• Title/Summary/Keyword: Alkali Activated Cement

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Durability of Alkali-Activated Blast Furnace Slag Concrete: Chloride Ions Diffusion (알칼리 활성 슬래그 콘크리트의 내구성: 콘크리트의 염소이온 확산)

  • Nam, Hong Ki;Kyu, Park Jae;San, Jung Kyu;Hun, Han Sang;Hyun, Kim Jae
    • Journal of the Korean Society of Safety
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    • v.30 no.4
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    • pp.120-127
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    • 2015
  • The aim of the present study is to investigate some characteristics of concrete according to addition of blast furnace slag and alkali-activator dosages. Blast furnace slag was used at 30%, 50% replacement by weight of cement, and liquid sulfur having NaOH additives was chosen as the alkaline activator. In order to evaluate characteristics of blast furnace slag concrete with sulfur alkali activators, compressive strength test, total porosity, chloride ions diffusion coefficient test were performed. The early-compressive strength characteristics of blast furnace slag concrete using a sulufr-alkali activators was compared with those of reference concrete and added 30, 50% blast furnace slag concrete. Also, Blast furnace slag concrete using sulfur-alkali activators enhanced the total porosity, chloride ions diffusion coefficient than two standard concrete. Alkali-activated blast furnace slag concrete was related to total porosity, compressive strength and chloride ions diffusion coefficient each others. As a result, it should be noted that the sulfur-alkali activators can not only solve the demerit of blast furnace slag concrete but also offer the chloride resistance of blast furnace slag concrete using sulfur alkali activators to normal concrete.

Effects of NaOH and Na2SiO3·9H2O Addition on Strength Development of Class F Fly Ash-Mortar (F급 플라이 애쉬-모르타르의 강도발현에 대한 NaOH과 Na2SiO3·9H2O 첨가의 영향)

  • Park, Sang-Sook;Kang, Hwa-Young;Han, Sang-Ho;Kang, Hee-Bog
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.4
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    • pp.261-269
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    • 2005
  • The object of this research is to produce alkali activated fly ash-cement using low calcium fly ash as substitute for portland cement. The experimental program included activation of fly ash by a strong base(NaOH) at different concentration, temperature, and liquid-to-fly ash ratios. To achieve for higher compressive strength of the hardened product, sodium meta silicate is added to the alkaline solution. From the factors considered on strength development, the ratio of liquid/fly ash, the activator concentration and temperature always result to be significative factors. The optimization studied show that the alkaline solution concentration of $NaOH(210g)+Na_2SiO_3{\cdot}9H_2O(30g)+H_2O=1L$ at $50^{\circ}C$ produces the best alkali activation effect for the low calcium fly ash. SEM and XRD patterns showed that the components of alkali-activated fly ash consist mainly of mullite, quartz and amorphous aluminosilicate.

Study on the Fire Resistance of Light Weight Inorganic Polymer Concrete Panel Wall (Inorganic Polymer Concrete를 이용한 경량패널의 내화특성에 관한 실험적 연구)

  • Hwang, Ji-Soon;Kim, Woo-Jae;Kim, Dae-Hoi;Park, Dong-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.205-206
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    • 2011
  • Inorganic Polymer Concrete, a type of Alkali activated cement and concrete, is known for various excellent performances, especially for better performance in the area of high temperature heat resistance(thermal characteristic) than portland cement concrete.In this study, light weight concrete panel was manufactured using this Inorganic Polymer Concrete and then evaluated for fire resistance with a small-scale heating furnace. Since the result showed excellent fire resistance, it is considered usable for manufacturing fire resistant concrete panel wall.

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The Experimental Study on Hardening Characteristics of Bottom ash by Alkali Activation (알칼리 활성법에 의한 Bottom Ash의 경화 특성에 관한 실험적 연구)

  • Oh, Dong-Uk;Kim, Baek-Joong;Yi, Chong-Ku;Kang, Kyung-In
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.103-106
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    • 2008
  • Because the physical·chemical properties of bottom ash are inferior, most bottom ash is disused. But the use of bottom ash helps in reducing environmental pollution and solving some bottom ash waste problems. So, we have been investigating about the optimum mixture, hardening mechanism, curing condition and environmental safety of a paste composed of a bottom ash and alkali. optimal mixing proportion of bottom ash solid was cement 5%, water 30%, NaOH 10%. After curing during 28days, bottom ash solid can be achieved compressive strength 15.13MPa. As a result, Compressive strength tests of alkali-activated bottom ash have potential as a replacement of coarse aggregate.

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Green Technology in Concrete Industry : Geopolymer Concrete

  • Nguyen, Khoa Tan;Le, Tuan Anh;Ahn, Namshik
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.115-116
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    • 2011
  • TNowadays, the global warming is the most serious problem in the world and the cement industry is one of the factors which are responsible for it. Therefore, the development of new binders with enhanced environment and durability performance is needed. In this regard, the geopolymer technology is one of the breakthrough developments as an alternative to the portland cement. This paper shows some points of view on the development of geopolymers by reviewing previous researches including historical background, constituents of geopolymers, process of geopolymerization and several applications of geopolymer. Hence, the author proposes two research trends which are finding the best combination between the source materials and alkali liquid then, evaluating the corrosion for the metal bars.

