• 제목/요약/키워드: Al substitution

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액체로켓엔진 연소기에 적용된 니켈-크롬 코팅의 열차폐 효율과 내구성 (Thermal Barrier Efficiency and Endurance of Ni-Cr Coating in Liquid Rocket Engine Combustor)

  • 이광진;임병직;김종규;한영민;최환석
    • 항공우주기술
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    • 제8권1호
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    • pp.138-143
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    • 2009
  • 액체로켓엔진 연소기에 적용된 대기 플라즈마 코팅 및 전해/무전해 도금 코팅의 열차폐 효율과 내구성 평가를 수행하였다. 연소시험 결과 대기 플라즈마 방식의 $ZrO_2$, NiCrAlY 코팅은 로켓엔진 연소기의 초음속 유동영역에서 코팅이 표면에서 박리되는 현상이 간헐적으로 발생하였으며 따라서 이러한 문제를 극복할 수 있는 대체 코팅 방식이 요구되었다. 시험 결과 열차폐 효율 및 내구성 관점에서 대기 플라즈마 방식의 $ZrO_2$, NiCrAlY 코팅의 대안으로 무전해/전해 방식을 사용한 니켈-크롬 코팅을 사용할 수 있음을 알 수 있었다.

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A Note on Parametric Bootstrap Model Selection

  • Lee, Kee-Won;Songyong Sim
    • Journal of the Korean Statistical Society
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    • 제27권4호
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    • pp.397-405
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    • 1998
  • We develop parametric bootstrap model selection criteria in an example to fit a random sample to either a general normal distribution or a normal distribution with prespecified mean. We apply the bootstrap methods in two ways; one considers the direct substitution of estimated parameter for the unknown parameter, and the other focuses on the bias correction. These bootstrap model selection criteria are compared with AIC. We illustrate that all the selection rules reduce to the one sample t-test, where the cutoff points converge to some certain points as the sample size increases.

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Synthesis of C-(2-Furyl)-N-(4-nitrophenyl)methanohydrazonyl Bromide. Reactions with Nucleophiles and Active Methylene Compounds

  • Hassaneen, Hamdi M.;Shawali, Ahmad S.;Elwan, Nehal M.;Ibrahim, Al Hossien A.
    • Archives of Pharmacal Research
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    • 제14권3호
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    • pp.266-270
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    • 1991
  • Synthesis of C-(2-furyl)-N-(4-nitrophenyl)methanohydrazonyl bromide 2 is described. Treatment of 2 with uncleophiles affords the corresponding substitution products 3-7. Also, compound 2 reacts with selenocyanate anion and thiocyanate anion and give the corresponding selenadiazoline and thiadiazoline 8 and 9, respectively. Moreover, reaction of 2 with enolates of various active methylene compounds afforded the pyrazole derivatives 17-20.

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염분환경하 콘크리트 경화체의 내구성에 미치는 혼합재의 영향 (I) 시멘트 경화체중에서의 Cl-이온의 확산 (Effect of Blending Materials on the Durability of Concrete (I) Diffusion of Cl-ions through Hardened Cement Paste)

  • 김남중;최상흘;정재동;한기성
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1991년도 가을 학술발표회 논문집
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    • pp.11-14
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    • 1991
  • Apparent diffusion coefficients of Cl-ions through hardened cement paste(HCP), which were partly substituted blending materials, were determined. Also, pore solution was extracted from HCP which were immersed in NaCl solution, and Cl- concentration of the solution were analyzed. Partly substitution of pozzolanic materials considerably reduced the diffusion rate for Cl-ions and Cl- concentration of pore solution. Binding capacity of Cl- is related to the content of Al2O3 and pozzolanic reactivity.

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Inherently Chiral Calix[4]arene

  • 노광현;김종은
    • Bulletin of the Korean Chemical Society
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    • 제16권11호
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    • pp.1122-1125
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    • 1995
  • Three inherently chiral calix[4]arenes 3-5 were synthesized as racemate starting from the ethylation at 1.3-distal hydroxy groups of calix[4]arene 2 which has two phenyl groups at upper rim in AABB fashion, and then two remaining hydroxy groups were acetylated by treatment with acetyl chloride in the presence of NaH to produce calix[4]arene 4. Treatment of 4 with AlCl3 under Fries rearrangement conditions, only one acetyl group was rearranged to the para-position to afford calix[4]arene 5 with AABC substitution pattern at the upper rim of calix. The structure of chiral calix[4]arenes were confirmed based on NMR and massspectra.

