anisotropic Wettability (실리콘 기판 위에 제작된 나노 크기의 구조물을 가진 그루브 표면이 이방성 젖음에 미치는 영향)

  • Lee, Dong-Ki;Cho, Younghak
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.3_1spc
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    • pp.544-550
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    • 2013
  • A grooved surface with anisotropic wettability was fabricated on a silicon substrate using photolithography, reactive ion etching, and a KOH etching process. The contact angles (CAs) of water droplets were measured and compared with the theoretical values in the Cassie state and Wenzel state. The experimental results showed that the contact area between a water droplet and a solid surface was important to determine the wettability of the water. The specimens with native oxide layers presented CAs ranging from $71.6^{\circ}$ to $86.4^{\circ}$. The droplets on the specimens with a native oxide layer could be in the Cassie state because they had relatively smooth surfaces. However, the CAs of the specimens with thick oxide layers ranged from $33.4^{\circ}$ to $59.1^{\circ}$. This indicated that the surface roughness for a specimen with a relatively thick oxide layer was higher, and the water droplet was in the Wenzel state. From the CA measurement results, it was observed that the wetting on the grooved surface was anisotropic for all of the specimens.

Individual Charge Equalization Converter with Parallel Primary Winding of Transformer for Series Connected Lithium-Ion Battery Strings in an HEV

  • Kim, Chol-Ho;Park, Hong-Sun;Kim, Chong-Eun;Moon, Gun-Woo;Lee, Joong-Hui
    • Journal of Power Electronics
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    • v.9 no.3
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    • pp.472-480
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    • 2009
  • In this paper, a charge equalization converter with parallel-connected primary windings of transformers is proposed. The proposed work effectively balances the voltage among Lithium-Ion battery cells despite each battery cell has low voltage gap compared with its state of charge (SOC). The principle of the proposed work is that the equalizing energy from all battery strings moves to the lowest voltage battery through the isolated dc/dc converter controlled by the corresponding solid state relay switch. For this research a prototype of four Lithium-Ion battery cells is optimally designed and implemented, and experimental results show that the proposed method has excellent cell balancing performance.

Synthesis and Superconductivity in $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ System ($(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$ 계의 합성 및 초전도 특성)

  • Lee, H.K.;Bae, S.M.
    • Progress in Superconductivity
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    • v.10 no.2
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    • pp.128-132
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    • 2009
  • Polycrystalline samples of $(Ru_{0.8}Nb_{0.2})Sr_2(Gd_{1.5-x}Nd_xCe_{0.5})Cu_2O_z$($ 0{\leq}x{\leq}1.25$) have been synthesized by a solid-state reaction route. The X-ray diffraction data revealed that the Nd solubility limit can be placed between x=0.5 and x=0.75. The superconducting transition temperature decreased with increasing Nd content, confirming that Nd entered the lattice. Room-temperature thermoelectric power measurements showed that all the samples are in the underdoped state and the partial substitution of Nd for Gd resulted in a decrease in the carrier density on the superconducting layers.

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PEOPLE-한국광학회 회장 이종민

  • Korea Association for Photonics Industry Development
    • Photonics industry news
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    • s.2
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    • pp.30-31
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    • 2001
  • 20여년 동안 지속해 온 레이저 개발 및 레이저분공기술 분야에 대한 연구를 지속적으로 추진하고 있는 이종민 한국광학회 회장. 이 회장은 최근 주된 관심사는 고출력 DPSSL (Diode-laser Pumped Sclid-state Laser)레이저, 원적외선 자유전자레이저, 그리고 레이저의 원자력 응용에 관한 연구들이라 말한다. 특히 이 분야들은 이미 5년 전부터 착수된 연구들로서 특히 레이저의 고출력화 및 전고체화 (all-solid-state)에 집중적인 노력을 아끼지 않는다고 또한 그는 인터넷 홈페이지를 통해서 산업 현장의 어려운 목소리를 듣고 직접 해당 전문가의 자문을 받을 수 있는 창구를 개설할 계획이다. 이를 통해 광기술관련 자료의 데이터베이스를 정립하고 지식정보 교환의 장을 구축하여 기초 학문의 실용화를 앞당기며, 기술인력의 정보교환도 자연스럽게 이루워지도록 할 것이며 이러한 사업이 성공적으로 이루어지면 학회와 산업계 모두에게 보람있는 일이 될 것이라고 밝혔다.

