• Title/Summary/Keyword: Agent technology

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Separation and Solidification of Rare Earth Nuclides from LiCl-KCl Based Eutectic Waste Salts using a series of Phosphorylation/Distillation/Solidification Processes (인산화/증류/고화의 일련공정을 이용한 LiCl-KCl 공융염폐기물 내 희토류 핵종 분리 및 고화)

  • Eun, Hee-Chul;Choi, Jung-Hoon;Cho, In-Hak;Park, Hwan-Seo;Park, Geun-Il
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.11 no.4
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    • pp.325-332
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    • 2013
  • Pyroporcessing of spent nuclear fuel generates a considerable amount of LiCl-KCl eutectic waste salt containing radioactive rare earth (RE) chlorides. In this study, a series of processes, which consist of a phosphorylation/distillation process and a solidification process, were performed to minimize volume of the LiCl-KCl eutectic waste salt and solidify a residual waste into a stable form at a relatively low temperature. Over 99wt% of RE chlorides in LiCl-KCl eutectic salt was converted and separated into $REPO_4$ in the phosphorylation/distillation process using a mixture of $Li_3PO_4-K_3PO_4$. The separated $REPO_4$ was solidified into a homogeneous and fine-grained form at $1,050^{\circ}C$ using LIP(Lead Iron Phosphate) as a solidification agent. The final waste volume was reduced below about 10% through the series of the processes.

Extraction Behavior of Am(III) and Eu(III) From Nitric Acid Using Room Temperature Ionic Liquid (질산용액으로부터 이온성 액체를 이용한 Am(III)과 Eu(III)의 추출 거동)

  • Kim, Ik-Soo;Chung, Dong-Yong;Lee, Keun-Young;Lee, Eil-Hee
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.347-357
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    • 2018
  • The applicability of room temperature ionic liquids (RTILs), 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([$C_nmim$] [$Tf_2N$]), was investigated for the extraction of Am(III) and Eu(III) from nitric acid using n-octyl(phenyl)-N,N-diisobutyl carbamoylmethyl phosphine oxide (CMPO) and tri-n-butylphosphate (TBP) as extractants. The distribution ratios of Am(III) and Eu(III) in CMPO-TBP/[$C_nmim$][$Tf_2N$] were measured as a function of various parameters such as the concentrations of nitric acid, CMPO, and TBP. The results were compared with those obtained in CMPO-TBP/n-dodecane (n-DD). With comparable concentrations of the extractants, the distribution ratios obtained with RTILs were much higher than those obtained with n-DD. It was observed that the extraction efficiency was less for Eu(III) than for Am(III). The extraction of Am(III) and Eu(III) decreased with increases in the feed acidity for all three RTILs. The results suggest that the extraction of Am(III) and Eu(III) by CMPO in RTILs from nitric acid proceeds through the cation-exchange mechanism. The distribution ratios of Am(III) and Eu(III) increased with increases in the concentration of CMPO for all three RTILs. A linear regression analysis of the extraction data resulted in a straight line with a slope of about 3, suggesting the involvement of 3 molecules of CMPO during the extraction process.

The Design of IoT-based Drive Through Service System for Customers in Distribution Stores (대형 유통매장의 고객을 위한 IoT기반 드라이브 스루 서비스 시스템 설계)

  • Min, So-Yeon;Lee, Jong-Hee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.11
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    • pp.151-157
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    • 2017
  • Recently, the retail industry has created efficient store operations, and has differentiated customer service through the future store. The intelligence of these stores is being applied by using technologies such as the Internet of Things (IoT), and the business process is being improved through this. The process also focuses on efficient store operations and service developments to provide customers with shopping convenience. The change in trends in the industry means that domestic distribution has already reached maturity. Even in countries where retail industries are mature, such as the U.S. and Europe, recent trends are moving toward maximizing operational efficiency and customer service. The reason is that many retailers have already reached saturation and survived the competition. This paper is a study of a drive-through service for automation and efficiency in receiving service after ordering by a customer of the distribution store. When ordering a product being purchased by a customer, the product picking process is done in a timely fashion through a picking scheduling agent. When the customer enters the store parking lot, a service supports the entry of information and finding a parking place so the customer can quickly pick up the goods. The proposed service can be applied to a retail store drive-through system, the distribution store's delivery system, the digital picking system, and indoor/outdoor large parking management systems, and it is possible to provide one-dimensional customer service through the application of IoT technology.