원자층 증착법을 이용한 ZnO:Al 박막의 특성 (Characteristics of Atomic Layer-Controlled ZnO:Al Films by Atomic Layer Deposition)

  • 오병윤;백성호;김재현;이희준;강영구;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.40-40
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    • 2010
  • Structural, electrical, and optical properties of atomic layer-controlled AI-doped ZnO (ZnO:Al) films grown on glass by atomic layer deposition (ALD) were characterized with various $Al_2O_3$ film contents for use as transparent electrodes. Unlike films made using sputtering methods, the diffraction peak position of the films grown by ALD based on alternate self-limiting surface chemical reactions moved progressively to a wider angle (red shift) with increasing $Al_2O_3$ film content, which seems to be evidence of Zn substitution in the film by layer-by-layer growth. By adjusting the $Al_2O_3$ film content, the electrical resistivity of ZnO:Al film with the $Al_2O_3$ film content of 2.96% reached the lowest electrical resistivity of $9.80{\times}10^{-4}\Omega{\cdot}cm$, in which the carrier mobility, carrier concentration, and optical transmittance were $11.20\;cm^2V^{-1}s^{-1}$, $5.69{\times}10^{20}\;cm^{-3}$, and 94.23%, respectively. Moreover, the estimated figure of merit value for the transparent conductive oxide applications from our best sample was $7.7\;m{\Omega}^{-1}$.

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$Tb^{3+}$$Eu^{3+}$로 활성화된 $Al_3GdB_4O_{12}$ 형광체의 발광특성 (Photoluminance Properties of $Al_3GdB_4O_{12}$ Phosphors Activated by $Tb^{3+}$and $Eu^{3+}$)

  • 김기운;김성우;이임렬
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.594-597
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    • 1999
  • The new green and red phosphors for PDP application activated by T $b^{3+}$ and E $u^{3+}$ were synthesized, and their photoluminance properties were investigated. It was found that the brightness of $Al_3$Gd $B_4$ $O_{12}$ :T $b^{3+}$ green phosphor under 147nm VUV irradiation was higher than that of commercial Z $n_2$ $SiO_4$:M $n^{2+}$ phosphor. But the emitting intensity of A1$_3$Gd $B_4$ $O^{12}$ :E $u^{3+}$ red phosphor was inferior to the commercial (Y,Gd)B $O_3$:E $u^{3+}$. $Al_3$Gd $B_4$ $O_{12}$ Phosphor had a strong excitation band at 160nm associated with the host absorption, and also the photoluminance excitation intensity of $Al_3$Gd $B_4$ $O_{12}$ :T $b^{3+}$ was higher than that of Z $n_2$ $SiO_4$:M $n^{2+}$, but the intensity of $Al_3$Gd $B_4$ $O_{12}$ :E $u^{3+}$ phosphor was smaller than (Y,Gd)B $O_3$:E $u^{3+}$ phosphor In the VUV range. C $e^{3+}$ co-doping in A1$_3$Gd $B_4$ $O^{12}$ :E $u^{3+}$ and substitution of $Al^{3+}$ by G $a^{3+}$ A1$_3$Gd $B_4$ $O^{12}$ :E $u^{3+}$ phosphor were tried, but they did not improved the optical property .d the optical property .ty .

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Mn3O4를 첨가한 Al2O3 세라믹스의 소결 및 광학 특성 (Sintering and the Optical Properties of Mn3O4-added Al2O3)

