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A Study on Mossbauer Spectrum of the $NiAl_0.8Fe_1.2O_4$ ($NiAl_0.8Fe_1.2O_4$의 Mossbauer' Spectrum연구)

  • Lee, Cheol-Sae
    • The Journal of Natural Sciences
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    • v.7
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    • pp.19-25
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    • 1995
  • In this study, the Mossbauer effect of the $NiAl_0.8Fe_1.2O_4$ was investigated in the temperature range of 77K-1000K. The spectra were composed of two component, one is sixtet and the other doublet, at low temperature. From the temperature dependence of Mossbauer spectum, it is appeared that the magnetic properties of $NiAl_0.8Fe_1.2O_4$ varies from ferrimagnetism to paramagnetism as the increasing tempereture. And the magnetic relaxation patterns of the $NiAl_0.8Fe_1.2O_4$ were shown superparamagnetic effect.

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$Al/Al_2O_3/Si$(100) Solar Cell 제작 및 특성 평가

  • Min, Gwan-Hong;Yu, Jeong-Jae;Yeon, Je-Min;;Jeong, Sang-Hyeon;Kim, Gwang-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.313.2-313.2
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    • 2013
  • 본 연구에서는 기존에 연구된 Solar Cell 보다 구조 및 제작이 단순한 $Al/Al_2O_3/Si$(100) Solar cell을 제작하여 평가하였다. 기판으로는 p-type Si(100), 0.5~2 ${\Omega}{\cdot}cm$을 사용하여 chemical cleaning 후 ALD(Atom Layer Deposition)법으로 Al2O3 터널링 절연막을 증착하였으며, 박막의 두께를 1~10 nm로 변화시켜 MIS 커패시터의 터널링 효과를 평가하였다. MIS 커패시터의 전기적 특성평가를 위해 누설전류 밀도-전계 특성은 pA meter/DC Voltage source를 사용하였고, 커패시턴스-전압특성, D-factor 특성은 precision LCR meter를 사용하였다. $Al/Al_2O_3/Si$(100) Solar cell의 특성평가를 위해 300~1100nm 파장영역에 따른 양자 효율을 평가하기 위해 Quantum Efficiency system (QE)을 사용하였고, Stanard Test Conditions 100 $mW/cm^2$, AM1.5, $25^{\circ}C$ 조건의 Voc, Isc, Jsc, FF (Fill Factor) 및 Efficiency(%)를 평가하기 위해 Solar simulator를 이용하였다.

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A Study on the Potassium Gettering in Al-1%Si/SiO2/PSG Multilevel Thin Films (Al-1%Si/SiO2/PSG 적층 박막에서 potassium 게터링에 관한 연구)

  • Kim, Jin Young
    • Journal of Surface Science and Engineering
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    • v.48 no.5
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    • pp.233-237
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    • 2015
  • In order to investigate the potassium (K) gettering, Al-1%Si/$SiO_2$/PSG multilevel thin films were fabricated. Al-1%Si thin films and $SiO_2$/PSG passivations were deposited by using DC magnetron sputter techniques and APCVD (atmosphere pressure chemical vapor deposition), respectively. Heat treatment was carried out at $300^{\circ}C$ for 5 h in air. SIMS (secondary ion mass spectrometry) depth profiling analysis was used to determine the distribution of K, Al, Si, P, and other elements throughout the $SiO_2$/PSG passivated Al-1%Si thin film interconnections. Potassium peaks were observed throughout the $SiO_2$/PSG passivation layers, and especially the interface gettering at the $SiO_2$/PSG and at the Al-1%Si/$SiO_2$ interfaces was observed. Potassium gettering in Al-1%Si/$SiO_2$/PSG multilevel thin films is considered to be caused by a segregation type of gettering.