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Effect of Unit Binder Content on the Slump and Compressive Strength of Alkali-Activated Slag Concrete (알칼리활성 슬래그 콘크리트의 슬럼프 및 압축강도에 대한 단위결합재량의 영향)

  • Cho, A-Ram;Yang, Keun-Hyeok;Song, Jin-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.361-362
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    • 2010
  • Six alkali-activated(AA) concrete mixes were tested to ascertain the effect of unit binder content on the slump and compressive strength of concrete. Test results showed that the compressive strength of AA-concrete increased with the increase of the unit binder content, while the increasing rate was lower that recorded in ordinary portland cement concrete.

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Strength behaviour and hardening mechanism of alkali activated fly ash Mortars (알카리 활성화에 의한 fly ash 경화체의 강도 발현 메카니즘에 관한 연구)

  • Jo Byung Wan;Moon Rin Gon;Park Seung Kook;Lim Sang Hun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.321-324
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    • 2004
  • The discharge of fly ash that is produced by coal-fired electric power plants is rapidly increasing in Korea. The utilization of fly ash in the raw materials would contribute to the elimination of an environmental problem and to the development of new high-performance materials. So it is needed to study the binder obtained by chemically activation of pozzolanic materials by means of a substitute for the exiting cement. This paper concentrated on the strength development according to the kind of chemical activators, the curing temperature, the heat curing time. Also Scanning electron microscopy and X-Ray diffraction analysis show what the reaction products of the alkali activated fly ash are.

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The Fundamental Properties of Alkali-Activated Slag Cement (AASC) Mortar with Different Water-Binder Ratios and Fine Aggregate-Binder Ratios (물-결합재 비와 잔골재-결합재 비에 따른 알칼리 활성화 슬래그 모르타르의 기초특성)

  • Kim, Tae-Wan;Hahm, Hyung-Gil;Lee, Seong-Haeng;Eom, Jang-Sub
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.5
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    • pp.77-86
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    • 2013
  • This study investigates the fundamental properties of the water-binder (W/B) ratio and fine aggregate-binder (F/B) ratio in the alkali-activated slag cement (AASC) mortar. The W/B ratios are 0.35, 0.40, 0.45, and 0.50, respectively. And then the F/B ratios varied between 1.00 and 3.00 at a constant increment of 0.25. The alkali activator was an 2M and 4M NaOH. The measured mechanical properties were compared, flow, compressive strength, absorption, ultra sonic velocity, and dry shrinkage. The flow, compressive strength, absorption, ultra sonic velocity and dry shrinkage decreased with increases W/B ratio. The compressive strength decreases with increase F/B ratio at same W/B ratio. Also, at certain value of F/B ratio significant increase in strength is observed. And S2 (river sand 2) had lower physical properties than S1 (river sand 1) due to the fineness modulus. The results of experiments indicated that the mechanical properties of AASC depended on the W/B ratio and F/B ratio. The optimum range for W/B ratios and F/B ratios of AASC is suggested that the F/B ratios by 1.75~2.50 at each W/B ratios. Moreover, the W/(B+F) ratios between 0.13 and 0.14 had a beneficial effect on the design of AASC mortar.

The Strength Characteristics of Activated Multi-Component Cement with Kaolinite (카올린을 혼합한 활성화된 다성분계 시멘트의 강도 특성)

  • Kim, Tae-Wan;Kim, Im-Gon
    • Journal of the Korea Concrete Institute
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    • v.28 no.5
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    • pp.593-600
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    • 2016
  • The paper presented investigates the effects of kaolinite on strength properties of alkali-activated multi-component cement. The binders of this study was blended of ground granulated blast furnace slag (GGBFS), fly ash (FA), silica fume (SF) and kaolinite (KA). In this study, the specimens of combination of 20%~70% GGBFS, 10%~60% FA, 10% SF (constant ratio) and 10%~50% KA binder were used for strength properties tests. The water/binder ratio was 0.5. The binders (GGBFS + FA + SF + KA) was activated by sodium hydroxide (NaOH) and sodium silicate ($Na_2SiO_3$) was 10% by total binder weight (10% NaOH + 10% $Na_2SiO_3$). The research carried out is on the compressive strength, water absorption, ultrasonic pulse velocity (UPV) and X-ray diffraction (XRD). The compressive strength decreased as the contents of KA increase. One of the major reason for this is the low reactivity of KA compared with other raw materials used as precursors such as GGBFS or FA. The presence of remaining KA indicates that the initially used quantity has not fully reacted during hydration. Moreover, the results have indicated that increased of KA contents decreased UPV under all experimental conditions. The drying shrinkage and water absorption increased as the content of KA increase. Test result clearly showed that the strength development of multi-component blended cement were significantly dependent on the content of KA and GGBFS.