Low and Intermediate Level Radioactive Waste Certification Program Plan (중.저준위 방사성폐기물 인증 프로그램 계획)

  • Ahn Sum-Jin;Kim Tae-Kook;Lee Young-Hee;Kang Ill-Sik;Shon Jong-Sik;Hong Kwon-Pyo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.2
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    • pp.187-195
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    • 2006
  • The regulation for the low and intermediate level radioactive waste to be transferred to the disposal facility, recently revised, require that radioactive waste generators should set up waste certification program to verify the radioactive waste conform to the waste acceptance criteria(WAC) before disposal. The radioactive waste disposal facility, scheduled to be constructed in Korea, will institute WAC for the wastes to be transferred to the facility. This WAC is expected to compose of the requirements for the radiological characterization, physical and chemical characterization, physical/chemical restriction, prohibited item, packaging, identification, labeling, and documentation. For the compliance with this regulation, The radioactive waste generators should verify that the waste meet WAC through performance of the waste certification program and are responsible for handing in all the certification documents to the disposal facility. This waste certification program plan was set up as a preliminary program for the certification of radioactive waste generated in Korea Atomic Energy Research Institute (KAERI) and should be further revised until preparation of WAC by disposal agent.

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Anti-carcinogenic effects of non-polar components containing licochalcone A in roasted licorice root

  • Park, So Young;Kim, Eun Ji;Choi, Hyun Ju;Seon, Mi Ra;Lim, Soon Sung;Kang, Young-Hee;Choi, Myung-Sook;Lee, Ki Won;Yoon Park, Jung Han
    • Nutrition Research and Practice
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    • v.8 no.3
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    • pp.257-266
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    • 2014
  • BACKGROUND/OBJECTIVE: Licorice has been shown to possess cancer chemopreventive effects. However, glycyrrhizin, a major component in licorice, was found to interfere with steroid metabolism and cause edema and hypertension. The roasting process of licorice modifies the chemical composition and converts glycyrrhizin to glycyrrhetinic acid. The purpose of this study was to examine the anti-carcinogenic effects of the ethanol extract of roasted licorice (EERL) and to identify the active compound in EERL. MATERIALS/METHODS: Ethanol and aqueous extracts of roasted and un-roasted licorice were prepared. The active fraction was separated from the methylene chloride (MC)-soluble fraction of EERL and the structure of the purified compound was determined by nuclear magnetic resonance spectroscopy. The anti-carcinogenic effects of licorice extracts and licochalcone A was evaluated using a MTT assay, Western blot, flow cytometry, and two-stage skin carcinogenesis model. RESULTS: EERL was determined to be more potent and efficacious than the ethanol extract of un-roasted licorice in inhibiting the growth of DU145 and MLL prostate cancer cells, as well as HT-29 colon cancer cells. The aqueous extracts of un-roasted and roasted licorice showed minimal effects on cell growth. EERL potently inhibited growth of MCF-7 and MDA-MB-231 breast, B16-F10 melanoma, and A375 and A2058 skin cancer cells, whereas EERL slightly stimulated the growth of normal IEC-6 intestinal epithelial cells and CCD118SK fibroblasts. The MC-soluble fraction was more efficacious than EERL in inhibiting DU145 cell growth. Licochalcone A was isolated from the MC fraction and identified as the active compound of EERL. Both EERL and licochalcone A induced apoptosis of DU145 cells. EERL potently inhibited chemically-induced skin papilloma formation in mice. CONCLUSIONS: Non-polar compounds in EERL exert potent anti-carcinogenic effects, and that roasted rather than un-roasted licorice should be favored as a cancer preventive agent, whether being used as an additive to food or medicine preparations.

A Study on the Fluorescence Characteristics of Dye-doped Silica Nanoparticles for Integrated Bio Imaging (융합 바이오 이미징을 위한 염료 도핑 된 실리카 나노입자의 형광 특성에 관한 연구)

  • Kim, Ki-Chul
    • Journal of Convergence for Information Technology
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    • v.8 no.5
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    • pp.45-50
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    • 2018
  • The functional nanomaterials of fluorescent dye-doped silica nanoparticles(NPs) are applied to bio applications such as bio-labeling of DNA micro-array, and bio-imaging. Organic dye-doped fluorescent silica NPs exhibit excellent bio-compatibility, non-toxic, and highly hydrophilic properties. In this study, organic fluorescent dyes were dissolved in ethanol, and deionized(DI) water. Organic fluorescent dyes were physically adsorbed to silica NPs and chemically doped to silica NPs. The fluorescence characteristics(FLC) was investigated by UV lamp irradiation of 365 nm wavelength. As results, the FLC of dye-doped silica NPs exhibits better than dye-adsorbed silica NPs and the FLC was improved with the increase of concentration of doped-dyes. The fluorescent organic dyes were well dissolved in ethanol than DI water. The photostability of dye-doped silica NPs was superior than pure fluorescent organic dye. The FLC of optimized dye-doped silica NPs would be applied to agent of non-invasive fluorescence bio-imaging in live cell and in vivo.