Catalytic Behavior of Ni/CexZr1-xO2-Al2O3 Catalysts for Methane Steam Reforming: The CexZr1-xO2 Addition Effect on Water Activation (메탄 습식 개질 반응용 Ni/CexZr1-xO2-Al2O3 촉매의 반응 특성: CexZr1-xO2 첨가에 의한 물 활성화 효과)

  • Haewon Jung;Huy Nguyen-Phu;Mingyan Wang;Sang Yoon Kim;Eun Woo Shin
    • Korean Chemical Engineering Research
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    • v.61 no.3
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    • pp.479-486
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    • 2023
  • In this study, we investigated the effect of the CexZr1-xO2 (CZ) addition onto Ni/Al2O3 catalysts on the catalytic performance in methane steam reforming. In the reaction results, the CZ-added Ni/Al2O3 catalyst showed higher CH4 conversion and H2 yield under the same reaction conditions than Ni/Al2O3. From the characterization data, the two catalysts had similar support porosity and Ni dispersion, confirming that the two properties could not determine the catalytic performance. However, the oxygen vacancy over the CZ-added Ni/Al2O3 catalyst induced an efficient steam activation at low reaction temperatures, resulting in an increase in the catalytic activity and H2 yield.

Properties of the $\beta-SiC-TiB_2$ Composites with $Al_2O_3+Y_2O_3$ additives ($Al_2O_3+Y_2O_3를 첨가한 {\beta}-SiC-TiB_2$ 복합체의 특성)

  • Yim, Seung-Hyuk;Shin, Yong-Deok;Ju, Jin-Young;Yoon, Se-Won;Song, Joon-Tae
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.7
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    • pp.394-399
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    • 2000
  • The mechanical and electrical properties of pressed and annealed $\beta-SiC-TiB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of $Al_2O_3+Y_2O_3$. Phase analysis of composites by XRD revealed $\alpha$-SiC(6H), TiB2, and (Al5Y3O12). Reaction between Al2O3 and $Y_2O_3$ formed YAG but the relative density decreased with increasing $Al_2O_3+Y_2O_3$ contents. The Flexural strength showed the value of 458.9 MPa for composites added with 4 wt% $Al_2O_3+Y_2O_3$ additives at room temperatures. Owing to crack deflection and crack bridging, the fracture toughness showed 6.2, 6.0 and 6.6 MPa.m1/2 for composites added with 4, 8 and 12 wt% Al2O3+Y2O3 additives respectively at room temperature. The resistance temperature coefficient showed the value of $3.6\times10^{-3},\; 2.9\times10^{-3}\; and\; 3.0\times10^{-3} /^{\circ}C$$^{\circ}C$ for composite added with 4, 8 and 12 wt% $Al_2O_3+Y_2O_3$additives respectively at room temperature. The electrical resistivity of the composites was all positive temperature coefficient resistance(PTCR) in the temperature range of $25^{\circ}C\; to\; 700^{\circ}$.

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The Properties of $\beta-SiC-ZrB_2$ Electroconductive Ceramic Composites with $Al_2O_3+Y_2O_3$Contents ($Al_2O_3+Y_2O_3 첨가량에 따른 {\beta}-SiC-ZrB_2$계 전도성 복합체의 특성)

  • Shin, Yong-Deok;Ju, Jin-Young;Hwang, Chul
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.9
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    • pp.516-522
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    • 2000
  • The mechanical and electrical properties of the hot-pressed and annealed $\beta-SiC-ZrB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of$Al_2O_3+Y_2O_3$ Phase analysis of composites by XRD revealed $\alpha-SiC(6H) ZrB_2\; and YAG(Al_5Y_3O_{12})$ The relative density of composites were increased with increased Al2O3+Y2O3 contents. The Flexural strength showed the highest value of 390.6MPa for composites added with 20wt% Al2O3+Y2O3 additives at room temperature. Owing to crack deflection crack bridging phase transition and YAG of fracture toughness mechanism the fracture toughness showed the highest value of 6.3MPa.m1/2 for composites added with 24wt% Al2O3+Y2O3 additives at room temperature. The resistance temperature coefficient showed the value of$ 2.46\times10^{-3}\;, 2.47\times10^{-3},\; 2.52\times10^{-3}/^{\circ}C$ for composite added with 16, 20, 24wt% Al2O3+Y2O3 additives respectively. The electrical resistivity of the composites was all positive temperature coefficient resistance(PTCR) in the temperature range of $256{\circ}C\; to\; 900^{\circ}C$.