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Plasma, the First State of the Universe (우주 최초의 물질상태 - 플라즈마)

  • Lee, Hae June
    • Vacuum Magazine
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    • v.1 no.2
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    • pp.4-8
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    • 2014
  • On this earth, we usually encounter three states of matter: solid, liquid, and gas. Those are the states we experience directly and most often in everyday life. However, if we consider the whole universe, more than 99.99 percent of our visible universe is in plasma state. The earth is in very unusual situation in the universe, and it is great virtue to whole creatures on this planet. In the beginning of the universe, however, there was only plasma. The other stuff came later after then. The Big Bang, beginning of our universe, was dominated by high-temperature plasma. It is where we all came from, and it continues to play a major role not only in our universe but also in various industrial applications of human being.

Buckling and bending analyses of a sandwich beam based on nonlocal stress-strain elasticity theory with porous core and functionally graded facesheets

  • Mehdi, Mohammadimehr
    • Advances in materials Research
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    • v.11 no.4
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    • pp.279-298
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    • 2022
  • In this paper, the important novelty and the defining a physical phenomenon of the resent research is the development of nonlocal stress and strain parameters on the porous sandwich beam with functionally graded materials in the top and bottom face sheets.Also, various beam models including Euler-Bernoulli, Reddy and the generalized formulation of two-variable beam theories are obtained in this research. According to a nonlocal strain elasticity theory, the strain at a reference point in the body is dependent not only on the stress state at that point, but also on the stress state at all of the points throughout the body. Thus, the nonlocal stress-strain elasticity theory is defined that can be actual at micro/nano scales. It can be seen that the critical buckling load and transverse deflection of sandwich beam by considering both nonlocal stress-strain parameters is higher than the nonlocal stress parameter. On the other hands, it is noted that by considering the nonlocal stress-strain parameters simultaneously becomes the actual case.

An Investigation into the State of Doctors' Linkage and Oriental Medical Treatment at All Postpartum Care Center in Seoul (서울시 소재 산후조리원의 의료인 연계 및 한방의료 현황 조사)

  • Jang, Suk-Woo;Heo, Su-Jeong;Cho, Hyun-Ju
    • The Journal of Korean Obstetrics and Gynecology
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    • v.24 no.4
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    • pp.174-185
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    • 2011
  • Objectives: The purpose of this study is to investigate all postpartum care center in Seoul about its state of doctors' linkage and oriental medical treatment. Methods: From May 1st 2011 to July 10th 2011, survey was done using a selfmade questionnaire by phone or visit. There were 12 categories including the state of doctors' linkage in postpartum care centers, treatment form of oriental medical doctors, utilization of herbal medicine and so on. The data collected was analyzed using Excel 2007 FOR WINDOWS. Results: 1. The doctors' linkage with postpartum centers included pediatricians(96.1%), oriental medicine doctors(61.2%), and gynecologists(34.0%). Of those postpartum centers, 66% had both pediatrician and oriental medical doctor which were the vast majority. 2. Out of 70 postpartum centers providing herbal medicine, 9 of them were supplied of herbal medicine by herb sellers(not doctor). Where as, at 63 oriental medical doctors-affiliated centers, 85.7% of them had oriental medical doctors' examinations. 3. Out of 70 postpartum centers providing herbal medicine, personalized prescription amounted to 35(50.0%), same prescriptions amounted to 34(48.6%), and 1(1.4%) refused to answer. 4. Out of all the patients that received explanation about the effects of herbal medicine, 62.9% had them explained by oriental medical doctors. Conclusions: These findings suggests that oriental medical doctors are actively involved with postpartum care centers but problems surfaced regarding individualized prescription insufficiency and the lack of administration. In the near future, if the expertise expand in the areas of pediatrics as well as obstetrics and gynecology, oriental medicine will have a more solid role in postpartum care part.