  • 김진호;백승우
    • 한국전기전자재료학회논문지
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    • 제29권9호
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    • pp.539-545
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    • 2016
  • Alumina added with Mn3O4 up to 7.5 cat% of Mn was prepared by conventional ceramic processing, and the sintering behavior and the optical properties of which were studied as functions of Mn content. Densification and grain growth of alumina were enhanced by Mn addition up to 0.75 cat% but was leveled off at higher concentrations. XRD revealed that $Al_2MnO_4$(galaxite) was formed as a second phase in the specimens with more than 0.75 cat% of Mn. Thus it is believed that either the solid solution effect of Mn or the Zener effect of $Al_2MnO_4$ becomes predominant in the sintering of Mn-added $Al_2O_3$ according to the additive concentration. UV-VIS reflectivity(SCI) spectra of Mn-added $Al_2O_3$ consisted of smooth bottoms in 300~550 nm wavelength range and plateaus at wavelengths longer than 650 nm. The reflectivity spectrum continuously moved downward, and the specimen color became darker and thicker with increasing Mn content. The CIELAB color change with respect to standard white was also dependent on the amount of Mn added: ${\Delta}L^*$(D65) negatively increased and ${\Delta}E_{ab}^*$(D65) positively increased with increasing Mn content, probably due to Mn substitution to Al and/or the mixing effect of black $Al_2MnO_4$ as a second phase.

Pb(Mn1/3Nb2/3)O3-PbZrO3-PbTiO3 세라믹스의 압전특성에 미치는 Al2O3의 영향 (Effects of Al2O3 on the Piezoelectric Properties of Pb(Mn1/3Nb2/3)O3-PbZrO3-PbTiO3 Ceramics)

  • 김미정;김재창;김영민;어순철;김일호
    • 한국재료학회지
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    • 제15권7호
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    • pp.453-457
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    • 2005
  • Piezoelectric properties of $Pb(Mn_{1/3}Nb_{2/3})O_3-PbZrO_3-PbTiO_3$ ceramics were investigated with $Al_2O_3$ content $(0.0-1.0 wt\%)$. The constituent phases, microstructure, electromechanical coupling factor, dielectric constant, piezoelectric charge and voltage constants were analyzed. Diffraction peaks for (002) and (200) planes were identified by X-ray diffractometer for all the specimens doped with $Al_2O_3$, indicating the MPB (morphotropic phase boundary) composition of tetragonal structures. The highest sintered density of $7.8 g/cm^3$ was obtained for $0.2wt\%\;Al_2O_3-doped$ specimen. Grain size increased by doping $Al_2O_3$ up to $0.3 wt\%$, and it decreased by more doping. Electromechanical coupling factor, dielectric constant, piezoelectric charge and voltage constants increased by doping $Al_2O_3$ up to $0.2wt\%$, and it decreased by more doping. This might result from the formation of oxygen vacancies due to defects in $O^{2-}$ ion sites and the substitution of $Al^{3+}$ ions.

A Novel RGB Image Steganography Using Simulated Annealing and LCG via LSB

  • Bawaneh, Mohammed J.;Al-Shalabi, Emad Fawzi;Al-Hazaimeh, Obaida M.
    • International Journal of Computer Science & Network Security
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    • 제21권1호
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    • pp.143-151
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    • 2021
  • The enormous prevalence of transferring official confidential digital documents via the Internet shows the urgent need to deliver confidential messages to the recipient without letting any unauthorized person to know contents of the secret messages or detect there existence . Several Steganography techniques such as the least significant Bit (LSB), Secure Cover Selection (SCS), Discrete Cosine Transform (DCT) and Palette Based (PB) were applied to prevent any intruder from analyzing and getting the secret transferred message. The utilized steganography methods should defiance the challenges of Steganalysis techniques in term of analysis and detection. This paper presents a novel and robust framework for color image steganography that combines Linear Congruential Generator (LCG), simulated annealing (SA), Cesar cryptography and LSB substitution method in one system in order to reduce the objection of Steganalysis and deliver data securely to their destination. SA with the support of LCG finds out the optimal minimum sniffing path inside a cover color image (RGB) then the confidential message will be encrypt and embedded within the RGB image path as a host medium by using Cesar and LSB procedures. Embedding and extraction processes of secret message require a common knowledge between sender and receiver; that knowledge are represented by SA initialization parameters, LCG seed, Cesar key agreement and secret message length. Steganalysis intruder will not understand or detect the secret message inside the host image without the correct knowledge about the manipulation process. The constructed system satisfies the main requirements of image steganography in term of robustness against confidential message extraction, high quality visual appearance, little mean square error (MSE) and high peak signal noise ratio (PSNR).