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Hydration in the System of Fluorogypsum-Blast Furnace Slag (불산석고-고로슬래그계의 수화반응)

  • 송종택;고상열;노재성
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.933-938
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    • 1998
  • The hydration for the system of fluorogypsum and 20wt% blast furnace slag was investigated at liquid/soild ratio of 0.45 for 1, 3, and 7 days by using 3 kinds of accelerators such as K2SO4 Al2(SO4)3 $.$16-18H2O and AlK(SO4)2$.$12H2O After curing the hardened specimen was characterized by the compressive strength the content of combined water XRD, DTA and SEM It was found that the activating effect was increased in the order of K2SO4

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Properties of the $\beta$-SiC-$ZrB_2$ Composites with $Al_{2}O_{3}+Y_{2}O_{3}$ additives ($Al_{2}O_{3}+Y_{2}O_{3}$를 첨가한 $\beta$-SiC-$ZrB_2$ 복합체의 특성)

  • Shin, Yong-Deok;Ju, Jin-Young
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.853-855
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    • 1998
  • The electrical resistivity and mechanical properties of the hot-pressed and annealed ${\beta}$-SiC+39vol.%$ZrB_2$ electroconductive ceramic composites were investigated as a function of the liquid forming additives of $Al_{2}O_{3}+Y_{2}O_{3}$(6:4wt%). In this microstructures. no reactions were observed between $\beta$-SiC and $ZrB_2$, and the relative density is over 97.6% of the theoretical density. Phase analysis of composites by XRD revealed mostly of a $\alpha$-SiC(6H, 4H), $ZrB_2$ and weakly $\beta$-SiC(15R) phase. The fracture toughness decreased with increased $Al_{2}O_{3}+Y_{2}O_{3}$ contents and showed the highest for composite added with 4wt% $Al_{2}O_{3}+Y_{2}O_{3}$ additives. The electrical resistivity increased with increased $Al_{2}O_{3}+Y_{2}O_{3}$ contents because of the increasing tendency of pore formation according to amount of liquid forming additives $Al_{2}O_{3}+Y_{2}O_{3}$. The electrical resistivity of composites is all positive temperature coefficient resistance(PTCR) against temperature up to $700^{\circ}C$.

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Synthesis of $TiB_2-Al_2O_3$ Composite by Self-Propagating High Temperature Synthesis (SHS) and Its Pressureless Sintering (SHS법에 의한 $TiB_2-Al_2O_3$계 복합물의 합성 및 상압소결에 관한 연구)

  • 최상욱;조동수;김세용;남건태
    • Journal of the Korean Ceramic Society
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    • v.31 no.5
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    • pp.552-560
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    • 1994
  • A composite of TiB2-Al2O3 system was successfully prepared from a mixture of TiO2, B2O3, and Al by self-propagating high temperature synthesis (SHS) with a novel characteristic, utilizing the internal oxidation heat of aluminium metal of the mixture, instead of by a conventional technique, externally heating a mixture of Ti, B and Al2O3. From a mixture with B/Ti molar ratio of =2.0, pure two phases of TiB2 and $\alpha$-Al2O3 with good crystallinity and small, uniform sizes were formed. However, when the B/Ti molar ratio of the mixture goes to a value less than 2.0, in addition to the above main minerals, a small smounts of metastable phases such as TiB and Ti3B4 were formed. It was found that about 60%, the optimum green density of compacts gave their highest reaction rate and temperature during SHS process. TiB2-Al2O3 system composite with B/Ti molar ratio of =2.0 could be pressurelessly sintered even at 190$0^{\circ}C$ under Ar gas flows without any addition of sintering aids, showing their good properties such as 91.2% in relative density, 2750 kgf/$\textrm{mm}^2$ in Vickers hardness and 2620 kgf/$\textrm{cm}^2$ in flexural strength.

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