Synthesis of $Fe/Al_2O_3$ and $Fe/TiO_2$ nanocomposite powder by mechanical alloying (기계적합금화에 의한 $Fe/Al_2O_3$$Fe/TiO_2$계 나노복합분말의 제조)

  • Lee, Seong-Hee;Lee, Chung-Hyo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.4
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    • pp.202-207
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    • 2009
  • Nanocomposite formation of metal-metal oxide systems by mechanical alloying (MA) has been investigated at room temperature. The systems we chose are the $Fe_3O_4$-M (M = AI, Ti), where pure metals are used as reducing agent. It is found that $Fe/Al_2O_3$ and $Fe/TiO_2$ nanocomposite powders in which $Al_2O_3$ and $TiO_2$ are dispersed in ${\alpha}$-Fe matrix with nano-sized grains are obtained by MA of $Fe_3O_4$ with Al and Ti for 25 and 75 hours, respectively. It is suggested that the shorter MA time for the nanocomposite formation in $Fe/Al_2O_3$ is due to a large negative heat associated with the chemical reduction of magnetite by aluminum. X-ray diffraction results show that the average grain size of ${\alpha}$-Fe in $Fe/TiO_2$ nanocomposite powders is in the range of 30 nm. The change in magnetic properties also reflects the details of the solid-state reduction of magnetite by pure metals during MA.

Communal Ontology of Landmarks for Urban Regional Navigation (도시 지역 이동을 위한 랜드마크의 공유 온톨로지 연구)

  • Hong, Il-Young
    • Journal of the Korean Geographical Society
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    • v.41 no.5 s.116
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    • pp.582-599
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    • 2006
  • Due to the growing popularity of mobile information technology, more people, especially in the general public, have access to computerized geospatial information systems for wayfinding tasks or urban navigation. One of the problems with the current services is that, whether the users are exploring or navigating, whether they are travelers who are totally new to a region or long-term residents who have a fair amount of regional knowledge, the same method is applied and the direction are given in the same way. However, spatial knowledge for a given urban region expands in proportion to residency. Urban navigation is highly dependent on cognitive mental images, which is developed through spatial experience and social communication. Thus, the wayfinding service for a regional community can be highly supported, using well-known regional places. This research is to develop the framework for urban navigation within a regional community. The concept of communal ontology is proposed to aid in urban regional navigation. The experimental work was implemented with case study to collect regional landmarks, develop the ontological model and represent it with formal structure. The final product of this study will provide the geographical information of a region to the other agent and be the fundamental information structure for cognitive urban regional navigation.

Compressive Strength Characteristics of Light-weight Air Foamed Soil Using Dredged Silty Soils (준설 실트질 점토를 이용한 경량기포혼합토의 압축강도 특성)

  • Kim, Donggyu;Yoon, Yeowon;Yoon, Gillim
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.5
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    • pp.27-33
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    • 2017
  • In this research, laboratory tests were carried out to investigate the engineering properties of Light-Weight Air Foamed Soil (LWAS) based on silty clays with the animal foaming agent and cement. LWAS has been used as an embankment material over soft ground for road and side extension of the existing road. In field, unit weight and flow value is measured right after producing in mixing plant in order to control the quality of LWAS, and laboratory tests are carried out to confirm the quality through compressive strength of LWAS as well. In this research, direct estimation of the specification requirement of strength using flow values in field is the main purpose of the study together with other characteristics. From the test results, it can be seen that flow values increase with the initial water content and unit weight increases with the depth due to material segregation. Compared to the upper specimen, lower end of 60 cm specimen shows about 2 times higher compressive strength. Relationship between flow values and normalized factor presented by Yoon & Kim (2004) was presented. With that relationship, compressive strength can be predicted from flow values in field. From the relationship, the normalized factor was calculated. Thereafter calculated compressive strengths according to the flow values were compared to measured strengths in the laboratory. The higher the initial water content of the dredged soil has, the better relationship between predicted and measured shows. Therefore it is necessary to predict the compressive strength in advance through the relationship between the flow value and the normalized factor to reflect it in the design stage.

The Thermal Conduction Property of Structural Concrete using Insulation Performance Improvement Materials (단열성능향상 재료를 사용한 구조용 콘크리트의 열전도 특성)

  • Park, Young-Shin;Kang, Min-Gi;Kim, Jung-Ho;Ji, Suk-Won;Jeon, Hyun-Kyu
    • Journal of the Korea Institute of Building Construction
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    • v.16 no.1
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    • pp.9-15
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    • 2016
  • The part of a building with the biggest energy loss is the exterior and many studies are actively conducted to reduce the energy loss on that part. However, most studies consider the window frames and insulation materials, but many studies do not discuss the concrete that takes more than 70% of the exterior. In order to minimize the energy loss of buildings, it is necessary to enhance the concrete's insulation performance and studies need to be conducted on this. Therefore, this study used a micro foam cell admixture, calcined diatomite powder, and lightweight aggregates as a part of a study to develop a type of concrete with improved insulation performance that has twice higher thermal conductivity compared to concrete. It particularly secured the porosity inside concrete to lower thermal conductivity. As a result of the experiment, the slump and air capacity showed fair results, but all mixtures containing micro foaming agent showed 14.3~35.1% lower mass per unit of volume compared to regular concrete. Compressive strength decreased slightly due to the materials used to improve the insulating performance, but it all satisfied this study's target strength(24MPa). Thermal conductivity was up to twice higher than that of regular concrete.